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1. 发明申请

WO1998007675A1 PROCESS FOR THE PRODUCTION OF 2-BUTYL-2-ETHYL-1,3-PROPANEDIOL 审中-公开
标题翻译： 2-丁基-2-乙基-1,3-丙二醇的制备方法
公开(公告)号：WO1998007675A1
公开(公告)日：1998-02-26
申请号：PCT/FI1997000484
申请日：1997-08-19
申请人： NESTE OY , LINDFORS, Lars-Peter , HEINOLA, Kalevi , KULMALA, Kari , HAKANPÄÄ-LAITINEN, Hannele , RINTALA, Lea , PARKKINEN, Lea , LEHTINEN, Vesa-Matti
发明人： NESTE OY
IPC分类号： C07C31/20
CPC分类号： C07C29/38 , C07C31/20
摘要： the present invention concerns a process for producing 2-butyl-2-ethyl-1,3-propanediol. According to the process, a reaction mixture is formed, containing 2-ethylhexanal and formaldehyde, into which a hydroxide compound is fed, whereby 2-ethylhexanal and formaldehyde are reacted to produce 2-butyl-2-ethyl-1,3-propanediol. According to the invention, the hydroxide compound is incrementally fed into the reaction mixture. Preferably, the hydroxide compound is fed at least at two input rates, in such a way that the heat production of the reaction between 2-ethylhexanal and formaldehyde immediately after each increase of the input rate of the hydroxide compound is at least almost the same. The invention allows for the production of BEPD in a controlled and safe manner, with excellent yields.
摘要翻译：本发明涉及一种生产2-丁基-2-乙基-1,3-丙二醇的方法。根据该方法，形成含有2-乙基己醛和甲醛的反应混合物，其中加入氢氧化物，由此使2-乙基己醛和甲醛反应，生成2-丁基-2-乙基-1,3-丙二醇。根据本发明，向反应混合物中逐渐加入氢氧化物。优选地，氢氧化物化合物至少以两种输入速率进料，使得在每次增加氢氧化物化合物的输入速率之后立即在2-乙基己醛和甲醛之间的反应的热产生至少几乎相同。本发明允许以控制和安全的方式生产BEPD，具有优异的产率。

2. 发明申请

WO1997041088A1 PROCESS FOR PREPARING MONOESTERS OF 1,3-DIOLS 审中-公开
标题翻译：制备1,3-二醇单体的方法
公开(公告)号：WO1997041088A1
公开(公告)日：1997-11-06
申请号：PCT/FI1997000263
申请日：1997-04-29
申请人： NESTE OY , HEINOLA, Kalevi , KARVINEN, Esko , LINDFORS, Lars-Peter , KULMALA, Kari , HAKANPÄÄ-LAITINEN, Hannele , RINTALA, Lea , KUISMA, Eija , PARKKINEN, Lea
发明人： NESTE OY
IPC分类号： C07C67/44
CPC分类号： C07C67/44 , C07C69/003 , C07C69/28
摘要： The invention relates to a process for preparing monoesters of 1,3-diols. The invention relates to a process for preparing in particular 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate, according to which process isobutyraldehyde is brought into contact with an alkalihydroxide catalyst. The alkali hydroxide catalyst used according to the invention is a dilute solution of lithium hydroxide, in which the concentration of lithium hydroxide is about 1 - 12 % by weight. An aqueous solution containing about 2 - 10 % by weight of sodium hydroxide and about 0.1 - 6 % by weight of lithium hydroxide, is used preferably. This enhances selectivity with respect to 1,3-diols, with an increased conversion of the aldehyde into a monoester and a subsequent decrease in recirculation volumes in the preparation process.
摘要翻译：本发明涉及一种制备1,3-二醇单酯的方法。本发明涉及一种制备特别是2,2,4-三甲基-1,3-戊二醇单异丁酸酯的方法，根据该方法使异丁醛与碱金属氢氧化物催化剂接触。根据本发明使用的碱金属氢氧化物催化剂是氢氧化锂的稀释溶液，其中氢氧化锂的浓度为约1至12重量％。优选使用含有约2-10重量％氢氧化钠和约0.1-6重量％氢氧化锂的水溶液。这提高了对1,3-二醇的选择性，醛的转化率增加到单酯中，随后在制备过程中再循环量减少。

