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1. 发明授权

US09006381B2 Impact-resistant polyamide composition and process for production of same 有权
标题翻译：耐冲击聚酰胺组合物及其制备方法
公开(公告)号：US09006381B2
公开(公告)日：2015-04-14
申请号：US13806055
申请日：2011-06-23
申请人： Tokizane Imanishi , Hirofumi Nishida
发明人： Tokizane Imanishi , Hirofumi Nishida
IPC分类号： C08G69/08 , C08G69/14 , C08G69/20 , C08L77/02 , C08G69/18
CPC分类号： C08G69/14 , C08G69/18 , C08G69/20 , C08L77/02 , C08L25/18
摘要： Provided are: an impact-resistant polyamide composition which exhibits improved toughness and improved impact strength and which can be easily polymerized in-situ in a molding stage; and a novel process for the production of the same. The novel process comprises initiating the anionic polymerization of ε-caprolactam in the presence of (A) an anionic polymerization catalyst, (B) an anionic polymerization activator, (C) 2.0 to 30% by weight (relative to the ε-caprolactam) of an N,N-disubstituted vinylbenzylamine, and (D) a radical polymerization initiator, and subjecting the resulting system to reaction under conditions comprising a reaction temperature of the reaction system of 120 to 180° C. and a reaction time of 10 seconds to 120 minutes. Since radical polymerization in the process is conducted without hindering the anionic polymerization, an alloyed polyamide composed of both polycaprolactam and poly (N,N-disubstituted vinylbenzylamine) can be obtained.
摘要翻译：提供：耐冲击聚酰胺组合物，其显示出改进的韧性和改善的冲击强度，并且可以容易地在模塑阶段中原位聚合; 和一种新的生产方法。该新方法包括在（A）阴离子聚合催化剂，（B）阴离子聚合活化剂，（C）2.0-30重量％（相对于ε-己内酰胺））的N，N-二取代的乙烯基苄基胺和（D）自由基聚合引发剂，并将所得体系在包括反应体系的反应温度为120-180℃并且反应时间为10秒的条件下反应至120分钟。由于在不阻碍阴离子聚合的情况下进行自由基聚合，所以可以得到由聚己内酰胺和聚（N，N-二取代乙烯基苄基胺）组成的合金化聚酰胺。

2. 发明授权

US08530053B2 Heat-resistant composite material 有权
标题翻译：耐热复合材料
公开(公告)号：US08530053B2
公开(公告)日：2013-09-10
申请号：US11666600
申请日：2005-10-25
申请人： Hirofumi Nishida , Norio Hirayama
发明人： Hirofumi Nishida , Norio Hirayama
IPC分类号： B32B27/26 , B32B27/04 , B32B27/38 , C08G59/22 , C08G59/32 , C08G59/38 , C08G59/68 , C08L63/00
CPC分类号： C08G59/32 , C08G59/38 , C08G59/42 , C08G59/681 , C08G59/685 , C08K7/14 , C08L63/00 , Y10T428/24994 , Y10T428/31511
摘要： A high heat-resistant composite material which comprises a polymerizable composition comprising a bi-functional epoxy compound, a tri- or more-functional epoxy compound and a polymerization initiator, wherein the polymerization initiator comprises a sodium salt or potassium salt of mono- or poly-functional carboxylic acid, and a reinforcing fiber such as a carbon fiber or a glass fiber; and a vehicle member or a construction member comprising the above heat-resistant composite material. Said composite material comprises an epoxy polymer having high heat-resistant physical properties over those of a conventional epoxy polymer as a matrix, and exhibits an extremely high retention factor of storage modulus at high temperature.
摘要翻译：一种高耐热复合材料，其包含可聚合组合物，其包含双功能环氧化合物，三官能或更多官能的环氧化合物和聚合引发剂，其中所述聚合引发剂包括单或多价的钠盐或钾盐官能羧酸，以及增强纤维如碳纤维或玻璃纤维; 以及包括上述耐热复合材料的车辆构件或构造构件。所述复合材料包含与作为基质的常规环氧聚合物相比具有高耐热物理性能的环氧聚合物，并且在高温下表现出非常高的储能模量保留因子。

