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    • 1. 发明授权
    • Silver halide color photographic element having improved bleachability
    • 具有改善的漂白性的卤化银彩色照相元件
    • US6043011A
    • 2000-03-28
    • US76155
    • 1998-05-11
    • Isabella CoglioloPaolo BerettaIvano DelpratoSergio Massirio
    • Isabella CoglioloPaolo BerettaIvano DelpratoSergio Massirio
    • G03C7/30G03C7/305G03C7/42G03C1/43G03C7/32G03C7/34
    • G03C7/30541G03C7/3029
    • A multilayer silver halide color photographic element comprises a support having coated thereon a silver antihalation layer, an interlayer, at least two red-sensitive silver halide emulsion layers, at least two green-sensitive silver halide emulsion layers a yellow filter layer, and at least two blue-sensitive silver halide emulsion layers, wherein a silver halide emulsion layer or a nonsensitive layer adjacent thereto comprises a bleach accelerator releasing coupler of formulaA-(TIME).sub.n -S-X-Rwherein A represents a coupler residue releasing from (TIME).sub.n -S-X-R upon reaction with the oxidation product of a color developing agent; TIME represents a timing group releasing S-X-R with delay under developing conditions; n represents 0 or 1; X represents a divalent linking groups consisting of an alkylene group containing 1 to 8 carbon atoms; and R represents a group selected in the group consisting of a), b) and c): ##STR1## wherein R.sub.1 represents hydrogen or a monovalent chemical group, n represents 0 or 1, Z represents the atoms necessary to complete a 5- or 6-membered ring or a fused ring, and R.sub.2 and R.sub.4, equal or different, each represents hydrogen, an alkyl group, an aryl group, --SO.sub.2 R.sub.4 or --COR.sub.4, wherein R.sub.4 represents an alkyl group or an aryl group. The invention provides reduction in residual silver levels after processing, without deleteriously affecting sensitometric properties and color reproduction performance of the photographic element.
    • 多层卤化银彩色照相元件包括其上涂有银防晕层,中间层,至少两个感红卤化银乳剂层,至少两个感绿卤化银乳剂层,黄色过滤层和至少 两个感蓝卤化银乳剂层,其中卤化银乳剂层或与其相邻的非敏感层包含式A-(TIME)nSX-R的漂白促进剂释放成色剂,其中A表示与(TIME)nSXR反应的成色剂残余物,与 彩色显影剂的氧化产物; TIME表示在开发条件下延迟释放S-X-R的定时组; n表示0或1; X表示由含有1至8个碳原子的亚烷基组成的二价连接基团; 并且R表示选自a),b)和c)中的基团:其中R 1表示氢或一价化学基团,n表示0或1,Z表示完成5-或6-元所需的原子 环或稠环,R 2和R 4相同或不同,各自表示氢,烷基,芳基,-SO 2 R 4或-COR 4,其中R 4表示烷基或芳基。 本发明提供了处理后残留银水平的降低,而不会有害地影响照相元件的感光性能和色彩再现性能。
    • 3. 发明授权
    • Spectrally sensitized silver halide photographic elements
    • 光谱增感卤化银照相元件
    • US5422236A
    • 1995-06-06
    • US286280
    • 1994-08-05
    • Ivano DelpratoIsabella Cogliolo
    • Ivano DelpratoIsabella Cogliolo
    • G03C5/08C09B23/01G03C1/00G03C1/22G03C1/26G03C1/10
    • C09B23/0083G03C1/22G03C1/26
    • The present invention refers to a silver halide photographic element containing a support having coated thereon at least a silver halide emulsion layer spectrally sensitized with a sensitizing dye according to the formula (I): ##STR1## wherein Z represents the atoms necessary to complete a 6-membered nitrogen-containing heterocyclic nucleus; at least 2 members of R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 --but not R.sub.1 and R.sub.2 together--represent an organic group carrying a water-solubilizing group in free acid form, in salt form or in latent form, and are same or different, the members of R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 that do not represent a said organic radical carrying a water-solubilizing group represent hydrogen, an alkyl group, an alkenyl group or an aryl group; and n is 0 or 1.The silver halide photographic material has the advantage to have a broad sensitivity in the red portion of the spectrum. It can be exposed to laser beam sources in the range of 600-700 nm.
    • 本发明涉及一种含有载体的卤化银照相元件,其上至少涂覆有根据式(I)的增感染料光谱增感的卤化银乳剂层:其中Z表示完成6 含氮杂环核; R 1,R 2,R 3,R 4和R 5中的至少2个成员,而不是R 1和R 2一起代表具有盐形式或潜伏形式的游离酸形式的水溶性基团的有机基团,并且相同或不同 不表示带有水溶性基团的所述有机基团的R1,R2,R3,R4和R5的成员表示氢,烷基,烯基或芳基; 并且n为0或1.卤化银照相材料具有在光谱的红色部分具有宽的灵敏度的优点。 它可以暴露于600-700 nm范围内的激光束源。