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1. 发明授权

US08816131B2 Method for synthesizing polyoxymethylene dimethyl ethers catalyzed by an ionic liquid 有权
标题翻译：由离子液体催化的聚甲醛二甲醚的合成方法
公开(公告)号：US08816131B2
公开(公告)日：2014-08-26
申请号：US13154359
申请日：2011-06-06
申请人： Jing Chen , Heyuan Song , Chungu Xia , Zhen Li
发明人： Jing Chen , Heyuan Song , Chungu Xia , Zhen Li
IPC分类号： C07C41/58 , C07C41/50 , C07C41/56
CPC分类号： C07C41/50 , B01J31/0279 , B01J31/0281 , B01J31/0284 , B01J31/0288 , B01J31/40 , B01J2231/40 , C07C41/14 , C07C41/56 , Y02P20/126 , Y02P20/584 , C07C43/30 , C07C43/10
摘要： It is related to a method for preparing polyoxymethylene dimethyl ethers by a continuous acetalation reaction of trioxymethylene and methanol or methylal catalyzed by an ionic liquid. The processing apparatus used in the method includes a reaction zone, a separation zone, a catalyst regeneration zone and a product dehydration zone. A manner of circulating tubular reaction is used, resulting in a high external heat exchange efficiency, a simple structure of design and a low investment. A film evaporator is used, realizing a rapid separation and recycling of the light component, with a high separation efficiency. The separation of the catalyst solution from the crude product is simple, thereby realizing the regeneration and recycling of the catalyst.
摘要翻译：它涉及一种通过三氯甲烷和甲醇或甲缩醛通过离子液体催化的连续缩醛反应制备聚甲醛二甲醚的方法。该方法中使用的处理装置包括反应区，分离区，催化剂再生区和产物脱水区。使用循环管状反应的方式，导致外部热交换效率高，设计结构简单，投资少。使用薄膜蒸发器，实现轻组分的快速分离和再循环，分离效率高。催化剂溶液与粗产物的分离是简单的，从而实现催化剂的再生和再循环。

2. 发明申请

US20080293954A1 Process For Synthesizing Trioxymethylene Using Ionic Liquid 失效
标题翻译：使用离子液体合成三聚甲醛的方法
公开(公告)号：US20080293954A1
公开(公告)日：2008-11-27
申请号：US12016837
申请日：2008-01-18
申请人： Jing CHEN , Heyuan Song , Chungu Xia , Zhonghua Tang , Xinzhi Zhang , Zhen Li , Enxiu Guo
发明人： Jing CHEN , Heyuan Song , Chungu Xia , Zhonghua Tang , Xinzhi Zhang , Zhen Li , Enxiu Guo
IPC分类号： C07D323/06
CPC分类号： C07D323/06
摘要： The present invention relates to a process for synthesizing trioxymethylene, wherein an aqueous solution of formaldehyde is used as the reactant; and an acidic ionic liquid in an amount of from 0.01 to 10 wt % is used as a catalyst.
摘要翻译：本发明涉及三甲氧基亚甲基合成方法，其中使用甲醛水溶液作为反应物; 使用0.01〜10重量％的酸性离子液体作催化剂。

3. 发明授权

US08987521B2 Method for preparing polyoxymethylene dimethyl ethers by acetalation reaction of formaldehyde with methanol 有权
标题翻译：通过甲醛与甲醇的缩醛化反应制备聚甲醛二甲醚的方法
公开(公告)号：US08987521B2
公开(公告)日：2015-03-24
申请号：US13164677
申请日：2011-06-20
申请人： Chungu Xia , Heyuan Song , Jing Chen , Zhen Li
发明人： Chungu Xia , Heyuan Song , Jing Chen , Zhen Li
IPC分类号： C07C41/14 , C07C41/56 , C07C41/58
CPC分类号： C07C41/56 , B01J31/0284 , B01J2231/14 , B01J2231/42 , C07C41/58 , Y02P20/582 , Y02P20/584 , C07C43/30
摘要： It is disclosed a method for preparing polyoxymethylene dimethyl ethers by continuous polymerization and acetalation reactions. The method may include two steps: performing a polymerization reaction of an aqueous formaldehyde solution under catalysis of an ionic liquid IL I to obtain a mixed aqueous solution of trioxymethylene and formaldehyde; and an acetalation reaction of the mixed aqueous solution of trioxymethylene and formaldehyde with methanol is performed under catalysis of an ionic liquid IL II to prepare polyoxymethylene dimethyl ethers. The method may use an aqueous formaldehyde solution as a starting material to prepare polyoxymethylene dimethyl ethers by continuous polymerization and acetalation reactions, achieving a high use ratio of formaldehyde. A film evaporator is used in the invention, realizing a rapid separation and recycling of the light components, with a high separation efficiency. The separation of the catalyst is simple, thereby realizing recycling of the catalyst.
摘要翻译：公开了通过连续聚合和缩醛化反应制备聚甲醛二甲醚的方法。该方法可以包括以下两个步骤：在离子液体IL I的催化下进行甲醛水溶液的聚合反应，得到三甲基甲醛和甲醛的混合水溶液; 并且在离子液体IL II的催化下进行三甲醛和甲醛与甲醇的混合水溶液的缩醛化反应，以制备聚甲醛二甲醚。该方法可以使用甲醛水溶液作为起始原料，通过连续聚合和缩醛化反应制备聚甲醛二甲醚，实现甲醛的高使用比例。在本发明中使用薄膜蒸发器，以高分离效率实现轻组分的快速分离和再循环。催化剂的分离是简单的，从而实现催化剂的再循环。

