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1. 发明申请

WO2002092549A1 AGITATION SYSTEM FOR ALKYLBENZENE OXIDATION REACTORS 审中-公开
标题翻译：氨基苯氧化反应器的催化体系
公开(公告)号：WO2002092549A1
公开(公告)日：2002-11-21
申请号：PCT/US2002/013216
申请日：2002-04-24
申请人： INCA INTERNATIONAL S.P.A. , GNAGNETTI, Andrea , PIRAS, Luciano , KAR, Kishore
发明人： GNAGNETTI, Andrea , PIRAS, Luciano , KAR, Kishore
IPC分类号： C07C51/265
CPC分类号： B01J19/0066 , B01F3/04531 , B01F7/00241 , B01F7/0025 , B01F7/00341 , B01F7/00641 , B01F7/16 , B01J8/222 , B01J2219/00779 , C07C51/265 , C07C63/24 , C07C63/16 , C07C63/26
摘要： The present invention relates to a process for producing aromatic dicarboxylic acids by the oxidation of dimethylbenzenes wherein the dimethylbenzenes are mixed with an oxygen containing gas, solvent and catalyst in a reactor, the improvement comprising agitating the reaction mixture with one or more asymmetric radial impellers in combination with at least one axial impeller.
摘要翻译：本发明涉及通过氧化二甲苯生产芳族二羧酸的方法，其中二甲基苯与含氧气体，溶剂和催化剂在反应器中混合，其改进包括用一个或多个不对称径向叶轮将反应混合物搅拌与至少一个轴向叶轮组合。

2. 发明申请

WO1996019518A1 POLYCONDENSATION CATALYZERS FOR THE SYNTHESIS OF POLYETHYLENE TEREPHTALATE 审中-公开
标题翻译：用于合成聚乙烯（TEREPHTALATEATE）的聚合催化剂
公开(公告)号：WO1996019518A1
公开(公告)日：1996-06-27
申请号：PCT/EP1995004883
申请日：1995-12-06
申请人： ENICHEM S.P.A. , INCA INTERNATIONAL S.P.A. , PO', Riccardo , PELOSINI, Luigi
发明人： ENICHEM S.P.A. , INCA INTERNATIONAL S.P.A.
IPC分类号： C08G63/82
CPC分类号： C08G63/82
摘要： The subject is a class of catalyzers to be used in the stage of polycondensation of the synthesis of poly(ethylene terephtalate), consisting of metal and non-metal derivatives in composition with sulfonic acids mixed with titanium compounds so that the final polymer contains a sulfur quantity of 5-60 ppm and a quantity of metals between 2 and 100 ppm.
摘要翻译：该主题是一类催化剂，用于在与钛化合物混合的磺酸的组合物中由金属和非金属衍生物组成的聚（对苯二甲酸乙二醇酯）的缩聚阶段中使用，使得最终聚合物含有硫数量为5-60ppm，金属量为2〜100ppm。

3. 发明授权

EP1254098B1 OXIDATION OF ALKYL AROMATIC COMPOUNDS TO AROMATIC ACIDS IN AN AQUEOUS MEDIUM 有权
标题翻译：烷基芳族化合物TO芳族酸在水性介质中的氧化
公开(公告)号：EP1254098B1
公开(公告)日：2005-11-30
申请号：EP00982303.0
申请日：2000-11-30
申请人： Inca International S.P.A.
发明人： KLIER, John , TUCKER, Christopher, J. , KALANTAR, Thomas, H. , BURDETT, Kenneth, A. , GREEN, Daniel, Patrick , PIRAS, Luciano , SCHENA, Sergio , LEE, Guo-shuh, John
IPC分类号： C07C51/265 , C07C63/26 , C07C63/38
CPC分类号： C07C51/265 , C07C63/33 , C07C65/24 , C07C65/21 , C07C63/06 , C07C53/10
摘要： The present invention pertains to an improved method of oxidizing substituted aromatic compounds (such as p xylene) to their corresponding aromatic acids (such as terephthalic acid). The improvement involves carrying out the oxidation reaction in an aqueous medium, wherein the aqueous medium contains at least 30 percent water, preferably up to 30 percent surfactant and preferably a low molecular weight material containing a hydrophilic end group as a co-surfactant. The reaction is carried out at a pH of less than 3.0.

