专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US06384256B1 Process for the preparation of sulfur-containing organosilicon compounds 有权
标题翻译：含硫有机硅化合物的制备方法
公开(公告)号：US06384256B1
公开(公告)日：2002-05-07
申请号：US09895720
申请日：2001-06-29
申请人： Michael Wolfgang Backer , Howard Marvin Bank , John Michael Gohndrone , William Charles Maki , Charles Edmund Skinner , Anil Kumar Tomar , Hongjun Yue
发明人： Michael Wolfgang Backer , Howard Marvin Bank , John Michael Gohndrone , William Charles Maki , Charles Edmund Skinner , Anil Kumar Tomar , Hongjun Yue
IPC分类号： C07F208
CPC分类号： C07F7/1892
摘要： A process for the production of organosilicon compounds of the formula: (RO)3−mRmSi-Alk-Sn-Alk-SiRm(OR)3−m where R is independently a monovalent hydrocarbon of 1 to 12 carbon atoms; Alk is a divalent hydrocarbon of 1 to 18 carbon atoms; m is an integer of 0 to 2, n is a number from 1 to 10; is disclosed. The process comprises: (A) reacting an alkali metal hydroxide compound, a sulfide compound having the formula M2Sn or MHS, where H is hydrogen, M is ammonium or an alkali metal, n is as defined above, and sulfur in water to form a polysulfide mixture, (B) reacting said polysulfide mixture with a silane compound of the formula; (RO)3−mRmSi-Alk-X where X is Cl, Br or I, and m is the same as above, in the presence of a phase transfer catalyst. The process provides sulfur containing organosilicon compounds based on phase transfer catalysis techniques that result in a final product composition having greater stability, purity, and appearance. The process also minimizes or eliminates hydrogen sulfide as a side product.
摘要翻译：一种制备下式的有机硅化合物的方法：其中R独立地是1至12个碳原子的一价烃; Alk为1〜18个碳原子的二价烃，m为0〜2的整数，n为1〜10的数。该方法包括：（A）使碱金属氢氧化物化合物，具有式M2Sn或MHS的硫化物，其中H是氢，M是铵或碱金属，n如上定义，和硫在水中形成（B）使所述多硫化物混合物与下式的硅烷化合物反应;其中X是Cl，Br或I，m与上述相同，在相转移催化剂的存在下。该方法基于相转移催化技术提供含硫有机硅化合物，其导致最终产物组合物具有更高的稳定性，纯度和外观。该方法还使作为副产物的硫化氢最小化或消除。

2. 发明授权

US06534668B2 Preparation of sulfur-containing organosilicon compounds using a buffered phase transfer catalysis process 有权
标题翻译：使用缓冲相转移催化方法制备含硫有机硅化合物
公开(公告)号：US06534668B2
公开(公告)日：2003-03-18
申请号：US09895719
申请日：2001-06-29
申请人： Michael Wolfgang Backer , Howard Marvin Bank , John Michael Gohndrone , William Charles Maki , Charles Edmund Skinner , Anil Kumar Tomar , Hongjun Yue
发明人： Michael Wolfgang Backer , Howard Marvin Bank , John Michael Gohndrone , William Charles Maki , Charles Edmund Skinner , Anil Kumar Tomar , Hongjun Yue
IPC分类号： C07F708
CPC分类号： C07F7/1892
摘要： A process for the production of sulfur containing organosilicon compounds of the formula: (RO)3−mRmSi—Alk—Sn—Alk—SiRm(OR)3−m where R is independently a monovalent hydrocarbon of 1 to 12 carbon atoms; Alk is a divalent hydrocarbon of 1 to 18 carbon atoms; m is an integer of 0 to 2, n is a number from 1 to 8; based on phase transfer catalysis techniques is disclosed. The process comprises reacting: (A) a sulfide compound having the formula M2Sn or MHS, where H is hydrogen, M is ammonium or an alkali metal, n is as defined above, with (B) a silane compound of the formula; (RO)3−mRmSi—Alk—X where X is Cl, Br or I, and m is the same as above, and optionally, (C) sulfur in the presence of a phase transfer catalyst and an aqueous phase containing a buffer. The improvement of the present invention is characterized by adding a buffer to the aqueous phase, which minimizes or prevents gelling of the sulfur containing organosilicon compounds. The present invention also teaches a process for the production of sulfur containing organosilicon compounds by controlling the pH of the aqueous phase.
摘要翻译：一种生产下式的含硫有机硅化合物的方法：其中R独立地为1至12个碳原子的一价烃; Alk是1至18个碳原子的二价烃; m是0至2的整数，n是1至8的数;基于相转移催化技术被公开。该方法包括：（A）具有式M2Sn或MHS的硫化物，其中H是氢，M是铵或碱金属，n如上定义，与（B）下式的硅烷化合物反应：其中X 是Cl，Br或I，m与上述相同，任选地，（C）硫在存在相转移催化剂和含有缓冲液的水相的存在下。本发明的改进的特征在于将缓冲剂加入水相，其最小化或防止含硫有机硅化合物的胶凝。本发明还教导了通过控制含水相的pH来生产含硫有机硅化合物的方法。

