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1. 发明申请

WO2013148722A1 CONTROL OF LIVING RADICAL POLYMERIZATION BY LIGHT 审中-公开
标题翻译：通过光线控制生活光谱聚合
公开(公告)号：WO2013148722A1
公开(公告)日：2013-10-03
申请号：PCT/US2013/033933
申请日：2013-03-26
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA , HAWKER, Craig J. , FORS, Brett P.
发明人： HAWKER, Craig J. , FORS, Brett P.
IPC分类号： C08F2/48
CPC分类号： C08F2/48 , C08F2438/00
摘要： Living radical polymerization processes have emerged as one of the most powerful synthetic strategies for the preparation of a wide variety of functional materials. The ability to regulate these processes with an external stimulus dramatically increases their utility and further allows living radical polymerization processes to provide new macromolecular structures and facilitate an even greater range of applications. This application discloses a living radical polymerization procedure that provides control over chain growth through mediation by visible light. Embodiments of the invention show an unprecedented activation and deactivation of polymerization reactions by visible light as well as an excellent control over the molecular weight and molecular weight distributions of polymers formed by this method.
摘要翻译：活性自由基聚合方法已经成为制备各种功能材料的最强大的合成策略之一。通过外部刺激调节这些过程的能力大大提高了其用途，并且进一步允许活性自由基聚合方法提供新的大分子结构并促进更大范围的应用。本申请公开了一种活性自由基聚合方法，其通过可见光的调解提供对链增长的控制。本发明的实施方案通过可见光显示出前所未有的聚合反应的活化和失活，以及通过该方法形成的聚合物的分子量和分子量分布的优异控制。

2. 发明申请

WO2009151834A3 SUPRAMOLECULAR BLOCK COPOLYMER COMPOSITIONS FOR SUB-MICRON LITHOGRAPHY 审中-公开
标题翻译：用于亚微米层析的分子嵌段共聚物组合物
公开(公告)号：WO2009151834A3
公开(公告)日：2010-02-25
申请号：PCT/US2009043113
申请日：2009-05-07
申请人： UNIV CALIFORNIA , HAWKER CRAIG J , TANG CHUANBING , KRAMER EDWARD J , FREDERICKSON GLENN
发明人： HAWKER CRAIG J , TANG CHUANBING , KRAMER EDWARD J , FREDERICKSON GLENN
IPC分类号： C08L33/12 , C08L25/08 , C08L25/18 , C08L35/08 , C08L71/02 , H01L21/027
CPC分类号： C08L53/00 , B82Y10/00 , B82Y40/00 , C08F293/005 , C08L2205/02 , G03F7/0002 , C08L2666/24 , C08L2666/04
摘要： A polymeric composition and method of preparation for application in sub-micron lithography, comprising a blend of A-B and B'-C block, random, branched, or graft copolymers, where: (i) the B and B' blocks or grafts have attractive supramolecular interactions characterized by a negative Flory-Huggins parameter; (ii) the composition exhibits a microphase-separated, three-domain morphology with A, C, and B/B' domains comprised largely of A blocks or grafts, C blocks or grafts, and a mixture of B and B' blocks or grafts, respectively. Long-range ordering of nanometer-scale domain features has been achieved in thin films of such supramolecular polymer blends, while avoiding macrophase separation. The strategy offers a diversity of morphologies for sub-micron lithographic applications in tandem with ease of chemical synthesis.
摘要翻译：一种制备用于亚微米光刻的聚合物组合物和方法，其包含AB和B'-C嵌段，无规，支链或接枝共聚物的共混物，其中：（i）B和B'嵌段或接枝物具有吸引力超分子相互作用以Flory-Huggins阴性参数为特征; （ii）组合物表现出微相分离的三结构域形态，其中主要由A嵌段或接枝物，C嵌段或接枝物组成的A，C和B / B'结构域以及B和B'嵌段或接枝物的混合物，分别。在这种超分子聚合物共混物的薄膜中已经实现了纳米尺度领域特征的长期排序，同时避免了巨噬细胞分离。该策略为亚微米光刻应用提供了多种形态，并且易于化学合成。

