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1. 发明授权

US08987183B2 Use of optionally oxidized thioethers of polyalkylene oxides in washing and cleaning compositions 有权
标题翻译：在洗涤和清洁组合物中使用聚氧化亚烷基的任选氧化硫醚
公开(公告)号：US08987183B2
公开(公告)日：2015-03-24
申请号：US13350046
申请日：2012-01-13
申请人： Sophie Maitro-Vogel , Jürgen Tropsch , Wolfgang Spiegler , Roman Benedikt Raether
发明人： Sophie Maitro-Vogel , Jürgen Tropsch , Wolfgang Spiegler , Roman Benedikt Raether
IPC分类号： C11D17/00 , C11D1/755 , C11D1/00 , C07C317/18 , C07C323/12
CPC分类号： C11D1/755 , C07C317/18 , C07C323/12 , C11D1/002
摘要： The present invention relates to the use of (oxidized) thioethers of polyalkylene oxides in washing and cleaning compositions, especially in dishwashing compositions, and to washing and cleaning compositions, especially dishwashing compositions, which comprise (oxidized) thioethers of alcohol alkoxylates. These (oxidized) thioethers are especially suitable as surfactants with rinse aid function (rinse aid surfactants). “Oxidized” relates to the sulfur atom in the thioether, which may be present in oxidized form as sulfoxide (SO) or sulfonyl (SO2). The invention also relates to particular oxidized thioethers of polyalkylene oxides.
摘要翻译：本发明涉及在洗涤和清洁组合物（特别是洗碗组合物）中使用聚氧化烯的（氧化）硫醚，以及洗涤和清洁组合物，特别是餐具洗涤组合物，其包含醇氧烷基化物的（氧化）硫醚。这些（氧化）硫醚特别适合作为具有漂洗助剂功能的表面活性剂（漂洗助剂表面活性剂）。 “氧化”涉及硫醚中的硫原子，其可以以亚砜（SO）或磺酰（SO 2）的形式存在于氧化形式中。本发明还涉及聚氧化烯的特定氧化硫醚。

2. 发明申请

US20120196784A1 DETERGENT FORMULATIONS FOR MACHINE DISHWASHING COMPRISING HYDROPHILICALLY MODIFIED POLYCARBOXYLATES 审中-公开
标题翻译：用于疏水改性聚碳酸酯的机械洗涤剂的洗涤剂配方
公开(公告)号：US20120196784A1
公开(公告)日：2012-08-02
申请号：US13444933
申请日：2012-04-12
申请人： Tanja Seebeck , Jürgen Tropsch , Lars Kissau
发明人： Tanja Seebeck , Jürgen Tropsch , Lars Kissau
IPC分类号： C11D3/37
CPC分类号： C11D3/3757 , C11D3/33
摘要： A phosphate-free detergent formulation for machine dishwashing is provided. The formulation contains as main components: copolymers of a monoethylenically unsaturated monocarboxylic acid and/or of a salt thereof, and an alkoxylated, monoethylenically unsaturated monomer, wherein the copolymer has a mean molecular weight Mw of from 30 000 to 500 000 g/mol and a K value of from 40 to 150, measured at pH 7 in 1% by weight aqueous solution at 25° C.; complexing agents; low-foaming nonionic surfactants; bleaches and, optionally, bleach activators; further builders; enzymes; and one or more further additives.
摘要翻译：提供了一种用于机洗餐具洗涤剂的无磷酸盐洗涤剂配方。该制剂含有：单烯属不饱和一元羧酸和/或其盐的共聚物和烷氧基化单烯属不饱和单体，其中共聚物的平均分子量Mw为30000至500000g / mol，在25℃在1重量％水溶液中在pH7测量的40至150的K值。络合剂; 低泡非离子表面活性剂; 漂白剂和任选的漂白活化剂; 进一步建设者酶; 和一种或多种其它添加剂。

