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    • 1. 发明申请
    • METHOD OF COMPENSATING FREQUENCY DRIFT IN AN INTERFEROMETER
    • 在干扰仪中补偿频率干扰的方法
    • WO2013056726A1
    • 2013-04-25
    • PCT/EP2011/068117
    • 2011-10-17
    • FOSS ANALYTICAL A/SJUHL, Henrik Vilstrup
    • JUHL, Henrik Vilstrup
    • G01J3/45
    • G01J3/45G01J2003/283
    • A method of compensating for frequency drift of a reference energy source in an FT interferometer based spectrometer instrument having an arithmetic unit into which has been obtained data representing a reference interferogram (40) collected in response to a trigger signal having been generated in dependence on the emission frequency of the reference energy source and data representing a target interferogram (42) recorded by the FT interferometer in response to a trigger signal also having been generated in dependence on the emission frequency of the reference energy source in the same manner. The method further comprises the comparing in the arithmetic unit the data representing the reference interferogram (40) and the data representing the target interferogram (42) to determining a phase shift (d) between the interferograms in a window W in at least one region (36) away from center-burst (44) and generating in the arithmetic unit a mathematical transform dependent on the determined shift or shifts (d) to be subsequently applied to control the operation of the spectrometer instrument in order to generate data representing a frequency stabilized interferogram of an unknown sample recorded by the FT interferometer.
    • 一种在具有算术单元的基于FT干涉仪的光谱仪器中补偿参考能量源的频率漂移的方法,其中已经获得表示根据已经根据所述基准干涉仪产生的触发信号而收集的参考干涉图(40)的数据 参考能量源的发射频率和由FT干涉仪记录的响应于也以相同方式根据参考能量源的发射频率产生的触发信号的目标干涉图(42)的数据。 该方法还包括在运算单元中比较表示参考干涉图(40)的数据和表示目标干涉图(42)的数据,以确定至少一个区域中的窗口W中的干涉图之间的相移(d) 36)远离中心突发(44)并且在算术单元中产生依赖于所确定的移位或移位(d)的数学变换,以便随后应用于控制光谱仪器的操作,以便产生表示频率稳定的数据 由FT干涉仪记录的未知样品的干涉图。
    • 2. 发明申请
    • DEVICE AND METHOD FOR ASSAYING A VINEFICATION LIQUID
    • 用于测定乙烯基液体的装置和方法
    • WO2009000615A1
    • 2008-12-31
    • PCT/EP2008/056868
    • 2008-06-04
    • FOSS ANALYTICAL A/SJUHL, Henrik Vilstrup
    • JUHL, Henrik Vilstrup
    • G01N33/14
    • G01N33/146
    • The invention concerns a device for the spectrometric assay of a liquid vinefication product (1) comprising an optical spectrometer (5) adapted to generate spectral information from the contents of a spectroscopic a sample cell (4); a data processor (10) having access to a chemometric calibration (11) developed from a spectral database (12) linking optical spectral information to compounds of interest in the liquid vinefication product (1) and configured to process the same to generate an output result (13) indicative of the presence of one or more compounds of interest in the liquid vinefication product (1) characterized in that the device further comprises a freezer unit (3) adapted for freeze distillation of the liquid vinefication product (1) to generate a liquid distillate for analysis in the spectroscopic sample cell (4).
    • 本发明涉及一种用于液体醋化产品(1)的光谱测定的装置,包括光谱仪(5),适于从分光的样品池(4)的内容产生光谱信息; 数据处理器(10)可以访问从光谱数据库(12)开发的化学计量校准(11),该光谱数据库(12)将光谱信息与液体葡萄产品(1)中的感兴趣化合物相连接,并且被配置为处理它以产生输出结果 (13),其指示一种或多种感兴趣的化合物在液体酿造产品(1)中的存在,其特征在于,所述装置还包括适于冷冻蒸馏所述液体葡萄酒产品(1)的冷冻装置(3),以产生 液体馏出物用于在光谱样品池中分析(4)。
    • 3. 发明申请
    • A METHOD OF DETERMINING THE CONTENT OF A COMPONENT IN A FLUID SAMPLE AND AN APPARATUS THEREFOR
    • 确定流体样品中组分含量及其装置的方法
    • WO0104612A3
    • 2001-07-19
    • PCT/DK0000370
    • 2000-07-06
    • FOSS ELECTRIC ASJUHL HENRIK VILSTRUP
    • JUHL HENRIK VILSTRUP
    • G01N21/3577G01N21/359G01N33/06G01N21/35
    • G01N21/359G01N21/3577G01N33/06
    • A method of quantitative determining the content or concentration of a component in a fluid sample by IR analysis, the method comprising the following steps: a) directing one or more IR light beams through each of a number, n, of different parts of a fluid sample, the IR light including at least one wavelength within a waveband which the component absorbs, b) for each of the n parts of the sample, detecting the IR light having passed through the respective part of the sample, c) obtaining, for each of the parts, at least one value on the basis of the detected IR light, the value representing information from which the content or concentration may be estimated, d) calculating at least two statistical parameters, such as statistical moments, eg. a mean value and a standard deviation, characteristic of a statistical distribution of the obtained values, and e) estimating or determining the content or concentration of the component on the basis of the at least two statistical parameters. Thereby the content may be determined fairly accurate even through the instrument is simple and the measured sample is not homogenised. The obtained accuracy depends on the number of repetitive measurements on each sample. A better accuracy may be obtained by increasing the number of measurements.