4. 发明公开

EP1250308A1 PROCESS FOR THE RECOVERY OF PURIFIED TEREPHTHALIC ACID (PTA) 审中-公开
标题翻译：中回收精对苯二甲酸
公开(公告)号：EP1250308A1
公开(公告)日：2002-10-23
申请号：EP00979877.8
申请日：2000-11-30
申请人： Inca International S.P.A.
发明人： PIRAS, Luciano , SCHENA, Sergio , CHIARELLI, Michelle , SORO, Luigi
IPC分类号： C07C51/43 , C07C63/26
CPC分类号： C07C51/43 , C07C51/47 , C07C63/26
摘要： A process for the preparation of purified terephthalic acid which comprises first introducing a liquid slurry containing crystalized terephthalic acid with impurities into a high pressure rotary filter, then filtering the slurry with the high pressure rotary filter and collecting at least some of the solid portion. The filter typically consists of a case, pressurized at process pressure, and a drum covered by a filtering device such as, for example, a cloth or equivalent filtering device, pressurized at a pressure suitably lower than the case. The drum is ideally divided into three zones: first zone, where the mother liquor is removed; second zone, where the solid is washed; third zone, where the excess of washing liquor is removed and the solid is discharged. The solid portion is washed, onto the filter drum, with additional amounts of water. The washed solid portion is then transferred to a letdown zone, which is at a pressure less than the zone in which the solid portion was collected. After the solid portion is transferred into the letdown zone, the connection between the letdown zone and the collection zone is sealed, such that a change of pressure in the letdown zone will not effect the pressure in the collection zone. The pressure of the letdown zone is then gradually reduced and the solid removed. The letdown zone is then pressurized back up so that it is ready to accept additional solid from the rotary filter.

5. 发明授权

EP0684269B1 Process for the preparation of re-usable bottles starting from modified PET 失效
标题翻译：一种用于改性聚对苯二甲酸乙酯的重复使用的瓶的制备方法
公开(公告)号：EP0684269B1
公开(公告)日：1998-11-11
申请号：EP95107115.8
申请日：1995-05-11
申请人： ENICHEM S.p.A. , INCA INTERNATIONAL S.p.A.
发明人： Occhiello, Ernesto , Po', Riccardo
IPC分类号： C08G63/60 , C08L67/00
CPC分类号： C08L67/00 , C08G63/605 , Y10T428/1352 , Y10T428/139 , Y10T428/1397 , Y10T428/31786

6. 发明公开

EP1409445A2 PROCESS FOR THE RECOVERY OF CRUDE TEREPHTHALIC ACID (CTA) 审中-公开
标题翻译：一种获得RAW对苯二甲酸
公开(公告)号：EP1409445A2
公开(公告)日：2004-04-21
申请号：EP00979871.1
申请日：2000-11-30
申请人： Inca International S.P.A.
发明人： PIRAS, Luciano , SCHENA, Sergio , CHIARELLI, Michelle , SORO, Luigi
IPC分类号： C07C51/42 , C07C51/47 , C07C63/26 , C07C51/43
CPC分类号： C07C51/42 , C07C51/47 , C07C63/26
摘要： The present invention relates to a process for the preparation of crude terephthalic acid which comprises first introducing a slurry containing crystallized terephthalic acid with impurities in an aliphatic carboxylic acid mother liquor into a rotary filter comprising a case and a rotating drum, wherein the rotating drum is subjected to a uniform pressure differential over the entire drum, and the inside of the drum is at a pressure approximately equal to atmospheric pressure or greater, then filtering said slurry; and finally collecting at least some of the solid portion. Other aspects of the invention include continuously adding the original slurry to the rotary filter and washing the solid portion with additional aliphatic carboxylic acid, water or a combination of the two. The solid portion can then be transferred to a reslurry tank which is at the same pressure as the pressure at the point where the solid portion was collected. The present invention also relates to a process for the preparation of crude terephthalic acid which comprises first introducing a slurry containing crystallized terephthalic acid with impurities in an aliphatic carboxylic acid mother liquor into a rotary filter comprising a case and a rotating drum, wherein the rotating drum is subjected to a uniform pressure differential over the entire drum, then filtering said slurry, washing the solid portion with water; and finally collecting at least some of the solid portion. Other aspects of the invention include continuously adding the original slurry to the rotary filter and additional washing with the aliphatic carboxylic acid mother liquor. The inside of the drum can be less than, greater than or approximately equal to atmospheric pressure. The solid portion can then be transferred to a reslurry tank which is at the same pressure as the pressure at the point where the solid portion was collected.

7. 发明公开

EP0799268A1 POLYCONDENSATION CATALYZERS FOR THE SYNTHESIS OF POLYETHYLENE TEREPHTALATE 失效
标题翻译： POLYKONDENSATIONSKATALYSATORE生产聚对苯二甲酸乙酯的
公开(公告)号：EP0799268A1
公开(公告)日：1997-10-08
申请号：EP95942112.0
申请日：1995-12-06
申请人： ENICHEM S.p.A. , INCA INTERNATIONAL S.P.A.
发明人： PO', Riccardo , PELOSINI, Luigi
IPC分类号： C08F4 , C08G63
CPC分类号： C08G63/82
摘要： The subject is a class of catalyzers to be used in the stage of polycondensation of the synthesis of poly(ethylene terephtalate), consisting of metal and non-metal derivatives in composition with sulfonic acids mixed with titanium compounds so that the final polymer contains a sulfur quantity of 5-60 ppm and a quantity of metals between 2 and 100 ppm.

