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1. 发明授权

US4390710A Catalyst system for manufacturing p-chlorophenyl-N-methyl carbamate 失效
标题翻译：用于制备对氯苯基-N-甲基氨基甲酸酯的催化剂体系
公开(公告)号：US4390710A
公开(公告)日：1983-06-28
申请号：US312207
申请日：1981-10-19
申请人： James A. Manner
发明人： James A. Manner
IPC分类号： C07C271/06 , C07D307/77 , C07C125/06 , C07D317/08
CPC分类号： C07D307/77 , C07C271/06
摘要： Aromatic esters of carbamic acid derivatives, e.g., p-chlorophenyl-N-methyl carbamate, are prepared by reaction of the corresponding aromatic alcohol, e.g., p-chlorophenol, and monoisocyanate, e.g., methyl isocyanate, in the presence of a catalytic amount of a combination of a 4-aminopyridine catalyst, e.g., 4-dimethylaminopyridine, and pyridine or methyl substituted pyridines. The product is substantially pure, having less than 0.80 weight percent allophanate ester by-product, e.g., p-chlorophenyl-N,N'-dimethyl allophanate, and less than 0.50 weight percent unreacted aromatic alcohol, e.g., p-chlorophenol. The reaction is readily controlled and characterized by the substantial absence of reflux. The product can be retained in the liquid state at reaction temperature for extended periods of time without significantly increasing the level of allophanate ester by-product.
摘要翻译：氨基甲酸衍生物的芳族酯，例如对氯苯基-N-甲基氨基甲酸酯，通过相应的芳族醇例如对氯苯酚和单异氰酸酯例如甲基异氰酸酯在催化量的 4-氨基吡啶催化剂，例如4-二甲基氨基吡啶和吡啶或甲基取代的吡啶的组合。该产品基本上是纯的，具有小于0.80重量％的脲基甲酸酯副产物，例如对氯苯基-N，N'-二甲基脲基甲酸酯和小于0.50重量％的未反应芳族醇，例如对氯苯酚。反应容易控制，并且基本上没有回流而表征。产物可以在反应温度下保持在液态较长时间，而不会显着提高脲基甲酸酯副产物的含量。

2. 发明授权

US4031126A Drying of dialkyl peroxydicarbonates 失效
标题翻译：干燥过氧化二碳酸二烷基酯
公开(公告)号：US4031126A
公开(公告)日：1977-06-21
申请号：US657526
申请日：1976-02-12
申请人： James A. Manner
发明人： James A. Manner
IPC分类号： C07C407/00 , C07C68/08
CPC分类号： C07C407/003
摘要： Dialkyl peroxydicarbonates are prepared in aqueous reaction media, washed with water, and then dried with sodium sulfate, calcium chloride, or the like. Peroxydicarbonates, particularly heat-sensitive peroxydicarbonates, may be dried safely and more effectively with the use of molecular sieves by contacting substantially phase water free peroxydicarbonate with sieves. Contact between heat-sensitive peroxydicarbonate and sieves should be effected in a way that avoids abrupt, excessive warming of peroxydicarbonate.
摘要翻译：在含水反应介质中制备过氧二碳酸二烷基酯，用水洗涤，然后用硫酸钠，氯化钙等进行干燥。过氧碳酸氢盐，特别是热敏性过氧化二碳酸酯，可以通过使基本相不含水的过氧化二碳酸酯与筛子接触而使用分子筛安全地和更有效地干燥。热敏过氧化二碳酸酯和筛子之间的接触应以避免过度二碳酸酯突然，过度升温的方式进行。

3. 发明授权

US3998888A Synthesis of sulfonyl peroxides 失效
标题翻译：磺酰过氧化物的合成
公开(公告)号：US3998888A
公开(公告)日：1976-12-21
申请号：US631008
申请日：1975-11-12
申请人： James A. Manner
发明人： James A. Manner
IPC分类号： C07C409/44 , C07C147/00
CPC分类号： C07C407/00 , C07C2101/14
摘要： Sulfonyl peroxides represented by the formula ##STR1## wherein R and R' independently are alkyl, cycloalkyl, or substituted alkyl or cycloalkyl groups having 1 to 20 carbons, are prepared in a liquid reaction phase by the sulfoxidation of an alkane or cycloalkane reactant with SO.sub.2 and O.sub.2 and acylation of the sulfoxidation product with a carboxylic acid anhydride. In the practice of this invention, an inert, immiscible organic solvent for the sulfonyl peroxide is introduced into the liquid reaction phase to dissolve the peroxide as it is formed and to produce a lower crude product phase containing the sulfonyl peroxide already dissolved in the inert solvent.

