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1. 发明公开

EP1613665A1 SUPPORTED METALLOCENE CATALYSTS 审中-公开
标题翻译：支持的茂金属催化剂
公开(公告)号：EP1613665A1
公开(公告)日：2006-01-11
申请号：EP04759233.2
申请日：2004-04-07
申请人： FINA TECHNOLOGY, INC. , Gauthier, William J. , Kerr, Margaret , Tian, Jun , Rauscher, David , Patrick, Constance Hayworth , Henry, Shady
发明人： GAUTHIER, William, J. , KERR, Margaret , TIAN, Jun , RAUSCHER, David , PATRICK, Constance, Hayworth , HENRY, Shady
IPC分类号： C08F4/02 , C08F4/44 , C08F4/60 , C08F110/06 , C08F110/02 , B01J31/00 , B01J37/00 , C07F17/00 , C07F9/00 , C07F11/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F4/65916 , C08F2500/18 , C08F2500/03 , C08F2500/12 , C08F2500/17 , C08F2500/15
摘要： Supported metallocene catalysts and processes for the use of such catalysts in isotactic polymerization of a C3+ ethylenically unsaturated monomer. The supported catalysts comprise a particulate silica support, an alkyl alumoxane component, and a metallocene catalyst component. The support has an average particle size of 10-50 microns, a surface area of 200-800 m2/g and a pore volume of 0.9-2.1 milliliters per gram (ml/g). alumoxane is incorporated onto the support to provide a weight ratio of alumoxane to silica of at least 0.8:1. The metallocene is present in an amount of at least 1 weight percent of the silica and the alumoxane and is of the formula B(CpRaRb)(Fl’)MQ2 in which Fl’ is an unsubstituted fluorenyl group or a fluorenyl group symmetrically substituted at the 3 and 6 positions, B is a structural bridge between Cp and Fl’, Ra is a bulky substituent in a distal position, Rb is a less bulky substituent in a distal position, Rb is a less bulky substituent proximal to the bridge and non-vicinal to the distal substituent, M is a Group IVB transition metal or vanadium, and Q is a halogen or a C1-C4 alkyl group.

2. 发明公开

EP1613665A4 SUPPORTED METALLOCENE CATALYSTS 审中-公开
标题翻译：支持的茂金属催化剂
公开(公告)号：EP1613665A4
公开(公告)日：2011-08-03
申请号：EP04759233
申请日：2004-04-07
申请人： FINA TECHNOLOGY , GAUTHIER WILLIAM J , KERR MARGARET , TIAN JUN , RAUSCHER DAVID , PATRICK CONSTANCE HAYWORTH , HENRY SHADY
发明人： GAUTHIER WILLIAM J , KERR MARGARET , TIAN JUN , RAUSCHER DAVID , PATRICK CONSTANCE HAYWORTH , HENRY SHADY
IPC分类号： C08F4/02 , B01J31/00 , B01J37/00 , C07F9/00 , C07F11/00 , C07F17/00 , C08F4/42 , C08F4/44 , C08F4/60 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F4/65916 , C08F2500/18 , C08F2500/03 , C08F2500/12 , C08F2500/17 , C08F2500/15

3. 发明申请

WO2006118932A1 PROCESS FOR INCREASING ETHYLENE INCORPORATION INTO RANDOM COPOLYMERS 审中-公开
标题翻译：将乙烯加入到随机共聚物中的方法
公开(公告)号：WO2006118932A1
公开(公告)日：2006-11-09
申请号：PCT/US2006/015966
申请日：2006-04-25
申请人： FINA TECHNOLOGY, INC. , GAUTHIER, William, John , TIAN, Jun , RAUSCHER, David, John , PATRICK, Constance, Hayworth , HENRY, Shady, Nader , WILLIAMS, Nathan
发明人： GAUTHIER, William, John , TIAN, Jun , RAUSCHER, David, John , PATRICK, Constance, Hayworth , HENRY, Shady, Nader , WILLIAMS, Nathan
IPC分类号： C08F2/00 , C08G85/00
CPC分类号： C08F210/16 , C08F4/65912 , C08F10/00 , C08F210/06 , C08F2500/03 , C08F2500/20 , C08F4/65927
摘要： A process for preparing low melting copolymers comprising contacting a mixture of olefin monomers with a CpFlu-type metallocene catalyst under reaction conditions sufficient to form a copolymer. The copolymers thus prepared desirably display melt temperatures from about 100°C to about 140°C and may be produced with reduced amounts of ethylene. The copolymers may also exhibit reduced levels of undesirable xylene solubles, relatively narrow molecular weight distribution, and other improved optical and physical properties.
摘要翻译：一种制备低熔点共聚物的方法，包括使烯烃单体的混合物与CpFlu型金属茂催化剂在足以形成共聚物的反应条件下接触。因此制备的共聚物希望显示约100℃至约140℃的熔融温度，并且可以用减少量的乙烯制备。共聚物也可以表现出不希望的二甲苯可溶物的水平降低，分子量分布相对窄，以及其他改进的光学和物理性能。

