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1. 发明授权

US08673502B2 Method for producing coated carbon particles and use of the latter in anode materials for lithium-ion batteries 有权
标题翻译：用于生产包覆碳颗粒的方法，并将其用于锂离子电池的阳极材料中
公开(公告)号：US08673502B2
公开(公告)日：2014-03-18
申请号：US11908458
申请日：2006-01-25
申请人： Frank-Martin Petrat , Hartmut Wiggers , Burkhard Reeken , Michael Holzapfel , Hilmi Buqa , Petr Novak
发明人： Frank-Martin Petrat , Hartmut Wiggers , Burkhard Reeken , Michael Holzapfel , Hilmi Buqa , Petr Novak
IPC分类号： H01M4/13
CPC分类号： H01M4/133 , C23C16/24 , C23C16/4417 , H01M4/364 , H01M4/366 , H01M4/386 , H01M4/587 , H01M10/0525
摘要： The invention relates to a process for producing coated carbon particles, which comprises coating electrically conductive carbon particles with elemental doped or undoped silicon by chemical vapor deposition from at least one gaseous silane in an oxygen-free gas atmosphere in a reaction space, with the electrically conductive carbon particles being in continual motion during the vapor deposition, and also correspondingly coated carbon particles and their use in anode materials for lithium ion batteries.
摘要翻译：本发明涉及一种生产被覆碳粒子的方法，该方法包括通过化学气相沉积从反应空间中的无氧气体气氛中的至少一种气态硅烷涂覆带有元素掺杂或未掺杂硅的导电碳颗粒，导电碳颗粒在气相沉积期间连续运动，以及相应地涂覆的碳颗粒及其在锂离子电池阳极材料中的应用。

2. 发明授权

US07927570B2 Nanoscale crystalline silicon powder 有权
标题翻译：纳米级结晶硅粉
公开(公告)号：US07927570B2
公开(公告)日：2011-04-19
申请号：US12829464
申请日：2010-07-02
申请人： Markus Pridoehl , Paul Roth , Hartmut Wiggers , Frank-Martin Petrat , Michael Kraemer
发明人： Markus Pridoehl , Paul Roth , Hartmut Wiggers , Frank-Martin Petrat , Michael Kraemer
IPC分类号： C01B33/027 , C01B33/02 , C01B33/021 , C01B33/06
CPC分类号： C01B33/03 , C01B33/02 , C01B33/029 , Y10T428/2982
摘要： An aggregated crystalline silicon powder with a BET surface area of 20 to 150 m2/g is provided. The aggregated crystalline silicon may be doped with a doping component and can be used to produce electronic components.
摘要翻译：提供BET表面积为20-150m2 / g的聚集的结晶硅粉末。聚集的晶体硅可以掺杂掺杂成分并且可以用于生产电子元件。

3. 发明申请

US20100264377A1 NANOSCALE CRYSTALLINE SILICON POWDER 有权
标题翻译：纳米结晶硅粉
公开(公告)号：US20100264377A1
公开(公告)日：2010-10-21
申请号：US12829464
申请日：2010-07-02
申请人： Markus Pridöhl , Paul Roth , Hartmut Wiggers , Frank-Martin Petrat , Michael Krämer
发明人： Markus Pridöhl , Paul Roth , Hartmut Wiggers , Frank-Martin Petrat , Michael Krämer
IPC分类号： H01B1/04 , B32B5/16
CPC分类号： C01B33/03 , C01B33/02 , C01B33/029 , Y10T428/2982
摘要： An aggregated crystalline silicon powder with a BET surface area of 20 to 150 m2/g is provided. The aggregated crystalline silicon may be doped with a doping component and can be used to produce electronic components.
摘要翻译：提供BET表面积为20-150m2 / g的聚集的结晶硅粉末。聚集的晶体硅可以掺杂掺杂成分并且可以用于生产电子元件。