3. 发明授权

US06448426B1 Process for the preparation of sulfur-containing organosilicon compounds 有权
标题翻译：含硫有机硅化合物的制备方法
公开(公告)号：US06448426B1
公开(公告)日：2002-09-10
申请号：US09895721
申请日：2001-06-29
申请人： Michael Wolfgang Backer , Howard Marvin Bank , John Michael Gohndrone , William Charles Maki , Charles Edmund Skinner , Anil Kumar Tomar , Hongjun Yue
发明人： Michael Wolfgang Backer , Howard Marvin Bank , John Michael Gohndrone , William Charles Maki , Charles Edmund Skinner , Anil Kumar Tomar , Hongjun Yue
IPC分类号： C07F708
CPC分类号： C07F7/1892 , B60C1/00 , C08K5/548 , C08L21/00
摘要： An improved process for the production of organosilicon compounds of the formula (RO)3−mRmSi—Alk—Sn—Alk—SiRm(OR)3−m where R is independently a monovalent hydrocarbon of 1 to 12 carbon atoms, Alk is a divalent hydrocarbon of 1 to 18 carbon atoms; m is an integer of 0 to 2, n is a number from 1 to 8 is disclosed. The process comprises: (A) reacting sulfur, a phase transfer catalyst, a sulfide compound having the formula M2Sn or MHS, where H is hydrogen, M is ammonium or an alkali metal, n is the same as above, and water to form an intermediate reaction product; (B) reacting said intermediate reaction product with a silane compound of the formula; (RO)3−mRmSi—Alk—X where X is Cl, Br or I, and m is the same as above (C) separating the organosilicon compound from the product mixture by adding water or a dilute acidic solution to the product mixture, and phase separating the product mixture into an organic phase containing the organosilicon compound and an aqueous phase.
摘要翻译：制备式R的有机硅化合物的改进方法独立地是1至12个碳原子的单价烃，Alk是1至18个碳原子的二价烃; m是0-2的整数，n是数从1到8被公开。该方法包括：（A）使硫，相转移催化剂，具有式M2Sn或MHS的硫化物反应，其中H是氢，M是铵或碱金属，n与上述相同，和水形成中间反应产物;（B）使所述中间体反应产物与下式的硅烷化合物反应;其中X为Cl，Br或I，m与上述相同（C）通过加入水分将有机硅化合物与产物混合物分离或稀酸性溶液，并将产物混合物相分离成含有有机硅化合物和水相的有机相。