3. 发明申请

WO2012083253A1 POLYMER ELECTROLYTES BASED ON POLY(GLYCIDYL ETHER)S 审中-公开
标题翻译：基于聚（乙二醇醚）的聚合物电解质
公开(公告)号：WO2012083253A1
公开(公告)日：2012-06-21
申请号：PCT/US2011/065647
申请日：2011-12-16
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA , LYND, Nathaniel A. , FREDRICKSON, Glenn H. , HAWKER, Craig J. , KRAMER, Edward J. , BARTEAU, Kate
发明人： LYND, Nathaniel A. , FREDRICKSON, Glenn H. , HAWKER, Craig J. , KRAMER, Edward J. , BARTEAU, Kate
IPC分类号： C08L63/00
CPC分类号： C08L71/00 , C08G2650/56 , Y10T29/49002
摘要： A polymer electrolyte composition including a metal salt and at least one polymer comprising a poly(glycidyl ether), where the at least one polymer is amorphous at ambient temperature. The poly(glycidyl ether) polymer can be a blend of poly(glycidyl ether) polymers, can be a poly(glycidyl ether) polymer blended with a mechanically strong solid polymer, and can be a block of a block copolymer that also includes a polymer block forming a mechanically strong solid polymer.
摘要翻译：一种包含金属盐和至少一种包含聚（缩水甘油醚）的聚合物的聚合物电解质组合物，其中所述至少一种聚合物在环境温度下是无定形的。聚（缩水甘油醚）聚合物可以是聚（缩水甘油醚）聚合物的共混物，可以是与机械强固体聚合物共混的聚（缩水甘油醚）聚合物，并且可以是嵌段共聚物的嵌段，其也包括聚合物块形成机械强固体聚合物。

4. 发明申请

WO2008054552A2 METHOD FOR PRODUCING BI-CONTINUOUS AND HIGH INTERNAL PHASE NANOSTRUCTURES 审中-公开
标题翻译：用于生产双连续和高内相的纳米结构的方法
公开(公告)号：WO2008054552A2
公开(公告)日：2008-05-08
申请号：PCT/US2007/013612
申请日：2007-06-08
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA , FREDRICKSON, Glenn, H. , KRAMER, Edward, J. , KIM, Bumjoon , HAWKER, Craig, J.
发明人： FREDRICKSON, Glenn, H. , KRAMER, Edward, J. , KIM, Bumjoon , HAWKER, Craig, J.
IPC分类号： H01L29/12
CPC分类号： C08J3/005 , C08K5/0008 , C08K9/08
摘要： A process for producing bi-continuous morphologies in polymer melts and solids, wherein two distinct domains or phases percolate and macroscopically connect throughout the composition. The process proceeds by simply mixing the components in a common solvent and casting a film by slow removal of the solvent. Bulk materials can be produced by mixing the components in an extruder, compounder, or other specialized equipment for processing molten polymers, and forming into a pellet, fiber, film, sheet, or molded part. The invention allows the production of materials with unique or unusual combinations of transparency, high electronic or ionic conductivity, high vapor transport rates, and/or high absorption rates of moisture or vapors. Particles used in the present invention are 5-1 Onm to yield a scale of the bi- continuous structures of 10-50nm. Tjhe materials can be produced in bulk form, or in films 1-100 microns thick.
摘要翻译：在聚合物熔体和固体中生产双连续形态的方法，其中两个不同的结构域或相渗透并且宏观地连接整个组合物。该方法通过简单地将组分混合在普通溶剂中并通过缓慢除去溶剂来浇铸膜来进行。散装材料可以通过在挤出机，混炼机或其他用于加工熔融聚合物的专用设备中混合组分并形成颗粒，纤维，薄膜，片材或模制件来制备。本发明允许生产具有透明度，高电子或离子电导率，高蒸气传输速率和/或高吸收率的水分或蒸汽的独特或不寻常的组合的材料。本发明中使用的颗粒为5-1Om，以产生10-50nm的双连续结构的尺度。 Tjhe材料可以批量生产，或在1-100微米厚的薄膜中生产。

5. 发明申请

WO2009151834A2 SUPRAMOLECULAR BLOCK COPOLYMER COMPOSITIONS FOR SUB-MICRON LITHOGRAPHY 审中-公开
标题翻译：用于亚微米层析的分子嵌段共聚物组合物
公开(公告)号：WO2009151834A2
公开(公告)日：2009-12-17
申请号：PCT/US2009/043113
申请日：2009-05-07
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA , HAWKER, Craig, J. , TANG, Chuanbing , KRAMER, Edward, J. , FREDERICKSON, Glenn
发明人： HAWKER, Craig, J. , TANG, Chuanbing , KRAMER, Edward, J. , FREDERICKSON, Glenn
IPC分类号： C08L33/12 , C08L25/18 , C08L25/08 , C08L71/02 , C08L35/08 , H01L21/027
CPC分类号： C08L53/00 , B82Y10/00 , B82Y40/00 , C08F293/005 , C08L2205/02 , G03F7/0002 , C08L2666/24 , C08L2666/04
摘要： A polymeric composition and method of preparation for application in sub-micron lithography, comprising a blend of A-B and B'-C block, random, branched, or graft copolymers, where: (i) the B and B' blocks or grafts have attractive supramolecular interactions characterized by a negative Flory-Huggins parameter; (ii) the composition exhibits a microphase-separated, three-domain morphology with A, C, and B/B' domains comprised largely of A blocks or grafts, C blocks or grafts, and a mixture of B and B' blocks or grafts, respectively. Long-range ordering of nanometer-scale domain features has been achieved in thin films of such supramolecular polymer blends, while avoiding macrophase separation. The strategy offers a diversity of morphologies for sub-micron lithographic applications in tandem with ease of chemical synthesis.
摘要翻译：一种制备用于亚微米光刻的聚合物组合物和方法，其包含AB和B'-C嵌段，无规，支链或接枝共聚物的共混物，其中：（i）B和B'嵌段或接枝物具有吸引力超分子相互作用以Flory-Huggins阴性参数为特征; （ii）组合物表现出微相分离的三结构域形态，其中主要由A嵌段或接枝物，C嵌段或接枝物组成的A，C和B / B'结构域以及B和B'嵌段或接枝物的混合物，分别。在这种超分子聚合物共混物的薄膜中已经实现了纳米尺度领域特征的长期排序，同时避免了巨噬细胞分离。该策略为亚微米光刻应用提供了多种形态，并且易于化学合成。

