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1. 发明申请

US20130233383A1 Electronic Device Module Comprising Film of Homogeneous Polyolefin Copolymer and Grafted Silane 审中-公开
标题翻译：包含均相聚烯烃共聚物和接枝硅烷的膜的电子器件模块
公开(公告)号：US20130233383A1
公开(公告)日：2013-09-12
申请号：US13701534
申请日：2011-06-06
申请人： John A. Naumovitz , Rajen M. Patel , Shaofu Wu , Debra H. Neimann
发明人： John A. Naumovitz , Rajen M. Patel , Shaofu Wu , Debra H. Neimann
IPC分类号： H01L31/0203 , H01L23/29
CPC分类号： H01L31/0203 , B32B17/10018 , B32B17/1055 , C08F210/16 , C08F255/02 , C08L23/08 , H01L23/293 , H01L31/0481 , H01L2924/0002 , Y02E10/50 , C08L2666/24 , C08F210/14 , C08F2500/02 , C08F2500/09 , C08F2500/11 , C08F2500/26 , H01L2924/00 , C08F230/08
摘要： An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) an ethylene interpolymer comprising an overall polymer density of not more than 0.905 g/cm3; total unsaturation of not more than 125 per 100,000 carbons; up to 3 long chain branches/1000 carbons; vinyl-3 content of less than 5 per 100,000 carbons; and a total number of vinyl groups/1000 carbons of less than the quantity (8000/Mn), wherein the vinyl-3 content and vinyl group measurements are measured by gel permeation chromatography (145° C.) and 1H-NMR (125° C.), (2) grafted vinyl silane, (3) optionally, free radical initiator or a photoinitiator in an amount of at least about 0.05 wt % based on the weight of the copolymer, and (3) optionally, a co-agent in an amount of at least about 0.05 wt % based upon the weight of the copolymer.
摘要翻译：一种电子设备模块，包括：A.至少一个电子设备，例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合物材料，所述聚合物材料包含（1）乙烯互聚物，其包含总聚合物密度不大于0.905g / cm3; 总不饱和度不超过125 / 100,000个碳; 最多3条长支链/ 1000个碳; 乙烯基-3含量小于5 / 100,000碳; 和总数（1000 / Mn）的乙烯基/ 1000个碳的总数，其中通过凝胶渗透色谱（145℃）和1 H-NMR（125°）测量乙烯基-3含量和乙烯基测量值 C.），（2）接枝的乙烯基硅烷，（3）任选的自由基引发剂或光引发剂，其量为基于共聚物重量的至少约0.05重量％，和（3）任选的助剂其量为基于共聚物重量的至少约0.05重量％。

2. 发明申请

US20130087199A1 Electronic Device Module Comprising Long Chain Branched (LCB), Block or Interconnected Copolymers of Ethylene and Optionally Silane 审中-公开
标题翻译：包括长链支化（LCB），乙烯和任选的硅烷的嵌段或互连共聚物的电子器件模块
公开(公告)号：US20130087199A1
公开(公告)日：2013-04-11
申请号：US13703639
申请日：2011-06-15
申请人： John A. Naumovitz , Debra H. Neimann , Rajen M. Patel , Shaofu Wu
发明人： John A. Naumovitz , Debra H. Neimann , Rajen M. Patel , Shaofu Wu
IPC分类号： H01L31/0203 , H05K1/03
CPC分类号： H01L31/0203 , B32B17/10018 , B32B17/1055 , B32B17/10678 , B32B17/10697 , H01L23/293 , H01L31/0481 , H01L2924/0002 , H05K1/032 , Y02E10/50 , H01L2924/00
摘要： An electronic device module is disclosed comprising: A. at least one electronic device, and B. a polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) An ethylenic polymer comprising at least 0.1 amyl branches per 1000 carbon atoms as determined by Nuclear Magnetic Resonance and both a highest peak melting temperature, Tm, in ° C., and a heat of fusion, Hf, in J/g, as determined by DSC Crystallinity, where the numerical values of Tm and Hf correspond to the relationship: Tm≧(0.2143*Hf)+79.643, and wherein the ethylenic polymer has less than about 1 mole percent ctane comonomer, and less than about 0.5 mole percent ctane, pentene, or ctane comonomer. (2) optionally, free radical initiator or a photoinitiator in an amount of at least about 0.05 wt % based on the weight of the copolymer, (3) optionally, a co-agent in an amount of at least about 0.05 wt % based upon the weight of the copolymer, and (4) optionally, a vinyl silane compound.
摘要翻译：公开了一种电子设备模块，包括：A.至少一个电子设备，以及B.与所述电子设备的至少一个表面紧密接触的聚合物材料，所述聚合物材料包含（1）包含至少0.1个戊基通过核磁共振确定的每1000个碳原子的分支，并且通过DSC结晶度测定的最高峰值熔融温度Tm，℃和熔融热Hf（J / g），其中数值 Tm和Hf对应于Tm≥（0.2143×Hf）+79.643的关系，并且其中乙烯类聚合物具有小于约1摩尔％的正丁烯共聚单体，和小于约0.5摩尔％的正丁烯，戊烯或者正庚烷共聚单体。（2）任选地，基于共聚物重量的至少约0.05重量％的自由基引发剂或光引发剂，（3）任选地，基于以下物质的至少约0.05重量％的量的助剂：共聚物的重量，和（4）任选的乙烯基硅烷化合物。