8. 发明公开

EP0684269A2 Process for the preparation of re-usable bottles starting from modified PET 失效
标题翻译：一种用于改性聚对苯二甲酸乙酯的重复使用的瓶的制备方法。
公开(公告)号：EP0684269A2
公开(公告)日：1995-11-29
申请号：EP95107115.8
申请日：1995-05-11
申请人： ENICHEM S.p.A. , INCA INTERNATIONAL S.p.A.
发明人： Occhiello, Ernesto , Po', Riccardo
IPC分类号： C08G63/60 , C08L67/00
CPC分类号： C08L67/00 , C08G63/605 , Y10T428/1352 , Y10T428/139 , Y10T428/1397 , Y10T428/31786
摘要： Process for the preparation of transparent re-usable bottles, which consists in moulding by injection-blow moulding cycle copolymers containing units deriving from terephthalic acid and ethylene glycol characterized in that said copolymers contain from 0.1 to 10% in moles of units deriving from aromatic diacids different from terephthalic acid and from 0.1 - 15% in moles of units deriving from aromatic hydroxyacids, making reference to the units deriving from terephthalic acid.
摘要翻译：用于制备透明可再用瓶，其中通过注射吹塑成型周期共聚物含有来自在那个特征的对苯二甲酸和乙二醇衍生单元在成型besteht处理所述共聚物包含从0.1到10％，从芳族二酸衍生的单元的摩尔 15％的芳族羟基酸衍生，使得参考从对苯二甲酸衍生单元单元的摩尔 - 由对苯二甲酸和0.1不同。

9. 发明公开

EP1254098A1 OXIDATION OF ALKYL AROMATIC COMPOUNDS TO AROMATIC ACIDS IN AN AQUEOUS MEDIUM 有权
标题翻译：氧化钌烷基化物在中性介质中的ZU芳香族
公开(公告)号：EP1254098A1
公开(公告)日：2002-11-06
申请号：EP00982303.0
申请日：2000-11-30
申请人： Inca International S.P.A.
发明人： KLIER, John , TUCKER, Christopher, J. , KALANTAR, Thomas, H. , BURDETT, Kenneth, A. , GREEN, Daniel, Patrick , PIRAS, Luciano , SCHENA, Sergio , LEE, Guo-shuh, John
IPC分类号： C07C51/265 , C07C63/26 , C07C63/38
CPC分类号： C07C51/265 , C07C63/33 , C07C65/24 , C07C65/21 , C07C63/06 , C07C53/10
摘要： The present invention pertains to an improved method of oxidizing substituted aromatic compounds (such as p xylene) to their corresponding aromatic acids (such as terephthalic acid). The improvement involves carrying out the oxidation reaction in an aqueous medium, wherein the aqueous medium contains at least 30 percent water, preferably up to 30 percent surfactant and preferably a low molecular weight material containing a hydrophilic end group as a co-surfactant. The reaction is carried out at a pH of less than 3.0.
摘要翻译：本发明涉及将取代的芳族化合物（例如对二甲苯）氧化成其相应的芳族酸（例如对苯二甲酸）的改进方法。改进包括在水性介质中进行氧化反应，其中水性介质含有至少30％的水，优选至多30％的表面活性剂，优选含有亲水端基作为辅助表面活性剂的低分子量材料。该反应在小于3.0的pH下进行。

10. 发明公开

EP0684269A3 Process for the preparation of re-usable bottles starting from modified PET 失效
标题翻译：一种用于改性聚对苯二甲酸乙酯的重复使用的瓶的制备方法。
公开(公告)号：EP0684269A3
公开(公告)日：1996-12-18
申请号：EP95107115.8
申请日：1995-05-11
申请人： ENICHEM S.p.A. , INCA INTERNATIONAL S.p.A.
发明人： Occhiello, Ernesto , Po', Riccardo
IPC分类号： C08G63/60 , C08L67/00
CPC分类号： C08L67/00 , C08G63/605 , Y10T428/1352 , Y10T428/139 , Y10T428/1397 , Y10T428/31786
摘要： Process for the preparation of transparent re-usable bottles, which consists in moulding by injection-blow moulding cycle copolymers containing units deriving from terephthalic acid and ethylene glycol characterized in that said copolymers contain from 0.1 to 10% in moles of units deriving from aromatic diacids different from terephthalic acid and from 0.1 - 15% in moles of units deriving from aromatic hydroxyacids, making reference to the units deriving from terephthalic acid.

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