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1. 发明授权

US09663603B2 Curable composition and polymer 有权
公开(公告)号：US09663603B2
公开(公告)日：2017-05-30
申请号：US14123147
申请日：2012-05-31
申请人： Tetsuya Noda , Fuminori Nakaya , Hajime Okutsu
发明人： Tetsuya Noda , Fuminori Nakaya , Hajime Okutsu
IPC分类号： C08F226/06 , C08F26/06 , C09D133/16 , C09D139/04 , C08F220/14 , C08F220/36 , C08F2/38 , C08F2/54 , C08F2/48 , C08F2/50 , C08F2/46
CPC分类号： C08F220/14 , C08F2/38 , C08F2/46 , C08F2/48 , C08F2/50 , C08F2/54 , C08F26/06 , C08F220/36 , C08F226/06 , C08J5/18 , C08J2333/12 , C08L2312/00 , C09D133/12 , C09D133/16 , C09D139/04 , C08F222/1006 , C08F220/60
摘要： An object of the invention is to provide a curable composition having a HALS skeleton and capable of producing polymers having excellent weather resistance and outer appearance. The present invention provides a curable composition including at least a monomer component that contains a monomer (A) represented by a certain formula and a monomer (B) polymerizable with the monomer (A). In the curable composition, the content of the monomer (A) is 0.01 to 35 mol % in the monomer component, and the content of the monomer (B) is 65 to 99.99 mol % in the monomer component.

2. 发明申请

US20060071363A1 Belt type continuous plate manufacturing device and method of manufacturing sheet polymer 审中-公开
标题翻译：带式连续板制造装置及其制造方法
公开(公告)号：US20060071363A1
公开(公告)日：2006-04-06
申请号：US10541155
申请日：2003-12-22
申请人： Hajime Okutsu , Hirotoshi Mizota
发明人： Hajime Okutsu , Hirotoshi Mizota
IPC分类号： B29D7/00
CPC分类号： B29C39/16 , B29C43/22
摘要： A belt type continuous plate manufacturing apparatus comprising two facing endless belts 1, 1′ and gaskets 7 sandwiched by belt surfaces at their both side edge portions, wherein a polymerizable raw material is fed into a space surrounded by the facing belt surfaces and the gaskets 7 from its one end, the polymerizable raw material is solidified together with running of the belts in a heating zone, and the plate polymer is taken out from the other end, characterized in that three or more upper and lower roll pairs satisfying the following formulae (1) and (2) are placed so that respective axes thereof orthogonally cross the belt running direction, between a raw material feeding position and a heating initiation position; and a method of producing a plate polymer by using it: D/Z≧0.04 (1), 0.30≦D/X≦0.99 (2) [D=outermost diameter of roll body portion (mm), Z=width of roll body portion (mm), X=distance between axis centers of adjacent upper and lower roll pairs (mm)].
摘要翻译：一种带式连续板制造装置，包括两个面对的环形带1,1'和在其两侧边缘部分被带表面夹持的垫圈7，其中可聚合原料被供给到由相对的带表面和垫圈7围绕的空间中从一端可聚合的原料与加速带中的带的运行一起固化，并且从另一端取出板状聚合物，其特征在于，满足下式的三个或更多个上下辊对（ 1）和（2）被放置成使得其各轴在原料供给位置和加热起始位置之间正交地穿过皮带行进方向; 和使用它的板状聚合物的制造方法：D / Z> = 0.04（1），0.30 <= D / X <= 0.99（2）[D =辊体部的最外径（mm）（mm），X =相邻的上下辊对的轴心之间的距离（mm）]。

