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1. 发明申请

US20100108994A1 ELECTROLUMINESCENT METAL COMPLEXES WITH BENZOTRIAZOLES 有权
标题翻译：电致发光金属复合物与苯甲酸酯
公开(公告)号：US20100108994A1
公开(公告)日：2010-05-06
申请号：US12527437
申请日：2008-02-13
申请人： Thomas Schäfer , Peter Murer , Gisèle Baudin , Manuela Kocher , François Maike , Stephan Allenbach , Rosemarie Sift , Beat Schmidhalter
发明人： Thomas Schäfer , Peter Murer , Gisèle Baudin , Manuela Kocher , François Maike , Stephan Allenbach , Rosemarie Sift , Beat Schmidhalter
IPC分类号： H01L51/00 , C07F17/00
CPC分类号： H01L51/0085 , C07F15/0033 , C07F15/0086 , C09K11/06 , C09K2211/1059 , C09K2211/185 , H01L51/006 , H01L51/0081 , H01L51/0087 , H01L51/5016
摘要： This invention relates to electroluminescent metal complexes with benzotriazoles of the formula (I), a process for their preparation, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays, and as catalysts.
摘要翻译：本发明涉及具有式（I）的苯并三唑的电致发光金属络合物，其制备方法，包含金属络合物的电子器件及其在电子器件中的用途，特别是有机发光二极管（OLED），作为氧敏感指示剂，如生物测定中的磷光指标，以及催化剂。

2. 发明授权

US07538104B2 Photoactivable nitrogen bases 有权
标题翻译：可光化氮碱
公开(公告)号：US07538104B2
公开(公告)日：2009-05-26
申请号：US10491813
申请日：2002-10-08
申请人： Gisèle Baudin , Kurt Dietliker , Tunja Jung
发明人： Gisèle Baudin , Kurt Dietliker , Tunja Jung
IPC分类号： C07D487/04 , C07D239/70
CPC分类号： C07D487/04 , B33Y70/00 , G03F7/0045 , G03F7/0295 , G03F7/031
摘要： Compounds of the formula I R7″N—R6 RS—C,N—R4 H C, R′/I R, 3 R 2 (I) in which R, is an aromatic or heteroaromatic radical which is capable of absorbing light in the wave-length range from 200 nm to 650 nm and which is unsubstituted or substituted one or more times by C,—C,8alkyl, C2-C,ealkenyl, C2-C,8alkynyl, C,—C,ehaloalkyl, NO2, NR,OR, CN, OR,2, SR,2, C(O)R,3, C(O)OR,4, halogen or a radical of the formula II R˜—N′ R6 1 R5-C,N.R4 H I C—R3 I R2 (II) and which on absorption brings about a photoelimination which leads to the generation of an amidine group, R2 and R3 independently of one another are hydrogen, C,—C,ealkyl or phenyl which is unsubstituted or is substituted one or more times by C,—C,8alkyl, CN, OR,2, SR,2, halogen or C,—C,ehaloalkyl; R5 is C,—C,ealkyl or NR8R9; R4, R6, R, R8, R9, R,o and R independently of one another are hydrogen or C,—C,8alkyl; or R4 and R6 together form a C2-C,2alkylene bridge which is unsubstituted or is substituted by one or more C1-C4alkyl radicals; or R5 and R, independently of R4 and R6, together form a C2-C,2alkylene bridge which is unsubstituted or is substituted by one or more C1-C4alkyl radicals; or, if R5 is a radical NR8R9, R, and R9 together form a C2-C,2alkylene bridge which is unsubstituted or is substituted by one or more C1-C4alkyl radicals; and R,2, R,3 and R,4 independently of one another are hydrogen or C,—C,ealkyl; are suitable as photoinitiators for compounds which react under base catalysis.
摘要翻译：式I R7''N-R6RS-C，N-R4HC，R'/ IR，R3R（Ⅰ）的化合物，其中R 1是能够吸收波中的光的芳族或杂芳族基团长度范围为200nm至650nm，未被取代或被C 1 -C 8烷基，C 2 -C 6烯基，C 2 -C 8炔基，C 1 -C 8卤代烷基，NO 2，NR， OR，CN，OR，2，SR，2，C（O）R，3，C（O）OR 4，卤素或式II的基团R 1 -N'R 6 R 5-C， HI C-R3 I R2（II），其在吸收时产生导致脒基的产生的光电离，R2和R3彼此独立地是氢，C 1 -C 6烷基或未被取代的苯基，或者是被C 1 -C 8烷基，CN，OR，2，SR 2，卤素或C 1 -C 6卤代烷基取代一次或多次; R5是C 1 -C 6烷基或NR 8 R 9; R4，R6，R，R8，R9，R，o和R彼此独立地是氢或C 1 -C 8烷基; 或R4和R6一起形成未被取代或被一个或多个C 1 -C 4烷基取代的C 2 -C 2亚烷基桥; 或者R 5和R 4独立于R 4和R 6一起形成未被取代或被一个或多个C 1 -C 4烷基取代的C 2 -C 2亚烷基桥; 或者如果R 5是NR 8 R 9基团，则R和R 9一起形成未被取代或被一个或多个C 1 -C 4烷基取代的C 2 -C 2亚烷基桥; 和R，2，R 3和R 4彼此独立地是氢或C 1 -C 6烷基; 适用于在碱催化下反应的化合物的光引发剂。

