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1. 发明申请

WO1998028309A1 PROCESS FOR THE PREPARATION OF 1-ALKOXY-1-TRIMETHYLSILYLOXYCYCLOPROPANES 审中-公开
标题翻译： 1-烷基-1-三甲氧基硅烷氧基化合物的制备方法
公开(公告)号：WO1998028309A1
公开(公告)日：1998-07-02
申请号：PCT/JP1997004705
申请日：1997-12-19
申请人： IHARA CHEMICAL INDUSTRY CO., LTD. , YOSHIDA, Yasuo
发明人： IHARA CHEMICAL INDUSTRY CO., LTD.
IPC分类号： C07F07/18
CPC分类号： C07F7/188
摘要： A process for the preparation of 1-alkoxy-1-trimethylsilyloxycyclopropanes of general formula (I), wherein R and R are each independently hydrogen or lower alkyl; and R is lower alkyl, by reacting finely divided metallic sodium dispersed in a hydrocarbon with a beta -halogeno carboxylic ester of general formula (II), wherein R , R and R are each as defined above; and X is halogen and chlorotrimethylsilane. According to this process, 1-alkoxy-1-trimethylsilyloxypropanes can be industrially prepared, easily, simply and economically advantageously without any special equipment by using not an ethereal solvent problematic in safety but finely divided metallic sodium dispersed in a hydrocarbon in a yield equivalent to or higher than that attained by using an ethereal solvent.
摘要翻译：制备通式（I）的1-烷氧基-1-三甲基甲硅烷氧基环丙烷的方法，其中R 1和R 2各自独立地为氢或低级烷基; 和R 3是低级烷基，通过使分散在烃中的细碎金属钠与通式（II）的β-卤代羧酸酯反应，其中R 1，R 2和R 3各自为如上所述; X为卤素和氯代三甲基硅烷。根据该方法，1-烷氧基-1-三甲基甲硅烷氧基丙烷可以在工业上制备，容易，简单和经济上有利地没有任何特殊的设备，通过使用不是安全的醚溶剂，而是分散在烃中的细分散的金属钠，产率相当于或高于通过使用醚类溶剂获得的浓度。

2. 发明申请

WO1998018766A1 PYRIMIDINYLOXYALKANOIC AMIDE DERIVATIVES AND FUNGICIDES FOR AGRICULTURAL AND HORTICULTURAL USE 审中-公开
标题翻译：农药和农药使用的吡咯烷酮氧化胺衍生物和杀真菌剂
公开(公告)号：WO1998018766A1
公开(公告)日：1998-05-07
申请号：PCT/JP1997003945
申请日：1997-10-30
申请人： KUMIAI CHEMICAL INDUSTRY CO., LTD. , IHARA CHEMICAL INDUSTRY CO., LTD.. , MASUDA, Katsumi , URUSHIBATA, Ikumi , ASAHARA, Tsuyoshi , FURUSE, Katsumi , KOJIMA, Yoshiyuki , MURAMATSU, Norimichi
发明人： KUMIAI CHEMICAL INDUSTRY CO., LTD. , IHARA CHEMICAL INDUSTRY CO., LTD..
IPC分类号： C07D239/34
CPC分类号： A01N43/54 , C07D239/34 , C07D239/38 , C07D239/52 , C07D239/58 , C07D239/74 , C07D405/12 , C07D409/12
摘要： Pyrimidinyloxyalkanoic amide derivatives of general formula (I), and fungicides for agricultural and horticultural use containing the same, wherein R is hydrogen, C1-C6 alkyl, C3-C6 cycloalkyl, or the like; R is C1-C6 alkyl, C1-C4 haloalkyl, or the like; R is hydrogen, C1-C6 alkyl, halogeno or the like; R is hydrogen, C1-C6 alkyl or the like; Q is cyano, C1-C6 alkoxycarbonyl or the like; and A is oxygen or sulfur. The fungicides exhibit a high controlling effect against rice blast or the like and the effect is remarkably superior to that of known compounds. Further, the fungicides do not cause chemical damage to crops and are also excellent in residual effect and rain resistance.
摘要翻译：通式（I）的嘧啶氧基烷基酰胺衍生物以及含有其的农业和园艺用杀真菌剂，其中R 1是氢，C 1 -C 6烷基，C 3 -C 6环烷基等; R 2是C 1 -C 6烷基，C 1 -C 4卤代烷基等; R 3是氢，C 1 -C 6烷基，卤代等; R 4是氢，C 1 -C 6烷基等; Q是氰基，C 1 -C 6烷氧基羰基等; A是氧或硫。杀真菌剂对稻瘟病等具有高的控制效果，其效果明显优于已知化合物。此外，杀真菌剂不会对作物造成化学损害，并且残留效果和耐雨性也优异。

