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    • 2. 发明申请
    • ALKALINE LIQUID DETERGENT COMPOSITIONS
    • 碱性液体洗涤剂组合物
    • WO2012104159A1
    • 2012-08-09
    • PCT/EP2012/050945
    • 2012-01-23
    • UNILEVER PLCUNILEVER N.V.HINDUSTAN UNILEVER LIMITEDCARSWELL, Robert, JohnCROSSMAN, Martin, CharlesJARVIS, Adam, PeterPARRY, Alyn, JamesROGERS, Susan, HenningWELLS, John, FrancisWINTER, Jeremy, Nicholas
    • CARSWELL, Robert, JohnCROSSMAN, Martin, CharlesJARVIS, Adam, PeterPARRY, Alyn, JamesROGERS, Susan, HenningWELLS, John, FrancisWINTER, Jeremy, Nicholas
    • C08G63/66C11D3/00C11D3/37C11D17/00
    • C11D3/3723C11D3/0036C11D3/30C11D3/3715
    • An aqueous alkaline isotropic concentrated detergent liquid composition with an undiluted pH of at least 7.8 and at most 9 comprising: a)10 to 60 wt% non-soap surfactant, b) 0 to 20 wt% hydrotrope, c) 0 to 4 wt% soap, d) 0 to 10 wt% nonionic EPEI, e) at least 1 wt% triethanolamine, characterised in that dissolved in the alkaline isotropic liquid there is: f) at least 1 wt%, preferably at least 1.5 wt% of a polyester substantive nonionic soil release polymer of the type E-M-L-E, where the midblock M is connected to a generally hydrophilic end block E and blocks E each comprise capped oligomers of polyethylene glycol remote from the midblock, with at least 10 EO repeat units, the end blocks being free from ester bonds, either directly or via linking moiety L which comprises the motif: B-Ar-B where B is selected from urethane, amide and ester moieties and Ar is,4 phenylene, and midblock M comprises the motif: wherein R1 and R2 may be the same or different selected from C1-C4 alkyl, C1-C4 alkoxy and Hydrogen, provided that R1 and R2 may not both be hydrogen, n is at least 2, preferably more than 5, the ester bonds may by 2 formed the other way around (not shown), if they are so reversed then all of them will be so reversed, G3107 (C) CPL -78- wherein the composition comprising the polymer provides soil release less than a ΔE of 5 with DMO on woven polyester after storage of the polymer in the detergent composition at 60°C for 8 days at a pH >7.5.
    • 具有至少7.8和至多9的未稀释pH的水性碱性各向同性浓缩洗涤剂液体组合物,其包含:a)10至60重量%的非皂表面活性剂,b)0-20重量%的水溶助长剂,c)0至4重量% 皂,d)0-10重量%的非离子EPEI,e)至少1重量%的三乙醇胺,其特征在于溶解在碱性各向同性液体中的有:f)至少1重量%,优选至少1.5重量%的聚酯 类型EMLE的实质性非离子去污聚合物,其中中间嵌段M连接到通常亲水的端嵌段E,嵌段E各自包含远离中间嵌段的聚乙二醇的封端低聚物,具有至少10个EO重复单元,末端嵌段 不含酯键,直接或通过连接部分L,其包含基序:B-Ar-B,其中B选自氨基甲酸酯,酰胺和酯部分,Ar是4-亚苯基,中间嵌段M包含该基序:其中R1和 R 2可以相同或不同,选自C 1 -C 4烷基,C 1 -C 4 烷氧基和氢,条件是R 1和R 2可以不都是氢,n至少为2,优选大于5,所以酯键可以以相反的方式形成(未示出),如果它们相反,则所有的 它们将如此扭转,G3107(C)CPL -78-其中包含聚合物的组合物在60℃下将聚合物保存在洗涤剂组合物中之后,在编织聚酯上提供少于ΔE5的污染物,其中DMO为8 天在pH> 7.5。
    • 3. 发明申请
    • POLYMERS, THEIR PRECURSORS AND PROCESSES FOR PREPARATION THEREOF
    • 聚合物,其前体及其制备方法
    • WO0107496A3
    • 2002-09-26
    • PCT/GB0002120
    • 2000-06-01
    • BP CHEM INT LTDHADDLETON DAVID MARKJARVIS ADAM PETER
    • HADDLETON DAVID MARKJARVIS ADAM PETER
    • C08F293/00
    • C08F293/005C08F2438/01
    • Novel block polymers of ethylenically unsaturated monomers and ethylenically unsaturated carboxylates such as vinyl acetate may be made by transition metal mediated, atom transfer polymerisation of an ethylenically unsaturated monomer with an alpha , omega di-functional polymer precursor having repeating units derived from an ethylenically unsaturated carboxylate, such as vinyl acetate. Also, novel alpha , omega di-functional polymer precursors may be made by the steps of (a) reacting an ethylenically unsaturated carboxylate with a radical initiator having a substitutable functional group; and (b) substituting the functional groups on the product of step (a) with substituents active for the formation of block polymers in a transition metal mediated, atom transfer polymerisation process.
