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1. 发明授权

US08168806B2 Boron chelate complexes 有权
标题翻译：硼螯合物
公开(公告)号：US08168806B2
公开(公告)日：2012-05-01
申请号：US12634963
申请日：2009-12-10
申请人： Ulrich Wietelmann , Uwe Lischka , Klaus Schade , Jan-Christoph Panitz
发明人： Ulrich Wietelmann , Uwe Lischka , Klaus Schade , Jan-Christoph Panitz
IPC分类号： C07D311/00
CPC分类号： H01M10/0525 , C07F5/022 , C07F5/04 , H01G11/06 , H01G11/58 , H01M10/0568 , Y02E60/13
摘要： Boron chelate complexes of the general formula are described, where X is either —C(R1R2)— or —C(R1R2)—C(═O)—, in which R1, R2 independently of one another denote H, alkyl (with 1 to 5 C atoms), aryl, silyl or a polymer, and one of the alkyl radicals R1 or R2 may be bonded to a further chelatoborate radical, or X denotes 1,2-aryl with up to two substituents S in the positions 3 to 6 in which S1, S2 independently of one another denote alkyl (with 1 to 5 C atoms), fluorine or a polymer, as well as M+ denotes Li+, Na+, K+, Rb+, Cs+ or [(R3R4R5R6)N]+ or H+, where R3, R4, R5, R6 independently of one another denote H or alkyl with preferably 1 to 4 C atoms.
摘要翻译：描述了通式的硼螯合物，其中X是-C（R 1 R 2） - 或-C（R 1 R 2）-C（= O） - ，其中R 1，R 2彼此独立地表示H，烷基（具有1 至5个C原子），芳基，甲硅烷基或聚合物，并且其中一个烷基R1或R2可以与另一个螯合硼酸根键合，或X表示1,2-二芳基与最多两个取代基S在3至 6，其中S1，S2彼此独立地表示烷基（具有1至5个C原子），氟或聚合物，以及M +表示Li +，Na +，K +，Rb +，Cs +或[（R3R4R5R6）N] +或H + 其中R3，R4，R5，R6彼此独立地表示H或具有优选1至4个C原子的烷基。

2. 发明申请

US20100168476A1 BORON CHELATE COMPLEXES 有权
标题翻译： BORON CHELATE复合物
公开(公告)号：US20100168476A1
公开(公告)日：2010-07-01
申请号：US12634963
申请日：2009-12-10
申请人： Ulrich Wietelmann , Uwe Lischka , Klaus Schade , Jan-Christoph Panitz
发明人： Ulrich Wietelmann , Uwe Lischka , Klaus Schade , Jan-Christoph Panitz
IPC分类号： C07F5/02
CPC分类号： H01M10/0525 , C07F5/022 , C07F5/04 , H01G11/06 , H01G11/58 , H01M10/0568 , Y02E60/13
摘要： Boron chelate complexes of the general formula are described, whereX is either —C(R1R2)— or —C(R1R2)—C(═O)—, in which R1, R2 independently of one another denote H, alkyl (with 1 to 5 C atoms), aryl, silyl or a polymer, and one of the alkyl radicals R1 or R2 may be bonded to a further chelatoborate radical, or X denotes 1,2-aryl with up to two substituents S in the positions 3 to 6 in which S1, S2 independently of one another denote alkyl (with 1 to 5 C atoms), fluorine or a polymer, as well as M+ denotes Li+, Na+, K+, Rb+, Cs+ or [(R3R4R5R6)N]+ or H+, where R3, R4, R5, R6 independently of one another denote H or alkyl with preferably 1 to 4 C atoms.
摘要翻译：描述了通式的硼螯合物，其中X是-C（R 1 R 2） - 或-C（R 1 R 2）-C（= O） - ，其中R 1，R 2彼此独立地表示H，烷基（具有1 至5个C原子），芳基，甲硅烷基或聚合物，并且其中一个烷基R1或R2可以与另一个螯合硼酸根键合，或X表示1,2-二芳基与最多两个取代基S在3至 6，其中S1，S2彼此独立地表示烷基（具有1至5个C原子），氟或聚合物，以及M +表示Li +，Na +，K +，Rb +，Cs +或[（R3R4R5R6）N] +或H + 其中R3，R4，R5，R6彼此独立地表示H或具有优选1至4个C原子的烷基。

