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    • 1. 发明申请
    • NMR Analysis of A Core Sample Employing An Open Permanent Magnet Removable from A Core Holder
    • 使用从芯夹可拆卸的开放永磁体的核心样品的NMR分析
    • US20150061670A1
    • 2015-03-05
    • US14362401
    • 2012-05-15
    • Edmund J. FordhamJonathan Mitchell
    • Edmund J. FordhamJonathan Mitchell
    • G01N24/08G01N1/00
    • G01N24/081G01N1/00G01R33/305G01R33/3806G01R33/383G01V3/32
    • An apparatus and method for NMR analysis of a plurality of core samples includes a core holder (11) that holds a core sample under pressurized conditions. A radio frequency coil (51) disposed about the core holder (11) generates a pulsed-mode magnetic field component over a sample volume occupied by the core sample. A support structure is removably secured to the respective core holder. A permanent magnet (65A, 65B) has an open configuration such that it is removably disposed into a position within the support structure about the radio frequency coil and the core holder. The open configuration allows the same permanent magnet to be used for NMR analysis of a plurality of core samples without the need for depressurizing the respective core holder and disassembling the core holder and corresponding load frame for each core sample. It also allows multiple core samples to be prepared for NMR analysis while separated from the NMR measurement apparatus.
    • 多个芯样品的NMR分析的装置和方法包括在加压条件下保持芯样品的芯保持器(11)。 设置在芯保持器(11)周围的射频线圈(51)在由核心样本占据的样本体积上产生脉冲模式磁场分量。 支撑结构可拆卸地固定到相应的芯保持器。 永磁体(65A,65B)具有打开构造,使得其可移除地设置在围绕射频线圈和芯保持器的支撑结构内的位置。 打开结构允许将相同的永磁体用于多个芯样品的NMR分析,而不需要对相应的芯保持器进行减压,并拆卸每个芯样品的芯架和相应的负载框架。 它还允许在与NMR测量装置分离的同时制备用于NMR分析的多个核心样品。
    • 4. 发明授权
    • Examining porous samples
    • 检查多孔样品
    • US09588067B2
    • 2017-03-07
    • US14005253
    • 2012-03-08
    • Jonathan MitchellEdmund Fordham
    • Jonathan MitchellEdmund Fordham
    • G01N24/08
    • G01N24/081
    • Apparatus for examining a fluid-containing porous sample, by a combination of centrifuging to move fluid into, out of, and/or within the sample and NMR to monitor the amount of fluid present at locations within the sample has a magnet system to provide a magnetic field; and a centrifuge rotor comprising a holder (18) for the sample and mounted to move the sample within the magnetic field. The apparatus preferably includes gradient coils (16, 116) superimposing a magnetic field gradient onto a field provided by magnets (11, 12, 111, 112). At least one radio-frequency coil (20) is located on the centrifuge rotor in a position 10 which surrounds the sample in the holder. The coil axis is transverse to the magnetic field and field gradient when measurement is made. Consequently NMR measurement of the distribution of fluid in the sample can be made while the centrifuge is in motion.