    • 可以通过过渡金属介导的烯属不饱和单体与具有源自烯属不饱和羧酸酯的重复单元的α,ω二官能聚合物前体的原子转移聚合来制备烯属不饱和单体和烯属不饱和羧酸酯如乙酸乙烯酯的新型嵌段聚合物 ,如乙酸乙烯酯。 此外,新的α,ω-二官能聚合物前体可以通过以下步骤制备:(a)使烯键式不饱和羧酸酯与具有可取代官能团的自由基引发剂反应; 和(b)用在过渡金属介导的原子转移聚合方法中用于形成嵌段聚合物的取代基取代有步骤(a)的产物的官能团。
    • 8. 发明申请
    • SOIL RELEASE POLYMERS
    • 土壤释放聚合物
    • WO2012104157A1
    • 2012-08-09
    • PCT/EP2012/050942
    • 2012-01-23
    • UNILEVER PLCUNILEVER N.V.HINDUSTAN UNILEVER LIMITEDCROSSMAN, Martin, CharlesJARVIS, Adam, PeterROGERS, Susanne, HenningWINTER, Jeremy, Nicholas
    • CROSSMAN, Martin, CharlesJARVIS, Adam, PeterROGERS, Susanne, HenningWINTER, Jeremy, Nicholas
    • C08G63/66C11D3/00
    • C08G63/672C11D3/0036C11D3/3707
    • A soil release polymer with the formula (I) : X-[(EO) q -block-(PO) p ]-[(A-R 1 -A-R 2 ) n ]-A-R 1 -A-[(PO) p -block-(EO) q ] X (I) where EO is predominantly ethylene oxide (CH 2 CH 2 O) that is to say that at least 75% of the repeat units in the block are ethylene oxide, preferably at least 90% and most preferably 100%; where PO comprises propylene oxide (CH 2 CH(CH 3 )O), that is the PO block must contain at least 50% propylene oxide repeat units, preferably at least 80% PO units and most preferably 100% PO units; where p is a number from 0 to 60, when present preferably from 2 to 50, more preferably from 5 to 45, even more preferably from 6 to 40, yet more preferably from 7 to 40 and most preferably from 8 to 40, even from 11 to 35; where q is a number from 6 to 120, preferably 18 to 80, most preferably 40 to 70, provided that q is greater than p; where X is a capping moiety, preferably selected from C 1-4 alkyl, branched and unbranched; where n is a number from 2 to 26; where the moieties R 1 are all 1,4 phenylene, where the moieties A are all esters, characterised in that 100% of the moieties R 2 are substituted ethylene of formula (II) wherein R 3 and R 4 are selected from Hydrogen, C 1-4 alkyl and C 1-4 alkoxy, provided that at least one of R 3 and R 4 is not hydrogen and that at least 10, preferably at least 20 mol% of the groups R 2 have neither R 3 nor R 4 as hydrogen.
