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1. 发明申请

US20050227854A1 Titanium dioxide photocatalyst containing carbon and method for its production 有权
公开(公告)号：US20050227854A1
公开(公告)日：2005-10-13
申请号：US11095817
申请日：2005-04-01
申请人： Jurgen Orth-Gerber , Horst Kisch
发明人： Jurgen Orth-Gerber , Horst Kisch
IPC分类号： B01J21/06 , B01J35/00 , C01G23/047 , C02F1/28 , C02F1/30 , C02F1/32 , C02F1/72 , C09C1/36 , B01J21/00
CPC分类号： B82Y30/00 , B01J21/063 , B01J35/0033 , B01J35/004 , C01G23/047 , C01P2002/30 , C01P2002/54 , C01P2002/72 , C01P2002/86 , C01P2004/04 , C01P2004/64 , C01P2006/12 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C02F1/283 , C02F1/32 , C02F1/725 , C02F2305/10 , C09C1/3669 , Y10T428/249921
摘要： The invention relates to a titanium dioxide-based photocatalyst containing carbon that is highly photoactive in visible light (vlp-TiO2) and to a method of manufacture. The vlp-TiO2 is manufactured by mixing a fine grained titanium compount (BET≧50 m2/g) with an organic carbon compound and subsequent thermal treatment at temperatures up to 350° C. The carbon content amounts to 0.05 to 4% by weight, preferably 0.4 to 0.8% by weight. The product is characterized by an ESR spectrum which displays only one significant signal in the g value range from 1.97 to 2.05 at g about 2.003. The inventive photocatalyst can be used for to degrade contaminants and pollutants in liquids and gases.

2. 发明申请

US20050226761A1 Titanium dioxide photocatalyst containing carbon and method for its production 有权
标题翻译：含有二氧化钛光催化剂的碳及其生产方法
公开(公告)号：US20050226761A1
公开(公告)日：2005-10-13
申请号：US11096299
申请日：2005-04-01
申请人： Jurgen Orth-Gerber , Horst Kisch
发明人： Jurgen Orth-Gerber , Horst Kisch
IPC分类号： B01J21/06 , B01J35/00 , C01G23/047 , C02F1/28 , C02F1/30 , C02F1/32 , C02F1/72 , C09C1/36 , C22C14/00
CPC分类号： B82Y30/00 , B01J21/063 , B01J35/0033 , B01J35/004 , C01G23/047 , C01P2002/30 , C01P2002/54 , C01P2002/72 , C01P2002/86 , C01P2004/04 , C01P2004/64 , C01P2006/12 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C02F1/283 , C02F1/32 , C02F1/725 , C02F2305/10 , C09C1/3669 , Y10T428/249921
摘要： The invention relates to a titanium dioxide-based photocatalyst containing carbon that is highly photoactive in visible light (vlp-TiO2) and to a method of manufacture. The vlp-TiO2 is manufactured by mixing a fine grained titanium compount (BET≧50 m2/g) with an organic carbon compound and subsequent thermal treatment at temperatures up to 350° C. The carbon content amounts to 0.05 to 4% by weight, preferably 0.4 to 0.8% by weight. The product is characterized by an ESR spectrum which displays only one significant signal in the g value range from 1.97 to 2.05 at g about 2.003. The inventive photocatalyst can be used for to degrade contaminants and pollutants in liquids and gases.
摘要翻译：本发明涉及含有在可见光（vlp-TiO 2）中具有高光活性的碳的二氧化钛类光催化剂及其制造方法。通过将细晶粒钛（BET）= 50m 2 / g / g）与有机碳化合物混合并随后在升温下进行热处理来制备vlp-TiO 2 至350℃。碳含量为0.05〜4重量％，优选为0.4〜0.8重量％。该产品的特征在于ESR光谱，其仅在g值范围从1.97至2.05，仅显示约2.003的一个显着信号。本发明的光催化剂可用于降解液体和气体中的污染物和污染物。