4. 发明授权

US06384255B1 Process for the preparation of sulfur-containing organosilicon compounds 有权
标题翻译：含硫有机硅化合物的制备方法
公开(公告)号：US06384255B1
公开(公告)日：2002-05-07
申请号：US09895700
申请日：2001-06-29
申请人： Michael Wolfgang Backer , Howard Marvin Bank , John Michael Gohndrone , William Charles Maki , Charles Edmund Skinner , Anil Kumar Tomar , Hongjun Yue
发明人： Michael Wolfgang Backer , Howard Marvin Bank , John Michael Gohndrone , William Charles Maki , Charles Edmund Skinner , Anil Kumar Tomar , Hongjun Yue
IPC分类号： C07F708
CPC分类号： C07F7/1804
摘要： A process for the production of organosilicon compounds of the formula (RO)3−mRmSi—Alk—Sn—Alk—SiRm(OR)3−m where R is independently a monovalent hydrocarbon of 1 to 12 carbon atoms, Alk is a divalent hydrocarbon of 1 to 18 carbon atoms; m is an integer of 0 to 2, n is a number from 1 to 8 is disclosed. The process comprises: (A) reacting sulfur, a phase transfer catalyst, a sulfide compound having the formula M2Sn or MHS, where H is hydrogen, M is ammonium or an alkali metal, n is the same as above, and water to form an intermediate reaction product; (B) reacting said intermediate reaction product with a silane compound of the formula; (RO)3−mRmSi—Alk—X where X is Cl, Br or I, and m is the same as above. The invention provides an improvement process characterized by adding the phase transfer catalyst to the aqueous phase prior to mixing the aqueous phase with the silane compound for the reaction.
摘要翻译：制备式R的有机硅化合物的方法独立地是1至12个碳原子的一价烃，Alk是1至18个碳原子的二价烃; m是0-2的整数，n是公开了图1至图8。该方法包括：（A）使硫，相转移催化剂，具有式M2Sn或MHS的硫化物反应，其中H是氢，M是铵或碱金属，n与上述相同，和水形成中间反应产物;（B）使所述中间体反应产物与下式的硅烷化合物反应; 其中X是Cl，Br或I，m与上述相同。本发明提供了一种改进方法，其特征在于在将水相与用于反应的硅烷化合物混合之前将相转移催化剂加入到水相中。

5. 发明授权

US06740767B1 Method of making sulfur containing organosilicon compounds 有权
标题翻译：制备含硫有机硅化合物的方法
公开(公告)号：US06740767B1
公开(公告)日：2004-05-25
申请号：US10293841
申请日：2002-11-12
申请人： Chad Aaron Buesing , John Michael Gohndrone
发明人： Chad Aaron Buesing , John Michael Gohndrone
IPC分类号： C07F708
CPC分类号： C07F7/1892
摘要： A process for producing organosilicon compounds of the formula (RO)3-mRmSi—Alk—Sn—Alk—SiRm(OR)3-m in which R is a monovalent hydrocarbon having 1-12 carbon atoms, Alk is a divalent hydrocarbon having 1-18 carbon atoms, m is 0, 1 or 2, and n is 2-8, preferably 3-8. The process consists generally of the steps of (I) heating and reacting (A) a sulfide compound such as M2Sn or MHS where H is hydrogen, M is ammonium or an alkali metal, and n is 1-8; with (B) a silane compound of the formula (RO)3-mRmSi—Alk—X where X is Cl, Br or I, and m is 0, 1, or 2; and with (C) sulfur. Step (I) is carried out in the presence of a phase transfer catalyst, and an aqueous phase containing a buffer or a basic compound, to form a product mixture. In step (II), the product mixture is again heated to a temperature of 80-100° C., preferably a temperature of 85-95° C., and most preferably to a temperature of 87-92° C., for about 1-3 hours, and the desired organosilicon compound can be obtained by separating it from the resulting product mixture. The result is a composition with improved color.
摘要翻译：一种制备式（RO）3-mRmSi-Alk-Sn-Alk-SiRm（OR）3-m的有机硅化合物的方法，其中R是具有1-12个碳原子的一价烃，Alk是具有1 -18个碳原子，m为0,1或2，n为2-8，优选为3-8。该方法通常包括以下步骤：（I）加热和（A）硫化物如M2Sn或MHS，其中H为氢，M为铵或碱金属，n为1-8; 与（B）式（RO）3-mRmSi-Alk-X的硅烷化合物，其中X为Cl，Br或I，m为0,1或2; 和（C）硫。步骤（I）在相转移催化剂和含有缓冲液或碱性化合物的水相存在下进行，以形成产物混合物。在步骤（II）中，将产物混合物再次加热至80-100℃，优选温度为85-95℃，最优选温度为87-92℃，约为 1-3小时，所需的有机硅化合物可以通过将其与所得产物混合物分离而获得。结果是具有改进颜色的组合物。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式