4. 发明申请

US20080145761A1 Method for Producing Coated Carbon Particles and Use of the Latter in Anode Materials for Lithium-Ion Batteries 有权
标题翻译：生产涂层碳粒子的方法及其在锂离子电池阳极材料中的应用
公开(公告)号：US20080145761A1
公开(公告)日：2008-06-19
申请号：US11908458
申请日：2006-01-25
申请人： Frank-Martin Petrat , Hartmut Wiggers , Burkhard Reeken , Michael Holzapfel , Hilmi Buqa , Petr Novak
发明人： Frank-Martin Petrat , Hartmut Wiggers , Burkhard Reeken , Michael Holzapfel , Hilmi Buqa , Petr Novak
IPC分类号： H01M4/06 , B05D5/12
CPC分类号： H01M4/133 , C23C16/24 , C23C16/4417 , H01M4/364 , H01M4/366 , H01M4/386 , H01M4/587 , H01M10/0525
摘要： The invention relates to a process for producing coated carbon particles, which comprises coating electrically conductive carbon particles with elemental doped or undoped silicon by chemical vapor deposition from at least one gaseous silane in an oxygen-free gas atmosphere in a reaction space, with the electrically conductive carbon particles being in continual motion during the vapor deposition, and also correspondingly coated carbon particles and their use in anode materials for lithium ion batteries.
摘要翻译：本发明涉及一种生产被覆碳粒子的方法，该方法包括通过化学气相沉积从反应空间中的无氧气体气氛中的至少一种气态硅烷涂覆带有元素掺杂或未掺杂硅的导电碳颗粒，导电碳颗粒在气相沉积期间连续运动，以及相应地涂覆的碳颗粒及其在锂离子电池阳极材料中的应用。

5. 发明授权

US09421518B2 Process for producing carbon substrates loaded with metal oxides and carbon substrates produced in this way 有权
标题翻译：用于生产以这种方式生产的负载有金属氧化物和碳衬底的碳基底的方法
公开(公告)号：US09421518B2
公开(公告)日：2016-08-23
申请号：US13054609
申请日：2009-07-16
申请人： Christof Schulz , Hartmut Wiggers
发明人： Christof Schulz , Hartmut Wiggers
IPC分类号： B01J21/06 , B01J21/18 , B01J23/22 , B01J23/30 , B01J23/46 , B01J23/48 , B01J23/72 , H01M4/92 , B01J23/40 , B01J23/745 , B01J35/00 , B01J37/08 , B01J37/10 , H01M4/86 , H01M4/88 , B01J37/02
CPC分类号： B01J21/063 , B01J21/18 , B01J23/22 , B01J23/30 , B01J23/40 , B01J23/48 , B01J23/72 , B01J23/745 , B01J35/0013 , B01J35/004 , B01J35/006 , B01J37/0201 , B01J37/084 , B01J37/105 , H01M4/8631 , H01M4/8673 , H01M4/8817 , H01M4/921 , Y02E60/50
摘要： The present invention relates to a process for producing a carbon substrate loaded with metal oxides, in particular a carbon material which contains metal oxide nanoparticles and is preferably suitable for use in a catalyst and/or as a catalyst, wherein, in a first process step, nanoparticles of metal oxides are introduced into a matrix based on at least one organic polymer, in particular are dispersed therein, and, in a second process step, the polymer matrix containing the nanoparticles is subsequently carbonized to carbon, optionally followed by a third process step of activation.
摘要翻译：本发明涉及一种负载有金属氧化物，特别是含有金属氧化物纳米颗粒并且优选适用于催化剂和/或催化剂的碳材料的碳基材的制备方法，其中在第一工艺步骤金属氧化物的纳米颗粒基于至少一种有机聚合物引入基质中，特别是分散于其中，并且在第二工艺步骤中，将含有纳米颗粒的聚合物基质随后碳化为碳，任选地随后进行第三种方法激活的一步。

6. 发明授权

US08945431B2 Intercalation of silicon and/or tin into porous carbon substrates 有权
标题翻译：将硅和/或锡插入多孔碳底物
公开(公告)号：US08945431B2
公开(公告)日：2015-02-03
申请号：US13054193
申请日：2009-07-14
申请人： Christof Schulz , Hartmut Wiggers
发明人： Christof Schulz , Hartmut Wiggers
IPC分类号： H01B1/04 , H01M4/13 , H01M4/58 , C01B31/00 , H01M4/04 , H01M4/133 , H01M4/134 , H01M4/1393 , H01M4/1395 , H01M4/38 , H01M4/587 , H01M10/0525
CPC分类号： C01B31/00 , C01B32/00 , H01M4/0416 , H01M4/0471 , H01M4/133 , H01M4/134 , H01M4/1393 , H01M4/1395 , H01M4/386 , H01M4/387 , H01M4/587 , H01M10/0525
摘要： The invention relates to a process for producing an electrically conductive, porous, silicon- and/or tin-containing carbon material which is suitable in particular for the production of an anode material, preferably for lithium ion batteries; in a first step of the process, preferably crystalline silicon nanoparticles and/or tin nanoparticles and/or silicon/tin nanoparticles are introduced into a matrix based on at least one organic polymer, being more particular dispersed therein, and subsequently, in a second step of the process, the resultant polymer matrix containing the silicon, tin and/or silicon/tin nanoparticles is carbonized to form carbon.
摘要翻译：本发明涉及一种用于生产导电，多孔，含硅和/或含锡的碳材料的方法，其特别适用于生产阳极材料，优选用于锂离子电池; 在该方法的第一步骤中，优选将基于至少一种有机聚合物的结晶硅纳米颗粒和/或锡纳米颗粒和/或硅/锡纳米颗粒引入基质中，更具体地分散在其中，随后在第二步骤所得到的含硅，锡和/或硅/锡纳米颗粒的聚合物基质被碳化以形成碳。