3. 发明授权

US4325793A Catalysis of photochemical production of hydrogen from water 失效
标题翻译：从水中催化光化学生成氢
公开(公告)号：US4325793A
公开(公告)日：1982-04-20
申请号：US266865
申请日：1981-05-26
申请人： Horst Kisch
发明人： Horst Kisch
IPC分类号： B01J19/12 , B01J31/22 , C01B3/04
CPC分类号： B01J31/1805 , B01J19/122 , B01J31/182 , B01J31/226 , C01B3/042 , B01J2531/10 , B01J2531/20 , B01J2531/22 , B01J2531/26 , B01J2531/40 , B01J2531/50 , B01J2531/60 , B01J2531/70 , B01J2531/80 , B01J2531/842 , B01J2531/847 , Y02E60/364 , Y10S204/909 , Y10S502/522
摘要： The invention is a catalytic process for splitting water to provide hydrogen by irradiating an aqueous solution with actinic light. The solution contains a catalyst comprising a complex compound of a metal of the Group Ib, IIb, IVb, Vb, VIb, VIIb and VIIIb of the periodic system or magnesium, having ligands linked to the metal atom via two sulfur atoms or via one sulfur atom and one nitrogen atom.
摘要翻译：本发明是通过用光化光照射水溶液来分解水以提供氢的催化方法。该溶液含有一种催化剂，其包含周期系统的Ib族，IIb族，IVb族，Vb族，VIb族，VIIb族和VIIIb族金属的络合物或镁，其具有通过两个硫原子与金属原子连接的配体或通过一个硫原子和一个氮原子。

4. 发明申请

US20100087310A1 Heptazine Modified Titanium Dioxide Photocatalyst and Method for Its Manufacture 审中-公开
标题翻译：七肽改性二氧化钛光催化剂及其制备方法
公开(公告)号：US20100087310A1
公开(公告)日：2010-04-08
申请号：US12570212
申请日：2009-09-30
申请人： Horst Kisch , Dariusz Mitoraj
发明人： Horst Kisch , Dariusz Mitoraj
IPC分类号： H01M4/88 , B01J31/02
CPC分类号： B01J35/004 , A61L9/205 , A61L2209/16 , B01D53/8678 , B01D2255/20707 , B01D2255/802 , B01D2257/70 , B01D2259/802 , B01J21/063 , B01J31/0244 , B01J31/0254 , B01J35/002 , B01J35/0033 , B01J35/1019 , B01J37/0225 , B01J37/08 , B01J37/082 , C02F1/30 , C02F2303/04 , C02F2305/10 , C09D5/14
摘要： The invention is a heptazine modified photocatalyst based on titanium dioxide that is photoactive in the visible range, also referred to as TiO2—(N═C)x below. The new photocatalyst permits pollutant degradation not only with artificial visible light but also with the diffuse daylight in rooms The invention also is a method for manufacturing a heptazine modified titanium dioxide (TiO2—(N═C)x) that is effective as a photocatalyst when irradiated with visible light.
摘要翻译：本发明是基于在可见光范围内具有光活性的二氧化钛的七嗪改性光催化剂，也称为TiO 2 - （N = C）x。新的光催化剂不仅可以通过人造可见光进行污染物降解，而且还可以与房间中的漫射日光一起使用本发明也是制备作为光催化剂有效的七嗪改性二氧化钛（TiO 2 - （N = C）x）的方法，用可见光照射。