4. 发明授权

US06239281B1 Process for preparing carbamoyl pyridinium compounds 失效
标题翻译：制备氨基甲酰吡啶鎓化合物的方法
公开(公告)号：US06239281B1
公开(公告)日：2001-05-29
申请号：US09468019
申请日：1999-12-20
申请人： Charles B. Kreutzberger , James A. Manner , Wendy E. Wallace
发明人： Charles B. Kreutzberger , James A. Manner , Wendy E. Wallace
IPC分类号： C07D21304
CPC分类号： C07D213/34
摘要： Novel process for preparing carbamoyl pyridinium compounds using novel solvent/fatty amine reaction systems.
摘要翻译：使用新的溶剂/脂肪胺反应体系制备氨基甲酰吡啶鎓化合物的新方法。

5. 发明授权

US5371264A Process for preparing N,O-disubstituted hydroxylamine compounds 失效
标题翻译：制备N，O-二取代羟胺化合物的方法
公开(公告)号：US5371264A
公开(公告)日：1994-12-06
申请号：US9528
申请日：1993-01-27
申请人： James A. Manner , Suresh B. Damle
发明人： James A. Manner , Suresh B. Damle
IPC分类号： C07C239/22 , C07C269/04 , C07C271/00 , C07C275/64 , C07C69/96
CPC分类号： C07C275/64 , C07C239/22 , C07C269/04 , C07C271/00
摘要： Describes a process for preparing N,O-disubstituted hydroxylamine compounds comprising reacting an aqueous solution of free hydroxylamine with an equimolar amount of a carbonyl halide-containing compound, e.g., a chloroformate such as phenyl chloroformate, in the presence of a substantially stoichiometric amount of a weak inorganic basic reagent, thereby to produce the N-substituted derivative, and thereafter further reacting an inert organic solvent solution of the N-substituted derivative with an equimolar amount of the corresponding carbonyl halide-containing compound in the presence of a substantially stoichiometric amount of weak inorganic basic reagent, thereby to produce the N,O-disubstituted derivative, e.g., N,O-bis(phenoxycarbonyl) hydroxylamine. In a preferred embodiment, the organic solvent is used also in the reaction that produces the N-substituted derivative. N,O-disubstituted hydroxylamine compounds containing less than 3 weight percent, e.g., less than 0.5 weight percent, of the hydrolysis by-product of the carbonyl halide-containing compound may be produced thereby.
摘要翻译：描述了制备N，O-二取代的羟胺化合物的方法，包括使游离羟胺的水溶液与等摩尔量的含羰基卤化合物，例如氯甲酸酯如氯甲酸苯酯，在基本上化学计量的弱的无机碱性试剂，从而产生N-取代的衍生物，然后在基本上化学计量的存在下，使N-取代的衍生物的惰性有机溶剂溶液与等摩尔量的相应的含羰基卤化合物进一步反应的弱无机碱性试剂，从而产生N，O-二取代的衍生物，例如N，O-双（苯氧基羰基）羟胺。在优选的实施方案中，有机溶剂也用于产生N-取代的衍生物的反应中。因此可以制备含有小于3重量％，例如小于0.5重量％的含羰基卤化合物的水解副产物的N，O-二取代羟胺化合物。

6. 发明授权

US4814524A Method for converting organic chloroformate to the corresponding organic chloride 失效
标题翻译：将有机氯甲酸酯转化为相应的有机氯化物的方法
公开(公告)号：US4814524A
公开(公告)日：1989-03-21
申请号：US891096
申请日：1986-07-31
申请人： Robert G. Briody , James A. Manner
发明人： Robert G. Briody , James A. Manner
IPC分类号： C07C17/363 , C07C17/24
CPC分类号： C07C17/363
摘要： Organic haloformate, e.g., chloroformate, compounds are converted to their corresponding halides, e.g., chlorides, by heating the haloformate, e.g., between 90.degree. C. and 150.degree. C., in the presence of a catalytic amount of an organic quaternary salt, e.g., quaternary ammonium or phosphonium salts, for a time sufficient to convert the haloformate to the corresponding halide.
摘要翻译：有机卤代甲酸酯，例如氯甲酸酯，通过加热卤代甲酸酯，例如在90℃至150℃之间，在催化量的有机季盐存在下将化合物转化成其相应的卤化物，例如氯化物，例如季铵或鏻盐，足以将卤代甲酸酯转化为相应的卤化物。