4. 发明申请

WO2006118844A1 PROCESS FOR INCREASING ETHYLENE INCORPORATION INTO RANDOM COPOLYMERS 审中-公开
标题翻译：将乙烯加入到随机共聚物中的方法
公开(公告)号：WO2006118844A1
公开(公告)日：2006-11-09
申请号：PCT/US2006/015378
申请日：2006-04-25
申请人： FINA TECHNOLOGY, INC. , GAUTHIER, William, John , TIAN, Jun , HENRY, Shady, Nader , WILLIAMS, Nathan
发明人： GAUTHIER, William, John , TIAN, Jun , HENRY, Shady, Nader , WILLIAMS, Nathan
IPC分类号： C08F4/44
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F210/06 , C08F4/65927 , C08F2500/03 , C08F2500/20
摘要： Random copolymers may be prepared using a process that includes polymerizing a mixture of monomers including at least propylene and ethylene monomer, in the presence of a catalyst system including a metallocene catalyst having the general structure: racemic-X(2-R 1 -4-R 2 -lnd) 2 MCI 2 wherein M is a Group 4, 5 or 6 transition metal, or a lanthanide or actinide series metal; X is a structural bridge imparting stereorigidity; R1 is hydrogen or an alkyl, aryl or a substitution moiety; R 2 is hydrogen, or a C1-C4 alkyl; and lnd is an indenyl group. The copolymers are prepared under reaction conditions suitable to form a copolymer, wherein the copolymer has a higher level of ethylene incorporation than a corresponding polymer formed under otherwise identical reaction conditions except that a different bisindeny metallocene catalyst having a 4-indenyl substitution larger than 4 carbons is used. The copolymers may have a lower melt temperature than the corresponding polymers. The resulting copolymers may be used to prepare articles of manufacture including, but not limited to films, fibers and injection molded articles.
摘要翻译：无规共聚物可以使用包括聚合包含至少丙烯和乙烯单体的单体混合物在内的方法在包括具有以下通式结构的茂金属催化剂的催化剂体系存在下的方法来制备：外消旋-X（2-R 1）其中M是第4,5或6族过渡金属，或者其中M是4或5族过渡金属，或镧系元素或锕系金属; X是赋予立体感的结构桥梁; R1是氢或烷基，芳基或取代部分; R 2是氢或C 1 -C 4烷基; 并且lnd是茚基。共聚物在适于形成共聚物的反应条件下制备，其中共聚物具有比在其他相同反应条件下形成的相应聚合物更高的乙烯掺入水平，不同之处在于使用具有4-茚基取代基大于4个碳原子的不同的双茚基茂金属催化剂用来。共聚物可以具有比相应聚合物更低的熔融温度。所得共聚物可用于制备制品，包括但不限于薄膜，纤维和注模制品。

5. 发明申请

WO2013176686A8 MULTI-COMPONENT METALLOCENE CATALYST SYSTEMS FOR THE PRODUCTION OF REACTOR BLENDS OF POLYPROPYLENE 审中-公开
公开(公告)号：WO2013176686A8
公开(公告)日：2013-11-28
申请号：PCT/US2012/042201
申请日：2012-06-13
申请人： FINA TECHNOLOGY, INC. , RAUSCHER, David, J. , TIAN, Jun , GAUTHIER, William, J. , HENRY, Shady, N.
发明人： RAUSCHER, David, J. , TIAN, Jun , GAUTHIER, William, J. , HENRY, Shady, N.
IPC分类号： C08F110/06
摘要： Embodiments of the invention generally include multicomponent catalyst systems, polymerization processes and reactor blends formed by the processes. The multicomponent catalyst system generally includes a first catalyst component and a second catalyst component, wherein the second catalyst component is different from the first catalyst component.