3. 发明申请

WO1998007676A1 PROCESS FOR SEPARATING 2-BUTYL-2-ETHYL-1,3-PROPANEDIOL FROM REACTION MIXTURES CONTAINING THE SAME 审中-公开
标题翻译：从含有它的反应混合物分离2-丁基-2-乙基-1,3-丙二醇的方法
公开(公告)号：WO1998007676A1
公开(公告)日：1998-02-26
申请号：PCT/FI1997000485
申请日：1997-08-19
申请人： NESTE OY , HOLMA, Hannu , HAAKANA, Rami , HEINOLA, Kalevi , KARVINEN, Esko , RINTALA, Lea , PARKKINEN, Lea , KUISMA, Eija
发明人： NESTE OY
IPC分类号： C07C31/20
CPC分类号： C07C29/80 , C07C29/38 , C07C29/86 , C12C11/02 , C07C31/205
摘要： The invention concerns a process for separating 2-butyl-2-ethyl-1,3-propanediol from a reaction blend, which has an organic phase containing BEPD, and an aqueous phase, and which has been produced by allowing 2-ethylhexanal and formaldehyde to react in a reactor in the presence of a hydroxide compound, whereby the hydroxide compound has been fed into the reactor principally during the whole time of reaction. A characterizing feature of the invention comprises allowing the reaction blend to phase into an organic phase and an aqueous phase and removing the aqueous phase immediately from the reactor, i.e. within ca. 0.1 minute to 2 hours from the completion of the input of the hydroxide compound. The organic phase is washed with an aqueous solution to remove impurities and BEPD is recovered by submitting the water washed organic phase to distillation. By the invention the number of process steps is reduced, and the raw material costs decrease, because the usual addition of sulphuric acid is not needed.
摘要翻译：本发明涉及从具有含有BEPD的有机相和水相的反应共混物中分离出2-丁基-2-乙基-1,3-丙二醇的方法，并且其通过使2-乙基己醛和甲醛在氢氧化物存在下在反应器中反应，由此氢化物化合物主要在反应的整个时间内进料到反应器中。本发明的特征特征包括使反应混合物相进入有机相和水相，并立即从反应器中除去水相，即在约从氢氧化合物的输入完成0.1分钟至2小时。有机相用水溶液洗涤以除去杂质，通过将水洗的有机相送入蒸馏来回收BEPD。通过本发明，减少了工艺步骤的数量，并且原料成本降低，因为不需要通常加入硫酸。

4. 发明申请

WO1992014724A1 PROCESS FOR PREPARING THIOPHENE AND ITS DERIVATIVES 审中-公开
标题翻译：制备噻吩及其衍生物的方法
公开(公告)号：WO1992014724A1
公开(公告)日：1992-09-03
申请号：PCT/FI1992000046
申请日：1992-02-20
申请人： NESTE OY , HEINOLA, Kalevi , HORMI, Osmo , NYHOLM, Per , NÄSMAN, Jan , TAMMI, Anna-Liisa , KOSKIMIES, Salme , TUOMINEN, Simo , LAHTINEN, Leila , KARJALAINEN, Sari , MONONEN, Pirjo , PARKKINEN, Lea
发明人： NESTE OY
IPC分类号： C07D333/08
CPC分类号： C07D333/08
摘要： In the process according to the invention for the preparation of thiophene and particularly a thiophene, the non-sulphur bound carbon of which is substituted, the product is produced by treating succinic anhydride or especially substituted succinic anhydride with a sulphur compound. The sulphur compound is preferably a sulphur compound, which contains phosphorus, such as phosphorus pentasulphide. The stated treatment with a sulphur compound forms according to one embodiment the end stage of the process, in which 1-alkene is attached to maleic anhydride to give an 1-alkenyl-succinic anhydride, the 1-alkenylsuccinic anhydride is hydrogenated catalytically to produce an alkylsuccinic anhydride and the alkylsuccinic anhydride is treated with the above-mentioned sulphur compound to give a thiophene, the non-sulphur bound carbon of which, e.g. 3-carbon, is substituted.
摘要翻译：在根据本发明的用于制备噻吩，特别是噻吩的方法中，其非硫结合的碳被取代，该产物通过用硫化合物处理琥珀酸酐或特别是取代的琥珀酸酐来制备。硫化合物优选为含有磷的硫化合物，例如五硫化二磷。根据一个实施方案，根据一个实施方案，所述的硫化合物的处理形成了该方法的最终阶段，其中1-烯烃连接到马来酸酐以得到1-烯基 - 琥珀酸酐，1-烯基琥珀酸酐被氢化为催化剂，以产生烷基琥珀酸酐和烷基琥珀酸酐用上述硫化合物处理，得到噻吩，其非硫结合的碳例如 3-碳，被取代。