3. 发明授权

US07709663B2 Boron chelate complexes 有权
标题翻译：硼螯合物
公开(公告)号：US07709663B2
公开(公告)日：2010-05-04
申请号：US11355863
申请日：2006-02-16
申请人： Ulrich Wietelmann , Uwe Lischka , Klaus Schade , Jan-Christoph Panitz
发明人： Ulrich Wietelmann , Uwe Lischka , Klaus Schade , Jan-Christoph Panitz
IPC分类号： C07D311/00
CPC分类号： H01M10/0525 , C07F5/022 , C07F5/04 , H01G11/06 , H01G11/58 , H01M10/0568 , Y02E60/13
摘要： Boron chelate complexes of the general formula are described, where X is either —C(R1R2)— or —C(R1R2)—C(═O)—, in which R1, R2 independently of one another denote H, alkyl (with 1 to 5 C atoms), aryl, silyl or a polymer, and one of the alkyl radicals R1 or R2 may be bonded to a further chelatoborate radical, or X denotes 1,2-aryl with up to two substituents S in the positions 3 to 6 in which S1, S2 independently of one another denote alkyl (with 1 to 5 C atoms), fluorine or a polymer, as well as M+ denotes Li+, Na+, K+, Rb+, Cs+ or [(R3R4R5R6)N]+ or H+, where R3, R4, R5, R6 independently of one another denote H or alkyl with preferably 1 to 4 C atoms.
摘要翻译：描述了通式的硼螯合物，其中X是-C（R 1 R 2） - 或-C（R 1 R 2）-C（= O） - ，其中R 1，R 2彼此独立地表示H，烷基（具有1 至5个C原子），芳基，甲硅烷基或聚合物，并且其中一个烷基R1或R2可以与另一个螯合硼酸根键合，或X表示1,2-二芳基与最多两个取代基S在3至 6，其中S1，S2彼此独立地表示烷基（具有1至5个C原子），氟或聚合物，以及M +表示Li +，Na +，K +，Rb +，Cs +或[（R3R4R5R6）N] +或H + 其中R3，R4，R5，R6彼此独立地表示H或具有优选1至4个C原子的烷基。

4. 发明授权

US07674911B2 Method for the production of hydrogen-bis (chelato) borates and alkali metal-bis (chelato) borates 有权
标题翻译：制备氢 - 双（螯合）硼酸盐和碱金属 - 双（螯合）硼酸盐的方法
公开(公告)号：US07674911B2
公开(公告)日：2010-03-09
申请号：US11717969
申请日：2007-03-14
申请人： Ulrich Wietelmann , Uwe Lischka , Klaus Schade , Jan-Christoph Panitz
发明人： Ulrich Wietelmann , Uwe Lischka , Klaus Schade , Jan-Christoph Panitz
IPC分类号： C07D231/00
CPC分类号： C07F5/022 , C07F5/04
摘要： Methods are described for the production of hydrogen-bis(chelato)borates of the general formula H[BL1L2] and of alkali metal-bis(chelato)borates of the general formula M[BL1L2] where M=Li, Na, K, Rb, Cs L1=—OC(O)—(CR1R2)n—C(O)O— or —OC(O)—(CR3R4)—O— where n=0 or 1, R1, R2, R3, R4 independently of one another denote H, alkyl, aryl or silyl, L2=—OC(O)—(CR5R6)n—C(O)O— or —OC(O)—(CR7R8)—O— where n=0 or 1, R5, R6, R7, R8 independently of one another denote H, alkyl, aryl or silyl, wherein the respective raw materials are mixed in solid form without the addition of solvents and are reacted. Lithium-bis(oxalato)borate, lithium-bis(malonato)borate, caesium-bis-(oxalato)borate, caesium-bis-(malonato)borate and the mixed salts lithium(lactato,oxalato)borate and lithium(glycolato,oxalato)borate for example may be produced in this way.
摘要翻译：描述了用于制备通式为H [BL1L2]的氢 - 双（螯合）硼酸盐和通式M [BL1L2]的碱金属 - 双（螯合）硼酸盐的方法，其中M = Li，Na，K，Rb ，Cs L1 = -OC（O） - （CR1R2）n-C（O）O-或-OC（O） - （CR3R4）-O-，其中n = 0或1，R1，R2，R3，R4独立于彼此表示H，烷基，芳基或甲硅烷基，L 2 = -OC（O） - （CR 5 R 6）n -C（O）O-或-OC（O） - （CR 7 R 8）-O-，其中n = 0或1， R 5，R 6，R 7，R 8彼此独立地表示H，烷基，芳基或甲硅烷基，其中各原料以固体形式混合而不加入溶剂并反应。双（草酸）硼酸锂，双（丙二酸）硼酸锂，二（草酸）硼酸铯，双（丙二酸）硼酸铯和混合盐锂（乳酸，草酸）硼酸锂和锂（乙醇酸，草酸））硼酸盐可以以这种方式生产。