4. 发明申请

US20100056830A1 METHOD FOR SYNTHESIZING POLYOXYMETHYLENE DIMETHYL ETHERS BY IONIC LIQUID CATALYSIS 有权
标题翻译：通过离子液体催化合成聚羟基甲基二甲基醚的方法
公开(公告)号：US20100056830A1
公开(公告)日：2010-03-04
申请号：US12548807
申请日：2009-08-27
申请人： Jing CHEN , Heyuan SONG , Chungu XIA , Xinzhi ZHANG , Zhonghua TANG
发明人： Jing CHEN , Heyuan SONG , Chungu XIA , Xinzhi ZHANG , Zhonghua TANG
IPC分类号： C07C41/01
CPC分类号： C07C41/50 , C07C43/30
摘要： The present invention discloses a method for synthesizing polyoxymethylene dimethyl ethers by ionic liquid catalysis. The method comprises synthesizing polyoxymethylene dimethyl ethers by using a functional acidic ionic liquid as catalyst and using methylal and trioxymethylene as reactant under a relative mild reaction condition. The invention has advantages of high catalyst activity and reaction conversion, simple reaction process, high operationability and controllability, as well as good product distribution and high raw material utilization ratio.
摘要翻译：本发明公开了一种通过离子液体催化合成聚甲醛二甲醚的方法。该方法包括使用功能性酸性离子液体作为催化剂，并在相对温和的反应条件下使用甲缩醛和三氧化亚甲基作为反应物来合成聚甲醛二甲醚。本发明具有催化剂活性高，反应转化率高，反应速度快，操作性好，可控性好，产品分布好，原料利用率高的优点。

5. 发明授权

US08344183B2 Method for synthesizing polyoxymethylene dimethyl ethers by ionic liquid catalysis 有权
标题翻译：通过离子液体催化合成聚甲醛二甲醚的方法
公开(公告)号：US08344183B2
公开(公告)日：2013-01-01
申请号：US12548807
申请日：2009-08-27
申请人： Jing Chen , Heyuan Song , Chungu Xia , Xinzhi Zhang , Zhonghua Tang
发明人： Jing Chen , Heyuan Song , Chungu Xia , Xinzhi Zhang , Zhonghua Tang
IPC分类号： C07C41/01
CPC分类号： C07C41/50 , C07C43/30
摘要： The present invention discloses a method for synthesizing polyoxymethylene dimethyl ethers by ionic liquid catalysis. The method comprises synthesizing polyoxymethylene dimethyl ethers by using a functional acidic ionic liquid as catalyst and using methylal and trioxymethylene as reactant under a relative mild reaction condition. The invention has advantages of high catalyst activity and reaction conversion, simple reaction process, high operationability and controllability, as well as good product distribution and high raw material utilization ratio.
摘要翻译：本发明公开了一种通过离子液体催化合成聚甲醛二甲醚的方法。该方法包括使用功能性酸性离子液体作为催化剂，并在相对温和的反应条件下使用甲缩醛和三氧化亚甲基作为反应物来合成聚甲醛二甲醚。本发明具有催化剂活性高，反应转化率高，反应速度快，操作性好，可控性好，产品分布好，原料利用率高的优点。