3. 发明申请

US20110315910A1 ALKOXYLATES AND USE THEREOF 有权
标题翻译：烷基酯及其用途
公开(公告)号：US20110315910A1
公开(公告)日：2011-12-29
申请号：US13169235
申请日：2011-06-27
申请人： Paul KLINGELHOEFER , Jürgen Tropsch , Rolf-Dieter Kahl , Andreas Senf
发明人： Paul KLINGELHOEFER , Jürgen Tropsch , Rolf-Dieter Kahl , Andreas Senf
IPC分类号： C11D1/86 , D06M13/224 , C09D11/02 , C07C229/24
CPC分类号： C11D1/44 , C09D11/102 , C11D1/62 , C11D1/65 , C11D1/835 , C11D3/2079 , C11D3/2082 , C11D10/04 , C14C1/08 , D06M13/17 , D06M13/325 , D06M13/463 , D06P1/6076 , D06P1/645 , D06P1/66
摘要： The present invention relates to the use of an alkoxylate based on 2-propylheptylamine which has been alkoxylated with ethylene oxide, propylene oxide, butylene oxide, pentylene oxide, styrene oxide, cyclohexylene oxide and/or decylene oxide, and/or its quaternized derivative in cleaning compositions, as emulsifier, in the manufacture of fibers, for leather treatment, in printing inks, in formulations for construction chemistry or in formulations for flotation. Furthermore, the present invention relates to a mixture comprising at least one of the specified alkoxylates and also at least one surface-active substance and use thereof.
摘要翻译：本发明涉及使用已经用环氧乙烷，环氧丙烷，环氧丁烷，环氧丁烷，氧化苯乙烯，环氧丁烷和/或二氧化碳进行烷氧基化的2-丙基庚胺的烷氧基化物，和/或其季铵化衍生物清洁组合物，作为乳化剂，用于制造纤维，皮革处理，印刷油墨，用于建筑化学的制剂或用于浮选的制剂中。此外，本发明涉及包含至少一种指定的烷氧基化物和至少一种表面活性物质的混合物及其用途。

4. 发明授权

US07595291B2 Esterified alkyl alkoxylates used as low-foam surfactants 有权
标题翻译：用作低泡沫表面活性剂的酯化烷基烷氧基化物
公开(公告)号：US07595291B2
公开(公告)日：2009-09-29
申请号：US11908432
申请日：2006-03-10
申请人： Christian Bittner , Jürgen Tropsch , Ralf Nörenberg
发明人： Christian Bittner , Jürgen Tropsch , Ralf Nörenberg
IPC分类号： C11D1/72 , C11D1/74 , C07C69/24
CPC分类号： C07C41/03 , C07C67/03 , C07C67/08 , C07C69/24 , C11D1/74 , C11D3/0026 , C07C43/11
摘要： The present invention relates to low-foam surfactant mixtures of the general formula (I) where R, Ra, R1 and R2, l, n and m have the meaning given in the description and the claims, and to the production thereof. For example, R=C13-alkyl, Ra=H, l=5, m=22, n=1, R1=methyl and R2=C6-C14-alkyl. The surfactants are suitable for detergent and cleaner formulations.
摘要翻译：本发明涉及通式（I）的低泡表面活性剂混合物，其中R，Ra，R1和R2，l，n和m具有说明书和权利要求书中给出的含义及其制备。例如，R = C13-烷基，Ra = H，l = 5，m = 22，n = 1，R1 =甲基，R2 = C6-C14-烷基。表面活性剂适用于洗涤剂和清洁剂配方。

5. 发明授权

US06963014B1 C13 alcohol mixture and functionalised C13 alcohol mixture 失效
标题翻译： C13醇混合物和官能化C13醇混合物
公开(公告)号：US06963014B1
公开(公告)日：2005-11-08
申请号：US10129980
申请日：2000-11-17
申请人： Edgar Zeller , Marc Walter , Wolfgang Richter , Klaus Diehl , Michael Röper , Jürgen Tropsch
发明人： Edgar Zeller , Marc Walter , Wolfgang Richter , Klaus Diehl , Michael Röper , Jürgen Tropsch
IPC分类号： B01F17/38 , C07B61/00 , C07C2/08 , C07C29/141 , C07C29/16 , C07C31/125 , C07C41/03 , C07C43/11 , C07C45/50 , C07F9/09 , C07F9/11 , C11D7/26 , C07C27/20 , C07C27/22 , C07C27/24 , C07C29/15
CPC分类号： C11D7/262 , C07C29/141 , C07C29/16 , C07C41/03 , C07C43/11 , C07C45/50 , C07F9/091 , C07F9/11 , C11D7/261 , C07C31/125 , C07C47/02
摘要： A process for preparing a C13-alcohol mixture comprises a) bringing a butene-containing C4-hydrocarbon stream containing less than 5% by weight, based on the butene fraction, of isobutene into contact with a nickel-containing heterogeneous catalyst at elevated temperature, b) isolating a C12-olefin fraction from the reaction mixture, c) hydroformylating the C12-olefin fraction by reaction with carbon monoxide and hydrogen in the presence of a cobalt catalyst and d) hydrogenating the product from c). The alcohol mixture is suitable for preparing surfactants by alkoxylation, glycosidation, sulfation, phosphation, alkoxylation and subsequent sulfation or alkoxylation and subsequent phosphation.
摘要翻译：制备C 13 - 醇混合物的方法包括a）将含有小于5％（重量）的含丁烯C 4 - 的异丁烯在升高的温度下与含镍的非均相催化剂接触，b）从反应混合物中分离出C 12 - 12α-烯烃部分，c）将C 12 - α-烯烃部分通过在一种钴催化剂存在下与一氧化碳和氢气反应，和d）从c）氢化产物。醇混合物适于通过烷氧基化，糖基化，硫酸化，磷酸化，烷氧基化和随后的硫酸化或烷氧基化和随后的磷酸化来制备表面活性剂。