7. 发明申请

US20110190118A1 PROCESS FOR PRODUCING CARBON SUBSTRATES LOADED WITH METAL OXIDES AND CARBON SUBSTRATES PRODUCED IN THIS WAY 有权
标题翻译：生产以金属氧化物形成的碳质基底和以这种方式生产的碳质基底的方法
公开(公告)号：US20110190118A1
公开(公告)日：2011-08-04
申请号：US13054609
申请日：2009-07-16
申请人： Christof Schulz , Hartmut Wiggers
发明人： Christof Schulz , Hartmut Wiggers
IPC分类号： B01J21/18 , B01J37/14 , B01J35/10 , C01B31/00 , B82Y30/00
CPC分类号： B01J21/063 , B01J21/18 , B01J23/22 , B01J23/30 , B01J23/40 , B01J23/48 , B01J23/72 , B01J23/745 , B01J35/0013 , B01J35/004 , B01J35/006 , B01J37/0201 , B01J37/084 , B01J37/105 , H01M4/8631 , H01M4/8673 , H01M4/8817 , H01M4/921 , Y02E60/50
摘要： The present invention relates to a process for producing a carbon substrate loaded with metal oxides, in particular a carbon material which contains metal oxide nanoparticles and is preferably suitable for use in a catalyst and/or as a catalyst, wherein, in a first process step, nanoparticles of metal oxides are introduced into a matrix based on at least one organic polymer, in particular are dispersed therein, and, in a second process step, the polymer matrix containing the nanoparticles is subsequently carbonised to carbon, optionally followed by a third process step of activation.
摘要翻译：本发明涉及一种负载有金属氧化物，特别是含有金属氧化物纳米颗粒并且优选适用于催化剂和/或催化剂的碳材料的碳基材的制备方法，其中在第一工艺步骤金属氧化物的纳米颗粒基于至少一种有机聚合物引入基质中，特别是分散于其中，并且在第二工艺步骤中，将含有纳米颗粒的聚合物基体随后碳化成碳，任选地随后进行第三种方法激活的一步。

8. 发明申请

US20100193746A1 NANOSCALE CRYSTALLINE SILICON POWDER 有权
标题翻译：纳米结晶硅粉
公开(公告)号：US20100193746A1
公开(公告)日：2010-08-05
申请号：US12759346
申请日：2010-04-13
申请人： Markus PRIDOEHL , Paul ROTH , Hartmut WIGGERS , Frank-Martin PETRAT , Michael KRAEMER
发明人： Markus PRIDOEHL , Paul ROTH , Hartmut WIGGERS , Frank-Martin PETRAT , Michael KRAEMER
IPC分类号： C01B33/02 , H01B1/04
CPC分类号： C01B33/03 , C01B33/02 , C01B33/029 , Y10T428/2982
摘要： An aggregated crystalline silicon powder with a BET surface area of 20 to 150 m2/g is provided. The aggregated silicon powder may be doped with phosphorus, arsenic, antimony, bismuth, boron, aluminium, gallium, indium, thallium, europium, erbium, cerium, praseodymium, neodymium, samarium, gadolinium, terbium, dysprosium, holmium, thulium, lutetium, lithium, ytterbium, germanium, iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper, silver, gold, or zinc.
摘要翻译：提供BET表面积为20-150m2 / g的聚集的结晶硅粉末。聚集的硅粉末可以掺杂有磷，砷，锑，铋，硼，铝，镓，铟，铊，铕，铒，铈，镨，钕，钐，钆，铽，镝，钬，ium，镥，锂，镱，锗，铁，钌，锇，钴，铑，铱，镍，钯，铂，铜，银，金或锌。

