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    • 7. 发明申请
    • ACRYLAMIDE DERIVATIVES AS CHROMOPHORIC PHOTOCROSSLINKING COMPOUND
    • 丙烯酰胺衍生物作为染料光致交联化合物
    • WO1997005101A1
    • 1997-02-13
    • PCT/US1996012355
    • 1996-07-26
    • MINNESOTA MINING AND MANUFACTURING COMPANYHEILMANN, Steven, M.BABU, Gaddam, N.KREPSKI, Larry, R.SMITH, Howell, K., IIMICKUS, Daniel, E.
    • MINNESOTA MINING AND MANUFACTURING COMPANY
    • C07C233/49
    • C07C233/49C07C2603/18C07C2603/24C07C2603/32C07D311/30C08F220/58
    • A photoactive compound of general formula (I) that is the reaction of an alkenyl azalactone compound and a nucleophilic aromatic ketone is described. Mer units derived from this compound can be used, for example, to crosslink via a hydrogen abstracting mechanism acrylic polymers in which they are incorporated. In said formula (I) wherein R is H or a C1 to C3 alkyl group; R and R are independently H, an alkyl group having 1 to 14 carbon atoms, a cycloalkyl group having 3 to 14 carbon atoms, an aryl group having 5 to 12 ring atoms, an arenyl group having 6 to 26 carbon atoms and 0 to 3 S, N, and nonperoxidic O heteroatoms, or R and R taken together with the carbon to which they are attached form a carbocyclic ring containing 4 to 12 ring atoms; n is 0 or 1; A is XCR R , [X(CH2CHR )]m ou X-[(CH2CHR Y)]m where X est O, S, NH, or NR ; Y is O, C(O)O, OC(O)NH, OC(O)O, or NHC(O)O; R and R are independently H, a C1 to C6 alkyl group, or an aryl group; and m is 0 or 1; and Z is a moiety derived from an acetophenone, benzophenone, anthraquinone, 9-fluorenone, anthrone, xanthone, thioxanthone, acridone, dibenzosuberone, benzil, or chromone.
    • 描述了作为烯基吖内酯化合物与亲核性芳族酮的反应的通式(I)的光活性化合物。 可以使用衍生自该化合物的Mer单元,例如通过氢萃取机理交联其中引入它们的丙烯酸聚合物。 在其中R 1为H或C 1至C 3烷基的所述式(I)中; R 2和R 3独立地为H,具有1至14个碳原子的烷基,具有3至14个碳原子的环烷基,具有5至12个环原子的芳基,具有6至26个的芳基 碳原子和0至3个S,N和非过氧O的杂原子,或R 2和R 3与它们所连接的碳一起形成含有4-12个环原子的碳环; n为0或1; A是XCR 4 R 5,[X(CH 2 CHR 1)] m - X - [(CH 2 CHR 1 Y)] m其中X est O,S,NH或NR 4; Y是O,C(O)O,OC(O)NH,OC(O)O或NHC(O)O; R 4和R 5独立地为H,C 1至C 6烷基或芳基; m为0或1; Z是衍生自苯乙酮,二苯甲酮,蒽醌,9-芴酮,蒽酮,呫吨酮,噻吨酮,吖啶酮,二苯并二酮,苯偶酰或色酮的部分。