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1. 发明专利

ZA954640B Method of modifying keratin fiber 未知
公开(公告)号：ZA954640B
公开(公告)日：1996-01-26
申请号：ZA954640
申请日：1995-06-06
申请人： HOJO HIROSHI
发明人： HOJO HIROSHI
IPC分类号： D06M20060101 , D06M

2. 发明专利

NZ272252A PROCESS FOR REMOVAL OF KERATIN LAYERS FROM THE OUTER SURFACE CELLS OF ANIMAL FIBER USING NON-CHLORINE BASE OXIDIZING AGENTS 未知
公开(公告)号：NZ272252A
公开(公告)日：1996-07-26
申请号：NZ27225295
申请日：1995-05-30
申请人： HOJO HIROSHI
发明人： HOJO HIROSHI
IPC分类号： D06M11/00 , D06M11/28 , D06M11/49 , D06M11/50 , D06M11/84 , D06M11/55 , D06M11/62 , D06M101/00 , D06M101/02 , D06M101/10 , D06M101/12 , D02J1/00 , D02J3/00 , D01G37/00 , D01C3/00
摘要： An improved method of modifying keratin fiber represented by wool is disclosed. Mechanical force is applied to keratin fiber in the presence of an aqueous solution of a transition metal salt to weaken and destroy the structure of the parts under the keratin layers in scales (surface cells) so that the transition metal may be introduced in the under-keratin layers locally at high a concentration. Then, the keratin fiber is immersed in a bath containing oxidizing agents such as hydrogen peroxide and monopersulfuric acid. The oxidizing agents are decomposed by catalytic effect of the transition metal. Mainly due to pressure of oxygen gas evolved by the decomposition keratin layers, which are scales on the keratin fiber, are peeled off. Thus, it is possible to remove only the keratin parts, which are not agreeable to the touch, without damaging the non-keratin protein, and to provide modified fiber which substantially contains no remaining metal. High shrink proof effect may be achieved without using the conventional chlorine compounds as the oxidizing agents.

3. 发明专利

DE69115587D1 未知
公开(公告)号：DE69115587D1
公开(公告)日：1996-02-01
申请号：DE69115587
申请日：1991-07-25
申请人： HOJO HIROSHI
发明人： KOGA JOICHI , HOJO HIROSHI , NOMURA KOICHI
IPC分类号： A61L15/16 , A61L15/40 , A61L27/00 , D06M11/30 , D06M11/84

4. 发明公开

EP0055778A1 VERFAHREN ZUM MODIFIZIEREN VON WOLLFASERN DURCH ENTFERNEN VON SCHUPPEN 失效
标题翻译：方法进行修改羊毛纤维的去除棚。
公开(公告)号：EP0055778A1
公开(公告)日：1982-07-14
申请号：EP81900299.9
申请日：1981-01-21
申请人： HOJO, Hiroshi , NOGUCHI, Sadao
发明人： HOJO, Hiroshi , NOGUCHI, Sadao
IPC分类号： D06M3/08 , D06M3/10
CPC分类号： D06M11/07
摘要： Die Erfindung bezieht sich auf ein Verfahren zur Verbesserung der Qualität tierischer Fasern, die von Schafen, Ziegen, Lamas und Alpaka gewonnen werden, wobei die Schuppen entfernt werden.
Dabei wird zunächst (a) ein Oxidationskatalysator von den hydrophilen Bereichen an der Oberfläche der Faser absorbiert, d.h. von den Verbindungsabschnitten (2) der Schuppen (1) und der Endokutikula (3). Danach wird (b) die Faser in eine Lösung eines Chlorierungsmittels oder eines Oxidationsmittels getaucht, um die Schuppen (1) durch Oxidation rasch zu zersetzen und damit zu entfernen. Anschließend wird (c) die Faser mit einer Lösung eines Reduktionsmittels behandelt. Der vorstehende Schritt (a) wird durchgeführt, indem die als Katalysator eingesetzte Säure in einer Lösung eines einfachen Salzes aus einer starken Säure und einer schwachen Base angewendet wird, oder indem ein saures Gas durch die gebundene Feuchtigkeit der Abschnitte (2) und (3) absorbiert wird oder indem an die hydrophilen Bereiche der Abschnitte (2) und (3) eine Lösung, die Übergangselemente, Mg oder A1 als lonen enthält, oder ein organisches Lösungsmittel, das diese Lösung dispergiert enthält, gebunden wird, worauf durch diese Metalle eine Chelat-Bildung erfolgt.
Durch die Erfindung wird die Qualität von mit tierischen Fasern gemischten Produkten oder Fellen wirksam innerhalb kurzer Zeit und bei Raumtemperatur verbessert.
摘要翻译：本发明涉及一种用于改善动物纤维，这是从绵羊，山羊，美洲驼和羊驼衍生的质量，其中，所述鳞片被去除的方法。这里，首先（a）中的氧化催化剂是由亲水性区域中的纤维，即表面上吸收从连接部（2）梭口（1）和endocuticle的（3）。此后（b）中浸渍纤维在氯化剂的溶液或以分解通过氧化梭口（1），并迅速将其删除的氧化剂。（C）所述纤维，然后用还原剂的溶液处理。上述步骤（a）是由用作催化剂的强酸的简单盐和弱碱的溶液施加的酸反应通过部分（2）和结合的湿气进行，或者通过酸气体（3）被吸收或通过施加到所述部分（2）和亲水性区域（3）含有过渡元素Mg或Al作为离子，或含有该溶液分散附着的有机溶剂中，随后通过这些金属螯合物中的溶液形成发生。通过本发明，与动物纤维或皮毛制品混合的质量，在短时间内，在室温下有效地提高。

