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1. 发明授权

US06680414B2 Process for the hydrogenation of hydroformylation mixtures 失效
标题翻译：加氢甲酰化混合物氢化的方法
公开(公告)号：US06680414B2
公开(公告)日：2004-01-20
申请号：US10014517
申请日：2001-12-14
申请人： Cord Knoop , Bernhard Scholz , Alfred Kaizik , Dietmar Gubisch , Joachim Schuler , Walter Tötsch , Wilfried Büschken
发明人： Cord Knoop , Bernhard Scholz , Alfred Kaizik , Dietmar Gubisch , Joachim Schuler , Walter Tötsch , Wilfried Büschken
IPC分类号： C07C2700
CPC分类号： C07C29/141 , C07C31/125
摘要： The present invention provides a process, which includes: in a homogeneous liquid phase including water, and over a fixed-bed catalyst, continuously hydrogenating at least one hydroformylation product obtained from a hydroformylation of one or more C4-16 olefins to produce at least one output mixture; wherein the fixed-bed catalyst includes at least one element of transition group eight of the Periodic Table of the Elements; wherein the output mixture includes at least one corresponding alcohol and from 0.05 to 10% by weight of water; and wherein in a steady-state operation of the process, from 3 to 50% more hydrogen is fed to the hydrogenation than is consumed by the hydrogenation.
摘要翻译：本发明提供了一种方法，其包括：在均匀的液相中包括水，并且在固定床催化剂上，连续氢化由一种或多种C 4-6-16烯烃的加氢甲酰化得到的至少一种加氢甲酰化产物，以产生至少一种输出混合物;其中固定床催化剂包括元素周期表第八族中至少一种元素;其中所述输出混合物包括至少一种相应的醇和0.05至10重量％的水;并且其中在该方法的稳态操作，比氢化消耗更多的氢被加入到氢化中3至50％。

2. 发明授权

US5646326A Alkylhydrogenchlorosilanes, process for their preparation and their use 失效
标题翻译：烷基氢氯硅烷，其制备及其用途
公开(公告)号：US5646326A
公开(公告)日：1997-07-08
申请号：US561320
申请日：1995-11-21
申请人： Joachim Schuler
发明人： Joachim Schuler
IPC分类号： B01J23/42 , B01J23/44 , B01J23/46 , B01J23/755 , C07B61/00 , C07F7/12 , C07F7/14 , C07F7/08
CPC分类号： C07F7/14 , C07F7/126
摘要： Alkylhydrogenchlorosilanes of formula IR.sub.(4-n-m) SiCl.sub.n H.sub.m (I),wherein m and n are each equal to 1 or 2 and m+n.ltoreq.3 and R is an alkyl group having from 1 to 5 carbon atoms, are prepared by reacting alkylchlorosilanes of formula IIR.sub.(4-p) SiCl.sub.p (II),wherein p is equal to 1, 2 or 3, with hydrogen.The alkylhydrogenchlorosilanes are employed as a starting material in hydrosilylation reactions.
摘要翻译：式IR（4-nm）SiClnHm（I）的烷基氢氯硅烷，其中m和n各自等于1或2，m + n <3，R是具有1至5个碳原子的烷基，由使式II R（4-p）SiClp（II）的烷基氯硅烷与氢反应，其中p等于1,2或3。在氢化硅烷化反应中使用烷基氢氯硅烷作为起始原料。

3. 发明授权

US06930213B1 Process for the hydrogenation of acetone 有权
标题翻译：丙酮氢化方法
公开(公告)号：US06930213B1
公开(公告)日：2005-08-16
申请号：US09618044
申请日：2000-07-17
申请人： Werner Pompetzki , Joachim Schuler , Dietrich Maschmeyer
发明人： Werner Pompetzki , Joachim Schuler , Dietrich Maschmeyer
IPC分类号： C07B61/00 , C07C29/145 , C07C31/10 , C07C29/136 , C07C29/143
CPC分类号： C07C29/145 , C07C31/10
摘要： Acetone is hydrogenated by a process comprising, conducting the liquid-phase hydrogenation of acetone in at least two hydrogenation process stages, thereby preparing isopropanol product with a high selectivity and in high purity.
摘要翻译：丙酮通过包括在至少两个氢化工艺阶段中进行丙酮的液相氢化的方法氢化，从而以高选择性和高纯度制备异丙醇产物。