    • 用于检查含流体的多孔样品的装置,通过离心以将流体移入,离开和/或在样品内和/或样品内和NMR中的组合来监测存在于样品内的位置处的流体的量,具有磁体系统以提供 磁场; 以及离心机转子,其包括用于样品的保持器(18)并且被安装成在所述磁场内移动所述样品。 该装置优选地包括将磁场梯度叠加在由磁体(11,12,111,112)提供的场上的梯度线圈(16,116)。 至少一个射频线圈(20)位于离心机转子上的包围保持器中的样品的位置10。 当进行测量时,线圈轴线横向于磁场和场梯度。 因此,可以在离心机运动时进行样品中流体分布的NMR测量。
    • 6. 发明授权
    • Examination of porosity by NMR and intrusion porosimetry
    • 通过NMR和侵入孔隙率法检查孔隙度
    • US09500608B2
    • 2016-11-22
    • US14005254
    • 2012-03-12
    • Jonathan MitchellEdmund Fordham
    • Jonathan MitchellEdmund Fordham
    • G01V3/00G01N24/08G01N15/08
    • G01N24/081G01N15/088G01N15/0886G01N2015/0866
    • Properties of a porous solid sample 19, which may be a core of rock taken from below ground are carried out using apparatus which performs both nuclear magnetic resonance (NMR) and porosimetry measurements. The apparatus has a magnet 11,12 providing a magnetic field and a radio frequency coil 20 for transmitting and/or receiving electromagnetic radiation so as to bring about NMR in the magnetic field, a pressure vessel 14, 15 to hold a sample 19 within the magnetic field, a supply of a non-wetting liquid connected to the vessel, means to apply pressure to the non-wetting liquid to force liquid into pores of the sample 19 means to measure applied pressure of the non-wetting liquid and means to measure volume thereof taken up by the sample. The pressure of non-wetting liquid may be increased in steps, using intruded liquid volume at each step to give a measurement of pore throat size using NMR at each step to give a measure of pore size such as diameter of equivalent sphere. The non-wetting liquid may be mercury and NMR may observe the Knight shift of 99 Hg.
    • 可以使用进行核磁共振(NMR)和孔隙率测量两者的设备来进行可以是从地下取下的岩心的多孔固体样品19的性质。 该装置具有提供磁场的磁体11,12和用于传送和/或接收电磁辐射的射频线圈20,以便在磁场中产生NMR;压力容器14,15将样品19保持在 磁场,连接到容器的非润湿液体的供应装置,用于向非润湿液体施加压力以迫使液体进入样品19的孔中的装置意味着测量非润湿液体的施加压力和测量装置 其体积被样品吸收。 非润湿液体的压力可以逐步增加,使用每个步骤中的入渗液体体积,以在每个步骤中使用NMR测量孔喉尺寸,以得到孔径的量度,例如等效球体的直径。 非润湿液体可以是汞,NMR可以观察到99Hg的骑士位移。
    • 7. 发明授权
    • System and method for emulating nuclear magnetic resonance well logging tool diffusion editing measurements on a bench-top nuclear magnetic resonance spectrometer for laboratory-scale rock core analysis
    • 用于实验室规模岩芯分析的台式核磁共振光谱仪上模拟核磁共振测井仪扩散编辑测量的系统和方法
    • US08427145B2
    • 2013-04-23
    • US12731005
    • 2010-03-24
    • Jonathan MitchellEdmund J. Fordham
    • Jonathan MitchellEdmund J. Fordham
    • G01V3/18G01V3/00
    • G01R33/48G01N24/081G01R33/448G01V3/32
    • A laboratory NMR methodology (and corresponding laboratory apparatus) defines a sample volume. The method stores downhole tool data corresponding to a hydrocarbon-bearing sample collected from a given subsurface formation. The downhole tool data includes parameters pertaining to magnetic fields used by a downhole tool during a suite of NMR measurements of the given subsurface formation. The sample is positioned in the sample volume of the laboratory apparatus, which applies a static magnetic field in the sample volume. Furthermore, the laboratory apparatus applies a suite of NMR measurements to the sample volume to thereby determine a property of the sample. The NMR measurements of the suite each include a pulse sequence of oscillating magnetic field in conjunction with a pulsed-mode gradient field. The pulsed-mode gradient field is based on the stored downhole tool data corresponding to the sample. A laboratory NMR methodology for optimizing downhole NMR measurements is also described.