5. 发明授权

EP0055778B1 VERFAHREN ZUM MODIFIZIEREN VON WOLLFASERN DURCH ENTFERNEN VON SCHUPPEN 失效
标题翻译：通过移除尺寸来修改羊毛纤维的方法
公开(公告)号：EP0055778B1
公开(公告)日：1985-06-05
申请号：EP81900299.9
申请日：1981-01-21
申请人： HOJO, Hiroshi , NOGUCHI, Sadao
发明人： HOJO, Hiroshi , NOGUCHI, Sadao
IPC分类号： D06M3/08 , D06M3/10
CPC分类号： D06M11/07
摘要： A process for modifying woolen fiber, obtained from sheep, goat, llama, alpaca, etc., by removing scales, comprising (a) depositing an oxidizing catalyst on hydrophilic portions of the fiber, i.e., (1) scale-binding portions (2) and endocuticles (3), (b) dipping it in an aqueous solution of a chlorinating agent or other oxidizing agent to cause rapid oxidative decomposition thus removing scales (1), then (c) treating it in a solution of a reducing agent. Step (a) is conducted by treating the fiber with an acid to be used as a catalyst in a solution saturated with a neutral salt or a strong acid-weak base salt, by treating the fiber in an acidic gas to thereby incorporate it into binding water in said portions (2) and (3), or by forming chelate bonds of transition metal, Mg or Al in an aqueous solution containing such a metal ion, or in an organic solvent containing dispersed therein said aqueous solution. This invention enables the treatment of woolen fiber at approximately ordinary temperatures in times as short as several minutes. Thus, mixed fabrics, fur goods, or woolen fibers can be easily upgraded.

6. 发明公开

EP0019639A4 VERFAHREN ZUR VEREDLUNG FASERIGEN WOLLMATERIALS. 失效
标题翻译：一种用于处理纤维状材料羊毛。
公开(公告)号：EP0019639A4
公开(公告)日：1980-11-28
申请号：EP79901188
申请日：1980-04-09
申请人： HOJO HIROSHI , NOGUCHI SADAO
发明人： HOJO HIROSHI
IPC分类号： D06M11/00 , D06M11/11 , D06M11/13 , D06M11/30 , D06M11/55 , D06M11/61 , D06M11/70 , D06M13/127 , D06M13/184 , D06M13/188 , D06M13/21 , D06M13/52 , D06M101/00 , D06M101/02 , D06M101/10 , D06M101/12 , D06M3/10 , D01C3/00
CPC分类号： D06M13/21 , D06M11/13 , D06M11/55 , D06M11/70 , D06M13/184 , D06M13/188