9. 发明申请

US20110311873A1 INTERCALATION OF SILICON AND/OR TIN INTO POROUS CARBON SUBSTRATES 有权
标题翻译：将硅和/或锡与多孔碳基体的交叉
公开(公告)号：US20110311873A1
公开(公告)日：2011-12-22
申请号：US13054193
申请日：2009-07-14
申请人： Christof Schulz , Hartmut Wiggers
发明人： Christof Schulz , Hartmut Wiggers
IPC分类号： H01M4/583 , H01M4/587 , H01B1/04 , B32B3/26 , B82Y30/00
CPC分类号： C01B31/00 , C01B32/00 , H01M4/0416 , H01M4/0471 , H01M4/133 , H01M4/134 , H01M4/1393 , H01M4/1395 , H01M4/386 , H01M4/387 , H01M4/587 , H01M10/0525
摘要： The invention relates to a process for producing an electrically conductive, porous, silicon- and/or tin-containing carbon material which is suitable in particular for the production of an anode material, preferably for lithium ion batteries; in a first step of the process, preferably crystalline silicon nanoparticies and/or tin nanoparticies and/or silicon/tin nanoparticles are introduced into a matrix based on at least one organic polymer, being more particular dispersed therein, and subsequently, in a second step of the process, the resultant polymer matrix containing the silicon, tin and/or silicon/tin nanoparticies is carbonized to form carbon.
摘要翻译：本发明涉及一种用于生产导电，多孔，含硅和/或含锡的碳材料的方法，其特别适用于生产阳极材料，优选用于锂离子电池; 在该方法的第一步中，优选将晶体硅纳米颗粒和/或锡纳米颗粒和/或硅/锡纳米颗粒基于至少一种有机聚合物引入到基质中，更具体地分散在其中，随后在第二步骤所得到的含有硅，锡和/或硅/锡纳米颗粒的聚合物基体被碳化以形成碳。

10. 发明授权

US08043909B2 Porous semiconductive film and process for its production 有权
标题翻译：多孔半导体膜及其生产工艺
公开(公告)号：US08043909B2
公开(公告)日：2011-10-25
申请号：US12053369
申请日：2008-03-21
申请人： André Ebbers , Martin Trocha , Robert Lechner , Martin S. Brandt , Martin Stutzmann , Hartmut Wiggers
发明人： André Ebbers , Martin Trocha , Robert Lechner , Martin S. Brandt , Martin Stutzmann , Hartmut Wiggers
IPC分类号： H01L21/8238
CPC分类号： H01L21/0257 , H01L21/02376 , H01L21/0242 , H01L21/02422 , H01L21/02532 , H01L21/02581 , H01L21/0259 , H01L21/02614 , H01L21/02628 , H01L29/78 , Y10S438/96
摘要： The present invention provides a porous semiconductive structure, characterized in that the structure has an electrical conductivity of 5·10−8 S·cm−1 to 10 S·cm−1, and an activation energy of the electrical conductivity of 0.1 to 700 meV, and a solid fraction of 30 to 60% by volume, and a pore size of 1 nm to 500 nm, the solid fraction having at least partly crystalline doped constituents which are bonded to one another via sinter necks and have sizes of 5 nm to 500 nm and a spherical and/or ellipsoidal shape, which comprise the elements silicon, germanium or an alloy of these elements, and also a process for producing a porous semiconductive structure, characterized in that A. doped semimetal particles are obtained, and then B. a dispersion is obtained from the semimetal particles obtained after step A, and then C. a substrate is coated with the dispersion obtained after step B, and then D. the layer obtained after step C is treated by means of a solution of hydrogen fluoride in water, and then E. the layer obtained after step D is treated thermally to obtain a porous semiconductive structure.
摘要翻译：本发明提供一种多孔半导体结构体，其特征在于，该结构的导电率为5×10 -8 S·cm -1〜10 S·cm -1，电导率为0.1〜700meV ，固体成分为30〜60体积％，孔径为1〜500nm，固体部分具有至少部分结晶的掺杂成分，其通过烧结颈部彼此结合，并且具有5nm〜 500nm，并且包括元素硅，锗或这些元素的合金的球形和/或椭圆形形状，以及制造多孔半导体结构的方法，其特征在于获得A.掺杂的半金属颗粒，然后B 从在步骤A后获得的半金属颗粒中获得分散体，然后C.将基材涂布在步骤B之后获得的分散液中，然后D.将步骤C后获得的层用氟化氢溶液在水中，然后E.在步骤D之后获得的层被热处理以获得多孔半导体结构。

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