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1. 发明申请

WO2009022262A3 METHOD OF ACTIVATING A FISCHER-TROPSCH CATALYST 审中-公开
标题翻译：活化Fischer-TROPSCH催化剂的方法
公开(公告)号：WO2009022262A3
公开(公告)日：2009-06-25
申请号：PCT/IB2008053135
申请日：2008-08-05
申请人： SASOL TECH PTY LTD , HUYSER JOHANNES JACOBUS , JANSE VAN VUUREN MATTHYS JOSEP , KOTZE RYNO
发明人： HUYSER JOHANNES JACOBUS , JANSE VAN VUUREN MATTHYS JOSEPHUS , KOTZE RYNO
IPC分类号： C10G2/00 , B01J23/745 , B01J37/18 , C07C1/04
CPC分类号： B01J23/745 , B01J23/78 , B01J37/16 , B01J37/18 , C10G2/332 , C10G2300/703
摘要： This invention relates to the field of Fischer-Tropsch catalysis, in particular to activation of a Fischer-Tropsch catalyst. More particcularly the invention relates to a method of activating an iron based Fischer-Tropsch catalyst which includes iron in a positive oxidation state by contacting in a reactor said iron based catalyst with a reducing gas selected from the group consisting of CO and a combination of H2 and CO; at a temperature of at least 245°C and below 280°C; at a reducing gas pressure of above 0.5 MPa and not more than 2.2 MPa; and at a GHSV of total gas fed to the reactor of at least 6000 ml(N)/g cat/h, thereby reducing the iron that is in a positive oxidation step in the catalyst.
摘要翻译：本发明涉及费 - 托催化领域，特别涉及费 - 托催化剂的活化。更具体地说，本发明涉及一种通过在反应器中使所述铁基催化剂与选自CO和H2的组合的还原气体在反应器中接触而活化包含正氧化态铁的铁基费 - 托催化剂的方法和CO; 在至少245℃且低于280℃的温度下; 在0.5MPa以上且不超过2.2MPa的还原气压下，并且以至少6000ml（N）/ g催化剂/小时供入反应器的总气体的GHSV，由此还原处于催化剂中的正氧化步骤中的铁。

2. 发明申请

WO2009022262A2 METHOD OF ACTIVATING A FISCHER-TROPSCH CATALYST 审中-公开
标题翻译：活化催化剂催化剂的方法
公开(公告)号：WO2009022262A2
公开(公告)日：2009-02-19
申请号：PCT/IB2008/053135
申请日：2008-08-05
申请人： SASOL TECHNOLOGY (PTY) LIMITED , HUYSER, Johannes Jacobus , JANSE VAN VUUREN, Matthys Josephus , KOTZE, Ryno
发明人： HUYSER, Johannes Jacobus , JANSE VAN VUUREN, Matthys Josephus , KOTZE, Ryno
IPC分类号： C10G2/00
CPC分类号： B01J23/745 , B01J23/78 , B01J37/16 , B01J37/18 , C10G2/332 , C10G2300/703
摘要： This invention relates to the field of Fischer-Tropsch catalysis, in particular to activation of a Fischer-Tropsch catalyst. More particcularly the invention relates to a method of activating an iron based Fischer-Tropsch catalyst which includes iron in a positive oxidation state by contacting in a reactor said iron based catalyst with a reducing gas selected from the group consisting of CO and a combination of H 2 and CO; at a temperature of at least 245°C and below 280°C; at a reducing gas pressure of above 0.5 MPa and not more than 2.2 MPa; and at a GHSV of total gas fed to the reactor of at least 6000 ml(N)/g cat/h, thereby reducing the iron that is in a positive oxidation step in the catalyst.
摘要翻译：本发明涉及费 - 托催化领域，特别涉及费 - 托催化剂的活化。更具体地说，本发明涉及一种活化含铁的费 - 托催化剂的方法，其包括处于正氧化态的铁，所述铁通过在反应器中接触所述铁基催化剂与选自CO和H2的组合的还原气体和CO; 在至少245℃和低于280℃的温度下; 在0.5MPa以上且2.2MPa以下的还原气体压力下，并且在进料到反应器的总气体的GHSV为至少6000ml（N）/ g cat / h，从而减少催化剂中正氧化步骤中的铁。