3. 发明申请

WO1995025089A1 PROCESSES FOR PRODUCING THIOARYL COMPOUND 审中-公开
标题翻译：生产硫酸化合物的方法
公开(公告)号：WO1995025089A1
公开(公告)日：1995-09-21
申请号：PCT/JP1995000455
申请日：1995-03-17
申请人： IHARA CHEMICAL INDUSTRY CO., LTD. , SUGIYAMA, Tatsuo , NAKAYAMA, Tadashi
发明人： IHARA CHEMICAL INDUSTRY CO., LTD.
IPC分类号： C07C319/06
CPC分类号： C07C319/14 , C07C319/06 , C07C323/52 , C07C323/34
摘要： A process for producing an alkali metal salt of an arylmercaptan compound represented by general formula (3), by the reaction of a disulfide compound represented by general formula (1) with a hydroxide of an alkali metal M in the presence of a sulfur compound represented by the general formula (2): H(2-i)S(M )i, another process for producing an alkoxycarbonylalkylthioaryl compound represented by general formula (5) by the reaction of the alkali metal salt of an arylmercaptan compound obtained above with a halogenated fatty acid ester represented by the general formula (4): X -R -COOR at a pH of 7 to 10; and still another process for producing the alkoxycarbonylalkylthioaryl compound by the reaction of the disulfide compound with the hydroxide of an alkali metal M in the presence of the sulfur compound, followed by the reaction of the obtained alkali metal salt of an arylmercaptan compound, without being isolated, with the halogenated fatty acid ester under the same condition.
摘要翻译：一种通式（3）表示的芳基硫醇化合物的碱金属盐的制备方法，通过在通式（1）表示的二硫化物与碱金属M 1的氢氧化物的反应中，由通式（2）表示的硫化合物：H（2-i）S（M 1）i，另外通过通式（5）表示的烷氧基羰基烷基硫代芳基化合物的制备方法，在通式（4）表示的卤代脂肪酸酯：X 1 -R 2 -COOR 3，pH7〜10的条件下，得到上述得到的芳基硫醇化合物; 还有在硫化合物存在下，通过二硫化物与碱金属M 1的氢氧化物的反应制备烷氧基羰基烷基硫代芳基化合物的另一种方法，然后将所得到的芳基硫醇化合物的碱金属盐，在不同的条件下与卤代脂肪酸酯分离。

4. 发明申请

WO1995021828A1 PROCESS FOR PRODUCING HEXAHYDROPYRIDAZINE AND HEXAHYDROPYRIDAZINE-1,2-DICARBOXYLATE DERIVATIVE 审中-公开
标题翻译：六氢呋喃并嘧啶衍生物的制造方法和二氢吡啶-2-基二甲氧基硅烷衍生物
公开(公告)号：WO1995021828A1
公开(公告)日：1995-08-17
申请号：PCT/JP1995000184
申请日：1995-02-10
申请人： IHARA CHEMICAL INDUSTRY CO., LTD. , SUGIYAMA, Tatsuo
发明人： IHARA CHEMICAL INDUSTRY CO., LTD.
IPC分类号： C07D237/04
CPC分类号： C07D237/04
摘要： A process for producing a hexahydropyridazine-1,2-dicarboxylate derivative represented by general formula (3) (wherein R and R represent each independently alkyl) by reacting a hydrazinedicarboxylate derivative represented by the general formula (1): R OOC-NH-NH-COOR (wherein R and R are each as defined above) with a dihalogenobutane represented by the general formula (2): X -CH2CH2CH2CH2-X (wherein X and X represent each independently halogen) in the presence of an alkali metal hydroxide, characterized by conducting the reaction in an aprotic polar solvent; and a process for producing hexahydropyridazine by decarboxylating the obtained hexahydropyridazine-1,2-dicarboxylate derivative (3), without being isolated, in the presence of an alkali metal hydroxide and a hydrogen donor compound.
摘要翻译：由通式（3）表示的肼基二羧酸酯衍生物（1）表示的通式（3）表示的六氢哒嗪-1,2-二羧酸酯衍生物的制造方法（其中R 1和R 2各自独立地为烷基） R 2 OOC-NH-NH-COOR 2（其中R 1和R 2各自如上所定义）与通式（2）表示的二卤代丁烷：X 1 -CH 2 CH 2 CH 2 CH 2 - X 2（其中X 1和X 2各自独立地为卤素）在碱金属氢氧化物的存在下反应，其特征在于在非质子极性溶剂中进行反应; 以及通过在碱金属氢氧化物和氢供体化合物的存在下将所得六氢哒嗪-1,2-二羧酸酯衍生物（3）脱羧而不分离来制备六氢哒嗪的方法。

