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    • 2. 发明授权
    • Structural object coated with superhydrophobic nanostructure composite and process for producing the same
    • 涂覆有超疏水纳米结构复合材料的结构物及其制造方法
    • US08017234B2
    • 2011-09-13
    • US12737128
    • 2009-05-25
    • Ren-Hua JinJian-Jun Yuan
    • Ren-Hua JinJian-Jun Yuan
    • D02G3/00
    • C09C1/30B08B17/065B82Y30/00C01P2004/03C01P2004/64C03C17/22C03C2217/76C09C1/3081Y10T428/1314Y10T428/2935
    • The present invention relates to a structural object coated with a superhydrophobic nanostructure composite, the structural object being obtained by densely coating a surface of a solid substrate having a desired shape with a nanostructure obtained by combining a polymer having a polyethyleneimine skeleton with silica on the nanometer order, and bonding a hydrophobic group to the surface of the nanostructure, and a process for producing the structural object. The present invention also relates to a structural object coated with a superhydrophobic nanostructure composite, the structural object being obtained by removing the polymer having the polyethyleneimine skeleton from the nanostructure and bonding a hydrophobic group to the surface of the residual nanostructure containing silica as a main constituent component, and a process for producing the structural object. Furthermore, the present invention provides a method of using the structural object as a container for transferring an aqueous solution.
    • 本发明涉及涂覆有超疏水纳米结构复合材料的结构物体,该结构物体通过将具有聚乙烯亚胺骨架的聚合物与二氧化硅在纳米上组合而获得的具有所需形状的固体基底的表面密集地涂覆而获得 将疏水性基团键合到纳米结构体的表面,以及制造该结构体的工序。 本发明还涉及一种涂覆有超疏水性纳米结构复合材料的结构物体,该结构物体是通过从纳米结构中除去具有聚乙烯亚胺骨架的聚合物而获得的,并将疏水基团结合到含有二氧化硅作为主要成分的残余纳米结构物的表面上 组件,以及用于生产结构对象的过程。 此外,本发明提供一种使用结构物作为水溶液转移容器的方法。
    • 3. 发明授权
    • Composite nanofiber, composite nanofiber association, complex structure, and production method thereof
    • 复合纳米纤维,复合纳米纤维关联,复合结构及其制备方法
    • US07670509B2
    • 2010-03-02
    • US11569300
    • 2005-05-27
    • Ren-Hua JinJian-Jun Yuan
    • Ren-Hua JinJian-Jun Yuan
    • H01B1/00
    • C08L79/02B82Y30/00D01F6/96D06M11/79D06M13/507D06M2101/30Y10T428/12035Y10T428/12174Y10T428/12438Y10T428/24603Y10T442/2885
    • A silica nanofiber is derived from a crystalline polymer filament of a polymer including straight chain polyethyleneimine backbones, which is capable of forming a water-insoluble crystal in the presence of water molecules at room temperature, and the crystalline polymer filament in the silica concentrates metal ions, thereby realizing a composite nanofiber including metals or metal ions in the silica. Furthermore, the composite nanofiber of the present invention can be easily produced by fixing a polymer structure in the silica as the scaffold for metal ions and concentrating metal ions at the scaffold or reducing the metal ions. Furthermore, a metal-containing silica nanofiber can be easily obtained by removing a polymer component from the composite nanofiber, the composite nanofiber association, and the complex nanofiber structure. These nanofibers can be assembled and integrated, and the assembled or integrated association or structure can realize various shapes.
    • 二氧化硅纳米纤维来源于包含直链聚乙烯亚胺骨架的聚合物的结晶聚合物长丝,其能够在室温下在水分子存在下形成水不溶性晶体,并且二氧化硅中的结晶聚合物长丝浓缩金属离子 从而实现在二氧化硅中包含金属或金属离子的复合纳米纤维。 此外,本发明的复合纳米纤维可以通过将二氧化硅中的聚合物结构固定在金属离子的支架上并将金属离子浓缩在支架上或还原金属离子而容易地制备。 此外,通过从复合纳米纤维,复合纳米纤维结合体和复合纳米纤维结构中除去聚合物组分,可以容易地获得含金属的二氧化硅纳米纤维。 这些纳米纤维可以组装和集成,并且组装或整合的关联或结构可以实现各种形状。
    • 7. 发明申请
    • STRUCTUAL OBJECT COATED WITH SUPERHYDROPHBIC NANOSTRUCTURE COMPOSITE AND PROCESS FOR PRODUCING THE SAME
    • 用超级纳米结构复合材料涂覆的结构物体及其制造方法
    • US20110160374A1
    • 2011-06-30
    • US12737128
    • 2009-05-25
    • Ren-Hua JinJian-Jun Yuan
    • Ren-Hua JinJian-Jun Yuan
    • C09D139/00B05D3/10B05D3/02B05D7/22B82Y30/00
    • C09C1/30B08B17/065B82Y30/00C01P2004/03C01P2004/64C03C17/22C03C2217/76C09C1/3081Y10T428/1314Y10T428/2935
    • The present invention relates to a structural object coated with a superhydrophobic nanostructure composite, the structural object being obtained by densely coating a surface of a solid substrate having a desired shape with a nanostructure obtained by combining a polymer having a polyethyleneimine skeleton with silica on the nanometer order, and bonding a hydrophobic group to the surface of the nanostructure, and a process for producing the structural object. The present invention also relates to a structural object coated with a superhydrophobic nanostructure composite, the structural object being obtained by removing the polymer having the polyethyleneimine skeleton from the nanostructure and bonding a hydrophobic group to the surface of the residual nanostructure containing silica as a main constituent component, and a process for producing the structural object. Furthermore, the present invention provides a method of using the structural object as a container for transferring an aqueous solution.