5. 发明申请

WO1998024752A1 PROCESS FOR PREPARING 2,2,4-TRIMETHYL-1,3-PENTANEDIOL ISOBUTYRATE 审中-公开
标题翻译：制备2,2,4-三甲基-1,3-苯二甲酸异丁酯的方法
公开(公告)号：WO1998024752A1
公开(公告)日：1998-06-11
申请号：PCT/FI1997000754
申请日：1997-12-03
申请人： NESTE OY , HEINOLA, Kalevi , KULMALA, Kari , LINDFORS, Lars-Peter , HAKANPÄÄ-LAITINEN, Hannele , RINTALA, Lea , PARKKINEN, Lea , LEHTINEN, Vesa-Matti
发明人： NESTE OY
IPC分类号： C07C69/28
CPC分类号： C07C67/44 , C07C69/28 , C07C69/003
摘要： A two-step process for preparing 2,2,4-trimethyl-1,3-pentanediol isobutyrate. The process comprises subjecting isobutyraldehyde to a first reaction in the presence of an alkali metal hydroxide to produce a first reaction mixture containing 2,6-diisopropyl-5,5-dimethyl-1,3-dioxan-4-ol, and then subjecting the reaction mixture to a second reaction in the presence of an alkaline earth metal hydroxide to produce a second reaction mixture containing 2,2,4-trimethyl-1,3-pentanediol isobutyrate. The 2,2,4-trimethyl-1,3-pentanediol isobutyrate is recovered from the second reaction mixture and purified. By means of the invention, the desired product can be obtained at high yields and with a minimum of side products.
摘要翻译：制备2,2,4-三甲基-1,3-戊二醇异丁酸酯的两步法。该方法包括在碱金属氢氧化物存在下使异丁醛进行第一反应，生成含有2,6-二异丙基-5,5-二甲基-1,3-二恶烷-4-醇的第一反应混合物，反应混合物在碱土金属氢氧化物的存在下进行第二反应以产生含有2,2,4-三甲基-1,3-戊二醇异丁酸酯的第二反应混合物。从第二反应混合物回收异丁酸2,2,4-三甲基-1,3-戊二醇并纯化。通过本发明，可以以高产率和最少的副产物获得所需的产物。

6. 发明申请

WO1995007254A1 PROCESS FOR THE PREPARATION OF 2-ETHYL-1,3-HEXANE DIOL 审中-公开
标题翻译：制备2-乙基-1,3-庚二醇的方法
公开(公告)号：WO1995007254A1
公开(公告)日：1995-03-16
申请号：PCT/FI1994000387
申请日：1994-09-02
申请人： NESTE OY , KULMALA, Kari , ANKNER, Kjell , RINTALA, Lea , LAHTINEN, Leila , HEINOLA, Kalevi
发明人： NESTE OY
IPC分类号： C07C31/20
CPC分类号： C07C31/20 , C07C29/141 , C07C29/38 , C07C45/72 , C07C47/19 , C07C31/12
摘要： The invention relates to a process for the preparation of 2-ethyl-1,3-hexane diol from n-butyraldehyde by aldol condensation in the presence of an alkali metal hydroxide or alkali earth metal hydroxide catalyst. To promote the reaction and to improve its controllability, a neutral phase-transfer catalyst is additionally used in the process according to the invention. 2-Ethyl-1,3-hexane diol is used in insecticides and, for example, in the preparation of polyesters.
摘要翻译：本发明涉及在碱金属氢氧化物或碱土金属氢氧化物催化剂存在下，通过醛醇缩合从正丁醛制备2-乙基-1,3-己二醇的方法。为了促进反应并提高其可控性，在本发明的方法中另外使用中性相转移催化剂。 2-乙基-1,3-己二醇用于杀虫剂，例如用于制备聚酯。

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