3. 发明申请

US20140094581A1 CURABLE COMPOSITION AND POLYMER 有权
标题翻译：可固化组合物和聚合物
公开(公告)号：US20140094581A1
公开(公告)日：2014-04-03
申请号：US14123147
申请日：2012-05-31
申请人： Tetsuya Noda , Fuminori Nakaya , Hajime Okutsu
发明人： Tetsuya Noda , Fuminori Nakaya , Hajime Okutsu
IPC分类号： C08F226/06
CPC分类号： C08F220/14 , C08F2/38 , C08F2/46 , C08F2/48 , C08F2/50 , C08F2/54 , C08F26/06 , C08F220/36 , C08F226/06 , C08J5/18 , C08J2333/12 , C08L2312/00 , C09D133/12 , C09D133/16 , C09D139/04 , C08F222/1006 , C08F220/60
摘要： An object of the invention is to provide a curable composition having a HALS skeleton and capable of producing polymers having excellent weather resistance and outer appearance. The present invention provides a curable composition including at least a monomer component that contains a monomer (A) represented by a certain formula and a monomer (B) polymerizable with the monomer (A). In the curable composition, the content of the monomer (A) is 0.01 to 35 mol % in the monomer component, and the content of the monomer (B) is 65 to 99.99 mol % in the monomer component.
摘要翻译：本发明的目的是提供一种具有HALS骨架的固化性组合物，并且能够制备具有优异耐候性和外观的聚合物。本发明提供一种可固化组合物，其至少包含含有由一定式表示的单体（A）的单体组分和可与单体（A）聚合的单体（B）。在固化性组合物中，单体成分中单体（A）的含量为0.01〜35摩尔％，单体成分中单体（B）的含量为65〜99.99摩尔％。

4. 发明申请

US20090140454A1 BELT-TYPE APPARATUS FOR CONTINUOUS PLATE FORMATION AND METHOD OF CONTINUOUS PLATE FORMATION WITH BELT 审中-公开
标题翻译：用于连续板形成的带式装置和带状连续板形成方法
公开(公告)号：US20090140454A1
公开(公告)日：2009-06-04
申请号：US11996595
申请日：2005-07-25
申请人： Tomonari Murakami , Hirotoshi Mizota , Hajime Okutsu
发明人： Tomonari Murakami , Hirotoshi Mizota , Hajime Okutsu
IPC分类号： B29D7/00 , B29C39/16
CPC分类号： B29C39/16 , B29K2033/12
摘要： Disclosed is an apparatus for continuous plate formation using belts, in which a polymerizable raw material is fed to one end of a space surrounded by opposed surfaces of two endless belts 1 and 1′ facing each other and by gaskets 7 disposed at side edges of these belt surfaces so as to be sandwiched between the surfaces, the polymerizable raw material is polymerized in a section where the belts are heated or cooled with warm water, and a plate-form polymer is taken out of the other end of the space, which contains three or more recovery vessels 13 for recovering the warm water used to heat or cool the belts, and temperature sensing elements (thermometers 14) for measuring the temperature of the warm water recovered in every recovery vessel 13. Also disclosed is a method of continuous plate formation using belts, which comprises producing a plate-form polymer from a polymerizable raw material containing methyl methacrylate while measuring temperature of warm water recovered in every recovery vessel 13 with thermometers 14 by using the apparatus for continuous plate formation using belts.
摘要翻译：公开了一种使用带的连续板形成装置，其中将可聚合原料供给到由相互面对的两个环形带1,1'的相对表面围绕的空间的一端以及通过设置在这些的侧边缘处的垫圈7 带状表面被夹在表面之间，可聚合原料在带被加热或用温水冷却的部分中聚合，并且将板状聚合物从空间的另一端取出，其中包含用于回收用于加热或冷却带的温水的三个或更多个回收容器13和用于测量在每个回收容器13中回收的温水的温度的温度感测元件（温度计14）。还公开了一种连续板使用带的形成，其包括从含有甲基丙烯酸甲酯的可聚合原料生产板状聚合物，同时测量在每个re中回收的温水的温度通过使用用于使用带连续板形成的装置，具有温度计14的托盘13。