3. 发明授权

US07105582B2 Surface-active siloxane photoinitiators 有权
标题翻译：表面活性硅氧烷光引发剂
公开(公告)号：US07105582B2
公开(公告)日：2006-09-12
申请号：US10503320
申请日：2003-01-28
申请人： Gisèle Baudin , Tunja Jung
发明人： Gisèle Baudin , Tunja Jung
IPC分类号： C08F2/50
CPC分类号： C08F2/50 , B33Y70/00
摘要： Compounds of the formula I are suitable photoinitiators which accumulates at the surface of the formulation in which R is for example phenyl and A is a surface-active radical of the formula III Y is a divalent group C3–C12cycloalkylene, C6–C12bicycloalkylene; C1–C6alkylenen-C3–C12cycloalkylene, C1–C6alkylene- C6–C12bicycloalkylene or C1–C10alkylene interrupted by one or more non-consecutive C3–C12cycloalkylene, —U—C3–C12cycloalkylene, C6–C12bicycloalkylene or —U—C6–C12bicycloalkylene; C1–C10alkylene interrupted by one or more non-consecutive O and C3–C12cycloalkylene, —U—C3–C12cycloalkylene, C6–C12bicycloalkylene and/or —U—C6–C12bicycloalkylene; U is U′ or U″ U′ is —(CH2)aCOO—; U″ is —Si(CH3)(CH3)— or —(CH2)a—Si(CH3)(CH3)—, a is a number from 1 to 10; b is a number from 0 to 10; with the proviso that they are, however, at least 1 if the methylene group in question is between two oxygen atoms.
摘要翻译：式I的化合物是在制剂的表面积聚的适合的光引发剂，其中R是例如苯基，A是式III的表面活性基团Y是二价基团C 3 - C 12亚环烷基，C 6 -C 12亚环烷基; C 1 -C 6亚烷基-C 3 -C 12亚环烷基，C 1〜 C 1 -C 6亚烷基-C 6亚烷基或C 1 -C 10亚烷基-C 12 - 由一个或多个非连续C 3 -C 12亚环烷基，-UC 3 -C 12间隔的亚烷基亚烷基，亚烷基，C 6 -C 12亚环烷基或-CUC 6 -C 12二环亚烷基; 被一个或多个不连续的O和C 3 -C 12亚环烷基间隔的C 1 -C 10亚烷基，-CUC 3 -C 12亚环烷基，C 6 -C 12二环亚烷基和/或-UC _{6 -C 12二环亚烷基; U是U'或U“U'是 - （CH 2）n CO 2 - U“是-Si（CH 3）3（CH 3） - 或 - （CH 2 CH 2）a - -Si（CH 3 3）（CH 3） - ，a为1至10的数; b是从0到10的数字; 但是，如果所讨论的亚甲基在两个氧原子之间，则它们至少为1。}