    • 本发明涉及涂覆有超疏水纳米结构复合材料的结构物体,该结构物体通过将具有聚乙烯亚胺骨架的聚合物与二氧化硅在纳米上组合而获得的具有所需形状的固体基底的表面密集地涂覆而获得 将疏水性基团键合到纳米结构体的表面,以及制造该结构体的工序。 本发明还涉及一种涂覆有超疏水性纳米结构复合材料的结构物体,该结构物体是通过从纳米结构中除去具有聚乙烯亚胺骨架的聚合物而获得的,并将疏水基团结合到含有二氧化硅作为主要成分的残余纳米结构物的表面上 组件,以及用于生产结构对象的过程。 此外,本发明提供一种使用结构物作为水溶液转移容器的方法。
    • 8. 发明申请
    • Composite nanofiber, composite nanofiber association, complex structure, and production method thereof
    • 复合纳米纤维,复合纳米纤维关联,复合结构及其制备方法
    • US20070197708A1
    • 2007-08-23
    • US11569300
    • 2005-05-27
    • Ren-Hua JinJian-Jun Yuan
    • Ren-Hua JinJian-Jun Yuan
    • C08K3/08
    • C08L79/02B82Y30/00D01F6/96D06M11/79D06M13/507D06M2101/30Y10T428/12035Y10T428/12174Y10T428/12438Y10T428/24603Y10T442/2885
    • A silica nanofiber is derived from a crystalline polymer filament of a polymer including straight chain polyethyleneimine backbones, which is capable of forming a water-insoluble crystal in the presence of water molecules at room temperature, and the crystalline polymer filament in the silica concentrates metal ions, thereby realizing a composite nanofiber including metals or metal ions in the silica. Furthermore, the composite nanofiber of the present invention can be easily produced by fixing a polymer structure in the silica as the scaffold for metal ions and concentrating metal ions at the scaffold or reducing the metal ions. Furthermore, a metal-containing silica nanofiber can be easily obtained by removing a polymer component from the composite nanofiber, the composite nanofiber association, and the complex nanofiber structure. These nanofibers can be assembled and integrated, and the assembled or integrated association or structure can realize various shapes.
    • 二氧化硅纳米纤维来源于包含直链聚乙烯亚胺骨架的聚合物的结晶聚合物长丝,其能够在室温下在水分子存在下形成水不溶性晶体,二氧化硅中的结晶聚合物长丝浓缩金属离子 从而实现在二氧化硅中包含金属或金属离子的复合纳米纤维。 此外,本发明的复合纳米纤维可以通过将二氧化硅中的聚合物结构固定在金属离子的支架上并将金属离子浓缩在支架上或还原金属离子而容易地制备。 此外,通过从复合纳米纤维,复合纳米纤维结合体和复合纳米纤维结构中除去聚合物组分,可以容易地获得含金属的二氧化硅纳米纤维。 这些纳米纤维可以组装和集成,并且组装或整合的关联或结构可以实现各种形状。
    • 10. 发明申请
    • NOVEL NANOPARTICLES
    • 新型纳米材料
    • US20100009001A1
    • 2010-01-14
    • US12438591
    • 2007-09-05
    • Steven ArmesJian-Jun Yuan
    • Steven ArmesJian-Jun Yuan
    • A61K9/14A61P43/00
    • A61K9/5089A61K9/501C08K3/36C08K9/00C08K9/02C08K9/12C08K2201/011C08K2201/013C08L53/00C08L2207/53C09D7/70G02B1/111Y10T428/254Y10T428/2998
    • The invention provides a composition comprising core-shell nanoparticles, the nanoparticles comprising (a) cationic core material comprising polymer; and (b) a shell material comprising silica. Preferred core materials comprise diblock copolymer micelles comprising one block of dialkylaminoethyl methacrylate units which are partially or fully quaternised and one block of dialkylaminoethyl methacrylate units that remain non-quaternised. The invention also provides a method for the preparation of the said composition, the method involving (a) preparing a cationic core material comprising polymer; and (b) coating the core material with a shell comprising silica by treating the polymer with a silica precursor under ambient conditions. The invention also envisages a composition comprising core-shell nanoparticles which is adapted to facilitate controlled delivery of at least one active agent into a system in response to controlled changes in the pH of the system.
    • 本发明提供包含核 - 壳纳米颗粒的组合物,所述纳米颗粒包含(a)包含聚合物的阳离子核心材料; 和(b)包含二氧化硅的壳材料。 优选的核心材料包括二嵌段共聚物胶束,其包含部分或全部季铵化的一个二烷基氨基乙基甲基丙烯酸酯单元和一个保持非季铵化的一个二烷基氨基乙基甲基丙烯酸酯单元。 本发明还提供了一种制备所述组合物的方法,所述方法包括(a)制备包含聚合物的阳离子核心材料; 和(b)在环境条件下用二氧化硅前体处理聚合物,用包含二氧化硅的壳涂覆芯材。 本发明还设想包含核 - 壳纳米颗粒的组合物,其适于响应于系统的pH的受控变化而促进至少一种活性剂被控制递送到系统中。