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    • 6. 发明申请
    • Method for preparing rubber-reinforced thermoplastic resin, and rubber-reinforced thermoplastic resin composition using the same
    • 制备橡胶增强热塑性树脂的方法和使用其的橡胶增强热塑性树脂组合物
    • US20070123648A1
    • 2007-05-31
    • US10563695
    • 2005-03-25
    • Jun-tae LeeKeun-hoon YooChan-hong LeeHyun-do KimChang-mook Kim
    • Jun-tae LeeKeun-hoon YooChan-hong LeeHyun-do KimChang-mook Kim
    • C08L51/00
    • C08F279/02C08F279/04C08F285/00C08F291/02C08L51/04C08L55/02C08F212/10C08L2666/02C08L2666/04
    • The present invention relates to a method for preparing a rubber-reinforced thermoplastic resin, a rubber-reinforced thermoplastic resin prepared by the same method, and a rubber-reinforced thermoplastic resin composition using the same, wherein the rubber-reinforced thermoplastic resin has excellent heat-sealability and thermal stability maintaining good mechanical properties. More specifically, the present invention relates to a method for preparing a rubber-reinforced thermoplastic resin, a rubber-reinforced thermoplastic resin prepared by the same method, and a rubber-reinforced thermoplastic resin composition using the same characterized by, on the basis of 100 weight parts of total monomer used to prepare graft copolymer, using the mixture comprising 10 to 30 weight parts of a rubber latex having average particle diameter of 0.08 to 0.16 μm and gel content of 65 to 95 weight % and 15 to 45 weight parts of a rubber latex having average particle diameter of 0.26 to 0.34 μm and gel content of 55 to 85 weight %, keeping the weight ratio of vinyl cyanide compound including acrylonitrile to aromatic vinyl compound including styrene from 16/84 to 24/76 as a monomer composition grafted on rubber latex, and adjusting the graft ratio of graft copolymer, i.e. rubber-reinforced thermoplastic resin, from 25 to 65.
    • 本发明涉及一种制备橡胶增强热塑性树脂的方法,通过相同方法制备的橡胶增强热塑性树脂和使用其的橡胶增强热塑性树脂组合物,其中橡胶增强热塑性树脂具有优异的热 - 密封性和热稳定性保持良好的机械性能。 更具体地,本发明涉及一种制备橡胶增强热塑性树脂的方法,通过相同方法制备的橡胶增强热塑性树脂和使用其的橡胶增强热塑性树脂组合物,其特征在于,基于100 用于制备接枝共聚物的总单体的重量份,使用包含10〜30重量份平均粒径为0.08〜0.16μm,凝胶含量为65〜95重量%,15〜45重量份的橡胶胶乳的混合物 橡胶胶乳的平均粒径为0.26〜0.34μm,凝胶含量为55〜85wt%,将包含丙烯腈的乙烯基氰化合物与包括苯乙烯的芳族乙烯基化合物的重量比从16/84至24/76保持为接枝的单体组合物 并将接枝共聚物(即橡胶增强热塑性树脂)的接枝率调节为25至65。