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    • 9. 发明授权
    • Mesh-adjustable molecular sieve
    • 可调式分子筛
    • US08337591B2
    • 2012-12-25
    • US12728299
    • 2010-03-22
    • Hong-Cai ZhouShengqian Ma
    • Hong-Cai ZhouShengqian Ma
    • B01D53/02B01J20/22
    • C07F15/065B01D2253/204B01J20/226B01J20/28078C07C51/09C07C63/331C07F1/005C07F3/003C07F15/045Y10S95/902
    • A metal-organic framework-based mesh-adjustable molecular sieve (MAMS) exhibiting a temperature-dependent mesh size. The MAMS comprises a plurality of metal clusters bound with a plurality of amphiphilic ligands, each ligand comprising a hydrophobic moiety and a functionalized hydrophilic moiety, and wherein the metal clusters and amphiphilic ligand functionalized hydrophilic moieties form a metal cluster layer, the metal cluster layer forming at least one hydrophilic pore. On each side of the metal cluster layer, a plurality of associated amphiphilic ligand hydrophobic moieties cooperate with the metal cluster layer to form a tri-layer and a plurality of tri-layers are packed in a facing-spaced apart relationship to form at least one hydrophobic pore.
    • 基于金属 - 有机骨架的可调网格分子筛(MAMS)显示温度依赖的网孔尺寸。 MAMS包括与多个两亲配体结合的多个金属簇,每个配体包含疏水部分和官能化的亲水部分,并且其中金属簇和两亲配体官能化的亲水部分形成金属簇层,形成金属簇层 至少一个亲水孔。 在金属簇层的每一侧上,多个相关联的两亲性配位体疏水部分与金属簇层配合形成三层,并且以面对间隔的关系填充多个三层以形成至少一个 疏水孔。