3. 发明申请

US20130087198A1 Electronic Device Module Comprising Heterogeneous Polyolefin Copolymer and Optionally Silane 审中-公开
标题翻译：包含非均相聚烯烃共聚物和任选的硅烷的电子器件模块
公开(公告)号：US20130087198A1
公开(公告)日：2013-04-11
申请号：US13703405
申请日：2011-06-15
申请人： John A. Naumovitz , Debra H. Niemann , Rajen M. Patel , Shaofu Wu
发明人： John A. Naumovitz , Debra H. Niemann , Rajen M. Patel , Shaofu Wu
IPC分类号： H01L31/0203 , H05K1/03
CPC分类号： H01L31/0203 , B32B17/10018 , B32B17/1055 , B32B17/10697 , B32B17/10788 , C08L23/0815 , C08L2203/204 , H01L31/0481 , H05K1/032 , Y02E10/50
摘要： An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) a polyolefin copolymer characterized as having has an average Mv and a valley temperature between the interpolymer and high crystalline fraction, Thc, such that the average Mv for a fraction above Thc from ATREF divided by average Mv of the whole polymer from ATREF (Mhc/Mp) is less than about 1.95 and wherein the copolymer has a CDBI of less than 60%, (2) optionally, a vinyl silane, (3) optionally, free radical initiator or a photoinitiator in an amount of at least about 0.05 wt % based on the weight of the copolymer, and (4) optionally, a co-agent in an amount of at least about 0.05 wt % based upon the weight of the copolymer.
摘要翻译：一种电子设备模块，包括：A.至少一个电子设备，例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合材料，所述聚合物材料包括（1）聚烯烃共聚物，具有在互聚物和高结晶部分Thc之间具有平均Mv和谷值温度，使得在ATREF之上的Thc以上的分数的平均Mv除以ATREF（Mhc / Mp）之外的整个聚合物的平均Mv小于约1.95，并且其中所述共聚物的CDBI小于60％，（2）任选的乙烯基硅烷，（3）任选的自由基引发剂或光引发剂，其量为至少约0.05重量％共聚物，和（4）任选地，基于共聚物的重量，至少约0.05重量％的助剂。

4. 发明授权

US5002989A Formulation for extrudable vinylidene chloride copolymers having high barrier properties 失效
标题翻译：具有高阻隔性的可挤出偏二氯乙烯共聚物的配方
公开(公告)号：US5002989A
公开(公告)日：1991-03-26
申请号：US402003
申请日：1989-09-01
申请人： John A. Naumovitz , Steven R. Jenkins , Mark J. Hall , Stephen R. Betso
发明人： John A. Naumovitz , Steven R. Jenkins , Mark J. Hall , Stephen R. Betso
IPC分类号： C08K3/22 , C08K3/32 , C08L23/06 , C08L23/30 , C08L27/08
CPC分类号： C08K3/22 , C08K3/32 , C08L27/08 , C08L23/06 , C08L23/30
摘要： The present invention is a formulated barrier composition containing tetrasodium pyrophosphate or magnesium hydroxide, high density polyethylene, epoxidzed vegetable oil, oxidized polyolefin and a paraffin or polyolefin wax. The composition has a substantially lower oxygen permeability than existing compositions and is at least equally extrudable.
摘要翻译：本发明是一种配制的阻挡组合物，其包含焦磷酸四钠或氢氧化镁，高密度聚乙烯，环氧化植物油，氧化聚烯烃和石蜡或聚烯烃蜡。该组合物具有比现有组合物显着更低的氧气渗透性，并且至少是同等可挤出的。