5. 发明申请

WO1993008152A1 PROCESS FOR PRODUCING HALOMETHYL ESTER OF ALIPHATIC CARBOXYLIC ACID 审中-公开
标题翻译：生产乙酰羧酸的甲醛的方法
公开(公告)号：WO1993008152A1
公开(公告)日：1993-04-29
申请号：PCT/JP1992001350
申请日：1992-10-16
申请人： IHARA CHEMICAL INDUSTRY CO., LTD. , OZAWA, Noriyuki , YAZAWA, Naoto
发明人： IHARA CHEMICAL INDUSTRY CO., LTD.
IPC分类号： C07C69/63
CPC分类号： C07C67/11 , C07C69/63
摘要： A process for producing a halomethyl ester of an aliphatic carboxylic acid by the reaction of a metallic salt of the acid with a dihalmethane in the presence of a phase transfer catalyst. The above reaction makes it possible to produce the halomethyl ester in good yields without forming halomethyl ether as by-product. This process is suitable for the industrial production of a halomethyl ester of an aliphatic carboxylic acid, because a bis-(aliphatic carbonyloxy)methane formed as a by-product is quantitatively hydrolyzed into an aliphatic carboxylic acid which can be recovered for reuse.

6. 发明申请

WO1992017468A1 PYRIDINE DERIVATIVE, PRODUCTION THEREOF, HERBICIDE AND METHOD OF WEEDING 审中-公开
标题翻译：吡啶衍生物，其生产方法，除草剂和加料方法
公开(公告)号：WO1992017468A1
公开(公告)日：1992-10-15
申请号：PCT/JP1992000362
申请日：1992-03-26
申请人： KUMIAI CHEMICAL INDUSTRY CO., LTD. , IHARA CHEMICAL INDUSTRY CO., LTD. , MIYAZAKI, Masahiro , MATSUZAWA, Masafumi , TORIYABE, Keiji , HIRATA, Michiya
发明人： KUMIAI CHEMICAL INDUSTRY CO., LTD. , IHARA CHEMICAL INDUSTRY CO., LTD.
IPC分类号： C07D401/12
CPC分类号： C07D401/12 , A01N43/54 , A01N43/66 , A01N43/68 , A01N43/70 , C07D401/14
摘要： A pyridine derivative represented by general formula (I), a process for producing the same, and a herbicide comprising the same. In formula (I) W represents oxygen, sulfur, NH or N-C(O)B wherein B represents hydrogen or alkoxy; and Z represents methine or nitrogen. This compound has an excellent herbicidal effect on annual and perennial weeds growing in lowland and upland fields even in an extremely low dose. Since it is harmless to wheat, cotton and corn, it can be used as a herbicide in the fields where these crops are cultivated.

