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    • 1. 发明授权
    • Method for remediating emissions
    • 补救排放的方法
    • US08225600B2
    • 2012-07-24
    • US12788597
    • 2010-05-27
    • Joseph R. Theis
    • Joseph R. Theis
    • F01N3/20
    • F01N3/0807F01N3/0814F01N3/206Y02T10/24
    • A method for remediating a NOx-containing lean diesel emission includes providing a LNT/SCR catalyst system including a SCR catalyst and a first and second LNT. The SCR catalyst is disposed downstream of the second LNT which is disposed downstream of the first LNT. The lean NOx-containing diesel emission is introduced to the first LNT with the NOx being absorbed on to the first LNT forming a substantially NOx-free lean diesel emission. An exotherm generating agent is introduced to the substantially NOx-free diesel emission between the first LNT and the second LNT to form a reactive lean diesel emission. The reactive lean diesel emission is introduced to the second LNT generating a quantity of heat effective for desorbing absorbed NOx. A reducing agent is introduced into the desorbed NOx between the second LNT and SCR catalyst. The desorbed NOx diesel emission is remediated in the SCR catalyst.
    • 一种用于补救含有NOx的贫柴油发动机的方法包括提供包括SCR催化剂和第一和第二LNT的LNT / SCR催化剂体系。 所述SCR催化剂设置在所述第二LNT的位于所述第一LNT的下游的下游。 将含稀少NOx的柴油发射引入第一LNT,其中NOx被吸收到第一LNT上,形成基本上无NOx的贫柴油发动机。 将放热产生剂引入第一LNT和第二LNT之间的基本上无NOx的柴油发射以形成反应性贫柴油发动机。 将反应性贫柴柴油发射引入第二LNT,产生有效解吸所吸收的NOx的热量。 将还原剂引入到第二LNT和SCR催化剂之间的脱附的NOx中。 在SCR催化剂中补充了脱硫的NOx柴油发射。
    • 2. 发明授权
    • Method for removing hydrogen sulfide from an emissions stream
    • 从排放物流中除去硫化氢的方法
    • US07998447B2
    • 2011-08-16
    • US10767339
    • 2004-01-28
    • Shane ElwartGopichandra SurnillaJoseph R. Theis
    • Shane ElwartGopichandra SurnillaJoseph R. Theis
    • B01D53/48
    • B01D53/96B01D2255/20753B01D2257/304
    • A method of removing hydrogen sulfide from an emissions stream is disclosed, wherein the method includes directing the emissions stream into a hydrogen sulfide converter having a metal oxide catalyst, adsorbing the hydrogen sulfide in the emissions stream to the metal oxide catalyst in the hydrogen sulfide converter, reacting the hydrogen sulfide with at least one of an oxidant and a reductant in the hydrogen sulfide converter to chemically transform the hydrogen sulfide, and adjusting an air-fuel ratio of the emissions stream based on exhaust temperature of an emission control device, where the adjustment varies a duration of at least one of lean and rich operation to perform the adsorbing and reacting even as exhaust temperature varies.
    • 公开了从排放物流中除去硫化氢的方法,其中所述方法包括将排放物流引入具有金属氧化物催化剂的硫化氢转化器中,将排放物流中的硫化氢吸附到硫化氢转化器中的金属氧化物催化剂 使所述硫化氢与所述硫化氢转化器中的氧化剂和还原剂中的至少一种反应,以化学转化所述硫化氢,并且基于排放控制装置的废气温度来调节排放流的空燃比,其中 调整改变贫和富操作中的至少一个的持续时间,以便即使排气温度变化也执行吸附和反应。
    • 5. 发明授权
    • Mechanical apparatus having a catalytic NOx storage and conversion device
    • 具有催化NOx储存和转化装置的机械装置
    • US07673445B2
    • 2010-03-09
    • US10985576
    • 2004-11-09
    • Christian T. Goralski, Jr.Joseph R. TheisGopichandra SurnillaJustin UraShane Elwart
    • Christian T. Goralski, Jr.Joseph R. TheisGopichandra SurnillaJustin UraShane Elwart
    • F01N3/00
    • F01N3/0814F01N3/0842F01N13/009F01N13/0097F02D41/0275Y02A50/2345Y02T10/22
    • A mechanical apparatus including a combustion engine, a conduit for transporting an exhaust stream away from the engine, a first catalytic NOx storage and conversion region disposed along the conduit, and a second catalytic NOx storage and conversion region disposed along the conduit at a location downstream from the first catalytic NOx storage and conversion region is disclosed. Each of the first catalytic NOx storage and conversion region and the second catalytic NOx storage and conversion region includes at least one catalytic metal configured to convert NOx to NO2 when the engine is supplied a lean air/fuel mixture, and at least one NOx adsorbing compound configured to adsorb NO2 for storage when the engine is supplied a lean air/fuel mixture, and wherein the one of the first and the second catalytic NOx storage and conversion regions has a lower concentration of catalytic metal than the other of the first and second catalytic NOx storage and conversion regions.
