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    • 5. 发明授权
    • Microporous membranes having increased pore densities and process for
making the same
    • 具有增加孔密度的微孔膜及其制造方法
    • US5013439A
    • 1991-05-07
    • US433450
    • 1989-11-09
    • Harold M. FisherDaniel E. LeoneJames J. Lowery
    • Harold M. FisherDaniel E. LeoneJames J. Lowery
    • B01D67/00C08J5/18D01D5/24
    • D01D5/24B01D67/0027B01D69/08B01D71/26C08J5/18B01D2323/08B01D2325/02B01D2325/20
    • Disclosed are a process for forming an open-celled microporous membrane (e.g., in film or fiber form) and a novel microporous membrane formed thereby. The process generally includes sequential cold and hot stretching operations, whereby the cold stretching operation is preferably accomplished in a plurality of discrete cold stretching steps. In this regard, the total cold stretch extension is of greater than about 30 percent, and advantageously greater than about 40 percent based upon the initial unstretched length of the nonporous precursor, with this total cold stretch ratio being distributed among a plurality of discrete cold stretching steps. The novel membranes of this invention are characterized by decreased pore size and increased pore densities. For example, the membranes of this invention will have an average pore radius as determined by mercury porosimetry of less than about 0.040 micron. The membranes of this invention, moreover, exhibit a distinctive "bluish" color hue (i.e., a Macbeth Coloreye.TM. b* value of less than about -10 as determined by placing a single ply sample of the membrane against a black background).
    • 公开了一种用于形成开孔微孔膜(例如,膜或纤维形式)和由其形成的新型微孔膜的方法。 该方法通常包括顺序冷和热拉伸操作,由此冷拉伸操作优选在多个分立的冷拉伸步骤中完成。 在这方面,基于无孔前体的初始未拉伸长度,总冷拉伸延伸率大于约30%,有利地大于约40%,其总冷拉伸比分布在多个离散冷拉伸 脚步。 本发明的新型膜的特征在于孔径减小和孔密度增加。 例如,本发明的膜将具有通过小于约0.040微米的水银孔率法测定的平均孔半径。 此外,本发明的膜表现出独特的“蓝色”色调(即,通过将膜的单层样品放置在黑色背景上来确定的小于约-10的Macbeth Coloreye TM b *值)。