3. 发明申请

WO2009022261A3 A HYDROCARBON SYNTHESIS PROCESS 审中-公开
公开(公告)号：WO2009022261A3
公开(公告)日：2009-02-19
申请号：PCT/IB2008/053134
申请日：2008-08-05
申请人： SASOL TECHNOLOGY (PTY) LIMITED , HUYSER, Johannes Jacobus , BEKKER, Riaan , JANSE VAN VUUREN, Matthys Josephus , KOTZE, Ryno
发明人： HUYSER, Johannes Jacobus , BEKKER, Riaan , JANSE VAN VUUREN, Matthys Josephus , KOTZE, Ryno
IPC分类号： C10G2/00 , B01J23/745 , B01J37/18 , C07C1/04
摘要： This invention relates to a Fischer Tropsch process using a catalyst activated in accordance with the invention. More particularly the invention relates to a three phase Low Temperature Fischer Tropsch process wherein CO and H 2 are converted to hydrocarbons and possibly oxygenates thereof by contacting syngas including CO and H 2 in the presence of an iron based Fischer Tropsch catalyst, wherein the ratio of H 2 :CO in the feed is between 2.5 and 1, and wherein the iron based Fischer Tropsch catalyst is activated according to the steps of: (a) providing an iron catalyst including iron in a positive oxidation state; and (b) contacting the iron catalyst in a reactor with a reducing gas selected from CO and a combination of H 2 and CO; at a temperature of at least 245°C and below 28O°C; at a reducing gas pressure of above 0.5 MPa and not more than 2.2 MPa; and at a GHSV of total gas fed to the reactor of at least 6000 ml(N)/g cat/h, thereby reducing the iron that is in a positive oxidation step in the catalyst.

4. 发明申请

WO2009022263A3 A HYDROCARBON SYNTHESIS PROCESS 审中-公开
公开(公告)号：WO2009022263A3
公开(公告)日：2009-02-19
申请号：PCT/IB2008/053137
申请日：2008-08-05
申请人： SASOL TECHNOLOGY (PTY) LIMITED , HUYSER, Johannes Jacobus , JANSE VAN VUUREN, Matthys Josephus
发明人： HUYSER, Johannes Jacobus , JANSE VAN VUUREN, Matthys Josephus
IPC分类号： C10G2/00 , B01J23/745 , B01J37/18 , C07C1/04
摘要： This invention relates to a hydrocarbon synthesis process. More particularly, but not exclusively, this invention relates to a Fischer Tropsch Process employing an activated catalyst and to the use of such an activated catalyst, wherein the Fischer Tropsch Process conditions favour the attainment of a low acid selectivity. More particularly the invention relates to a three-phase low temperature Fischer Tropsch (LTFT) process wherein a feed of H 2 and CO are converted to hydrocarbons and possible oxygenates thereof by contacting the H 2 and CO in the presence of an iron-based Fischer Tropsch catalyst in a reaction zone, wherein the molar ratio of H 2 : CO in the feed is from 0.5 and less than 1.0 and wherein the iron-based Fischer Tropsch catalyst is activated according to the steps of: (a) providing an iron-based catalyst including iron in a positive oxidation state; and (b) contacting the iron- based catalyst in a reactor with a reducing gas selected from CO and a combination of H 2 and CO; at a reduction temperature of at least 245°C and below 28O°C; at a reducing gas pressure of above 0.5 MPa and not more than 2.2 MPa; and at a GHSV of total reducing gas fed to the reactor of at least 6000 ml(N)/g cat/h, thereby reducing the iron that is in a positive oxidation step in the catalyst.

