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1. 发明授权

US06524993B2 Hydrogenation catalyst for aromatic hydrocarbons contained in hydrocarbon oils 有权
标题翻译：烃油中所含芳香烃的氢化催化剂
公开(公告)号：US06524993B2
公开(公告)日：2003-02-25
申请号：US10139796
申请日：2002-05-03
申请人： Toshio Yamaguchi , Yuki Kanai , Hideharu Yokozuka
发明人： Toshio Yamaguchi , Yuki Kanai , Hideharu Yokozuka
IPC分类号： B01J2340
CPC分类号： C10G45/52 , B01J21/14 , B01J23/40 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1057 , B01J35/1061 , B01J35/1066
摘要： A hydrogenation catalyst for hydrocarbon oils containing aromatic hydrocarbons is provided. The catalyst has a silica-magnesia oxide carrier with a magnesia content within a range from 25 to 50 weight percent calculated in terms of the metal oxide, to which a noble metal selected from among the group VIII metals of the periodic table is added as the active component. In addition, the pore characteristics of the catalyst are such that the volume of pores with a pore size of at least 4 nm as measured by a mercury porosimetry method is within the range from 0.3 to 0.6 ml/g, the volume of pores with a pore size of at least 200 nm as measured by a mercury porosimetry method is no more than 0.05 ml/g, the volume of pores with a pore size from 0.7 to 2 nm as measured by nitrogen adsorption-t-plot method is within the range from 0.2 to 0.3 ml/g, and the volume of pores with a pore size from 2 to 4 nm as measured by nitrogen adsorption-DH method is within the range from 0.15 to 0.2 ml/g.
摘要翻译：提供了含有芳族烃的烃油的氢化催化剂。该催化剂具有二氧化硅 - 氧化镁载体，其氧化镁含量为按金属氧化物计算的25至50重量％的范围，选自周期表第VIII族金属中的贵金属作为活性组分。此外，催化剂的孔特性使得通过水银孔隙率法测量的孔径至少为4nm的孔的体积在0.3至0.6ml / g的范围内，具有通过水银孔隙率法测定的孔径至少为200nm的孔径不大于0.05ml / g，通过氮吸附-t-绘图法测量孔径为0.7-2nm的孔的体积在该范围内 0.2〜0.3ml / g，通过氮吸附-DH法测定孔径为2〜4nm的孔的体积在0.15〜0.2ml / g的范围内。

2. 发明授权

US5468709A Catalysts for hydrotreating hydrocarbon oils and method of preparing the same 失效
标题翻译：用于加氢处理烃油的催化剂及其制备方法
公开(公告)号：US5468709A
公开(公告)日：1995-11-21
申请号：US154005
申请日：1993-11-18
申请人： Eiji Yamaguchi , Yuji Uragami , Hideharu Yokozuka , Kikoo Uekusa , Toshio Yamaguchi , Satoshi Abe , Tetsuro Kamo , Takao Suzuki
发明人： Eiji Yamaguchi , Yuji Uragami , Hideharu Yokozuka , Kikoo Uekusa , Toshio Yamaguchi , Satoshi Abe , Tetsuro Kamo , Takao Suzuki
IPC分类号： B01J21/04 , B01J23/85 , B01J27/188 , B01J27/19 , B01J31/02 , B01J31/28 , B01J31/34 , B01J35/10 , B01J37/02 , C10G45/08 , C10G49/04 , B01J27/18
CPC分类号： B01J31/068 , B01J23/85 , B01J27/188 , B01J31/0202 , B01J31/28 , B01J31/34 , B01J37/0203 , C10G45/08 , B01J21/04 , B01J35/1061 , B01J35/108 , B01J35/1085
摘要： Catalysts for hydrodesulfurization and hydrodenitrogenation of hydrocarbon oils are provided which have high catalytic activity, excellent productivity and low pollution. The catalysts are made from an alumina carrier substance, at least one active metal element selected from the Group VI metals in the periodic table, at least one active metal element chosen from the Group VIII metals in the periodic table, phosphoric acid, and an additive agent. The additive agent is at least one substance selected from dihydric or trihydric alcohols having 2-10 carbon atoms per one molecule, ethers of the alcohols, monosaccharides, disaccharides, and polysaccharides. A method for preparing the catalysts is also provided and includes impregnating the alumina carrier substance with a solution mixed with a certain amount of the active metal elements, phosphoric acid and the additive agent, and drying the impregnated carrier substance at a temperature of less than 200.degree. C.
摘要翻译：提供了具有高催化活性，优异生产率和低污染性的烃油加氢脱硫和加氢脱氮催化剂。催化剂由氧化铝载体物质，至少一种选自元素周期表第VI族金属的活性金属元素，至少一种选自周期表第Ⅷ族金属的活性金属元素，磷酸和添加剂代理商添加剂是选自每分子具有2-10个碳原子的二元或三元醇中的至少一种物质，醇，单糖，二糖和多糖的醚。还提供了制备催化剂的方法，包括用与一定量的活性金属元素，磷酸和添加剂混合的溶液浸渍氧化铝载体物质，并在低于200℃的温度下干燥浸渍的载体物质 DEG C.

3. 发明授权

US06280610B1 Hydrotreating catalyst: composition, preparation, and use thereof 有权
标题翻译：加氢处理催化剂：组合物，制备及其用途
公开(公告)号：US06280610B1
公开(公告)日：2001-08-28
申请号：US09475683
申请日：1999-12-30
申请人： Yuji Uragami , Eiji Yamaguchi , Hideharu Yokozuka , Kikoo Uekusa
发明人： Yuji Uragami , Eiji Yamaguchi , Hideharu Yokozuka , Kikoo Uekusa
IPC分类号： C10G4504
CPC分类号： C10G45/08 , B01J23/85 , B01J23/88 , B01J23/94 , B01J31/0202 , B01J31/0204 , B01J31/068 , B01J35/002 , B01J37/0203 , B01J38/52 , C10G2300/202 , C10G2300/703 , C10G2300/80
摘要： The invention pertains to a process for activating a hydrotreating catalyst comprising a Group VIII hydrogenation metal and a Group VI hydrogenation metal, which are substantially in the oxide form, on a carrier in which the hydrotreating catalyst is contacted with an additive which is at least one compound selected from the group of compounds comprising at least two hydroxyl groups and 2-10 carbon atoms, and the (poly)ethers of these compounds, after which the catalyst is dried under such conditions that at least 50% of the additive remains in the catalyst. The additive is preferably at least one compound selected from ethylene glycol, diethylene glycol, and polyethylene glycol, or a saccharide or a polysaccharide. The invention additionally pertains to the catalyst obtainable by this process, which shows high activity in hydrodesulphurization and hydrodenitrogenation reactions, and to the use of the catalyst in hydrotreating.
摘要翻译：本发明涉及一种活化加氢精制催化剂的方法，该加氢处理催化剂包含基本上为氧化物形式的第VIII族加氢金属和第VI族加氢金属，载体上加氢处理催化剂与至少一种选自包含至少两个羟基和2-10个碳原子的化合物的化合物和这些化合物的（多）醚，然后将催化剂在至少50％的添加剂保留在催化剂。添加剂优选为选自乙二醇，二甘醇和聚乙二醇，或糖或多糖中的至少一种化合物。本发明还涉及通过该方法获得的催化剂，其在加氢脱硫和加氢脱氮反应中显示出高活性，以及在加氢处理中使用催化剂。

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