4. 发明授权

US07005281B2 Enzymatic process for preparing organosilicon group containing photoinitiators 有权
公开(公告)号：US07005281B2
公开(公告)日：2006-02-28
申请号：US10506698
申请日：2003-02-25
申请人： Reinhold Öhrlein , Kai-Uwe Schöning , Gabriele Baisch , Jemima Schmidt , Gisèle Baudin , Tunja Jung
发明人： Reinhold Öhrlein , Kai-Uwe Schöning , Gabriele Baisch , Jemima Schmidt , Gisèle Baudin , Tunja Jung
IPC分类号： C12P7/62 , C12P7/26 , C12P13/02
CPC分类号： C07F7/0889 , C12P9/00
摘要： The invention relates to a process for preparing organosilicon group containing photoinitiators of the formula (I), wherein m is a number from 1 to 200; q is 0 or 1; A is IN-C(O)—O—CHR3—Y— or IN-C(O)—NH—CHR3—Y—; A′ is A or R1′; R1 and R1′, R2 and R2′ are C1–C18alkyl or phenyl, or —(O)q—SiR1R1′R2; R3 is hydrogen or C1–C6alkyl, Y is a divalent group selected from C1–C10alkeylene, C2–C10alkenylene or —(CH2)b—O—(CH2)a—; and b are each independently of the other a number of 1 to 6; IN is a photolabile functional moiety of the formula (II) or (III), wherein R4 is hydrogen or —C(O)—C(O)—OH or —C(O)—C(O)—OC1–C6alkyl and n is 1–3; R5 and R6 are C1–C12alkyl or together are cycloC5–C7alkyl; R7 is hydroxy, C1–C6alkoxy or morpholinyl; X is —(CH2)a—, —(CH2)b—O—(CH2)a— or —(CH2)b—O—CO—(CH2)a—; a and b are each independently of the other a number of 1 to 6; whereby the process is characterized in that a photolabile functional moiety containing a carboxy group (IN-COOH) or an alkoxycarbonyl group (IN-CO—OC1–C6alkyl) is reacted with a carbinol- or amino terminated organosilicon compound of the formula (IV), wherein m, R1 and R1′, R2 and R2′ are as defined above and B is —Y—CHR3—OH or —Y—CHR3—NH2; B′ is B or R1′, in the presence of an enzyme which catalyzes the esterification, transesterification or amidation reaction.

5. 发明授权

US06906113B2 Surface-active photoinitiators 失效
标题翻译：表面活性光引发剂
公开(公告)号：US06906113B2
公开(公告)日：2005-06-14
申请号：US10343617
申请日：2001-08-07
申请人： Gisèle Baudin , Tunja Jung
发明人： Gisèle Baudin , Tunja Jung
IPC分类号： C07C69/716 , C07C69/738 , C07F7/08 , C08F2/00 , C08F2/46 , C08F2/50 , C08L83/06 , C09D4/00 , C09D4/06 , C09D5/00 , C07D307/93
CPC分类号： C07C69/738 , B33Y70/00 , C07F7/0838 , C08F2/50 , Y10S522/905
摘要： Compounds of formula Ia, Ib and Ic, (Ic), in which R, R1 and R2 are e.g. phenyl, naphthyl, anthracyl, phenanthryl or a heterocyclic radical, are suitable as photoinitiators which accumulate at the surface of coatings.
摘要翻译：式Ia，Ib和Ic，（Ic）的化合物，其中R 1，R 1和R 2是例如。苯基，萘基，蒽基，菲基或杂环基，适合作为在涂层表面积聚的光引发剂。

6. 发明授权

US09362510B2 Electroluminescent metal complexes with benzotriazoles 有权
标题翻译：与苯并三唑的电致发光金属络合物
公开(公告)号：US09362510B2
公开(公告)日：2016-06-07
申请号：US12527437
申请日：2008-02-13
申请人： Thomas Schäfer , Peter Murer , Gisèle Baudin , Manuela Kocher , François Maike , Stephan Allenbach , Rosemarie Sift , Beat Schmidhalter
发明人： Thomas Schäfer , Peter Murer , Gisèle Baudin , Manuela Kocher , François Maike , Stephan Allenbach , Rosemarie Sift , Beat Schmidhalter
IPC分类号： H01L51/54 , C09K11/06 , H01L51/00 , C07F15/00 , H01L51/50
CPC分类号： H01L51/0085 , C07F15/0033 , C07F15/0086 , C09K11/06 , C09K2211/1059 , C09K2211/185 , H01L51/006 , H01L51/0081 , H01L51/0087 , H01L51/5016
摘要： This invention relates to electroluminescent metal complexes with benzotriazoles of the formula (I), a process for their preparation, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays, and as catalysts.
摘要翻译：本发明涉及具有式（I）的苯并三唑的电致发光金属络合物，其制备方法，包含金属络合物的电子器件及其在电子器件中的用途，特别是有机发光二极管（OLED），作为氧敏感指示剂，如生物测定中的磷光指标，以及催化剂。