    • 一种机械设备,包括内燃发动机,用于将排气流输送离开发动机的导管,沿导管设置的第一催化剂NOx存储和转化区,以及沿下游位置设置的第二催化剂NOx储存和转化区 公开了从第一催化剂NOx储存和转化区域。 第一催化剂NOx存储和转化区域和第二催化剂NOx储存和转化区域中的每一个包括至少一种催化金属,其被配置为当发动机供应稀薄空气/燃料混合物时将NOx转化为NO 2,并且至少一种NOx吸附化合物 被配置为当所述发动机供应贫空气/燃料混合物时吸附NO 2用于储存,并且其中所述第一和第二催化剂NOx储存和转化区域中的所述一个与所述第一和第二催化剂中的另一个具有较低的催化金属浓度 NOx储存和转化区域。
    • 6. 发明授权
    • Catalyst diagnostic system and method
    • 催化剂诊断系统及方法
    • US5630315A
    • 1997-05-20
    • US556292
    • 1995-10-06
    • Joseph R. Theis
    • Joseph R. Theis
    • F01N11/00F01N13/02F01N3/00
    • F01N11/002F01N13/0097F01N2550/02Y02T10/47
    • A catalytic converter catalyst diagnostic system comprising: a catalytic converter having a catalyst; a first sensor placed in a flow path of an engine exhaust gas flowing into the catalytic converter and providing a first measurement signal indicative of a temperature of the engine exhaust gas before it enters the catalytic converter catalyst; a second sensor mounted in or behind the catalytic converter catalyst and providing a second measurement signal indicative of a temperature of the catalytic converter catalyst; and a controller coupled to the first and second sensors and receiving the first and second measurement signals therefrom, wherein the controller determines a value indicative of exothermic activity of the catalytic converter responsive to the first and second measurement signals and compares the value indicative of exothermic activity to a threshold value, wherein values below the threshold value are indicative of an improperly operating catalytic converter catalyst.
    • 一种催化转化器催化剂诊断系统,包括:具有催化剂的催化转化器; 放置在流入所述催化转化器的发动机废气的流路中的第一传感器,并且在进入所述催化转化器催化剂之前提供表示所述发动机废气的温度的第一测量信号; 安装在催化转化器催化剂中或其后面的第二传感器,并提供指示催化转化器催化剂的温度的第二测量信号; 以及控制器,耦合到第一和第二传感器并从其接收第一和第二测量信号,其中响应于第一和第二测量信号,控制器确定指示催化转化器的放热活性的值,并比较指示放热活性的值 阈值,其中低于阈值的值表示不正确操作的催化转化器催化剂。
    • 9. 发明授权
    • Automotive vehicle catalyst diagnostic
    • 汽车催化剂诊断
    • US5509267A
    • 1996-04-23
    • US337703
    • 1994-11-14
    • Joseph R. Theis
    • Joseph R. Theis
    • F01N11/00F01N13/02F01N3/20
    • F01N11/007F01N13/009F01N2550/02Y02T10/47
    • A catalytic treatment device diagnostic for an automotive exhaust system having at least two catalytic treatment devices wherein reduced oxygen storage capacity of each of the devices may be diagnosed without significant loss in engine air/fuel ratio control precision by varying the source of an actual air/fuel ratio feedback signal from a sensor positioned upstream of the devices during normal operation to a sensor mounted downstream of at least one of the devices during a diagnostic period. Measurable change in the oxygen content of exhaust gas passing through each of such devices then becomes available for analysis during the diagnostic period.
    • 一种用于具有至少两个催化处理装置的汽车排气系统的催化处理装置诊断装置,其中可以通过改变实际空气/燃料比的来源来诊断每个装置的减少的氧气储存容量,而不会明显损失发动机空气/燃料比控制精度 在正常操作期间,位于设备上游的传感器的传感器燃料比反馈信号在诊断期间安装在至少一个装置的下游的传感器。 通过每个这样的装置的废气的氧含量的可测量的变化随后可用于诊断期间的分析。