3. 发明授权

US5482685A Deodorizing apparatus 失效
标题翻译：除臭装置
公开(公告)号：US5482685A
公开(公告)日：1996-01-09
申请号：US225808
申请日：1994-04-11
申请人： Tatsuo Fujita , Syuzo Tokumitsu , Hirofumi Nishida , Tadashi Suzuki , Yukiyoshi Ono , Tetsuo Terashima , Takeshi Tomizawa , Jiro Suzuki , Syuji Asada , Yukiyoshi Nishikori
发明人： Tatsuo Fujita , Syuzo Tokumitsu , Hirofumi Nishida , Tadashi Suzuki , Yukiyoshi Ono , Tetsuo Terashima , Takeshi Tomizawa , Jiro Suzuki , Syuji Asada , Yukiyoshi Nishikori
IPC分类号： B01D53/88 , F24F3/16 , F01N3/10
CPC分类号： F24F3/16 , B01D53/885 , F24F2003/1628
摘要： A catalyst 1 is provided in a gas passage 4 for communicating between a gas flow-in unit 12 and a gas flow-out unit 13, and the catalyst 1 is heated by a heater 2, and a temperature sensor 3 for detecting the temperature of the heater 2 is provided inside the heater 2. By feeding power to the heater 2, the wall temperature of the heater 2 is raised to heat the catalyst 1, and then malodorous gas containing odor substances is passed in from the gas flow-in unit 12. The malodorous gas passes through the catalyst 1 in the gas passage 4 to be oxidized to be harmless and odorless, and is discharged from the gas flow-out unit 13.
摘要翻译：催化剂1设置在用于气体流入单元12和气体流出单元13之间连通的气体通道4中，催化剂1被加热器2加热，温度传感器3用于检测温度加热器2设置在加热器2的内部。通过向加热器2供电，升温加热器2的壁温度以加热催化剂1，然后从气体流入单元中通入含气味物质的恶臭气体恶臭气体通过气体通道4中的催化剂1，被氧化成无害和无臭，并从气体流出单元13排出。

4. 发明授权

US08809470B2 Polymerizable composition 有权
标题翻译：可聚合组合物
公开(公告)号：US08809470B2
公开(公告)日：2014-08-19
申请号：US11661208
申请日：2005-08-24
申请人： Hirofumi Nishida
发明人： Hirofumi Nishida
IPC分类号： C08G59/40 , C08G59/42 , C08L63/00
CPC分类号： C08G59/4007 , C08G59/40 , C08G59/4207 , C08G59/68 , C08G59/685 , C08G65/105 , C08G65/2648 , C08L63/00
摘要： A polymerizable epoxy compound composition containing an anionic polymerization initiator which can be easily produced, can attain a high polymerization rate and a high degree of polymerization, and can realize an epoxy polymer having properties unobtainable so far, an improvement in cured polymer properties, etc.; and a method of polymerizing an epoxy compound. The composition is an anionically polymerizable composition comprising a monofunctional epoxy compound or a di- or more functional epoxy resin and a polymerization initiator, the polymerization initiator comprising the potassium or sodium salt of a monocarboxylic acid monomer. The method, which is for producing a polymer of epoxy compounds, comprises polymerizing a monofunctional epoxy compound or a di- or more functional epoxy resin by anionic polymerization with the aid of the potassium or sodium salt of a monocarboxylic acid monomer.
摘要翻译：可以容易地制造含有阴离子聚合引发剂的可聚合环氧化合物组合物可以获得高聚合速率和高聚合度，并且可以实现迄今为止无法获得的性能，聚合物固化性能的改善等的环氧聚合物。 ; 和环氧化合物的聚合方法。该组合物是包含单官能环氧化合物或二官能或更多功能的环氧树脂和聚合引发剂的阴离子可聚合组合物，聚合引发剂包含单羧酸单体的钾盐或钠盐。用于生产环氧化合物的聚合物的方法包括通过阴离子聚合在一元羧酸单体的钾盐或钠盐的作用下聚合单官能环氧化合物或二官能以上的环氧树脂。