6. 发明申请

US20110288343A1 METHOD FOR SYNTHESIZING POLYOXYMETHYLENE DIMETHYL ETHERS CATALYZED BY AN IONIC LIQUID 有权
标题翻译：合成由离子液体催化的聚甲基二甲基乙烯的方法
公开(公告)号：US20110288343A1
公开(公告)日：2011-11-24
申请号：US13154359
申请日：2011-06-06
申请人： JING CHEN , HEYUAN SONG , CHUNGU XIA , ZHEN LI
发明人： JING CHEN , HEYUAN SONG , CHUNGU XIA , ZHEN LI
IPC分类号： C07C41/58
CPC分类号： C07C41/50 , B01J31/0279 , B01J31/0281 , B01J31/0284 , B01J31/0288 , B01J31/40 , B01J2231/40 , C07C41/14 , C07C41/56 , Y02P20/126 , Y02P20/584 , C07C43/30 , C07C43/10
摘要： It is related to a method for preparing polyoxymethylene dimethyl ethers by a continuous acetalation reaction of trioxymethylene and methanol or methylal catalyzed by an ionic liquid. The processing apparatus used in the method includes a reaction zone, a separation zone, a catalyst regeneration zone and a product dehydration zone. A manner of circulating tubular reaction is used, resulting in a high external heat exchange efficiency, a simple structure of design and a low investment. A film evaporator is used, realizing a rapid separation and recycling of the light component, with a high separation efficiency. The separation of the catalyst solution from the crude product is simple, thereby realizing the regeneration and recycling of the catalyst.
摘要翻译：它涉及一种通过三氯甲烷和甲醇或甲缩醛通过离子液体催化的连续缩醛反应制备聚甲醛二甲醚的方法。该方法中使用的处理装置包括反应区，分离区，催化剂再生区和产物脱水区。使用循环管状反应的方式，导致外部热交换效率高，设计结构简单，投资少。使用薄膜蒸发器，实现轻组分的快速分离和再循环，分离效率高。催化剂溶液与粗产物的分离是简单的，从而实现催化剂的再生和再循环。

7. 发明授权

US07598402B2 Process for synthesizing trioxymethylene using ionic liquid 失效
标题翻译：使用离子液体合成三聚甲醛的方法
公开(公告)号：US07598402B2
公开(公告)日：2009-10-06
申请号：US12016837
申请日：2008-01-18
申请人： Jing Chen , Heyuan Song , Chungu Xia , Zhonghua Tang , Xinzhi Zhang , Zhen Li , Enxiu Guo
发明人： Jing Chen , Heyuan Song , Chungu Xia , Zhonghua Tang , Xinzhi Zhang , Zhen Li , Enxiu Guo
IPC分类号： C07D323/06
CPC分类号： C07D323/06
摘要： The present invention relates to a process for synthesizing trioxymethylene, wherein an aqueous solution of formaldehyde is used as the reactant; and an acidic ionic liquid in an amount of from 0.01 to 10 wt % is used as a catalyst.
摘要翻译：本发明涉及三甲氧基亚甲基合成方法，其中使用甲醛水溶液作为反应物; 使用0.01〜10重量％的酸性离子液体作催化剂。

8. 发明申请

US20110313202A1 METHOD FOR PREPARING POLYOXYMETHYLENE DIMETHYL ETHERS BY ACETALATION REACTION OF FORMALDEHYDE WITH METHANOL 有权
标题翻译：通过甲醛与甲醇的反应反应制备聚羟基甲基二甲基醚的方法
公开(公告)号：US20110313202A1
公开(公告)日：2011-12-22
申请号：US13164677
申请日：2011-06-20
申请人： Chungu Xia , Heyuan Song , Jing Chen , Zhen Li
发明人： Chungu Xia , Heyuan Song , Jing Chen , Zhen Li
IPC分类号： C07C41/14
CPC分类号： C07C41/56 , B01J31/0284 , B01J2231/14 , B01J2231/42 , C07C41/58 , Y02P20/582 , Y02P20/584 , C07C43/30
摘要： It is disclosed a method for preparing polyoxymethylene dimethyl ethers by continuous polymerization and acetalation reactions. The method may include two steps: performing a polymerization reaction of an aqueous formaldehyde solution under catalysis of an ionic liquid IL I to obtain a mixed aqueous solution of trioxymethylene and formaldehyde; and an acetalation reaction of the mixed aqueous solution of trioxymethylene and formaldehyde with methanol is performed under catalysis of an ionic liquid IL II to prepare polyoxymethylene dimethyl ethers. The method may use an aqueous formaldehyde solution as a starting material to prepare polyoxymethylene dimethyl ethers by continuous polymerization and acetalation reactions, achieving a high use ratio of formaldehyde. A film evaporator is used in the invention, realizing a rapid separation and recycling of the light components, with a high separation efficiency. The separation of the catalyst is simple, thereby realizing recycling of the catalyst.
摘要翻译：公开了通过连续聚合和缩醛化反应制备聚甲醛二甲醚的方法。该方法可以包括以下两个步骤：在离子液体IL I的催化下进行甲醛水溶液的聚合反应，得到三甲基甲醛和甲醛的混合水溶液; 并且在离子液体IL II的催化下进行三甲醛和甲醛与甲醇的混合水溶液的缩醛化反应，以制备聚甲醛二甲醚。该方法可以使用甲醛水溶液作为起始原料，通过连续聚合和缩醛化反应制备聚甲醛二甲醚，实现甲醛的高使用比例。在本发明中使用薄膜蒸发器，以高分离效率实现轻组分的快速分离和再循环。催化剂的分离是简单的，从而实现催化剂的再循环。

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