7. 发明授权

US5019659A Method of separating 2-nitrosophenol isomer from admixture with 4-nitrosophenol isomer 失效
标题翻译：将2-亚硝基苯酚异构体与4-亚硝基苯酚异构体混合分离的方法
公开(公告)号：US5019659A
公开(公告)日：1991-05-28
申请号：US569115
申请日：1990-08-17
申请人： James A. Manner , Charles H. Hoelscher
发明人： James A. Manner , Charles H. Hoelscher
IPC分类号： C07C201/00
CPC分类号： C07C201/00
摘要： Disclosed is a method for selectively separating 2-nitrosophenol from an isomeric mixture containing 2-nitrosophenol and 4-nitrosophenol by contacting the mixture with an organic solvent so as to preferentially dissolve the 2-nitrosophenol from the mixture.
摘要翻译：公开了通过使混合物与有机溶剂接触以从混合物中优先溶解2-亚硝基苯酚，从含有2-亚硝基苯酚和4-亚硝基苯酚的异构体混合物中选择性分离2-亚硝基苯酚的方法。

8. 发明授权

US4714785A Method for converting organic chloroformate to the corresponding organic chloride 失效
标题翻译：将有机氯甲酸酯转化为相应的有机氯化物的方法
公开(公告)号：US4714785A
公开(公告)日：1987-12-22
申请号：US907246
申请日：1986-09-15
申请人： James A. Manner
发明人： James A. Manner
IPC分类号： C07C17/363 , C07C41/18 , C07C41/01 , C07C17/00 , C07C19/02
CPC分类号： C07C17/363 , C07C41/18
摘要： Organic haloformate, e.g., chloroformate, compounds are converted to their corresponding halides, e.g., chlorides, by heating the haloformate, e.g., between 90.degree. C. and 150.degree. C., in the presence of a catalytic amount of a carbon catalyst for a time sufficient to convert the haloformate to the corresponding halide.
摘要翻译：有机卤代甲酸酯，例如氯甲酸酯，通过加热卤代甲酸酯，例如在90℃至150℃之间，在催化量的碳催化剂存在下将化合物转化成其相应的卤化物，例如氯化物，用于足以将卤代甲酸酯转化为相应的卤化物。

9. 发明授权

US4026956A Storage stabilized methylchloroform formulations 失效
标题翻译：储存稳定甲基氯仿制剂
公开(公告)号：US4026956A
公开(公告)日：1977-05-31
申请号：US585989
申请日：1975-06-11
申请人： James A. Manner
发明人： James A. Manner
IPC分类号： C07C17/42 , C07C17/40
CPC分类号： C07C17/42
摘要： Methylchloroform formulations containing 1,3-dioxolanes and/or 1,4-dioxane are storage-stabilized by the addition of aliphatic aldehyde hydrazone.
摘要翻译：含有1,3-二氧戊环和/或1,4-二恶烷的甲基氯仿制剂通过加入脂族醛腙来储存稳定。

10. 发明授权

US3985720A Polymerization of ethylenically unsaturated monomer employing a catalyst system comprising dialkylpyrocarbonate, organic acid anhydride, alkaline reagent and H.sub.2 O.sub.2 失效
标题翻译：使用包含焦磷酸二烷基酯，有机酸酐，碱性试剂和H {HD 2 {B O {HD 2
公开(公告)号：US3985720A
公开(公告)日：1976-10-12
申请号：US582499
申请日：1975-05-30
申请人： James A. Manner
发明人： James A. Manner
IPC分类号： C08F2/00 , C08F4/28 , C08F114/02 , C08F114/16 , C08G2/00 , C08G63/12
CPC分类号： C08F4/28 , Y10S260/28
摘要： Ethylenically unsaturated material susceptible to free-radical polymerization, e.g., vinyl chloride monomer, is polymerized, e.g., in an aqueous medium, with an initiator system comprising, in combination, alkaline reagent, e.g., sodium bicarbonate, organic acid anhydride, e.g., isobutyric anhydride, peroxygen compound selected from organic peroxy acid (peracid), e.g., peracetic acid, and hydrogen peroxide, and alkyl pyrocarbonate, e.g., diethyl pyrocarbonate. The initiator system is added to the polymerization medium in amounts sufficient to polymerize the ethylenically unsaturated material.
摘要翻译：易于自由基聚合的烯键式不饱和物质，例如氯乙烯单体，例如在含水介质中聚合，引发剂体系组合包含碱性试剂，例如碳酸氢钠，有机酸酐，例如异丁酸酸酐，选自有机过氧酸（过酸）的过氧化合物，例如过乙酸和过氧化氢，以及焦碳酸烷基酯，例如焦碳酸二乙酯。将引发剂体系以足以聚合烯属不饱和材料的量加入到聚合介质中。

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