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    • 3. 发明授权
    • Process for the preparation of flexible polyester urethane foams
    • 制备柔性聚酯聚氨酯泡沫的方法
    • US4588755A
    • 1986-05-13
    • US703736
    • 1985-02-21
    • Hans-Joachim KollmeierHans-Heinrich Schloens
    • Hans-Joachim KollmeierHans-Heinrich Schloens
    • C08G18/20C08J9/00C08G18/14
    • C08J9/0061C08G18/2027C08J2375/04C08J2483/00
    • In a process of the preparation of flexible polyester urethane foams by reacting polyester polyols having at least two hydroxyl groups in the molecule with at least difunctional polyisocyanates in the presence of water, optionally of physical blowing agents, catalysts, stabilizers and optionally of other conventional additives, the following two components are added for catalysis in the form of a mixture to the reaction formulation in the amounts given (which are based on the polyester polyol):(a) 0.2 to 1.5 weight percent of N,N'-dimethylpiperazine,(b) 0.05 to 0.5 weight percent of a polysiloxane-polyoxyalkylene block copolymer of the general formula ##STR1## in which R.sup.1 is a polyoxyalkylene radical of the general formula--(CH.sub.2).sub.3 O(C.sub.m H.sub.2m O).sub.n R.sup.2 in whichR.sup.2 is an alkyl radical with 1 to 4 carbon atoms;m=2 or 3, the average value of m being 2 to 2.5:n=a whole number corresponding to a molecular weight for the R.sup.1 radical of 250 to 1600;a=is a whole number from 3 to 12; andb=is a whole number from 3 to 12.Flexible polyether urethane foams with a high degree of open-cell character are obtained, whose amine odor is clearly reduced.
    • 在制备柔性聚酯聚氨酯泡沫的过程中,通过在水存在下使分子中具有至少两个羟基的聚酯多元醇与任选的物理发泡剂,催化剂,稳定剂和任选的其它常规添加剂 加入下列两种成分,以混合物形式的反应制剂形式的催化作用(以聚酯多元醇为基础):(a)0.2-1.5%(重量)N,N'-二甲基哌嗪( b)0.05至0.5重量%的通式为“IMAGE”的聚硅氧烷 - 聚氧化烯嵌段共聚物,其中R 1是通式为 - (CH 2)3 O(C m H 2 m O)n R 2的聚氧化烯基,其中R 2为具有1个 至4个碳原子; m = 2或3,m的平均值为2至2.5:n =对应于R1基团的分子量为250至1600的整数; a =从3到12的整数; b =是3〜12的整数。获得具有高开放性能的柔性聚醚聚氨酯泡沫,其明显降低了胺气味。