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1. 发明申请

WO1996023011A1 FUNCTIONALISED POLYMERS, PROCESS FOR PRODUCING THEM AND THEIR USE IN THERMOPLASTIC MOULDING COMPOUNDS 审中-公开
标题翻译：功能化的聚合物，生产方法和它们在热塑性模塑化合物
公开(公告)号：WO1996023011A1
公开(公告)日：1996-08-01
申请号：PCT/DE1996000087
申请日：1996-01-23
申请人： BUNA SOW LEUNA OLEFINVERBUND GMBH , GERECKE, Jochen , WULFF, Dirk , GRUBER, Klaus , HOFMANN, Tatjana , STUDE, Joachim , NAGEL, Marion
发明人： BUNA SOW LEUNA OLEFINVERBUND GMBH
IPC分类号： C08F255/00
CPC分类号： C08F291/00 , C08F8/00 , C08F8/04 , C08F297/00
摘要： It is possible by the radical solid phase graft polymerisation of function monomers with at least one functional group selected from among mono and dicarboxylic groups or groups derived therefrom, especially anhydride groups, and hydroxy, epoxy, amino and silane groups, possible mixed with an additional comonomer in the proportion of 1 to 99% related to the total monomer mass, especially from the group of styrenes and/or (meth)acrylates, with a polymerised monomer porportion in relation to the graft product mass of 0.05 to 50% on an olefinic and/or dienic spinal polymer (compound), including hydrated conjugated dienic homopolymer, copolymer and especially block copolymer backbones which contain a quantity of a mineral and/or native oil added before the functionalisation reaction, to obtain functionalised polymers, preferably carboxylated thermoplastic elastomers (TPE-S, TPE-O) characterized by improved adhesive strength and especially impact resistance when used in a large number of thermoplastic moulding compounds, polymer blends and composites. Preference is given to (saturated) paraffinic/naphthenic process oils used in quantities of between 10 parts by mass and at maximum concentrations corresponding to 20 to 400 parts by mass, in relation to 100 parts by mass of the spinal polymer, taking account of the dry-flowing consistency of the spinal polymer to be maintained.
摘要翻译：通过从由其衍生的单羧酸和二或基团，特别是酸酐基团，以及羟基，环氧基，氨基和硅烷基团，任选与1〜99％混合，基于选择的至少一种官能团的自由基Festphasenpfropfpolymerisation Funktionsmonomeren 所述Gesamtmonomermasse，一个Zusatzcomonomers，尤其选自苯乙烯和/或（甲基）丙烯酸酯，与相关于0.05 Pfropfproduktmasse聚合的单体含量至50％的上一个烯属的和/或dienisches主链聚合物（化合物），其中包括氢化的共轭二烯均聚物，共聚物，特别是阻止包含雄加入之前的矿物和/或天然油的官能化反应的比例，被官能化的聚合物，优选得到的羧基化热塑性弹性体（TPE-S，TPE-O），共聚主链，其通过改进的粘合强度和BES 其特征唐德斯Schlagzähwirkung当并入许多热塑性模塑化合物，聚合物共混物和-Composites。优选的是（饱和的）石蜡/环烷加工油，在对应于基于100质量份Rückgratpolymerisat可以使用考虑到主链聚合物的aufrechtzuerhaltenden干燥可流动的稠度为20〜400重量份质量份和最大浓度10之间的量存在。

2. 发明申请

WO1995016718A1 FUNCTIONALIZED OLEFINIC HOMO- AND COPOLYMERS 审中-公开
标题翻译：官能化的烯烃均聚物和共聚物
公开(公告)号：WO1995016718A1
公开(公告)日：1995-06-22
申请号：PCT/DE1994001352
申请日：1994-11-17
申请人： BUNA GMBH , WULFF, Dirk , GERECKE, Jochen , HOFMANN, Tatjana , STUDE, Joachim , GRUBER, Klaus , HÄUSSLER, Lutz
发明人： BUNA GMBH
IPC分类号： C08F255/02
CPC分类号： C08F255/00 , C08F8/00 , C08F10/00
摘要： Functionalized olefinic homo- and copolymers with set levels of crosslinking are produced by radical solid phase graft polymerization of alpha , beta -ethylenically unsaturated compounds with functional groups (functional monomers) such as, in particular, mono- and dicarboxylic acids or their anhydrides, epoxides and hydroxides, amines, amides and imides, alone or mixed with comonomers from the series of monovinylaromates, acrylates or methacrylates and monovinylesters, backbone polymers or elastomers based on completely or predominately olefinic units, having different degrees of branchings in the range of 0 to 400 CH3 end groups per 1000 carbon atoms and types of branching, in particular aliphatic short-chain branchings, including those linked via ester (or carboxyl) groups, and/or long-chain branchings, and with an average molar mass in the range of 5 x 10 to 5 x 10 g/mol. Considering the type and concentration of the three components of functional monomer, addition comonomer and backbone polymer (or elastomer), for the latter especially with regard to degree and structure of branching as well as average molar mass, the gel content can be targetedly set, generally either gel-free to low-gel (gel content of 0 to 30 mass %) or gel-bearing to gel-rich (gel content of >30 to 100 mass %), which is critical for the concrete application - preferably as hot-melt adhesive, coating material or as component in laminates, sandwich foils or adhesion-resistant coatings and/or as compatibilizer (impact resistance modifier, coupler) in polymer blends or composites.
摘要翻译：交联官能化的烯烃均聚物和共聚物具有调节程度由阿尔法的自由基产生Festphasenpfropfpolymerisation具有官能团（Funktionsmonomere）是特别单和二羧酸或它们的酸酐，环氧化物，氢氧化物，胺，酰胺和酰亚胺，单独，β-烯属不饱和化合物或与选自Monovinylaromate，丙烯酸酯或甲基丙烯酸酯和单乙烯基酯，从构成主链的聚合物和弹性体具有在从0到400 CH3端基/ 1000个碳原子的范围内不同的分支号码完整数据或主要烯烃单元的共聚单体的混合物和支化，特别是脂族短链，包括通过酯（或羧基）连接的短支链基团，和/或长链支链，并且在5×10 <3>至5×范围具有的平均分子量得到10 <6>克/摩尔。这里，考虑三种组分Funktionsmonomer，另外的共聚单体和主链聚合物（弹性体），对于后者的类型和浓度，特别是关于分支和结构，和中等分子量的程度的，凝胶含量具体调整，通常要么gelarm（无凝胶的从0到的凝胶含量 30质量％）或gelhaltig到gelreich的质量> 30至100％（凝胶含量），主要用于具体使用 - 优选为热熔粘合剂，涂层材料或作为层压材料，复合箔或adhäsionsfesten涂层和/或作为成分增容剂（冲击改性剂，联接器）的聚合物共混物或-Composites - 是至关重要的。