7. 发明授权

US07001644B2 Surface-active photoinitiators 有权
标题翻译：表面活性光引发剂
公开(公告)号：US07001644B2
公开(公告)日：2006-02-21
申请号：US10450228
申请日：2001-12-06
申请人： Gisèle Baudin , Tunja Jung
发明人： Gisèle Baudin , Tunja Jung
IPC分类号： C08J3/24 , C08J3/28 , C08F2/46 , C08F2/50
CPC分类号： G03F7/031 , B33Y70/00 , C07C45/54 , C07C45/64 , C07C45/71 , C07C49/825 , C07C49/84 , C08F2/50 , Y10T428/12097 , Y10T428/12104
摘要： A process for the production of coatings with scratch-resistant durable surfaces that comprise as photoinitiator (B) in a photocurable formulation at least one surface-active photoinitiator, concentrated at the surface of the formulation, of formula (Ia) or (Ib), wherein Ra is a radical of formula (IIa), Rb is a radical of formula (IIb)), or Ra and Rb are naphthyl, anthracyl, phenanthryl or a heterocyclic radical each of which is unsubstituted or substituted; R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 are, for example, each independently of the others hydrogen; A-Y; C1–C12alkyl, halogen or phenyl; R11 and R12 are, for example, C1–C12 alkyl; X is —OR20 or —N(R21)(R22); R20 is, for example, hydrogen or C1–C4alkyl; R21 and R22 are, for example, hydrogen or C1–C12 alkyl; X1 is, for example, —O—; Y is, for example, a single bond or —O—; Y1 is, for example, a single bond; and A is, for example, C6–C30alkyl.
摘要翻译：一种用于生产具有抗划伤耐久表面的涂层的方法，其在光固化制剂中包含作为光引发剂（B）的至少一种表面活性光引发剂，其在制剂的表面浓缩，式（Ia）或（Ib），其中R a a是式（IIa）的基团，R b b是式（IIb）的基团）或R a a和R a b是萘基，蒽基，菲基或杂环基，其各自为未取代或取代的; R 1，R 2，R 3，R 4，R 5， R 6，R 7，R 8，R 9和R 10是，例如，各自独立地为氢; A-Y; C 1 -C 12烷基，卤素或苯基; R 11和R 12是例如C 1 -C 12烷基; X是-OR 20或-N（R 21）（R 22）; R 20是例如氢或C 1 -C 4烷基; R 21和R 22是例如氢或C 1 -C 12烷基; X 1是例如-O-; Y是例如单键或-O-; Y 1是例如单键; A是例如C 6 -C 30烷基。

8. 发明授权

US06929828B2 Surface-active photoinitiators 失效
公开(公告)号：US06929828B2
公开(公告)日：2005-08-16
申请号：US10432301
申请日：2001-12-06
申请人： Gisèle Baudin , Tunja Jung
发明人： Gisèle Baudin , Tunja Jung
IPC分类号： C08F2/46 , C08F2/50 , G03F7/031 , B05D3/02 , B05D3/06
CPC分类号： C08F2/50 , B33Y70/00
摘要： A process for the production of coatings having scratch-resistant durable surfaces, in which there is used a photocurable formulation comprising a surface-active photoinitiator, concentrated at the surface of the formulation, of formula (Ia) or (Ib), wherein R and R3 are, for example, a radical of formula (II); R1 is, for example, hydrogen, A1-X1- or a radical of formula (II); R2 is, for example, unsubstituted or substituted C1-C12alkyl or A2-X2-; R4 is, for example, hydrogen or A4-X4-; R5 is, for example, hydrogen or A5-X5- or is a radical of formula (II); R6, R7, R8, R9 and R10 are each independently of the others, for example, hydrogen, A-X- , A3-X3- or C1-C12alkyl; A, A1, A2, A3, A4 and A5 are each independently of the others, for example, a surface-active radical of formula (III); n is a number from 1 to 1000, m is a number from 0 to 100; p is a number from 0 to 10 000; R18, R19, R20, R21, G1 and G2 are, for example, C1-C18alkyl; and X, X1, X2, X3, X4 and X5 are, for example, a single bond.