5. 发明授权

US07268323B2 Heat treating apparatus and heat treating method for sheet-like article 有权
标题翻译：片状物的热处理装置及热处理方法
公开(公告)号：US07268323B2
公开(公告)日：2007-09-11
申请号：US10547554
申请日：2004-02-27
申请人： Hitoshi Tomobe , Hirotoshi Mizota , Hajime Okutsu , Tomonari Murakami , Daisuke Morimoto
发明人： Hitoshi Tomobe , Hirotoshi Mizota , Hajime Okutsu , Tomonari Murakami , Daisuke Morimoto
IPC分类号： H05B1/02
CPC分类号： B29C71/02 , B29C35/045 , B29C35/06
摘要： To be provided are a heat treatment apparatus having blocking members which block gaps between the side walls of nozzle boxes provided with slit nozzles, whose size in the lengthwise direction is greater than the width of a sheet, and the side walls of a heat treatment chamber, and gas having a uniform velocity fluctuating no more than ±25% in the lengthwise direction of the slit nozzles is blown out of the slit nozzles to subject the sheet to heat treatment, resulting in little unevenness of temperature in the widthwise direction and reduced energy loss, and a heat treatment method using this heat treatment apparatus.
摘要翻译：提供一种热处理装置，其具有阻挡构件，其阻挡设置有狭缝喷嘴的喷嘴盒的侧壁之间的间隙，狭缝喷嘴的长度方向的尺寸大于片材的宽度，并且热处理室的侧壁，并且在狭缝喷嘴的长度方向上具有波动不大于±25％的均匀速度的气体从狭缝喷嘴吹出，以对片材进行热处理，导致宽度方向上的温度不均匀和能量减少损失和使用该热处理装置的热处理方法。

6. 发明申请

US20110230623A1 METHOD FOR CONTINUOUSLY PRODUCING ACRYLIC RESIN SHEET TECHNICAL FIELD 审中-公开
标题翻译：连续生产丙烯酸树脂片的方法技术领域
公开(公告)号：US20110230623A1
公开(公告)日：2011-09-22
申请号：US13058430
申请日：2009-08-07
申请人： Takayuki Hirano , Hajime Okutsu , Naoki Nishida , Eita Funami , Hiroshi Okafuji , Hideto Yamazawa , Dalsuke Takayama , Yutaka Ishihara
发明人： Takayuki Hirano , Hajime Okutsu , Naoki Nishida , Eita Funami , Hiroshi Okafuji , Hideto Yamazawa , Dalsuke Takayama , Yutaka Ishihara
IPC分类号： B29C35/10 , C08F265/06
CPC分类号： C08F2/46 , B29C35/10 , B29C39/16 , B29C2035/0827 , B29C2035/0833 , B29C2035/0844 , B29C2035/0877 , B29K2033/08 , B29K2033/12 , C08F265/00 , C08F265/02 , C08F265/04
摘要： Disclosed is a method for continuously producing an acrylic resin sheet containing 50% by mass or more of methyl methacrylate units, which comprises irradiating an active energy ray-polymerizable viscous liquid 2 which contains a polymer, satisfies the following equations (1) and (2), and has a viscosity of 5,000 Pa·s or more with the active energy ray to cure the liquid while transferring the liquid in the state of being held between an endless belt 3 and a film 5 transmissive to the active energy ray or between first and second films transmissive to the active energy ray, 30,000≦Mw≦500,000 (1) 35−(9/200,000)×Mw≦P≦60 (2) wherein, in these equations, Mw represents a weight average molecular weight [−] of the polymer contained in the liquid, and P represents a content [% by mass] of the polymer contained in the liquid.
摘要翻译：公开了一种连续制造含有50质量％以上的甲基丙烯酸甲酯单元的丙烯酸树脂片的方法，其包括照射含有聚合物的活性能量射线聚合性粘性液体2，满足下述式（1）和（2）），并且通过活性能量射线具有5000Pa·s以上的粘度以固化液体，同时在保持在环状带3和透射于活性能量射线的膜5之间的状态下或在第一对于活性能量射线透射的第二膜，30,000和1000; Mw＆lt; 100; 500,000（1）35-（9 / 200,000）×Mw＆nlE; P＆nlE; 60（2）其中，在这些方程式中，Mw表示重均分子量[ ]，P表示包含在液体中的聚合物的含量[质量％]。