5. 发明授权

US07524793B2 Titanium dioxide photocatalyst containing carbon and method for its production 有权
标题翻译：含有二氧化钛光催化剂的碳及其生产方法
公开(公告)号：US07524793B2
公开(公告)日：2009-04-28
申请号：US11095817
申请日：2005-04-01
申请人： Jürgen Orth-Gerber , Horst Kisch , Sakthivel Shanmugasundaram
发明人： Jürgen Orth-Gerber , Horst Kisch , Sakthivel Shanmugasundaram
IPC分类号： B01J23/00 , C01G23/047 , B05D7/00
CPC分类号： B82Y30/00 , B01J21/063 , B01J35/0033 , B01J35/004 , C01G23/047 , C01P2002/30 , C01P2002/54 , C01P2002/72 , C01P2002/86 , C01P2004/04 , C01P2004/64 , C01P2006/12 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C02F1/283 , C02F1/32 , C02F1/725 , C02F2305/10 , C09C1/3669 , Y10T428/249921
摘要： The invention relates to a titanium dioxide-based photocatalyst containing carbon that is highly photoactive in visible light (vlp-TiO2) and to a method of manufacture. The vlp-TiO2 is manufactured by mixing a fine grained titanium compound (BET≧50 m2/g) with an organic carbon compound and subsequent thermal treatment at temperatures up to 350° C. The carbon content amounts to 0.05 to 4% by weight, preferably 0.4 to 0.8% by weight. The product is characterized by an ESR spectrum which displays only one significant signal in the g value range from 1.97 to 2.05 at g about 2.003. The inventive photocatalyst can be used for to degrade contaminants and pollutants in liquids and gases.
摘要翻译：本发明涉及含有在可见光（vlp-TiO2）中具有高度光活性的碳的二氧化钛类光催化剂及其制造方法。通过将细晶粒钛化合物（BET> = 50m 2 / g）与有机碳化合物混合并随后在高达350℃的温度下进行热处理来制备vlp-TiO 2。碳含量为0.05-4重量％，优选为0.4〜0.8重量％。该产品的特征在于ESR光谱，其仅在g值范围从1.97至2.05，仅显示约2.003的一个显着信号。本发明的光催化剂可用于降解液体和气体中的污染物和污染物。

6. 发明申请

US20120270028A1 Titanium dioxide photocatalyst containing carbon and method for its production 审中-公开
标题翻译：含有二氧化钛光催化剂的碳及其生产方法
公开(公告)号：US20120270028A1
公开(公告)日：2012-10-25
申请号：US12427078
申请日：2009-04-21
申请人： Jurgen Orth-Gerber , Horst Kisch , Shanmugasundaram Sakthivel
发明人： Jurgen Orth-Gerber , Horst Kisch , Shanmugasundaram Sakthivel
IPC分类号： B01J21/18 , C08K5/053 , C04B35/46 , C04B24/02 , C09K3/00 , C08K5/092 , C04B24/04
CPC分类号： B82Y30/00 , B01J21/063 , B01J35/0033 , B01J35/004 , C01G23/047 , C01P2002/30 , C01P2002/54 , C01P2002/72 , C01P2002/86 , C01P2004/04 , C01P2004/64 , C01P2006/12 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C02F1/283 , C02F1/32 , C02F1/725 , C02F2305/10 , C09C1/3669 , Y10T428/249921
摘要： The invetion relates to a titanium dioxide-based photocatalyst containing carbon that is highly photoactive in visible light (vlp-TiO2) and to a method of manufacture. The vlp-TiO2is manufactured by mixing a fine grained titanium compount (BET≧50 m2/g) with an organic carbon compound and subsequent thermal treatment at temperatures up to 350° C. The carbon content amounts to 0.05 to 4% by weight, preferably 0.4 to 0.8% by weight. The product is characterized by an ESR spectrum which displays only one significant signal in the g value range from 1.97 to 2.05 at g about 2.003. The inventive photocatalyst can be used for to degrade contaminants and pollutants in liquids and gases.
摘要翻译：该投入涉及含有在可见光（vlp-TiO2）中具有高度光活性的碳的二氧化钛基光催化剂以及制造方法。 vlp-TiO2是通过将细晶粒钛（BET≥50m2 / g）与有机碳化合物混合，然后在高达350℃的温度下进行热处理制造的。碳含量为0.05-4重量％，优选 0.4〜0.8重量％。该产品的特征在于ESR光谱，其仅在g值范围从1.97至2.05，仅显示约2.003的一个显着信号。本发明的光催化剂可用于降解液体和气体中的污染物和污染物。