5. 发明申请

US20140096825A1 MULTILAYERED POLYOLEFIN-BASED FILMS HAVING INTEGRATED BACKSHEET AND ENCAPSULATION PERFORMANCE COMPRISING A LAYER COMPRISING CRYSTALLINE BLOCK COPOLYMER COMPOSITE OR BLOCK COPOLYMER COMPOSITE 审中-公开
标题翻译：具有一体化背衬的多层聚烯烃基膜和包含结晶嵌段共聚物复合材料或嵌段共聚物复合材料层的包封性能
公开(公告)号：US20140096825A1
公开(公告)日：2014-04-10
申请号：US14122720
申请日：2012-06-28
申请人： Jeffrey E Bonekamp , Yushan Hu , Nichole E. Nickel , Lih-Long Chu , John a. Naumovitz , Mark G. Hofius
发明人： Jeffrey E Bonekamp , Yushan Hu , Nichole E. Nickel , Lih-Long Chu , John a. Naumovitz , Mark G. Hofius
IPC分类号： H01L31/048 , B32B27/08 , H01L31/18 , B32B27/32
CPC分类号： B32B27/32 , B32B27/08 , B32B27/327 , B32B2250/242 , B32B2307/704 , B32B2457/12 , C08L53/00 , H01L31/0481 , H01L31/049 , H01L31/18 , Y02E10/50
摘要： A multilayer film structure comprising a top encapsulation layer A, a tie Layer B between top Layer A and bottom Layer C and a bottom layer C, the multilayer film structure characterized in that tie Layer B comprises a crystalline block composite resin or a block composite resin and bottom Layer C comprises a polyolefin having at least one melting point greater than 125° C.
摘要翻译：一种多层膜结构，其包括顶部封装层A，顶层A和底层C之间的连接层B和底层C，多层膜结构的特征在于连接层B包含结晶嵌段复合树脂或嵌段复合树脂并且底层C包含具有至少一个熔点大于125℃的聚烯烃。

6. 发明申请

US20080274245A1 Multicomponent Structures Having Improved Adhesion Between Components 审中-公开
标题翻译：具有改善组分之间粘附性的多组分结构
公开(公告)号：US20080274245A1
公开(公告)日：2008-11-06
申请号：US11547486
申请日：2005-04-05
申请人： Eric K.C. Lee , John A. Naumovitz , Mladen Ladika
发明人： Eric K.C. Lee , John A. Naumovitz , Mladen Ladika
IPC分类号： B29C65/14 , B32B27/36 , B32B27/30 , B29C47/08 , B65D81/34 , B32B7/10 , B32B1/08
CPC分类号： B32B7/12 , B32B27/08 , B32B27/30 , B32B27/304 , B32B2310/0837 , B32B2439/00 , C08J5/12 , Y10T428/1307 , Y10T428/1321 , Y10T428/1352 , Y10T428/1362 , Y10T428/31616 , Y10T428/31667 , Y10T428/31681 , Y10T428/31797
摘要： The present invention includes a multicomponent structure comprising at least two components having a tie layer or adhesive layer directly between them, the tie layer comprising at least one olefin unsaturated ester copolymer and at least one photoinitiator and optionally a crosslinking enhancer. The tie layer is preferably irradiated with sufficient actinic radiation to result in increased interlayer adhesion strength between the two components as compared with the interlayer adhesion strength before treatment with the actinic radiation or between the components having a tie layer of the same composition except without the added photoinitiator or crosslinking enhancer. Without the photoinitiator, optionally crosslinking enhancer, and radiation the interlayer adhesion of the components is preferably less than 55 N/m. At least one of the components (first component or layer) preferably comprises a halopolymer, more preferably vinylidene chloride polymer, most preferably at least a majority of a vinyl idene chloride polymer. In another embodiment, at least one component exhibits interlayer adhesion strength similar to vinylidene chloride polymers. The structure optionally is or comprises such structures as a multilayer film, bag, or package, a lined or composite pipe, or other structure having more than one component. The tie layer is advantageously irradiated with an amount of UV light effective to increase the adhesion strength between the first and second components.
摘要翻译：本发明包括多组分结构，其包含至少两个在其间直接连接层或粘合剂层的组分，所述粘结层包含至少一种烯烃不饱和酯共聚物和至少一种光引发剂和任选的交联增强剂。与使用光化辐射处理之前的层间粘合强度或具有相同组成的粘结层的组分之间相比，接合层优选用足够的光化辐射照射以导致两组分之间的层间粘合强度增加，除了不添加光引发剂或交联增强剂。没有光引发剂，任选的交联增强剂和辐射，组分的层间粘附优选小于55N / m。组分（第一组分或第一组分）中的至少一种优选包含卤代聚合物，更优选偏二氯乙烯聚合物，最优选氯乙烯基氯化聚合物的至少大部分。在另一个实施方案中，至少一种组分显示类似于偏二氯乙烯聚合物的层间粘合强度。该结构任选地或包括诸如多层膜，袋或包装，衬里或复合管或具有多于一种组分的其它结构的结构。接合层有利地用一定量的UV光照射，以有效地增加第一和第二组分之间的粘合强度。