5. 发明申请

US20090215929A1 Method for Producing Fiber-Reinforced Thermally Meltable Epoxy Resin 审中-公开
标题翻译：生产纤维增强热熔胶环氧树脂的方法
公开(公告)号：US20090215929A1
公开(公告)日：2009-08-27
申请号：US11920497
申请日：2006-05-12
申请人： Hirofumi Nishida , Norio Hirayama
发明人： Hirofumi Nishida , Norio Hirayama
IPC分类号： C08L63/00
CPC分类号： C08G59/62 , C08G59/245 , C08G59/621 , C08J5/043 , C08J5/24 , C08J2363/02
摘要： Disclosed herein are a method for producing a fiber-reinforced thermally meltable epoxy resin having excellent heat resistance using a thermally meltable epoxy resin having a high melting initiation temperature and a fiber-reinforced plastic molded by the method. The method for producing a fiber-reinforced thermally meltable epoxy resin comprises the steps of: (I) impregnating reinforcing fibers with a compound (A) having two epoxy groups in one molecule and a compound (B) having two phenolic hydroxyl groups in one molecule; and (II) linearly polymerizing the compounds (A) and (B) impregnated into the reinforcing fibers by polyaddition reaction, wherein at least a part of the compound (A) and/or at least a part of the compound (B) are/is a compound having a fluorene skeleton, and the compound (A) and the compound (B) are mixed in such a ratio that the number of moles of epoxy groups in the compound (A) is 0.9 to 1.1 times the number of moles of phenolic hydroxyl groups in the compound (B).
摘要翻译：本文公开了一种使用具有高熔融起始温度的热熔性环氧树脂和通过该方法成型的纤维增强塑料来制造具有优异耐热性的纤维增强的热熔性环氧树脂的方法。纤维增强热熔性环氧树脂的制造方法包括以下步骤：（I）在一分子中用具有两个环氧基的化合物（A）和在一个分子中具有两个酚羟基的化合物（B））浸渍增强纤维 ; 和（II）通过加聚反应线性聚合浸渍到增强纤维中的化合物（A）和（B），其中化合物（A）和/或至少部分化合物（B）的至少一部分为/ 是具有芴骨架的化合物，化合物（A）和化合物（B）以使化合物（A）中的环氧基的摩尔数为0.9〜1.1倍摩尔数的比例混合化合物（B）中的酚羟基。

6. 发明授权

US5844053A Organo-polysiloxane derivartives 失效
标题翻译：有机聚硅氧烷衍生物
公开(公告)号：US5844053A
公开(公告)日：1998-12-01
申请号：US737253
申请日：1996-10-29
申请人： Hirofumi Nishida
发明人： Hirofumi Nishida
IPC分类号： C08G18/10 , C08G18/61 , C08L63/00 , C08L83/04 , C08F283/00
CPC分类号： C08G18/10 , C08G18/61 , C08L63/00 , C08L83/04 , C08G2220/00 , C08G77/12 , C08G77/14 , C08G77/16 , C08G77/26 , C08G77/28 , C08G77/42
摘要： The disclosed organo-polysiloxane derivative is useful as a dispersing agent for homogeneously dispersing a silicone gel in a curable resin such as an epoxy resin. The organo-polysiloxane derivative is prepared by first reacting an organo-polysiloxane compound A having an active hydrogen-containing group in each of its both terminals and having from 5 to 70 siloxane bonds with a bifunctional organic compound B having two functional groups reactable with active hydrogen. The reaction mixture obtained in the first reaction is reacted with a mixture of a bifunctional organic compound C having two active hydrogens and a bifunctional organic compound D having two functional groups reactable with the active hydrogen.
摘要翻译： PCT No.PCT / JP96 / 00649 Sec。 371日期1996年10月29日第 102（e）日期1996年10月29日PCT 1996年3月14日PCT公布。公开号WO96 / 28496 日期1996年9月19日所公开的有机聚硅氧烷衍生物可用作将硅凝胶均匀分散在诸如环氧树脂的可固化树脂中的分散剂。有机聚硅氧烷衍生物通过首先在其两端各自具有含有活性氢基团的有机聚硅氧烷化合物A和具有5至70个硅氧烷键的双官能有机化合物B反应，该双官能有机化合物B具有可与活性反应的两个官能团氢。将在第一反应中获得的反应混合物与具有两个活性氢的双官能有机化合物C和具有两个与活性氢反应的官能团的双官能有机化合物D的混合物反应。