5. 发明申请

US20070269715A1 Conducting Salts for Galvanic Cells, the Production thereof and Their Use 有权
标题翻译：对电镀细胞进行盐渍化，生产和使用
公开(公告)号：US20070269715A1
公开(公告)日：2007-11-22
申请号：US10591509
申请日：2005-03-08
申请人： Jan-Christoph Panitz , Andreas Potschke , Rainer Dietz , Ulrich Wietelmann
发明人： Jan-Christoph Panitz , Andreas Potschke , Rainer Dietz , Ulrich Wietelmann
IPC分类号： H01M6/04
CPC分类号： H01M10/0568 , H01M2300/002
摘要： The invention relates to conducting salts which contain lithium bis(oxalato)borate (LiBOB) and mixed lithium borate salts of the type of formula the conducting salt is 0.01 to 20 mole-% and X in formula (I) is a bridge linked with the boron via two oxygen atoms, selected from formula (II), wherein Y1 and Y2 together=O, m=1, n=0 and Y3 and Y4 independently represent H or an alkyl group with 1 to 5 C atoms, or Y1, Y2, Y3, Y4 independently represent OR (with R=alkyl group with to 5 C atoms), or H or an alkyl group with 1 to 5 C atoms, and wherein m=0 or 1, n=0 or 1, or Y2 and Y3 are members of a 5- or 6-membered aromatic or heteroaromatic ring (with N, O or S as the hetero element) which can be optionally substituted with alkyl, alkoxy, carboxy or nitrile, and if so, Y1 and Y4 are not applicable and n>0, m=0 or 1. The invention also relates to a method for producing the inventive conducting salts.
摘要翻译：本发明涉及含有双（草酸）硼酸锂（LiBOB）的锂盐和导电盐的混合硼酸锂盐，其导电盐为0.01至20摩尔％，式（I）中的X为与选自式（II）中的两个氧原子的硼，其中Y 1和Y 2一起= O，m = 1，n = 0和Y 3 Y 4和Y 4独立地表示H或具有1至5个C原子的烷基或Y 1，Y 2，Y Y 4独立地表示OR（R =烷基至5个C原子）或H或具有1至5个C原子的烷基，其中m = 0或1，n = 0或1，或Y 2和Y 3是5或6元芳族或杂芳族环（N，O 或S作为杂原子），其可以任选被烷基，烷氧基，羧基或腈取代，如果是，Y 1和Y 4不适用，并且n> 0，m = 0或1.本发明还涉及一种方法引起本发明的导电盐。