7. 发明公开

EP0687764A2 Method of modifying keratin fiber 失效
标题翻译： Verfahren zum Modifizieren von Keratinfasern
公开(公告)号：EP0687764A2
公开(公告)日：1995-12-20
申请号：EP95108640.4
申请日：1995-06-06
申请人： Hojo, Hiroshi
发明人： Hojo, Hiroshi
IPC分类号： D06M11/50
CPC分类号： D06M11/55 , D06M11/28 , D06M11/50 , D06M11/62 , D06M2101/12 , D06M2200/45
摘要： An improved method of modifying keratin fiber represented by wool is disclosed. Mechanical force is applied to keratin fiber in the presence of an aqueous solution of a transition metal salt to weaken and destroy the structure of the parts under the keratin layers in scales (surface cells) so that the transition metal may be introduced in the under-keratin layers locally at high a concentration. Then, the keratin fiber is immersed in a bath containing oxidizing agents such as hydrogen peroxide and monopersulfuric acid. The oxidizing agents are decomposed by catalytic effect of the transition metal. Mainly due to pressure of oxygen gas evolved by the decomposition keratin layers, which are scales on the keratin fiber, are peeled off. Thus, it is possible to remove only the keratin parts, which are not agreeable to the touch, without damaging the non-keratin protein, and to provide modified fiber which substantially contains no remaining metal. High shrink proof effect may be achieved without using the conventional chlorine compounds as the oxidizing agents.
摘要翻译：公开了改进由羊毛代表的角蛋白纤维的改进方法。在过渡金属盐水溶液的存在下，对角蛋白纤维施加机械力，以削弱和破坏鳞片（表面细胞）角质层下部分的结构，从而将过渡金属引入到底层局部高浓度的角蛋白层。然后将角蛋白纤维浸渍在含有氧化剂如过氧化氢和单过硫酸的浴中。氧化剂被过渡金属的催化作用分解。主要是由角蛋白纤维上鳞片上分解的角蛋白层释放的氧气的压力被剥离。因此，可以仅去除不符合触摸的角蛋白部分，而不损害非角蛋白蛋白质，并且提供基本上不含剩余金属的改性纤维。不使用常规氯化合物作为氧化剂可以实现高收缩效果。

8. 发明专利

DE3170786D1 PROCESS FOR MODIFYING WOOLEN FIBER BY REMOVING SCALES 未知
公开(公告)号：DE3170786D1
公开(公告)日：1985-07-11
申请号：DE3170786
申请日：1981-01-21
申请人： HOJO HIROSHI , NOGUCHI SADAO
发明人： HOJO HIROSHI
IPC分类号： D06M11/00 , D06M11/07 , D06M11/11 , D06M11/13 , D06M11/155 , D06M11/17 , D06M11/28 , D06M11/30 , D06M11/51 , D06M11/54 , D06M11/56 , D06M11/57 , D06M11/65 , D06M11/83 , D06M13/08 , D06M13/188 , D06M13/364 , D06M23/00 , D06M101/00 , D06M101/02 , D06M101/10 , D06M101/12 , D06M3/08 , D06M3/10
摘要： PCT No. PCT/JP81/00015 Sec. 371 Date Aug. 20, 1981 Sec. 102(e) Date Aug. 20, 1981 PCT Filed Jan. 21, 1981 PCT Pub. No. WO81/02752 PCT Pub. Date Oct. 1, 1981.This present invention relates to a method of improving the quality of animal fibers collected from sheep, goat, llama, or alpaca by removing scales. Firstly, (a), an oxidizing catalyst is absorbed in the hydrophilic areas on the surface of a fiber, that is, the joint sections (2) of the scales (1) and the end cuticles (3). Then, (b), the fiber is immersed in a solution of a chlorinating agent or an oxidizing agent to decompose the scales rapidly by oxidation in order to remove the scales (1). Then, (c), the fiber is treated with a solution of a reducing agent. The above process (a) is carried out by processing the acid to be used as a catalyst in a solution of a simple salt consisting strong acid and weak base or in an acidic gas in order to absorb it to the bonded moisture of the sections (2) and (3), or by bonding to the hydrophilic areas of the section (2) and (3) in a solution containing transition elements, Mg, or Al as ions, or in an organic solvent in which said solution is dispereded, after producing chelete bonding of said metals. This present invention improves the quality of blended products with animal fibers or furs efficiently in a short time at a room temperature.