7. 发明授权

US5634600A Refuse processing machine 失效
标题翻译：垃圾处理机
公开(公告)号：US5634600A
公开(公告)日：1997-06-03
申请号：US225329
申请日：1994-04-08
申请人： Tadashi Kubota , Motomichi Mishima , Yukio Hayashida , Hisao Tsunaga , Hideaki Sakatani , Hirofumi Nishida , Katsuyuki Ishibashi , Tatsuo Kikawa , Syuji Asada , Tatsuo Fujita , Yukiyoshi Nishikori , Hidenori Kitamura , Syuzo Tokumitu , Kenichiro Sunaba
发明人： Tadashi Kubota , Motomichi Mishima , Yukio Hayashida , Hisao Tsunaga , Hideaki Sakatani , Hirofumi Nishida , Katsuyuki Ishibashi , Tatsuo Kikawa , Syuji Asada , Tatsuo Fujita , Yukiyoshi Nishikori , Hidenori Kitamura , Syuzo Tokumitu , Kenichiro Sunaba
IPC分类号： B02C17/00 , B09B3/00 , F26B11/12 , F26B25/22 , B02C18/40
CPC分类号： B09B3/00 , B02C17/002 , F26B11/12 , F26B25/22 , Y10S241/38
摘要： The refuse processing machine of the invention reduces the bulk of the waste by heating and drying the waste in the waste container by heating means. The grinding and stirring means is operated while heating and drying, and the waste is ground and stirred. The waste is ground into small pieces by the grinding and stirring means, and heat of the heating means is hence smoothly transmitted to the inside of the waste, so that the moisture in the waste may be removed efficiently.
摘要翻译：本发明的垃圾处理机通过加热和干燥废物容器中的废物通过加热装置来减少大量的废物。研磨和搅拌装置在加热和干燥的同时进行操作，并将废物研磨和搅拌。通过研磨和搅拌装置将废弃物研磨成小块，因此加热装置的热量平稳地传递到废物的内部，从而可以有效地除去废物中的水分。

8. 发明申请

US20130190471A1 IMPACT-RESISTANT POLYAMIDE COMPOSITION AND PROCESS FOR PRODUCTION OF SAME 有权
标题翻译：抗冲击聚酰胺组合物及其制造方法
公开(公告)号：US20130190471A1
公开(公告)日：2013-07-25
申请号：US13806055
申请日：2011-06-23
申请人： Tokizane Imanishi , Hirofumi Nishida
发明人： Tokizane Imanishi , Hirofumi Nishida
IPC分类号： C08G69/14 , C08G69/18
CPC分类号： C08G69/14 , C08G69/18 , C08G69/20 , C08L77/02 , C08L25/18
摘要： Provided are: an impact-resistant polyamide composition which exhibits improved toughness and improved impact strength and which can be easily polymerized in-situ in a molding stage; and a novel process for the production of the same. The novel process comprises initiating the anionic polymerization of ε-caprolactam in the presence of (A) an anionic polymerization catalyst, (B) an anionic polymerization activator, (C) 2.0 to 30% by weight (relative to the ε-caprolactam) of an N,N-disubstituted vinylbenzylamine, and (D) a radical polymerization initiator, and subjecting the resulting system to reaction under conditions comprising a reaction temperature of the reaction system of 120 to 180° C. and a reaction time of 10 seconds to 120 minutes. Since radical polymerization in the process is conducted without hindering the anionic polymerization, an alloyed polyamide composed of both polycaprolactam and poly (N,N-disubstituted vinylbenzylamine) can be obtained.
摘要翻译：提供：耐冲击聚酰胺组合物，其显示出改进的韧性和改善的冲击强度，并且可以容易地在模塑阶段中原位聚合; 和一种新的生产方法。该新方法包括在（A）阴离子聚合催化剂存在下引发ε-己内酰胺的阴离子聚合，（B）阴离子聚合活化剂，（C）2.0-30重量％（相对于ε-己内酰胺） N，N-二取代的乙烯基苄胺和（D）自由基聚合引发剂，并将所得体系在包括反应体系的反应温度为120至180℃，反应时间为10秒至120℃的条件下反应分钟。由于在不阻碍阴离子聚合的情况下进行自由基聚合，所以可以得到由聚己内酰胺和聚（N，N-二取代乙烯基苄基胺）组成的合金化聚酰胺。