6. 发明申请

US20070166622A1 Method for the production of hydrogen-bis (chelato) borates and alkali metal-bis (chelalo) borates 有权
标题翻译：制备氢 - 双（螯合）硼酸盐和碱金属 - 双（螯合）硼酸盐的方法
公开(公告)号：US20070166622A1
公开(公告)日：2007-07-19
申请号：US11717969
申请日：2007-03-14
申请人： Ulrich Wietelmann , Uwe Lischka , Klaus Schade , Jan-Christoph Panitz
发明人： Ulrich Wietelmann , Uwe Lischka , Klaus Schade , Jan-Christoph Panitz
IPC分类号： H01M6/16 , C07F5/04
CPC分类号： C07F5/022 , C07F5/04
摘要： Methods are described for the production of hydrogen-bis(chelato)borates of the general formula H[BL1L2] and of alkali metal-bis(chelato)borates of the general formula M [BL1L2] where M=Li, Na, K, Rb, Cs L1=—OC(O)—(CR1R2)n—C(O)O— or —OC(O)—(CR3R4)—O—where n=0 or 1, R1, R2, R3, R4 independently of one another denote H, alkyl, aryl or silyl, L2=—OC(O)—(CR5R6)n—C(O)O— or —OC(O)—(CR7R8)—O—where n=0 or 1, R5, R6, R7, R8 independently of one another denote H, alkyl, aryl or silyl, wherein the respective raw materials are mixed in solid form without the addition of solvents and are reacted. Lithium-bis (oxalato) borate, lithium-bis (malonato)borate, caesium-bis-(oxalato)borate, caesium-bis-(malonato)borate and the mixed salts lithium (lactato, oxalato) borate and lithium(glycolato,oxalato)borate for example may be produced in this way.
摘要翻译：描述了用于生产通式为H [BL 1 L 2]的氢 - 双（螯合）硼酸盐和碱金属 - 双（螯合）硼酸盐的碱金属 - 双（螯合）硼酸盐的方法，通式M [BL 1]其中M = Li，Na，K，Rb，Cs L 1 = - OC（O ） - （CR 1）R 2 - （O）O-或-OC（O） - （CR 3）其中n = 0或1，R 1，R 2，R 3， R 4彼此独立地表示H，烷基，芳基或甲硅烷基，L 2 = -OC（O） - （CR 5）（O）O-或-OC（O） - （CR 7 R 8） / SUP>）-O-其中n = 0或1，R 5，R 6，R 7，R 8，彼此独立地表示H，烷基，芳基或甲硅烷基，其中相应的原料以固体形式混合而不加入溶剂并反应。双（草酸）硼酸锂，双（丙二酸）硼酸锂，二（草酸）硼酸铯，双（丙二酸）硼酸铯和混合盐锂（乳酸，草酸）硼酸锂和锂（乙醇酸，草酸））硼酸盐可以以这种方式生产。

7. 发明授权

US07226704B2 Electrolytes for lithium ion batteries 有权
标题翻译：锂离子电池用电解液
公开(公告)号：US07226704B2
公开(公告)日：2007-06-05
申请号：US10469471
申请日：2002-03-05
申请人： Jan-Christoph Panitz , Ulrich Wietelmann , Markus Scholl
发明人： Jan-Christoph Panitz , Ulrich Wietelmann , Markus Scholl
IPC分类号： H01M6/16
CPC分类号： H01M10/0525 , H01M6/166 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M2300/0037
摘要： Electrolytes containing lithium-bis(oxalato)borate, a cyclic carbonate, one or more compounds selected from acrylic carbonates, aliphatic esters, alicyclic ethers and aliphatic, difunctional ethers, one or more compounds selected from lactones, dinitriles, compounds that contain at least one carboxylic acid ester group and an ether group, compounds that contain at least one carbonic acid group and an ether group, compounds that contain at least one nitrile group and an ether group, trialkyl phosphoric acid esters and trialkyl boric acids.
摘要翻译：含有双（草酸）硼酸锂的电解质，环状碳酸酯，一种或多种选自丙烯酸碳酸酯，脂族酯，脂环族醚和脂族二官能醚的化合物，一种或多种选自内酯，二腈的化合物，含有至少一种羧酸酯基和醚基，含有至少一个碳酸基和醚基的化合物，含有至少一个腈基和醚基的化合物，三烷基磷酸酯和三烷基硼酸。