    • 具有式(I)的去污聚合物:X - [(EO)q-嵌段 - (PO)p] - [(A-R1-A-R2)n] -A-R1-A - [(PO) 其中EO主要是环氧乙烷(CH 2 CH 2 O)的对 - 块 - (EO)q] X(I),也就是说该嵌段中至少75%的重复单元是环氧乙烷,优选至少90% 100%; 其中PO包括环氧丙烷(CH 2 CH(CH 3)O),即PO嵌段必须含有至少50%环氧丙烷重复单元,优选至少80%PO单元,最优选100%PO单元; 其中p为0至60的数,当优选为2至50,更优选为5至45,甚至更优选为6至40,还更优选为7至40,最优选为8至40。 11至35; 其中q是6至120,优选18至80,最优选40至70的数,条件是q大于p; 其中X是封端部分,优选选自C 1-4烷基,支链和非支链; 其中n是从2到26的数字; 其中部分R1全部是1,4-亚苯基,其中部分A全部是酯,其特征在于100%的部分R 2是式(II)的取代的亚乙基,其中R 3和R 4选自氢,C 1-4烷基和 C 1-4烷氧基,条件是R 3和R 4中的至少一个不是氢,并且基团R 2的至少10个,优选至少20mol%既不具有R3也不具有R4作为氢。
    • 9. 发明申请
    • SOIL RELEASE POLYMERS
    • 土壤释放聚合物
    • WO2012104156A1
    • 2012-08-09
    • PCT/EP2012/050941
    • 2012-01-23
    • UNILEVER PLCUNILEVER N.V.HINDUSTAN UNILEVER LIMITEDCROSSMAN, Martin, CharlesJARVIS, Adam, PeterROGERS, Susanne, HenningWINTER, Jeremy, Nicholas
    • CROSSMAN, Martin, CharlesJARVIS, Adam, PeterROGERS, Susanne, HenningWINTER, Jeremy, Nicholas
    • C08G63/66C11D3/00
    • C08G63/672C11D3/0036C11D3/3715
    • A linear soil release polymer with the formula (I): X-[(EO) q -block-(PO) p ]-[(A-R 1 -A-R 2 ) n ]-A-R 1 -A-[(PO) p -block-(EO) q ] -X (I) where the linking moieties A are esters, where the R 1 moieties are 1,4 - phenylene moities, where the R 2 moieties are substituted ethylene moieties having C 1-4 alkyl substituents and the R 2 moieties comprise substituted ethylene moieties derived from the condensation of 2,3 butane diol, where the EO blocks are 100% ethylene oxide (CH 2 CH 2 O), where the PO blocks are 100% propylene oxide (CH 2 CH(CH 3 )O), where p is a number from 2 to 50, preferably from 5 to 45, more preferably from 6 to 40, yet more preferably from 7 to 40 and most preferably from 8 to 40, even from 1 1 to 35; where q is a number from 6 to 120, preferably 18 to 80, most preferably 40 to 70, provided that q is greater than p and preferably q is at least 1.5 times as large as p; where X is a suitable capping moiety, preferably selected from C 1-4 alkyl, branched and unbranched; where n is a number from 2 to 16.
    • 具有式(I)的线性去污聚合物:X - [(EO)q-嵌段 - (PO)p] - [(A-R1-A-R2)n] -A-R1-A - [(PO )对 - 嵌段 - (EO)q] -X(I)其中连接部分A是酯,其中R 1部分是1,4-亚苯基,其中R 2部分是具有C 1-4烷基取代基的取代的亚乙基部分, R2部分包含衍生自2,3-丁二醇缩合的取代的乙烯部分,其中EO嵌段是100%环氧乙烷(CH 2 CH 2 O),其中PO嵌段是100%环氧丙烷(CH 2 CH(CH 3)O)),其中p 是2〜50,优选5〜45,更优选6〜40,进一步优选7〜40,最优选8〜40,甚至11〜35的数。 其中q是6至120,优选18至80,最优选40至70的数,条件是q大于p且优选q至少为p的1.5倍; 其中X是合适的封端部分,优选选自C 1-4烷基,支链和非支链的; 其中n是从2到16的数字。