9. 发明申请

US20070010611A1 Method for producing fiber-reinforced thermoplastics plastic and fiber-reinforced thermoplastic prastic 审中-公开
标题翻译：纤维增强热塑性塑料和纤维增强热塑性塑料的生产方法
公开(公告)号：US20070010611A1
公开(公告)日：2007-01-11
申请号：US10540540
申请日：2003-12-26
申请人： Norio Hirayama , Hirofumi Nishida
发明人： Norio Hirayama , Hirofumi Nishida
IPC分类号： C08K3/40
CPC分类号： B29C43/003 , C08J5/043
摘要： A method of manufacturing a fiber-reinforced thermoplastics, comprising a mixing step for mixing an uncured thermosetting resin with reinforcing fibers to obtain a mixture, and a reaction step for forming the thermoplastics by causing a polymerization reaction of the thermosetting resin in the mixture so that the thermosetting resin polymerizes.
摘要翻译：一种制造纤维增强热塑性塑料的方法，包括将未固化的热固性树脂与增强纤维混合以获得混合物的混合步骤，以及通过使热固性树脂在混合物中的聚合反应形成热塑性塑料的反应步骤，使得热固性树脂聚合。

10. 发明申请

US20080139758A1 Polymerizable Composition 有权
标题翻译：可聚合组合物
公开(公告)号：US20080139758A1
公开(公告)日：2008-06-12
申请号：US11661208
申请日：2005-08-24
申请人： Hirofumi Nishida
发明人： Hirofumi Nishida
IPC分类号： C08G59/68 , C08L63/00
CPC分类号： C08G59/4007 , C08G59/40 , C08G59/4207 , C08G59/68 , C08G59/685 , C08G65/105 , C08G65/2648 , C08L63/00
摘要： A polymerizable epoxy compound composition containing an anionic polymerization initiator which can be easily produced, can attain a high polymerization rate and a high degree of polymerization, and can realize an epoxy polymer having properties unobtainable so far, an improvement in cured polymer properties, etc.; and a method of polymerizing an epoxy compound. The composition is an anionically polymerizable composition comprising a monofunctional epoxy compound or a di- or more functional epoxy resin and a polymerization initiator, the polymerization initiator comprising the potassium or sodium salt of a monocarboxylic acid monomer. The method, which is for producing a polymer of epoxy compounds, comprises polymerizing a monofunctional epoxy compound or a di- or more functional epoxy resin by anionic polymerization with the aid of the potassium or sodium salt of a monocarboxylic acid monomer.
摘要翻译：可以容易地制造含有阴离子聚合引发剂的可聚合环氧化合物组合物可以获得高聚合速率和高聚合度，并且可以实现迄今为止无法获得的性能，聚合物固化性能的改善等的环氧聚合物。 ; 和环氧化合物的聚合方法。该组合物是包含单官能环氧化合物或二官能或更多功能的环氧树脂和聚合引发剂的阴离子可聚合组合物，聚合引发剂包含单羧酸单体的钾盐或钠盐。用于生产环氧化合物的聚合物的方法包括通过阴离子聚合在一元羧酸单体的钾盐或钠盐的作用下聚合单官能环氧化合物或二官能以上的环氧树脂。

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