4. 发明申请

US20090304948A1 ENVIRONMENTALLY FRIENDLY, SOLVENT-FREE PRINTING INK AND USE THEREOF 审中-公开
标题翻译：环保的无溶剂印刷油墨及其使用
公开(公告)号：US20090304948A1
公开(公告)日：2009-12-10
申请号：US12309901
申请日：2007-07-26
申请人： Markus Witter , Marion Homuth , Christian Tiller , Heiko Schneider , Joachim Schuler , Wolfgang Weiss
发明人： Markus Witter , Marion Homuth , Christian Tiller , Heiko Schneider , Joachim Schuler , Wolfgang Weiss
IPC分类号： B05D3/06 , C09D11/02
CPC分类号： C09D11/00 , B41M7/0072 , B41M7/009 , C03C17/42 , C03C2217/445 , C03C2217/485 , C09D11/03 , C09D11/36
摘要： The invention relates to an environmentally friendly, solvent-free printing ink, particular for printing single-pane safety glass, and also to its use in the form of a process for producing this printing, for example as an alternative way of achieving an in-line coloration of flat glass.The problem addressed by this invention, that of providing an environmentally-friendly, solvent-free printing ink, in particular for colored printing of a substrate, for example glass/single-pane safety glass, and also the use of this printing ink which avoids the disadvantages of the prior art is solved by the presence of a pigmented system in a lacquer slurry, the printing ink being water soluble and digitally printable, so that a process for producing a coating on glass using this printing ink comprising the steps of cleaning the glass surface (in glass washing system or manually by using special cleaner [comprising acetic acid]) pretreating the glass surface in a flame pyrolysis process to generate an SiOx layer (addition of siloxanes into the flame) applying an adhesion-promoting primer (primer) by air brush (adhesion promoter based on isopropanol and comprising silane as adhesion-promoting component) flushing the primer layer off (for about 5 min in the example) preparing the printed image with the invention's CPS by means of a commercial digital ink jet process curing the CPS by means of infrared, is made possible.
摘要翻译：本发明涉及一种环境友好的无溶剂印刷油墨，特别用于印刷单面板安全玻璃，并且还涉及其用于生产该印刷的方法的形式，例如作为实现印刷的另一种方法，平板玻璃线条着色。本发明解决的问题是提供一种环境友好的无溶剂印刷油墨，特别是用于诸如玻璃/单层玻璃安全玻璃的基材的着色印刷，以及避免使用这种印刷油墨现有技术的缺点通过在漆浆中存在着色系统来解决，印刷油墨是水溶性的并且可数字打印的，使得使用该印刷油墨在玻璃上生产涂层的方法包括以下步骤：玻璃表面（在玻璃洗涤系统中或通过使用特殊清洁剂（包含乙酸）手动地在玻璃表面进行火焰热解处理，以产生SiO x层（向火焰中加入硅氧烷），施加粘附促进底漆（底漆）通过空气刷（基于异丙醇的粘合促进剂和包含硅烷作为粘合促进成分）冲洗底漆层（在该实施例中约5分钟），制备pri 通过使用红外线固化CPS的商业数字喷墨工艺，使用本发明的CPS的图像成为可能。

5. 发明授权

US06239318B1 Process for the selective hydrogenation of hydroformylation mixtures 失效
标题翻译：加氢甲酰化混合物的选择性氢化方法
公开(公告)号：US06239318B1
公开(公告)日：2001-05-29
申请号：US09396210
申请日：1999-09-15
申请人： Joachim Schuler , Alfred Kaizik , Bernhard Scholz , Wilfried Bueschken , Wilhelm Droste
发明人： Joachim Schuler , Alfred Kaizik , Bernhard Scholz , Wilfried Bueschken , Wilhelm Droste
IPC分类号： C07C2916
CPC分类号： C07C31/125 , C07C29/141 , C07C29/16
摘要： The invention relates to a process for the selective hydrogenation of reaction mixtures from the hydroformylation of C5 to C24 olefins using hydrogen and a supported catalyst which, as active components, comprises copper, nickel and chromium.
摘要翻译：本发明涉及使用氢和作为活性组分包含铜，镍和铬的负载型催化剂从C5至C24烯烃的加氢甲酰化中选择氢化反应混合物的方法。

6. 发明授权

US5478791A Nickel/aluminum oxide catalyst, preparation thereof, use thereof and hydrogenation of aromatic hydrocarbons with the aid of the catalyst 失效
标题翻译：镍/氧化铝催化剂，其制备方法，借助催化剂氢化芳烃
公开(公告)号：US5478791A
公开(公告)日：1995-12-26
申请号：US221774
申请日：1994-04-01
申请人： Wolfgang Baldauf , Martin Rupp , Heinz Bolz , Hans-Gerd Luken , Joachim Schuler , Bernd Nowitzki
发明人： Wolfgang Baldauf , Martin Rupp , Heinz Bolz , Hans-Gerd Luken , Joachim Schuler , Bernd Nowitzki
IPC分类号： B01J23/755 , B01J33/00 , B01J35/02 , B01J35/10 , B01J37/00 , B01J37/14 , B01J37/18 , C07C5/10 , C10G45/48 , B01J21/04
CPC分类号： C10G45/48 , B01J23/755 , B01J35/023 , C07C5/10 , B01J33/00 , B01J35/006 , B01J35/1038 , B01J35/1042 , B01J35/108 , B01J37/0009 , B01J37/14 , B01J37/18 , C07C2521/04 , C07C2523/755
摘要： A nickel/aluminum oxide catalyst having a nickel content from 10 to 60% by weight, based on the total catalyst, in which the nickel is in the form of crystallites having an average diameter ranging from 15 nm to 50 nm.
摘要翻译：一种镍/铝氧化物催化剂，其镍含量为总催化剂的10-60重量％，其中镍为平均直径为15nm至50nm的微晶形式。

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