8. 发明授权

US07208131B2 Method for the production of hydrogen-bis(chelato) borates and alkali metal-bis(chelato)borates 有权
标题翻译：制备氢 - 双（螯合）硼酸盐和碱金属 - 双（螯合）硼酸盐的方法
公开(公告)号：US07208131B2
公开(公告)日：2007-04-24
申请号：US10467838
申请日：2002-02-15
申请人： Ulrich Wietelmann , Uwe Lischka , Klaus Schade , Jan-Christoph Panitz
发明人： Ulrich Wietelmann , Uwe Lischka , Klaus Schade , Jan-Christoph Panitz
IPC分类号： C01B35/10
CPC分类号： C07F5/022 , C07F5/04
摘要： Methods are described for the production of hydrogen-bis(chelato)borates of the general formula H[BL1L2] and of alkali metal-bis(chelato)borates of the general formula M[BL1L2] where M=Li, Na, K, Rb, Cs L1=—OC(O)—(CR1R2)n—C(O)O— or —OC(O)—(CR3R4)—O— where n=0 or 1, R1, R2, R3, R4 independently of one another denote H, alkyl, aryl or silyl, L2=—OC(O)—(CR5R6)n—C(O)O— or —OC(O)—(CR7R8)—O— where n=0 or 1, R5, R6, R7, R8 independently of one another denote H, alkyl, aryl or silyl, wherein the respective raw materials are mixed in solid form without the addition of solvents and are reacted. Lithium-bis(oxalato)borate, lithium-bis(malonato)borate, caesium-bis-(oxalato)borate, caesium-bis-(malonato)borate and the mixed salts lithium(lactato,oxalato)borate and lithium(glycolato,oxalato)borate for example may be produced in this way.
摘要翻译：描述了用于生产通式为H [BL 1 L 2]的氢 - 双（螯合）硼酸盐和碱金属 - 双（螯合）硼酸盐的碱金属 - 双（螯合）硼酸盐的方法，通式M [BL 1]其中M = Li，Na，K，Rb，Cs L 1 = - OC（O ） - （CR 1）R 2 - （O）O-或-OC（O） - （CR 3） R 4，其中n = 0或1，R 1，R 2，R 3， R 4彼此独立地表示H，烷基，芳基或甲硅烷基，L 2 = -OC（O） - （CR 5）（O）O-或-OC（O） - （CR 7 R 8） / SUP）） - O-，其中n = 0或1，R 5，R 6，R 7，R 8，彼此独立地表示H，烷基，芳基或甲硅烷基，其中相应的原料以固体形式混合而不加入溶剂并反应。双（草酸）硼酸锂，双（丙二酸）硼酸锂，二（草酸）硼酸铯，双（丙二酸）硼酸铯和混合盐锂（乳酸，草酸）硼酸锂和锂（乙醇酸，草酸））硼酸盐可以以这种方式生产。