6. 发明授权

US08951955B2 Use of optionally oxidized thioethers of alcohol alkoxylates in washing and cleaning compositions 有权
标题翻译：在洗涤和清洁组合物中使用任选氧化的醇烷氧基化物的硫醚
公开(公告)号：US08951955B2
公开(公告)日：2015-02-10
申请号：US13350169
申请日：2012-01-13
申请人： Sophie Maitro-Vogel , Jürgen Tropsch , Wolfgang Spiegler , Roman Benedikt Raether , Christian Bittner
发明人： Sophie Maitro-Vogel , Jürgen Tropsch , Wolfgang Spiegler , Roman Benedikt Raether , Christian Bittner
IPC分类号： C11D3/60 , C11D3/34 , C07C323/12 , C07C317/18 , C11D1/00 , C11D1/755
CPC分类号： C07C323/12 , C07C317/18 , C11D1/002 , C11D1/755
摘要： The present invention relates to the use of (oxidized) thioethers of alcohol alkoxylates in washing and cleaning compositions, especially in dishwashing compositions, and to washing and cleaning compositions, especially dishwashing compositions, which comprise (oxidized) thioethers of alcohol alkoxylates. These (oxidized) thioethers are especially suitable as surfactants with rinse aid function (rinse aid surfactants). “Oxidized” relates to the sulfur atom in the thioether, which may be present in oxidized form as sulfoxide (SO) or sulfonyl (SO2).
摘要翻译：本发明涉及醇氧烷基化物的（氧化）硫醚在洗涤和清洁组合物中，特别是洗碗组合物中的用途，以及洗涤和清洗组合物，特别是餐具洗涤组合物，其包含醇氧烷基化物的（氧化）硫醚。这些（氧化）硫醚特别适合作为具有漂洗助剂功能的表面活性剂（漂洗助剂表面活性剂）。 “氧化”涉及硫醚中的硫原子，其可以以亚砜（SO）或磺酰（SO 2）的形式存在于氧化形式中。

7. 发明申请

US20120190605A1 USE OF TALLOW FATTY ALCOHOL ETHOXYLATES IN MACHINE DISHWASHING 审中-公开
标题翻译：在机器洗涤中使用粉末状的乙醇酸乙酯
公开(公告)号：US20120190605A1
公开(公告)日：2012-07-26
申请号：US13354776
申请日：2012-01-20
申请人： Sonja Fischer , Jürgen Tropsch , Heike Weber , Roland Ettl
发明人： Sonja Fischer , Jürgen Tropsch , Heike Weber , Roland Ettl
IPC分类号： C11D3/60 , C07C43/11 , C07C43/10
CPC分类号： C11D1/72 , C07C43/11 , C11D1/721 , C11D1/825
摘要： The invention relates to nonionic surfactants of ethoxylates of linear C16-C18-alcohols with, on average, 8.5 to 9.5 mol of ethylene oxide per mole of linear C16-C18-alcohol.
摘要翻译：本发明涉及线性C 16 -C 18醇的乙氧基化物的非离子表面活性剂，平均每摩尔线性C 16 -C 18醇具有8.5至9.5摩尔环氧乙烷。