9. 发明专利

AU6708381A PROCESS FOR MODIFYING WOOLEN FIBER BY REMOVING SCALES 未知
公开(公告)号：AU6708381A
公开(公告)日：1981-10-09
申请号：AU6708381
申请日：1981-01-21
申请人： HOJO HIROSHI NOGUCHI SADAO
发明人： HOJO H , NOGUCHI S
IPC分类号： D06M11/00 , D06M11/07 , D06M11/11 , D06M11/13 , D06M11/155 , D06M11/17 , D06M11/28 , D06M11/30 , D06M11/51 , D06M11/54 , D06M11/56 , D06M11/57 , D06M11/65 , D06M11/83 , D06M13/08 , D06M13/188 , D06M13/364 , D06M23/00 , D06M101/00 , D06M101/02 , D06M101/10 , D06M101/12 , D06M3/08 , D06M3/10
摘要： PCT No. PCT/JP81/00015 Sec. 371 Date Aug. 20, 1981 Sec. 102(e) Date Aug. 20, 1981 PCT Filed Jan. 21, 1981 PCT Pub. No. WO81/02752 PCT Pub. Date Oct. 1, 1981.This present invention relates to a method of improving the quality of animal fibers collected from sheep, goat, llama, or alpaca by removing scales. Firstly, (a), an oxidizing catalyst is absorbed in the hydrophilic areas on the surface of a fiber, that is, the joint sections (2) of the scales (1) and the end cuticles (3). Then, (b), the fiber is immersed in a solution of a chlorinating agent or an oxidizing agent to decompose the scales rapidly by oxidation in order to remove the scales (1). Then, (c), the fiber is treated with a solution of a reducing agent. The above process (a) is carried out by processing the acid to be used as a catalyst in a solution of a simple salt consisting strong acid and weak base or in an acidic gas in order to absorb it to the bonded moisture of the sections (2) and (3), or by bonding to the hydrophilic areas of the section (2) and (3) in a solution containing transition elements, Mg, or Al as ions, or in an organic solvent in which said solution is dispereded, after producing chelete bonding of said metals. This present invention improves the quality of blended products with animal fibers or furs efficiently in a short time at a room temperature.

10. 发明专利

IT8120772D0 未知
公开(公告)号：IT8120772D0
公开(公告)日：1981-03-27
申请号：IT2077281
申请日：1981-03-27
申请人： HOJO HIROSHI
发明人： HIROSHI HOJO , SADAO NOGUCHI
IPC分类号： D06M11/00 , D06M11/07 , D06M11/11 , D06M11/13 , D06M11/155 , D06M11/17 , D06M11/28 , D06M11/30 , D06M11/51 , D06M11/54 , D06M11/56 , D06M11/57 , D06M11/65 , D06M11/83 , D06M13/08 , D06M13/188 , D06M13/364 , D06M23/00 , D06M101/00 , D06M101/02 , D06M101/10 , D06M101/12 , C14C
摘要： PCT No. PCT/JP81/00015 Sec. 371 Date Aug. 20, 1981 Sec. 102(e) Date Aug. 20, 1981 PCT Filed Jan. 21, 1981 PCT Pub. No. WO81/02752 PCT Pub. Date Oct. 1, 1981.This present invention relates to a method of improving the quality of animal fibers collected from sheep, goat, llama, or alpaca by removing scales. Firstly, (a), an oxidizing catalyst is absorbed in the hydrophilic areas on the surface of a fiber, that is, the joint sections (2) of the scales (1) and the end cuticles (3). Then, (b), the fiber is immersed in a solution of a chlorinating agent or an oxidizing agent to decompose the scales rapidly by oxidation in order to remove the scales (1). Then, (c), the fiber is treated with a solution of a reducing agent. The above process (a) is carried out by processing the acid to be used as a catalyst in a solution of a simple salt consisting strong acid and weak base or in an acidic gas in order to absorb it to the bonded moisture of the sections (2) and (3), or by bonding to the hydrophilic areas of the section (2) and (3) in a solution containing transition elements, Mg, or Al as ions, or in an organic solvent in which said solution is dispereded, after producing chelete bonding of said metals. This present invention improves the quality of blended products with animal fibers or furs efficiently in a short time at a room temperature.

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