    • 一种通过IR分析定量测定流体样品中组分的含量或浓度的方法,所述方法包括以下步骤:a)将一个或多个IR光束引导通过流体的不同部分的数量n中的每一个 样品,包括成分吸收的波段内的至少一个波长的IR光,b)对于样品的n个部分中的每一个,检测通过样品的各部分的IR光,c)对于每个 基于所检测的IR光的至少一个值,表示可以从其估计内容或浓度的信息的值,d)计算至少两个统计参数,例如统计矩,例如, 平均值和标准偏差,所获得的值的统计分布的特征,以及e)基于所述至少两个统计参数来估计或确定组分的含量或浓度。 因此,即使通过仪器简单,测量样品不均匀,也可以确定内容相当准确。 获得的精度取决于每个样品的重复测量次数。 通过增加测量次数可以获得更好的精度。
    • 4. 发明申请
    • SPECTROPHOTOMETER
    • 分光光度计
    • WO2006058741A1
    • 2006-06-08
    • PCT/EP2005/012820
    • 2005-12-01
    • FOSS ANALYTICAL A/SJUHL, Henrik, Vilstrup
    • JUHL, Henrik, Vilstrup
    • G01N21/03G01N21/31
    • G01N21/0303G01N21/31G01N2021/036G01N2201/066G01N2201/0662G01N2201/1293
    • A spectrophotometer (2)comprising a source of radiation (6), preferably optical radiation, disposed to emit radiation at a plurality of wavelengths towards a sample in a sample holder (4) and a detection arrangement 8 for detecting the radiation after its interaction with the sample. The sample holder (4) is adapted to present a plurality of different path lengths for the emitted radiation through the sample. An arithmetic unit (10;10b)is operably connected to receive an intensity dependent output from the detection arrangement (8) and is adapted to store an intensity value of the detected emitted radiation indexed to its wavelength at two or more path lengths of the plurality of different path lengths and to calculate a value dependent on the ratio of the indexed intensity values at each of two path lengths by which an indication of the presence of a substance of interest withiA spectrophotometer (2)comprise a source of radiation (6), preferably optical radiation, disposed to emit radiation at a plurality of wavelengths towards a sample in a sample holder (4) and a detection arrangement 8 for detecting the radiation after its interaction with the sample. The sample holder (4) is dapted to present a plurality of different path lengths for the emitted radiation through the sample. An arithmetic unit (10;10b)is operably connected to receive an intensity dependent output from the detection arrangement (8) and is adapted to store an intensity value of the detected emitted radiation indexed to its wavelength at two or more path lengths of the plurality of different path lengths and to calculate a value dependent on the ratio of the indexed intensity values at each of two path lengths by which an indication of the presence of a substance of interest within the retained sample can be obtained.
    • 一种分光光度计(2),包括辐射源(6),优选光辐射,被设置成朝向样品保持器(4)中的样品发射多个波长的辐射;以及检测装置8,用于在与 例子。 样品保持器(4)适于对通过样品的发射辐射呈现多个不同的路径长度。 算术单元(10; 10b)可操作地连接以接收来自检测装置(8)的与强度相关的输出,并且适于将检测到的发射的辐射的强度值存储在其波长的两个或更多个路径长度上 并且计算取决于两个路径长度中的每一个处的索引强度值的比率的值,通过该值,用分光光度计(2)存在感兴趣的物质的指示包括辐射源(6), 优选地,光辐射被设置为以多个波长朝向样品保持器(4)中的样品发射辐射;以及检测装置8,用于在与样品相互作用之后检测辐射。 样品保持器(4)被折叠以对于通过样品的发射辐射呈现多个不同的路径长度。 算术单元(10; 10b)可操作地连接以接收来自检测装置(8)的与强度相关的输出,并且适于将检测到的发射的辐射的强度值存储在其波长的两个或更多个路径长度上 并且计算取决于两个路径长度中的每一个处的索引强度值的比率的值,通过该值,可以获得在保留的样品内存在感兴趣物质的指示。