6. 发明申请

WO2009032613A1 TRANSITION METAL CATALYSTS AND FORMATION THEREOF 审中-公开
标题翻译：过渡金属催化剂及其形成
公开(公告)号：WO2009032613A1
公开(公告)日：2009-03-12
申请号：PCT/US2008/074279
申请日：2008-08-26
申请人： FINA TECHNOLOGY, INC. , THORMAN, Joseph, L. , HENRY, Shady, N.
发明人： THORMAN, Joseph, L. , HENRY, Shady, N.
IPC分类号： C08F4/06 , B01J31/00
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/06 , C08F4/65912 , C08F4/65916 , C08F2500/18 , C08F2500/03
摘要： Supported catalysts systems and method of forming the same are described herein. The method generally includes providing a support material, providing a single site transition metal catalyst compound, contacting the transition metal catalyst compound with triisobutyl aluminum (TiBAl) to form a modified catalyst compound and contacting the support material with the modified catalyst compound to form a supported catalyst system.
摘要翻译：载体催化剂体系及其形成方法在本文中描述。该方法通常包括提供支撑材料，提供单个位点过渡金属催化剂化合物，使过渡金属催化剂化合物与三异丁基铝（TiBAl）接触以形成改性的催化剂化合物，并使载体材料与改性催化剂化合物接触以形成负载催化剂体系。

7. 发明申请

WO2007127013A2 TRANSITION METAL CATALYSTS AND FORMATION THEREOF 审中-公开
标题翻译：过渡金属催化剂及其形成
公开(公告)号：WO2007127013A2
公开(公告)日：2007-11-08
申请号：PCT/US2007007858
申请日：2007-03-29
申请人： FINA TECHNOLOGY , TIAN JUN , GAUTHIER WILLIAM , THORMAN JOSEPH , HENRY SHADY
发明人： TIAN JUN , GAUTHIER WILLIAM , THORMAN JOSEPH , HENRY SHADY
IPC分类号： B01J23/70 , B01J31/00 , C10G9/00
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F4/65912 , C08F4/65916 , C08F2500/18 , C08F2500/03
摘要： Catalyst systems and methods of forming the catalyst systems are described herein. The methods generally include contacting a support material with an activator to form a support composition, contacting a component with at least a portion of an aluminum containing compound including TIBAl, wherein the component is selected from the support composition, the transition metal catalyst compound and combinations thereof and contacting the support composition with a transition metal catalyst compound to form a supported catalyst system.
摘要翻译：本文描述了形成催化剂体系的催化剂体系和方法。所述方法通常包括使支撑材料与活化剂接触以形成载体组合物，使组分与包含TIBAl的含铝化合物的至少一部分接触，其中所述组分选自载体组合物，过渡金属催化剂化合物和组合并使载体组合物与过渡金属催化剂化合物接触以形成负载型催化剂体系。

8. 发明申请

WO2013176686A1 MULTI-COMPONENT METALLOCENE CATALYST SYSTEMS FOR THE PRODUCTION OF REACTOR BLENDS OF POLYPROPYLENE 审中-公开
标题翻译：用于生产聚丙烯反应器混合物的多组分金属催化剂体系
公开(公告)号：WO2013176686A1
公开(公告)日：2013-11-28
申请号：PCT/US2012042201
申请日：2012-06-13
申请人： FINA TECHNOLOGY , RAUSCHER DAVID J , TIAN JUN , GAUTHIER WILLIAM J , HENRY SHADY N
发明人： RAUSCHER DAVID J , TIAN JUN , GAUTHIER WILLIAM J , HENRY SHADY N
IPC分类号： C08F110/06
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , C08F210/16 , C08F2500/12 , C08F2500/20 , C08F4/65904
摘要： Embodiments of the invention generally include multicomponent catalyst systems, polymerization processes and reactor blends formed by the processes. The multicomponent catalyst system generally includes a first catalyst component and a second catalyst component, wherein the second catalyst component is different from the first catalyst component.
摘要翻译：本发明的实施方案通常包括通过该方法形成的多组分催化剂体系，聚合方法和反应器共混物。多组分催化剂体系通常包括第一催化剂组分和第二催化剂组分，其中第二催化剂组分不同于第一催化剂组分。