7. 发明申请

WO1992007846A1 PICOLINIC ACID DERIVATIVE, PRODUCTION THEREOF, AND HERBICIDE 审中-公开
标题翻译：皮质醇衍生物，生产和除草剂
公开(公告)号：WO1992007846A1
公开(公告)日：1992-05-14
申请号：PCT/JP1991001459
申请日：1991-10-25
申请人： KUMIAI CHEMICAL INDUSTRY CO., LTD. , IHARA CHEMICAL INDUSTRY CO., LTD. , TAKABE, Fumiaki , SAITO, Yoshihiro , TAMARU, Masatoshi , TACHIKAWA, Shigehiko , HANAI, Ryo
发明人： KUMIAI CHEMICAL INDUSTRY CO., LTD. , IHARA CHEMICAL INDUSTRY CO., LTD.
IPC分类号： C07D401/12
CPC分类号： C07D401/12 , A01N43/54 , C07D401/14
摘要： A novel picolinic acid represented by general formula (1) and its salt, a process for producing the same, and a herbicide containing the same as the active ingredient, wherein R represents hydrogen, alkyl, etc.; R?1 and R2¿ may be the same or different from each other and each represents cyano, phenoxy, etc.; Y represents oxygen, sulfur, etc.; and n represents 0 or 1. The derivative and its salt have an excellent herbicidal effect on a wide variety of weeds even in small doses, so that they are applicable as a herbicide to lowland and upland fields, non-crop land, and so forth.

8. 发明申请

WO1996038406A1 PHENYLALKANAMIDE DERIVATIVES AND AGROHORTICULTURAL BACTERICIDES 审中-公开
标题翻译：苯甲酰胺衍生物和农业杀菌剂
公开(公告)号：WO1996038406A1
公开(公告)日：1996-12-05
申请号：PCT/JP1996001419
申请日：1996-05-29
申请人： KUMIAI CHEMICAL INDUSTRY CO., LTD. , IHARA CHEMICAL INDUSTRY CO., LTD. , MASUDA, Katsumi , URUSHIBATA, Ikumi , ASAHARA, Tsuyoshi , FURUSE, Katsumi , KOJIMA, Yoshiyuki , ABE, Hiroshi
发明人： KUMIAI CHEMICAL INDUSTRY CO., LTD. , IHARA CHEMICAL INDUSTRY CO., LTD.
IPC分类号： C07C233/51
CPC分类号： C07D213/643 , A01N37/46 , A01N37/48 , A01N41/10 , A01N43/10 , A01N43/40 , C07C233/51 , C07C237/22 , C07C255/25 , C07C255/29 , C07C255/31 , C07C255/46 , C07C255/57 , C07C317/44 , C07C323/62 , C07C2601/02 , C07C2601/08 , C07D213/54 , C07D213/65 , C07D213/68 , C07D213/70 , C07D307/54 , C07D333/24
摘要： Phenylalkanamide derivatives represented by general formula (1) and novel agrohorticultural bactericides containing the same as the active ingredient, wherein R represents hydrogen, alkyl, etc.; R , R and R represent each alkyl, hydrogen, etc.; Q represents cyano, carboxyl, etc.; X represents alkyl, alkoxy, halogeno, aryl, etc.; n represents an integer of 0 to 3; and Y and Z represent each alkyl, hydrogen, etc. The bactericides have a remarkably high preventive effect on rice blast, apple scab, and so forth without adversely affecting the crops, and excellent in permeability and translocatability, thus exhibiting a remarkably high control effect on rice blast in submerged application.
摘要翻译：由通式（1）表示的苯基烷酰胺衍生物和含有与活性成分相同的新型农业园艺杀菌剂，其中R 1表示氢，烷基等; R 2，R 3和R 4分别代表烷基，氢等; Q表示氰基，羧基等; X表示烷基，烷氧基，卤代，芳基等; n表示0〜3的整数， Y和Z代表烷基，氢等。杀菌剂对稻瘟病，苹果痂等具有非常高的预防效果，对作物不会有不利影响，渗透性和易位性优异，因此显示出显着的控制效果在水稻淹水应用中。