7. 发明申请

US20100058954A1 Novel Carbon-Modified Photocatalyst Films and Method for Producing Same 审中-公开
标题翻译：新型碳改性光催化膜及其制备方法
公开(公告)号：US20100058954A1
公开(公告)日：2010-03-11
申请号：US12555326
申请日：2009-09-08
申请人： Horst Kisch
发明人： Horst Kisch
IPC分类号： C09D7/12 , C23C16/44
CPC分类号： C23C16/405 , B01J21/063 , B01J27/20 , B01J35/004 , B01J37/0219 , B01J37/0238 , B01J37/086 , C01G23/07 , C23C16/4482 , Y02A50/2327
摘要： A novel carbon-modified titanium dioxide film (CMF-TiO2) and a method for producing same by a CVD method at atmospheric pressure. The precursor compounds used in this context for the titanium dioxide and the carbon component are titanium-organic compounds and unsaturated aromatic hydrocarbons. Thermal treatment at about 250° C. to about 600° C., preferable at about 250° C. to about 300° C. forms a CMF-TiO2, the carbon content of which is about 0.2% to about 10.0% by weight, preferably about 0.2% to about 6.0% by weight and particularly preferably about 0.2% to about 2.5% by weight. A CMF-TiO2 film is characterised by high catalytic activity in the degradation of air and water pollutants with visible light and light absorption in the range from 400 nm to 700 nm, as well as by 1) a quasi-Fermi level of the electrons of −0.5 V at pH 7 (relative to NHE) and/or by 2) C1s bonding energies of 284.8, 286.3 and 288.8 eV; and/or by 3) an isotropic electronic spin resonance (ESR) signal at a g-value of 1.900 to 2.005.
摘要翻译：一种新型碳改性二氧化钛膜（CMF-TiO2）及其在大气压下通过CVD法制造的方法。在本文中用于二氧化钛和碳组分的前体化合物是钛 - 有机化合物和不饱和芳族烃。约250℃至约600℃，优选约250℃至约300℃的热处理形成CMF-TiO 2，其碳含量为约0.2重量％至约10.0重量％优选约0.2％至约6.0％重量，特别优选约0.2％至约2.5％重量。 CMF-TiO2膜的特征在于在空气和水污染物的降解中具有高的催化活性，可见光和光吸收在400nm至700nm的范围内，以及1）准费米能级的电子 -0.5V（相对于NHE）和/或通过2）C1s键合能量为284.8,286.3和288.8eV; 和/或3）在g值为1.900至2.005的各向同性电子自旋共振（ESR）信号。

8. 发明授权

US07615512B2 Titanium dioxide photocatalyst containing carbon and method for its production 有权
标题翻译：含有二氧化钛光催化剂的碳及其生产方法
公开(公告)号：US07615512B2
公开(公告)日：2009-11-10
申请号：US11096299
申请日：2005-04-01
申请人： Jürgen Orth-Gerber , Horst Kisch
发明人： Jürgen Orth-Gerber , Horst Kisch
IPC分类号： B01J23/00 , C01G23/047 , B05D7/00
CPC分类号： B82Y30/00 , B01J21/063 , B01J35/0033 , B01J35/004 , C01G23/047 , C01P2002/30 , C01P2002/54 , C01P2002/72 , C01P2002/86 , C01P2004/04 , C01P2004/64 , C01P2006/12 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C02F1/283 , C02F1/32 , C02F1/725 , C02F2305/10 , C09C1/3669 , Y10T428/249921
摘要： The invention relates to a titanium dioxide-based photocatalyst containing carbon that is highly photoactive in visible light (vlp-TiO2) and to a method of manufacture. The vlp-TiO2 is manufactured by mixing a fine grained titanium compount (BET≧50 m2/g) with an organic carbon compound and subsequent thermal treatment at temperatures up to 350° C. The carbon content amounts to 0.05 to 4% by weight, preferably 0.4 to 0.8% by weight. The product is characterized by an ESR spectrum which displays only one significant signal in the g value range from 1.97 to 2.05 at g about 2.003. The inventive photocatalyst can be used for to degrade contaminants and pollutants in liquids and gases.
摘要翻译：本发明涉及含有在可见光（vlp-TiO2）中具有高度光活性的碳的二氧化钛类光催化剂及其制造方法。 vlp-TiO2是通过将细晶粒钛（BET> = 50m2 / g）与有机碳化合物混合并在高达350℃的温度下进行热处理来制造的。碳含量为0.05-4重量％，优选为0.4〜0.8重量％。该产品的特征在于ESR光谱，其仅在g值范围从1.97至2.05，仅显示约2.003的一个显着信号。本发明的光催化剂可用于降解液体和气体中的污染物和污染物。

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