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    • 4. 发明授权
    • Homogeneous photosensitive optically variable ink compositions for ink jet printing
    • 用于喷墨印刷的均匀光敏光学可变油墨组合物
    • US06793723B2
    • 2004-09-21
    • US10143468
    • 2002-05-09
    • Judith D AuslanderJohn GriffithsJohn Mama
    • Judith D AuslanderJohn GriffithsJohn Mama
    • C09D1102
    • G06K19/06056C09D11/328C09D11/50C09K11/06C09K2211/1003C09K2211/1018
    • Ink compositions described are suitable for ink jet printing (ink jet inks) and are highly effective for simultaneously imparting visible and fluorescent images. In the preferred forms, both a dark, visible image and a complementary fluorescent image will be visually discernable as well as machine readable to enable efficient hand and automated processing or handling of the objects printed. These results are achieved by ink formulations that moderate the typically occurring phenomenon of quenching while possessing the physical properties necessary for an ink jet ink. In one form, the inks comprise a first colorant comprising at least one fluorescent dye, the fluorescent dye emitting light within a characteristic emission band when excited by fluorescent-exciting radiation; a second colorant having a light absorption band at longer wavelengths than the characteristic emission band of the first colorant, the second colorant comprising a water-soluble polymeric dye of effective molecular configuration to inhibit quenching of fluorescence of said first colorant due to collisional and resonance energy transfer with said second colorant; and an aqueous liquid vehicle comprising water and a water-soluble vehicle in sufficient amounts to achieve an ink viscosity and surface tension effective for application of the ink to a substrate in a predetermined pattern by ink jet printing. The colorants are present in combination in the aqueous ink in amounts effective to cause the ink, when dry, to exhibit a dark color due to the net absorption spectra of the colorants in the visual range and machine-readable or visually-discernable fluorescence when subjected to fluorescent-exciting radiation.
    • 所描述的油墨组合物适用于喷墨印刷(喷墨油墨),并且对于同时赋予可见光和荧光图像是非常有效的。 在优选的形式中,黑色,可见图像和互补的荧光图像将在视觉上可辨别以及机器可读性,以实现对打印物体的高效手动和自动处理或处理。 这些结果是通过调节通常发生的淬火现象的墨水配方实现的,同时具有喷墨油墨所需的物理特性。 在一种形式中,所述油墨包括包含至少一种荧光染料的第一着色剂,所述荧光染料在通过荧光激发辐射激发时发射特征发射带内的光; 第二着色剂具有比第一着色剂的特征发射带更长波长的光吸收带,第二着色剂包含有效分子构型的水溶性聚合染料,以抑制由于碰撞和共振能量而使所述第一着色剂的荧光猝灭 与所述第二着色剂一起转移; 以及含有足够量的水和水溶性载体的含水液体载体,以达到通过喷墨印刷以预定图案将油墨施加到基材上的油墨粘度和表面张力有效。 着色剂在水性油墨中的组合存在,以有效方式使油墨在干燥时由于着色剂在视觉范围内的净吸收光谱和机器可读或视觉辨别的荧光而呈现深色 到荧光激发辐射。