7. 发明申请

US20130269776A1 SILANE-CONTAINING THERMOPLASTIC POLYOLEFIN COPOLYMER RESINS, FILMS, PROCESSES FOR THEIR PREPARATION AND PHOTOVOLTAIC MODULE LAMINATE STRUCTURE COMPRISING SUCH RESINS AND FILMS 审中-公开
标题翻译：含硅的热塑性聚烯烃共聚物树脂，膜，其制备和包含这种树脂和膜的光伏模块层压结构的方法
公开(公告)号：US20130269776A1
公开(公告)日：2013-10-17
申请号：US13994315
申请日：2011-11-08
申请人： Shaofu Wu , Lih-Long Chu , John D. Weaver , John A. Naumovitz , Richard C. Abel
发明人： Shaofu Wu , Lih-Long Chu , John D. Weaver , John A. Naumovitz , Richard C. Abel
IPC分类号： H01L31/048 , H01L31/18
CPC分类号： H01L31/1876 , B32B17/10018 , B32B2323/04 , B32B2457/12 , C08F255/02 , C08J5/18 , C08J2351/06 , H01L31/0481 , Y02E10/50 , C08F230/08
摘要： Disclosure are films based on alkoxysilane-containing polyolefin resins with reduced melt strength, photovoltaic cell laminate structures and methods for their preparation. In the disclosed alkoxysilane-containing polyolefin resin films according to the invention, reduced melt strength is provided by, among other things, using optimized silane:initiator ratios and is shown to reduce detrimental film shrinkage and provide improved photovoltaic laminate structures.
摘要翻译：披露是基于具有降低的熔体强度的含烷氧基硅烷的聚烯烃树脂的膜，光伏电池层压结构及其制备方法。在所公开的本发明的含烷氧基硅烷的聚烯烃树脂膜中，除了别的以外，使用优化的硅烷：引发剂比率提供降低的熔体强度，并且显示出减少有害的膜收缩并提供改进的光伏层压结构。

8. 发明申请

US20130206224A1 Electronic Device Module Comprising Film of Homogeneous Polyolefin Copolymer and Adhesive Property Enhancing Graft Polymer 审中-公开
标题翻译：包含均匀聚烯烃共聚物膜和粘合剂性能的电子装置模块增强接枝聚合物
公开(公告)号：US20130206224A1
公开(公告)日：2013-08-15
申请号：US13701060
申请日：2011-06-06
申请人： John A. Naumovitz , Rajen M. Patel , Shaofu Wu , Debra H. Niemann
发明人： John A. Naumovitz , Rajen M. Patel , Shaofu Wu , Debra H. Niemann
IPC分类号： H05K1/03 , H01L31/048
CPC分类号： H05K1/0353 , B32B17/10018 , B32B17/1055 , B32B17/10697 , C08F210/16 , C08L23/08 , H01L31/0481 , Y02E10/50 , C08L2666/24 , C08F210/14 , C08F2500/08 , C08F2500/09 , C08F2500/26
摘要： An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) an ethylene interpolymer comprising an overall polymer density of not more than 0.905 g/cm3; total unsaturation of not more than 125 per 100,000 carbons; and; up to 3 long chain branches/1000 carbons; vinyl-3 content of less than 5 per 100,000 carbons; and a total number of vinyl groups/1000 carbons of less than the quantity (8000/Mn), wherein the vinyl-3 content and vinyl group measurements are measured by gel permeation chromatography (145° C.) and 1H-NMR (125° C.), (2) a graft polymer to enhance the adhesion, (3) optionally, free radical initiator or a photoinitiator in an amount of at least about 0.05 wt % based on the weight of the copolymer, and (3) optionally, a co-agent in an amount of at least about 0.05 wt% based upon the weight of the copolymer.
摘要翻译：一种电子设备模块，包括：A.至少一个电子设备，例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合物材料，所述聚合物材料包含（1）乙烯互聚物，其包含总聚合物密度不大于0.905g / cm3; 总不饱和度不超过125 / 100,000个碳; 和; 最多3条长支链/ 1000个碳; 乙烯基-3含量小于5 / 100,000碳; 和总数（1000 / Mn）的乙烯基/ 1000个碳的总数，其中通过凝胶渗透色谱（145℃）和1 H-NMR（125°）测量乙烯基-3含量和乙烯基测量值（3）任选的自由基引发剂或光引发剂，其量为至少约0.05重量％，基于共聚物的重量，和（3）任选地，基于共聚物的重量，至少约0.05重量％的量的助剂。

