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    • 8. 发明授权
    • Production of carbon monoxide
    • 生产一氧化碳
    • US06592836B2
    • 2003-07-15
    • US09775976
    • 2001-02-02
    • Jeffrey Raymond HuftonShankar Nataraj
    • Jeffrey Raymond HuftonShankar Nataraj
    • C10K120
    • C01B32/40
    • A process is provided which includes the steps of providing a CO-SER unit, feeding a feed gas of an equimolar mix of CO2 and H2 with a slight excess of CO2 to the CO-SER unit to produce a CO-SER product gas of CO, a small amount of CO2, and substantially no H2 at high pressure, providing a TSA unit having a plurality of adsorber vessels, each adsorber vessel having an adsorbent capable of selectively adsorbing CO2, the adsorber vessel being at high pressure and ambient temperature, and feeding the CO-SER product gas to one of the adsorber vessels in the TSA unit to selectively remove CO2 gas to produce a TSA product gas that is of high purity and of high pressure. The feeding continues to the one adsorber vessel until a point prior to CO2 breakthrough occurring. The process further includes regenerating any adsorber vessels having adsorbent that is substantially spent.
    • 提供了一种方法,其包括提供CO-SER单元的步骤,将CO 2和CO 2的等摩尔混合物的进料气体与稍微过量的CO 2进料到CO-SER单元以产生CO-SER产物气体CO ,少量二氧化碳,并且在高压下基本上不含H2,提供具有多个吸附容器的TSA单元,每个吸附容器具有能够选择性吸附CO 2的吸附剂,吸附容器处于高压和环境温度,以及 将CO-SER产物气体供给到TSA单元中的一个吸附器容器以选择性地除去CO 2气体以产生高纯度和高压的TSA产物气体。 进料继续到一个吸附器容器直到发生二氧化碳突破之前的一个点。 该方法还包括再生具有基本上消耗的吸附剂的任何吸附容器。