    • 实验室NMR方法(和相应的实验室装置)定义了样品体积。 该方法存储对应于从给定地下地层采集的含烃样品的井下工具数据。 井下工具数据包括与在给定地下地层的一组NMR测量期间由井下工具使用的磁场有关的参数。 样品定位在实验室设备的样品体积中,其在样品体积中施加静态磁场。 此外,实验室装置对样品体积应用一套NMR测量,从而确定样品的性质。 套件的NMR测量值包括与脉冲模式梯度场一起的振荡磁场的脉冲序列。 脉冲模式梯度场基于对应于样本的存储的井下工具数据。 还描述了用于优化井下NMR测量的实验室NMR方法。
    • 9. 发明申请
    • EXAMINATION OF POROSITY BY NMR AND INTRUSION POROSIMETRY
    • 通过核磁共振和浸入式方法检查孔隙度
    • US20140002081A1
    • 2014-01-02
    • US14005254
    • 2012-03-12
    • Jonathan MitchellEdmund Fordham
    • Jonathan MitchellEdmund Fordham
    • G01N24/08
    • G01N24/081G01N15/088G01N15/0886G01N2015/0866
    • Properties of a porous solid sample 19, which may be a core of rock taken from below ground are carried out using apparatus which performs both nuclear magnetic resonance (NMR) and porosimetry measurements. The apparatus has a magnet 11,12 providing a magnetic field and a radio frequency coil 20 for transmitting and/or receiving electromagnetic radiation so as to bring about NMR in the magnetic field, a pressure vessel 14, 15 to hold a sample 19 within the magnetic field, a supply of a non-wetting liquid connected to the vessel, means to apply pressure to the non-wetting liquid to force liquid into pores of the sample 19 means to measure applied pressure of the non-wetting liquid and means to measure volume thereof taken up by the sample. The pressure of non-wetting liquid may be increased in steps, using intruded liquid volume at each step to give a measurement of pore throat size using NMR at each step to give a measure of pore size such as diameter of equivalent sphere. The non-wetting liquid may be mercury and NMR may observe the Knight shift of 99 Hg.
    • 可以使用进行核磁共振(NMR)和孔隙率测量两者的设备来进行可以是从地下取下的岩心的多孔固体样品19的性质。 该装置具有提供磁场的磁体11,12和用于传送和/或接收电磁辐射的射频线圈20,以便在磁场中产生NMR;压力容器14,15将样品19保持在 磁场,连接到容器的非润湿液体的供应装置,用于向非润湿液体施加压力以迫使液体进入样品19的孔中的装置意味着测量非润湿液体的施加压力和测量装置 其体积被样品吸收。 非润湿液体的压力可以逐步增加,使用每个步骤中的入渗液体体积,以在每个步骤中使用NMR测量孔喉尺寸,以得到孔径的量度,例如等效球体的直径。 非润湿液体可以是汞,NMR可以观察到99Hg的骑士位移。
    • 10. 发明申请
    • EXAMINING POROUS SAMPLES
    • 检查多孔样品
    • US20130342208A1
    • 2013-12-26
    • US14005253
    • 2012-03-08
    • Jonathan MitchellEdmund Fordham
    • Jonathan MitchellEdmund Fordham
    • G01N24/08
    • G01N24/081
    • Apparatus for examining a fluid-containing porous sample, by a combination of centrifuging to move fluid into, out of, and/or within the sample and NMR to monitor the amount of fluid present at locations within the sample has a magnet system to provide a magnetic field; and a centrifuge rotor comprising a holder (18) for the sample and mounted to move the sample within the magnetic field. The apparatus preferably includes gradient coils (16, 116) superimposing a magnetic field gradient onto a field provided by magnets (11, 12, 111, 112). At least one radio-frequency coil (20) is located on the centrifuge rotor in a position 10 which surrounds the sample in the holder. The coil axis is transverse to the magnetic field and field gradient when measurement is made. Consequently NMR measurement of the distribution of fluid in the sample can be made while the centrifuge is in motion.
    • 用于检查含流体的多孔样品的装置,通过离心以将流体移入,离开和/或在样品内和/或样品内和NMR中的组合来监测存在于样品内的位置处的流体的量,具有磁体系统以提供 磁场; 以及离心机转子,其包括用于样品的保持器(18)并且被安装成在所述磁场内移动所述样品。 该装置优选地包括将磁场梯度叠加在由磁体(11,12,111,112)提供的场上的梯度线圈(16,116)。 至少一个射频线圈(20)位于离心机转子上的包围保持器中的样品的位置10。 当进行测量时,线圈轴线横向于磁场和场梯度。 因此,可以在离心机运动时进行样品中流体分布的NMR测量。