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    • 6. 发明申请
    • PHOTOPOLYMERIZABLE INKJET INK
    • 光聚合喷墨墨水
    • WO2013069580A1
    • 2013-05-16
    • PCT/JP2012/078555
    • 2012-10-30
    • Ricoh Company, Ltd.HIRAOKA, Takao
    • HIRAOKA, Takao
    • C09D11/00B41J2/01B41M5/00
    • B41J2/17503C09D11/101C09D11/30
    • To provide a photopolymerizable inkjet ink, which contains photopolymerizable monomers containing at least one selected from the following compound group (A) compounds of which are negative for skin sensitization, and at least one selected from the following compound group (B) compounds of which are negative for skin sensitization, wherein the compound group (A) is a compound group consisting of caprolactone-modified dipentaerythritol hexaacrylate, polyethoxylated tetramethylol methane tetraacrylate, ethylene oxide-modified bisphenol A diacrylate, caprolactone-modified hydroxy pivalic acid neopentyl glycol diacrylate, polypropylene glycol diacrylate [CH 2 =CH―CO―(OC 3 H 6 )n―OCOCH=CH 2 (n≈12)], hydroxyethyl acryl amide, trimethylol propane trimethacrylate, and tricyclodecane dimethanol dimethacrylate, and the compound group (B) is a compound group consisting of ethylene oxide-modified phenolacrylate, isostearyl acrylate, ethylene oxide-modified trimethylol propane trimethacrylate, stearyl methacrylate, and glycerin dimethacrylate.
    • 为了提供含有光聚合性单体的光聚合性喷墨油墨,所述光聚合性单体含有选自下述化合物组(A)中的至少一种化合物,其对于皮肤敏化是阴性的,以及选自下列化合物组(B)中的至少一种: 其中化合物组(A)是由己内酯改性的二季戊四醇六丙烯酸酯,聚乙氧基化四羟甲基甲烷四丙烯酸酯,环氧乙烷改性的双酚A二丙烯酸酯,己内酯改性的羟基新戊酸新戊二醇二丙烯酸酯,聚丙二醇二丙烯酸酯 [CH2 = CH_CO_(OC3H6)n_OCOCH = CH2(n≈12)],羟乙基丙烯酰胺,三羟甲基丙烷三甲基丙烯酸酯和三环癸烷二甲醇二甲基丙烯酸酯,化合物(B)是由环氧乙烷改性的苯酚丙烯酸酯,异硬脂基 丙烯酸酯,环氧乙烷改性的三羟甲基丙烷三甲基丙烯酸酯,硬脂基 乙基丙烯酸酯和甘油二甲基丙烯酸酯。