8. 发明申请

US20120122748A1 DETERGENT FORMULATIONS FOR MACHINE DISHWASHING COMPRISING HYDROPHILICALLY MODIFIED POLYCARBOXYLATES 有权
标题翻译：用于疏水改性聚碳酸酯的机械洗涤剂的洗涤剂配方
公开(公告)号：US20120122748A1
公开(公告)日：2012-05-17
申请号：US13325446
申请日：2011-12-14
申请人： Tanja Seebeck , Jürgen Tropsch , Lars Kissau
发明人： Tanja Seebeck , Jürgen Tropsch , Lars Kissau
IPC分类号： C11D7/60 , C11D3/60
CPC分类号： C11D3/3757 , C11D3/33
摘要： A mixed powder or mixed granule for use in detergent formulations for machine dishwashing contains the following components: a) from 10 to 95% by weight of a copolymer of al) from 50 to 93 mol % of acrylic acid and/or of a water-soluble salt of acrylic acid, a2) from 5 to 30 mol % of methacrylic acid and/or of a water-soluble salt of methacrylic acid, and a3) from 2 to 20 mol % of at least one nonionic monomer, wherein monomers a1) to a3) are copolymerized in a random or block manner, b) from 5 to 80% by weight of a complexing agent selected from the group consisting of a glycine-N,N-diacetic acid derivative and glutamic acid N,N-diacetic acid and salts thereof, c) from 0 to 20% by weight of a polyethylene glycol, of a nonionic surfactant or of a mixture thereof.
摘要翻译：用于机洗餐具洗涤剂的洗涤剂配方中使用的混合粉末或混合颗粒包含以下组分：a）10至95重量％的共聚物，Al）为50至93摩尔％的丙烯酸和/或水 - 丙烯酸的可溶性盐，a2）5〜30摩尔％的甲基丙烯酸和/或甲基丙烯酸的水溶性盐，以及a3）2〜20摩尔％的至少一种非离子单体，其中单体a1）至a3）以无规或嵌段方式共聚，b）5-80重量％的选自甘氨酸-N，N-二乙酸衍生物和谷氨酸N，N-二乙酸的络合剂和其盐，c）0至20重量％的聚乙二醇，非离子表面活性剂或其混合物。

9. 发明申请

US20100249010A1 CLEANING FORMULATIONS FOR MACHINE DISHWASHING COMPRISING HYDROPHILICALLY MODIFIED POLYCARBOXYLATES 审中-公开
公开(公告)号：US20100249010A1
公开(公告)日：2010-09-30
申请号：US12783804
申请日：2010-05-20
申请人： Tanja Seebeck , Jürgen Tropsch , Lars Kissau
发明人： Tanja Seebeck , Jürgen Tropsch , Lars Kissau
IPC分类号： C11D3/37
CPC分类号： C11D3/3757 , C11D3/33
摘要： A phosphate-free detergent formulation for machine dishwashing is provided. The formulation contains as main components: copolymers of a monoethylenically unsaturated monocarboxylic acid and/or of a salt thereof, and an alkoxylated, monoethylenically unsaturated monomer, wherein the copolymer has a mean molecular weight Mw of from 30 000 to 500 000 g/mol and a K value of from 40 to 150, measured at pH 7 in 1% by weight aqueous solution at 25° C.; complexing agents; low-foaming nonionic surfactants; bleaches and, optionally, bleach activators; further builders; enzymes; and one or more further additives.

10. 发明申请

US20100227787A1 CLEANING FORMULATIONS FOR MACHINE DISHWASHING COMPRISING HYDROPHILICALLY MODIFIED POLYCARBOXYLATES 有权
标题翻译：用于疏水改性聚碳酸酯的机器清洗清洁配方
公开(公告)号：US20100227787A1
公开(公告)日：2010-09-09
申请号：US12783726
申请日：2010-05-20
申请人： Tanja Seebeck , Jürgen Tropsch , Lars Kissau
发明人： Tanja Seebeck , Jürgen Tropsch , Lars Kissau
IPC分类号： C11D3/37
CPC分类号： C11D3/3757 , C11D3/33
摘要： A phosphate-free detergent formulation for machine dishwashing is provided. The formulation contains as main components: copolymers of a monoethylenically unsaturated monocarboxylic acid and/or of a salt thereof, and an alkoxylated, monoethylenically unsaturated monomer, wherein the copolymer has a mean molecular weight Mw of from 30 000 to 500 000 g/mol and a K value of from 40 to 150, measured at pH 7 in 1% by weight aqueous solution at 25° C.; complexing agents; low-foaming nonionic surfactants; bleaches and, optionally, bleach activators; further builders; enzymes; and one or more further additives.
摘要翻译：提供了一种用于机洗餐具洗涤剂的无磷酸盐洗涤剂配方。该制剂含有：单烯属不饱和一元羧酸和/或其盐的共聚物和烷氧基化单烯属不饱和单体，其中共聚物的平均分子量Mw为30000至500000g / mol，在25℃在1重量％水溶液中在pH7测量的40至150的K值。络合剂; 低泡非离子表面活性剂; 漂白剂和任选的漂白活化剂; 进一步建设者酶; 和一种或多种其它添加剂。

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