5. 发明申请

WO2009022261A2 A HYDROCARBON SYNTHESIS PROCESS 审中-公开
标题翻译：油气合成方法
公开(公告)号：WO2009022261A2
公开(公告)日：2009-02-19
申请号：PCT/IB2008053134
申请日：2008-08-05
申请人： SASOL TECH PTY LTD , HUYSER JOHANNES JACOBUS , BEKKER RIAAN , JANSE VAN VUUREN MATTHYS JOSEP , KOTZE RYNO
发明人： HUYSER JOHANNES JACOBUS , BEKKER RIAAN , JANSE VAN VUUREN MATTHYS JOSEPHUS , KOTZE RYNO
IPC分类号： C10G2/00
CPC分类号： B01J23/745 , B01J23/78 , B01J37/16 , B01J37/18 , C10G2/332 , C10G2300/703
摘要： This invention relates to a Fischer Tropsch process using a catalyst activated in accordance with the invention. More particularly the invention relates to a three phase Low Temperature Fischer Tropsch process wherein CO and H2 are converted to hydrocarbons and possibly oxygenates thereof by contacting syngas including CO and H2 in the presence of an iron based Fischer Tropsch catalyst, wherein the ratio of H2:CO in the feed is between 2.5 and 1, and wherein the iron based Fischer Tropsch catalyst is activated according to the steps of: (a) providing an iron catalyst including iron in a positive oxidation state; and (b) contacting the iron catalyst in a reactor with a reducing gas selected from CO and a combination of H2 and CO; at a temperature of at least 245°C and below 28O°C; at a reducing gas pressure of above 0.5 MPa and not more than 2.2 MPa; and at a GHSV of total gas fed to the reactor of at least 6000 ml(N)/g cat/h, thereby reducing the iron that is in a positive oxidation step in the catalyst.
摘要翻译：本发明涉及使用根据本发明活化的催化剂的费 - 托法。更具体地说，本发明涉及一种三相低温费 - 托法，其中CO和H 2在铁基费 - 托催化剂存在下，通过使包含CO和H 2的合成气接触将CO和H 2转化成烃，并且其中CO 2和H 2的比例进料中的CO为2.5〜1，其中铁基费托催化剂根据以下步骤活化：（a）提供包含正氧化态的铁的铁催化剂; 和（b）使反应器中的铁催化剂与选自CO和H 2和CO的组合的还原气体接触; 在至少245℃和低于280℃的温度下; 在0.5MPa以上且2.2MPa以下的还原气体压力下，并且在进料到反应器的总气体的GHSV为至少6000ml（N）/ g cat / h，从而减少催化剂中正氧化步骤中的铁。

6. 发明申请

WO2009022263A2 A HYDROCARBON SYNTHESIS PROCESS 审中-公开
标题翻译：油气合成方法
公开(公告)号：WO2009022263A2
公开(公告)日：2009-02-19
申请号：PCT/IB2008053137
申请日：2008-08-05
申请人： SASOL TECH PTY LTD , HUYSER JOHANNES JACOBUS , JANSE VAN VUUREN MATTHYS JOSEP
发明人： HUYSER JOHANNES JACOBUS , JANSE VAN VUUREN MATTHYS JOSEPHUS
IPC分类号： C10G2/00
CPC分类号： B01J23/78 , B01J23/745 , B01J37/18 , C10G2/332 , C10G2300/703
摘要： This invention relates to a hydrocarbon synthesis process. More particularly, but not exclusively, this invention relates to a Fischer Tropsch Process employing an activated catalyst and to the use of such an activated catalyst, wherein the Fischer Tropsch Process conditions favour the attainment of a low acid selectivity. More particularly the invention relates to a three-phase low temperature Fischer Tropsch (LTFT) process wherein a feed of H2 and CO are converted to hydrocarbons and possible oxygenates thereof by contacting the H2 and CO in the presence of an iron-based Fischer Tropsch catalyst in a reaction zone, wherein the molar ratio of H2 : CO in the feed is from 0.5 and less than 1.0 and wherein the iron-based Fischer Tropsch catalyst is activated according to the steps of: (a) providing an iron-based catalyst including iron in a positive oxidation state; and (b) contacting the iron- based catalyst in a reactor with a reducing gas selected from CO and a combination of H2 and CO; at a reduction temperature of at least 245°C and below 28O°C; at a reducing gas pressure of above 0.5 MPa and not more than 2.2 MPa; and at a GHSV of total reducing gas fed to the reactor of at least 6000 ml(N)/g cat/h, thereby reducing the iron that is in a positive oxidation step in the catalyst.
摘要翻译：本发明涉及烃合成方法。更具体地但非唯一地，本发明涉及使用活化催化剂的费 - 托法和这种活化催化剂的用途，其中费托法条件有利于获得低酸选择性。更具体地说，本发明涉及一种三相低温费托（LTFT）方法，其中通过在铁基费托催化剂存在下使H 2和CO接触，将H 2和CO的进料转化成烃和可能的含氧化合物在反应区中，其中进料中H 2 :CO的摩尔比为0.5至小于1.0，并且其中所述铁基费托催化剂根据以下步骤活化：（a）提供铁基催化剂，其包括正铁氧化态; 和（b）使反应器中的铁基催化剂与选自CO和H 2和CO的组合的还原气体接触; 在至少245℃和低于280℃的还原温度下; 在0.5MPa以上且2.2MPa以下的还原气体压力下，并且在进料到反应器的总还原气体的GHSV为至少6000ml（N）/ g cat / h，从而减少催化剂中正氧化步骤中的铁。

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