9. 发明申请

US20060142608A1 Boron chelate complexes 有权
标题翻译：硼螯合物
公开(公告)号：US20060142608A1
公开(公告)日：2006-06-29
申请号：US11355863
申请日：2006-02-16
申请人： Ulrich Wietelmann , Uwe Lischka , Klaus Schade , Jan-Christoph Panitz
发明人： Ulrich Wietelmann , Uwe Lischka , Klaus Schade , Jan-Christoph Panitz
IPC分类号： C07F5/04
CPC分类号： H01M10/0525 , C07F5/022 , C07F5/04 , H01G11/06 , H01G11/58 , H01M10/0568 , Y02E60/13
摘要： Boron chelate complexes of the general formula are described, where X is either —C(R1R2)— or —C(R1R2)—C(═O)—, in which R1, R2 independently of one another denote H, alkyl (with 1 to 5 C atoms), aryl, silyl or a polymer, and one of the alkyl radicals R1 or R2 may be bonded to a further chelatoborate radical, or X denotes 1,2-aryl with up to two substituents S in the positions 3 to 6 in which S1, S2 independently of one another denote alkyl (with 1 to 5 C atoms), fluorine or a polymer, as well as M+ denotes Li+, Na+, K+, Rb+, Cs+ or [(R3R4R5R6)N]+ or H+, where R3, R4, R5, R6 independently of one another denote H or alkyl with preferably 1 to 4 C atoms.
摘要翻译：描述了通式的硼螯合络合物，其中X为-C（R 1，R 2） - 或-C（R 1）其中R 1，R 2彼此独立地表示H，烷基（具有1个至5个C原子），芳基，甲硅烷基或聚合物，并且其中一个烷基R 1或R 2可以与另一个螯合硼酸根键合，或X表示在其中S 1，S 2，3彼此独立的3至6位中具有至多两个取代基S的2-芳基表示烷基（具有1至5个碳原子原子），氟或聚合物，以及M + +表示Li +， - ， - ， - ，，Rb + +或/（R 3），R 4，R 5，...，其中R 3，R 4，...，N 2，...，N 2， >，R 5，R 6彼此独立地表示H或具有优选1至4个C原子的烷基。

10. 发明授权

US08945778B2 Conducting salts for galvanic cells, the production thereof and their use 有权
标题翻译：导电电池的盐，其生产和使用
公开(公告)号：US08945778B2
公开(公告)日：2015-02-03
申请号：US10591509
申请日：2005-03-08
申请人： Jan-Christoph Panitz , Andreas Pötschke , Rainer Dietz , Ulrich Wietelmann
发明人： Jan-Christoph Panitz , Andreas Pötschke , Rainer Dietz , Ulrich Wietelmann
IPC分类号： H01M10/0562 , H01M6/04 , H01M10/0568
CPC分类号： H01M10/0568 , H01M2300/002
摘要： The invention relates to conducting salts which contain lithium bis(oxalato)borate (LiBOB) and mixed lithium borate salts of the type of formula (I), wherein the portion of compound (I) in the conducting salt is 0.01 to 20 mole-% and X in formula (I) is a bridge linked with the boron via two oxygen atoms, selected from formula (II), wherein Y1 and Y2 together=O, m=1, n=0 and Y3 and Y4 independently represent H or an alkyl group with 1 to 5 C atoms, or Y1, Y2, Y3, Y4 independently represent OR (with R=alkyl group with to 5 C atoms), or H or an alkyl group with 1 to 5 C atoms, and wherein m=0 or 1, n=0 or 1, or Y2 and Y3 are members of a 5- or 6-membered aromatic or heteroaromatic ring (with N, O or S as the hetero element) which can be optionally substituted with alkyl, alkoxy, carboxy or nitrile, and if so, Y1 and Y4 are not applicable and n>0, m=0 or 1. The invention also relates to a method for producing the inventive conducting salts.
摘要翻译：本发明涉及含有双（草酸）硼酸锂（LiBOB）和式（I）类型的混合硼酸锂盐的导电盐，其中导电盐中化合物（I）的部分为0.01至20摩尔％式（I）中的X是通过选自式（II）的两个氧原子与硼连接的桥，其中Y1和Y2一起= O，m = 1，n = 0，Y 3和Y 4独立地表示H或具有1至5个C原子的烷基或Y1，Y2，Y3，Y4独立地表示OR（其中R =具有至5个C原子的烷基）或H或具有1至5个C原子的烷基，其中m = 0或1，n = 0或1，或Y 2和Y 3是5-或6-元芳族或杂芳族环（其中N，O或S作为杂元素）的成员，其可任选被烷基，烷氧基，羧基或腈，如果是，则Y1和Y4不适用，n> 0，m = 0或1.本发明还涉及制备本发明的导电盐的方法。

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