9. 发明申请

WO1996033168A1 BENZYLSULFIDE DERIVATIVE, PROCESS FOR ITS PRODUCTION AND PESTICIDE 审中-公开
标题翻译： BENZYLSULFIDE DERIVATIVE，PROCESS FOR I PRODUCTIVE AND PESTICIDE
公开(公告)号：WO1996033168A1
公开(公告)日：1996-10-24
申请号：PCT/JP1996001055
申请日：1996-04-18
申请人： KUMIAI CHEMICAL INDUSTRY CO., LTD. , IHARA CHEMICAL INDUSTRY CO., LTD. , TORIYABE, Keiji , SASAKI, Hideharu , MASUYAMA, Naoshi , NAGAI, Akihide , YANO, Hiroyuki , KAWASHIMA, Mieko , KURIHARA, Yutaka , SHIMAZU, Tomonori
发明人： KUMIAI CHEMICAL INDUSTRY CO., LTD. , IHARA CHEMICAL INDUSTRY CO., LTD.
IPC分类号： C07C317/28
CPC分类号： C07C317/28 , A01N33/26 , A01N35/04 , A01N35/10 , A01N37/28 , A01N41/06 , A01N41/10 , A01N43/36 , A01N43/40 , A01N43/653 , A01N47/02 , A01N47/24 , A01N47/34 , A01N51/00 , C07C251/86 , C07C323/48 , C07C323/60 , C07D213/61
摘要： The present invention presents a benzylsulfide derivative of formula (I) or its salt: wherein R is a C1-6 alkyl group, a C1-6 haloalkyl group, a C2-4 alkenyl group, a cyano group, etc., and each of R and R is a hydrogen atom, a halogen atom, a cyano group, a C1-4 alkyl group, a C1-3 haloalkyl group, etc., R is a hydrogen atom, a halogen atom, a C1-4 alkyl group, etc., A is a hydrazinoaralkyl group or hydrazonoaralkyl group, and n is 0, 1 or 2; a process for its production; and a pesticide containing such a benzylsulfide derivative as an active ingredient. The benzylsufide derivative of the present invention is capable of controlling various pests without adversely affecting crop plants.
摘要翻译：本发明提供式（I）的苄基硫醚衍生物或其盐：其中R 1为C 1-6烷基，C 1-6卤代烷基，C 2-4链烯基，氰基等， R 2和R 3各自为氢原子，卤素原子，氰基，C 1-4烷基，C 1-3卤代烷基等，R 4为氢原子卤素原子，C 1-4烷基等，A为亚肼基烷基或亚肼基烷基，n为0,1或2; 一个生产过程; 以及含有苄基硫醚衍生物作为有效成分的农药。本发明的苄基硒化物衍生物能够控制各种害虫而不会不利地影响作物。

10. 发明申请

WO1995009165A1 PROCESS FOR PRODUCING 2-SUBSTITUTED BENZO[b]THIOPHENE 审中-公开
标题翻译：生产2-取代苯并[b]噻吩的方法
公开(公告)号：WO1995009165A1
公开(公告)日：1995-04-06
申请号：PCT/JP1994001578
申请日：1994-09-26
申请人： IHARA CHEMICAL INDUSTRY CO., LTD. , YAZAWA, Naoto , SAITO, Yoshinori , HIYOSHI, Hidetaka , YOSHIDA, Yasuo
发明人： IHARA CHEMICAL INDUSTRY CO., LTD.
IPC分类号： C07D333/56
CPC分类号： C07D333/60 , C07D333/56 , C07D333/70
摘要： An industrial process for producing a 2-substituted benzo[b]thiophene which is highly effective in that it can afford the target compound in a high yield with a simple operation without the necessity for using unstable starting materials. The process comprises reacting an optionally substituted 2-halogenobenzaldehyde with either a compound represented by the general formula (1): HiSjMk (wherein M represents an alkali metal atom; i represents an integer of 0 or 1; j represents an integer of 1 or above; and k represents an integer of 1 or 2; provided i + k = 2) and sulfur, or a compound represented by the above formula (1) (wherein j is 2 or above) in the presence of an aprotic polar solvent, and then reacting the reaction product with a compound represented by the general formula (2): XCH2R (wherein X represents a halogen atom; and R represents acyl, optionally substituted alkoxycarbonyl, optionally substituted arylcarbonyl, or cyano) to effect intramolecular ring closure.
摘要翻译：用于生产2-取代的苯并[b]噻吩的工业方法是非常有效的，因为它可以通过简单的操作以高产率获得目标化合物，而不需要使用不稳定的起始材料。该方法包括使任选取代的2-卤代苯甲醛与由通式（1）表示的化合物：HiSjMk（其中M表示碱金属原子; i表示0或1的整数; j表示1以上的整数） ; k表示1或2的整数; i + k = 2）和硫，或由上式（1）表示的化合物（其中j为2以上）在非质子极性溶剂的存在下，以及然后使反应产物与由通式（2）表示的化合物：XCH 2 R（其中X表示卤素原子; R表示酰基，任选取代的烷氧基羰基，任选取代的芳基羰基或氰基）反应以实现分子内闭环。

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