9. 发明申请

US20130167926A1 Electronic Device Module Comprising Ethylene-Alpha Olefin Tapered Block Copolymers and Optional Vinyl Silane 审中-公开
标题翻译：包含乙烯-α烯烃锥形嵌段共聚物和任选的乙烯基硅烷的电子器件模块
公开(公告)号：US20130167926A1
公开(公告)日：2013-07-04
申请号：US13821272
申请日：2011-09-02
申请人： Debra H. Niemann , John A. Naumovitz , Rajen M. Patel , Shaofu Wu
发明人： Debra H. Niemann , John A. Naumovitz , Rajen M. Patel , Shaofu Wu
IPC分类号： H01L31/048
CPC分类号： H01L31/0481 , B32B17/10018 , B32B17/10036 , B32B17/1055 , B32B2457/12 , Y02E10/50
摘要： An electronic device module such as a solar cell is described. The electronic device module is made using a polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising a tapered block copolymer comprising an A block, and a B block.
摘要翻译：描述了诸如太阳能电池的电子设备模块。电子器件模块使用与电子器件的至少一个表面紧密接触的聚合物材料制成，聚合物材料包含包含A嵌段和B嵌段的渐缩嵌段共聚物。

10. 发明授权

US06685872B2 Method for preparing multilayer films 有权
标题翻译：多层膜制备方法
公开(公告)号：US06685872B2
公开(公告)日：2004-02-03
申请号：US09899614
申请日：2001-07-03
申请人： Joseph Dooley , Steve R. Jenkins , John A. Naumovitz
发明人： Joseph Dooley , Steve R. Jenkins , John A. Naumovitz
IPC分类号： B29C4706
CPC分类号： B29C47/28 , B29C47/0023 , B29C47/0026 , B29C47/06 , B29C47/062 , B29C47/065 , B29C47/20 , B29C47/26 , B29C47/261 , B29C47/38 , B29C47/56 , B29C47/70 , B32B1/08 , B32B27/08 , B32B37/153 , Y10T137/87571 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383 , Y10T428/1393 , Y10T428/3175 , Y10T428/3192
摘要： A method for coextruding a multilayer tubular film having a barrier material comprises (a) extruding a core extrudate of barrier material with a core extruder; (b) providing a preencapsulation die adjacent the outlet of the core extruder, the prencapsulation die capable of producing a non-uniform layer thickness; (c) extruding a preencapsular extrudate of preencapsular material and directing said preencapsular extrudate to the preencapsulation die; (d) joining the core extrudate and the preencapsular extrudate in the preencapsulation die in a coaxial relationship wherein the preencapsular extrudate is disposed radially outwardly of the core extrudate to form a preencapsulated core extrudate having a non-uniform layer thickness; (e) extruding an inner layer extrudate and an outer layer extrudate; (f) feeding the preencapsulated ore extrudate through a distribution manifold to a coextrusion die, the distribution manifold designed to overlap opposing longitudinally extending edges; and (g) forming a multilayer blown film having the inner layer extrudate disposed radially inwardly of the preencapsulated core extrudate and the outer layer extrudate disposed radially outwardly of the preencapsulated core extrudate. In preferred embodiments the inner layer extrudate and the outer layer extrudate are joined to the preencapsulated core extrudate before, or alternatively while, the preencapsulated core extrudate is fed through the coextrusion die.
摘要翻译：用于共挤出具有阻隔材料的多层管状膜的方法包括（a）用芯挤出机挤出阻挡材料的芯挤出物; （b）提供邻近核心挤出机的出口的预包装模具，所述预包装模具能够产生不均匀的层厚度; （c）挤出预胶囊材料的预胶囊挤出物并将所述预胶囊挤出物引导到预包封模具; （d）以同轴关系将预包封模具中的核心挤出物和预胶囊挤出物连接在一起，其中预胶囊挤出物径向向外设置在芯挤出物上以形成具有不均匀层厚度的预包封的芯挤出物; （e）挤出内层挤出物和外层挤出物; （f）将预包装的矿石挤出物通过分配歧管进料到共挤出模头，该分配歧管设计成与相对的纵向延伸的边缘重叠; 和（g）形成具有内层挤出物的多层吹塑薄膜，所述内层挤出物设置在预包封的芯挤出物的径向内侧，而外层挤出物位于预包封的芯挤出物的径向外侧。在优选的实施方案中，将内层挤出物和外层挤出物在预包封的芯挤出物通过共挤出模头进料之前或备选地与先前封装的芯挤出物相连。

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