9. 发明申请

WO2007127013A3 TRANSITION METAL CATALYSTS AND FORMATION THEREOF 审中-公开
公开(公告)号：WO2007127013A3
公开(公告)日：2007-11-08
申请号：PCT/US2007/007858
申请日：2007-03-29
申请人： FINA TECHNOLOGY, INC. , TIAN, Jun , GAUTHIER, William , THORMAN, Joseph , HENRY, Shady
发明人： TIAN, Jun , GAUTHIER, William , THORMAN, Joseph , HENRY, Shady
IPC分类号： B01J21/00
摘要： Catalyst systems and methods of forming the catalyst systems are described herein. The methods generally include contacting a support material with an activator to form a support composition, contacting a component with at least a portion of an aluminum containing compound including TIBAl, wherein the component is selected from the support composition, the transition metal catalyst compound and combinations thereof and contacting the support composition with a transition metal catalyst compound to form a supported catalyst system.

10. 发明申请

WO2004092225A1 SUPPORTED METALLOCENE CATALYSTS 审中-公开
标题翻译：支持金属催化剂
公开(公告)号：WO2004092225A1
公开(公告)日：2004-10-28
申请号：PCT/US2004/010725
申请日：2004-04-07
申请人： FINA TECHNOLOGY, INC. , GAUTHIER, William, J. , KERR, Margaret , TIAN, Jun , RAUSCHER, David , PATRICK, Constance, Hayworth , HENRY, Shady
发明人： GAUTHIER, William, J. , KERR, Margaret , TIAN, Jun , RAUSCHER, David , PATRICK, Constance, Hayworth , HENRY, Shady
IPC分类号： C08F4/02
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F4/65916 , C08F2500/18 , C08F2500/03 , C08F2500/12 , C08F2500/17 , C08F2500/15
摘要： Supported metallocene catalysts and processes for the use of such catalysts in isotactic polymerization of a C 3+ ethylenically unsaturated monomer. The supported catalysts comprise a particulate silica support, an alkyl alumoxane component, and a metallocene catalyst component. The support has an average particle size of 10-50 microns, a surface area of 200-800 m 2 /g and a pore volume of 0.9-2.1 milliliters per gram (ml/g). alumoxane is incorporated onto the support to provide a weight ratio of alumoxane to silica of at least 0.8:1. The metallocene is present in an amount of at least 1 weight percent of the silica and the alumoxane and is of the formula B(CpRaRb)(Fl’)MQ 2 in which Fl’ is an unsubstituted fluorenyl group or a fluorenyl group symmetrically substituted at the 3 and 6 positions, B is a structural bridge between Cp and Fl’, Ra is a bulky substituent in a distal position, Rb is a less bulky substituent in a distal position, Rb is a less bulky substituent proximal to the bridge and non-vicinal to the distal substituent, M is a Group IVB transition metal or vanadium, and Q is a halogen or a C 1 -C 4 alkyl group.
摘要翻译：负载型茂金属催化剂和在C3 +烯属不饱和单体的全同立构聚合中使用这种催化剂的方法。载体催化剂包括颗粒二氧化硅载体，烷基铝氧烷组分和茂金属催化剂组分。载体的平均粒度为10-50微米，表面积为200-800平方米/克，孔体积为0.9-2.1毫升/克（毫升/克）。将铝氧烷引入载体上以提供至少0.8:1的铝氧烷与二氧化硅的重量比。金属茂的存在量为二氧化硅和铝氧烷的至少1重量％，并且具有式B（CpRaRb）（F1'）MQ2，其中F1'是未取代的芴基或在该位置上对称取代的芴基 3和6位，B是Cp和Fl'之间的结构桥，Ra是远端位置的庞大的取代基，Rb是远端位置较不庞大的取代基，Rb是靠近桥的较小体积的取代基，与远端取代基相邻，M为IVB族过渡金属或钒，Q为卤素或C1-C4烷基。

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