3. 发明申请

WO2012025187A2 FUROPYRIDINE DERIVATIVES 审中-公开
标题翻译：丙烯酰胺衍生物
公开(公告)号：WO2012025187A2
公开(公告)日：2012-03-01
申请号：PCT/EP2011/003831
申请日：2011-07-29
申请人： MERCK PATENT GMBH , BURGDORF, Lars , SCHULTZ, Melanie , HOFMANN, Tatjana , HODOUS, Brian , POTNICK, Justin , SUTTON, Amanda E. , HUCK, Bayard R.
发明人： BURGDORF, Lars , SCHULTZ, Melanie , HOFMANN, Tatjana , HODOUS, Brian , POTNICK, Justin , SUTTON, Amanda E. , HUCK, Bayard R.
IPC分类号： C07D491/04
CPC分类号： C07D491/048 , A61K31/4355 , A61K31/4709 , A61K31/496 , A61K31/506 , A61K31/5377 , A61K31/5383 , A61K45/06 , C07D491/04 , C07D519/00
摘要： Compounds of the formula I in which R 1 and R 2 have the meanings indicated in Claim 1, are inhibitors of Syk, and can be employed, inter alia, for the treatment of rheumatoid arthritis and / or systemic lupus.
摘要翻译：其中R1和R2具有权利要求1所述含义的式I化合物是Syk的抑制剂，并且可以用于治疗类风湿性关节炎和/或系统性红斑狼疮。

4. 发明申请

WO2012025187A3 FUROPYRIDINE DERIVATIVES 审中-公开
标题翻译：丙烯酰胺衍生物
公开(公告)号：WO2012025187A3
公开(公告)日：2012-06-21
申请号：PCT/EP2011003831
申请日：2011-07-29
申请人： MERCK PATENT GMBH , BURGDORF LARS , SCHULTZ MELANIE , HOFMANN TATJANA , HODOUS BRIAN , POTNICK JUSTIN , SUTTON AMANDA E , HUCK BAYARD R
发明人： BURGDORF LARS , SCHULTZ MELANIE , HOFMANN TATJANA , HODOUS BRIAN , POTNICK JUSTIN , SUTTON AMANDA E , HUCK BAYARD R
IPC分类号： C07D491/04 , A61K31/4355
CPC分类号： C07D491/048 , A61K31/4355 , A61K31/4709 , A61K31/496 , A61K31/506 , A61K31/5377 , A61K31/5383 , A61K45/06 , C07D491/04 , C07D519/00
摘要： Compounds of the formula (I) in which R1 denotes Ar1 or Het1, R2 denotes Ar2, Het2, NH(CH2)nAr2, O(CH2)nAr2 or NH(CH2)nHet2, are inhibitors of Syk, and can be employed, inter alia, for the treatment of rheumatoid arthritis and/or systemic lupus.
摘要翻译：其中R 1表示Ar 1或Het 1的式（I）化合物，R 2表示Ar 2，Het 2，NH（CH 2）nAr 2，O（CH 2）n Ar 2或NH（CH 2）n Het 2）是Syk的抑制剂，尤其用于治疗类风湿性关节炎和/或系统性红斑狼疮。

5. 发明申请

WO1993024537A1 PROCESS FOR PRODUCING CARBOXYLATED STYRENE-DIENE BLOCK COPOLYMERS 审中-公开
标题翻译：用于生产羧化苯乙烯 - 丁二烯嵌段共聚物
公开(公告)号：WO1993024537A1
公开(公告)日：1993-12-09
申请号：PCT/DE1993000373
申请日：1993-04-28
申请人： BUNA AG , GERECKE, Jochen , WULFF, Dirk , THIELE, Klaus , HOFMANN, Tatjana , GRUBER, Klaus , NAGEL, Marion , HÄUSSLER, Lutz
发明人： BUNA AG
IPC分类号： C08F08/00
CPC分类号： C08F8/00 , C08F8/46 , C08F297/00
摘要： Carboxylated styrene-diene block copolymers are produced by high yield radical grafting of 0.2 to 10 parts by mass β-ethylenically unsaturated monocarboxylic and/or dicarboxylic acids or their anhydrides (carboxylic monomers), if required mixed with up to 10 parts by mass carboxyl-group free and anhydride-group free comonomers, with respect to 100 parts by mass of a block copolymer backbone, on non-hydrated and/or selectively hydrated styrene-diene block copolymers in a dry powdery, crumbly or granulated reaction phase at polymerisation temperatures from 40 to 100 °C. The functionalisation degree of the block copolymer can be accurately set in a range from 0.1 to 10 % graft polymerised carboxyl monomer, with respect to the available backbone mass.

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