7. 发明申请

US20060157468A1 Heat treating apparatus and heat treating method for sheet-like article 有权
标题翻译：片状物的热处理装置及热处理方法
公开(公告)号：US20060157468A1
公开(公告)日：2006-07-20
申请号：US10547554
申请日：2004-02-27
申请人： Hitoshi Tomobe , Hirotoshi Mizota , Hajime Okutsu , Tomonari Murakami , Daisuke Morimoto
发明人： Hitoshi Tomobe , Hirotoshi Mizota , Hajime Okutsu , Tomonari Murakami , Daisuke Morimoto
IPC分类号： F27B9/28 , F27B9/36
CPC分类号： B29C71/02 , B29C35/045 , B29C35/06
摘要： To be provided are a heat treatment apparatus having blocking members which block gaps between the side walls of nozzle boxes provided with slit nozzles, whose size in the lengthwise direction is greater than the width of a sheet, and the side walls of a heat treatment chamber, and gas having a uniform velocity fluctuating no more than ±25% in the lengthwise direction of the slit nozzles is blown out of the slit nozzles to subject the sheet to heat treatment, resulting in little unevenness of temperature in the widthwise direction and reduced energy loss, and a heat treatment method using this heat treatment apparatus.
摘要翻译：提供一种热处理装置，其具有阻挡构件，其阻挡设置有狭缝喷嘴的喷嘴盒的侧壁之间的间隙，狭缝喷嘴的长度方向的尺寸大于片材的宽度，并且热处理室的侧壁，并且在狭缝喷嘴的长度方向上具有不大于±25％的均匀速度的气体从狭缝喷嘴吹出，以对片材进行热处理，导致宽度方向上的温度差不大，能量减少损失和使用该热处理装置的热处理方法。

8. 发明申请

US20060078640A1 Belt type continuous plate manufacturing apparatus and method of manufacturing sheet polymer 审中-公开
标题翻译：带式连续板制造装置及其制造方法
公开(公告)号：US20060078640A1
公开(公告)日：2006-04-13
申请号：US10537919
申请日：2003-12-08
申请人： Hajime Okutsu , Hirotoshi Mizota , Tomonari Murakami , Hitoshi Tomobe , Daisuke Morimoto
发明人： Hajime Okutsu , Hirotoshi Mizota , Tomonari Murakami , Hitoshi Tomobe , Daisuke Morimoto
IPC分类号： B30B5/06
CPC分类号： B29C43/22 , B29C39/16
摘要： Disclosed are a belt type continuous plate manufacturing apparatus including two endless belts 11, 11′ with their facing belt surfaces running toward the same direction at the same speed, and a gasket 7 sandwiched by belt surfaces at their both side edge portions, in which a polymerizable raw material is fed into a space surrounded by the facing belt surfaces and the gasket from its one end, and solidified together with running of the belts in a heating zone, and a plate polymer is taken out from the other end, wherein a plurality of upper and lower roll pairs 4, 4′ each composed of an upper roll 4 and a lower roll 4′ and having axes orthogonally grossing the belt running direction are placed along the belt running direction as a mechanism of holding the belt surfaces of the endless belts 1, 1′ in the heating zone, and the outer diameter D of the roll body portion of the upper and lower roll pair is in the range of 100 mm to 500 mm; and a method of producing a plate polymer using this apparatus.
摘要翻译：公开了一种带式连续板制造装置，其包括两个环形带11,11'，其相对的带表面以相同的速度朝相同的方向延伸，并且在其两个侧边缘部分处夹着带表面的垫圈7，可聚合原料从其一端进给到由相对的带表面和垫圈包围的空间中，并随着带的运行而在加热区中凝固，并且从另一端取出板状聚合物，其中多个由上辊4和下辊4'构成的上下辊对4,4'和沿着带运行方向正交地累积的轴，作为保持环形带的表面的机构加热区域中的带1,1'，上辊对和下辊对的辊体部分的外径D在100mm至500mm的范围内; 以及使用该装置制造板状聚合物的方法。

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