6. 发明申请

WO2009148712A1 HIGHLY EFFICIENT AGENTS FOR DISPERSION OF NANOPARTICLES IN MATRIX MATERIALS 审中-公开
标题翻译：在基质材料中分散纳米颗粒的高效药剂
公开(公告)号：WO2009148712A1
公开(公告)日：2009-12-10
申请号：PCT/US2009/041136
申请日：2009-04-20
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA , MITSUBISHI CHEMICAL CORPORATION , HAWKER, Craig, J. , VESTBERG, Robert , UENO, Nobuhiko
发明人： HAWKER, Craig, J. , VESTBERG, Robert , UENO, Nobuhiko
IPC分类号： C08G85/00
CPC分类号： C08L101/005 , C08G83/003
摘要： Dendritic macroinitiator compositions are provided comprising a compound of the general formula, Fx-[G-n]-l, where F is the chain end functional group of the dendrimer, x is the number of chain end functional groups, G is the dendrimer, n is the generation number of the dendrimer, and I is the initiating group. Hybrid dendritic-linear copolymers made from these macroinitators can act as highly efficient dispersing agents for a range of nanoparticles in matrix materials.
摘要翻译：提供树枝状大分子引发剂组合物，其包含通式为Fx- [Gn] -1的化合物，其中F是树枝状聚合物的链端官能团，x是链端官能团的数目，G是树枝状聚合物，n是树枝状大分子的产生数，I是起始组。由这些大型化合物制成的混合树枝状 - 线性共聚物可以作为基质材料中一系列纳米粒子的高效分散剂。

7. 发明申请

WO2008054552A3 METHOD FOR PRODUCING BI-CONTINUOUS AND HIGH INTERNAL PHASE NANOSTRUCTURES 审中-公开
标题翻译：用于生产双连续和高内相的纳米结构的方法
公开(公告)号：WO2008054552A3
公开(公告)日：2009-04-09
申请号：PCT/US2007013612
申请日：2007-06-08
申请人： UNIV CALIFORNIA , FREDRICKSON GLENN H , KRAMER EDWARD J , KIM BUMJOON , HAWKER CRAIG J
发明人： FREDRICKSON GLENN H , KRAMER EDWARD J , KIM BUMJOON , HAWKER CRAIG J
IPC分类号： B23B5/16 , B23B1/00
CPC分类号： C08J3/005 , C08K5/0008 , C08K9/08
摘要： A process for producing bi-continuous morphologies in polymer melts and solids, wherein two distinct domains or phases percolate and macroscopically connect throughout the composition. The process proceeds by simply mixing the components in a common solvent and casting a film by slow removal of the solvent. Bulk materials can be produced by mixing the components in an extruder, compounder, or other specialized equipment for processing molten polymers, and forming into a pellet, fiber, film, sheet, or molded part. The invention allows the production of materials with unique or unusual combinations of transparency, high electronic or ionic conductivity, high vapor transport rates, and/or high absorption rates of moisture or vapors. Particles used in the present invention are 5-1 Onm to yield a scale of the bi- continuous structures of 10-50nm. Tjhe materials can be produced in bulk form, or in films 1-100 microns thick.
摘要翻译：一种在聚合物熔体和固体中生产双连续形态的方法，其中两个不同的结构域或相渗透并且宏观地连接整个组合物。该方法通过简单地将组分混合在普通溶剂中并通过缓慢除去溶剂来浇铸膜来进行。散装材料可以通过在挤出机，混炼机或其他用于加工熔融聚合物的专用设备中混合组分并形成颗粒，纤维，薄膜，片材或模制件来制备。本发明允许生产具有透明度，高电子或离子电导率，高蒸气传输速率和/或高吸收率的水分或蒸汽的独特或不寻常的组合的材料。本发明中使用的颗粒为5-1Om，以产生10-50nm的双连续结构的尺度。 Tjhe材料可以批量生产，或在1-100微米厚的薄膜中生产。

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