9. 发明授权

US07754863B2 High-capacity optical storage media 失效
标题翻译：大容量光存储介质
公开(公告)号：US07754863B2
公开(公告)日：2010-07-13
申请号：US11659993
申请日：2005-07-06
申请人： Jean-Pierre Bacher , Gisèle Baudin , Frédérique Wendeborn , Jean-Marie Adam , Urs Lehmann , Jean-Luc Birbaum
发明人： Jean-Pierre Bacher , Gisèle Baudin , Frédérique Wendeborn , Jean-Marie Adam , Urs Lehmann , Jean-Luc Birbaum
IPC分类号： C09B45/34 , C09B69/02 , G11B7/24
CPC分类号： G11B7/2467 , C09B45/20 , C09B45/34 , C09B69/045 , G11B7/246 , G11B7/247 , G11B7/2472 , G11B7/2492 , G11B7/2495 , G11B7/2498 , G11B7/2531 , G11B7/2533 , G11B7/2534 , G11B7/2535 , G11B7/256 , G11B7/2575 , G11B7/259 , G11B2007/25706 , G11B2007/2571 , G11B2007/25713 , G11B2007/25715 , G11B2007/25716
摘要： The invention accordingly relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula (I) or a mesomeric or a tautomeric form thereof, wherein M1 is a metal cation in the oxidation state +3, a hydroxy or halogeno metal group wherein the metal is in the oxidation state +4, or an oxo metal group wherein the metal is in the oxidation state +5; (III) and (IV)are each independently of the other (V), (VI) or (VII); (VIII) is (IX), (X), (XI), (XII), (XIII), or (XIV); (XV) is (XVI) or C2-C8heteroaryl unsubstituted or mono- or poly-substituted by R10, R11, R12 and/or R13; Q1 is N or CR18, Q2 is N or CR19, Q3, Q5 and Q7 are each independently of the other CR20R21, O, S or NR22, Q4 is CR16 or N and Q6 is CR17 or N; and R2 and/or R6 are O, S or NR33. Please see the disclosure for the other substituents which are less relevant. The compounds of formula (I) are novel and also claimed, as well as the compound of formula (II), or a mesomer or tautomer thereof, wherein R38 is halogen , CF3, NO2, CN, COR22, COOR23, SO3R23, NCO or SCN, G1, G2M1, R1R2, R4, R5, R6, R8, R22 and R23 are as defined in formula (I), M2m+ is a cation with m positive charges, and m is an integer 1, 2 or 3. The optical recording media are remarkably suitable for DVD±R (658 nm), especially at high recording speeds.
摘要翻译：因此，本发明涉及一种包括基底，反射层和记录层的光学记录介质，其中记录层包含式（I）化合物或其互变异构体或互变异构体，其中M1是金属阳离子氧化态+3，其中金属处于氧化态+4的羟基或卤代金属基团，或其中金属处于氧化态+5的氧代金属基团; （III）和（IV）各自独立于另一个（V），（VI）或（VII）; （VIII）为（IX），（X），（XI），（XII），（XIII）或（XIV）; （XV）是（XVI）或未被取代或被R10，R11，R12和/或R13单取代或多取代的C 2 -C 8杂芳基; Q1是N或CR18，Q2是N或CR19，Q3，Q5和Q7各自独立于另一个CR20R21，O，S或NR22，Q4是CR16或N，Q6是CR17或N; 且R 2和/或R 6为O，S或NR 33。请参阅其他不太相关的其他取代基的披露。式（I）化合物是新的，也要求保护的，以及式（II）化合物或其互变异构体或互变异构体，其中R38是卤素，CF3，NO2，CN，COR22，COOR23，SO3R23，NCO或 SCN，G1，G2M1，R1R2，R4，R5，R6，R8，R22和R23如式（I）中所定义，M2m +是具有m个正电荷的阳离子，m是整数1,2或3.光学记录介质非常适合于DVD±R（658nm），特别是在高记录速度下。

10. 发明授权

US06693141B2 Surface-active photoinitiators 有权
标题翻译：表面活性光引发剂
公开(公告)号：US06693141B2
公开(公告)日：2004-02-17
申请号：US10026238
申请日：2001-12-21
申请人： Gisèle Baudin , Tunja Jung
发明人： Gisèle Baudin , Tunja Jung
IPC分类号： C08F250
CPC分类号： C07F7/21 , C07F7/0838 , C08F2/50 , Y10S522/905 , Y10T428/31663
摘要： The invention relates to the use of surface-active photoinitiators of formula I the units being arranged randomly or in blocks, and wherein n is a number from 1 to 1000; m is a number from 0 to 100; p is a number from 0 to 10,000; x is the number 1, or, when n is 1, x may also be the number 2; A1 and A2 are, for example, C1-C18alkyl; or A1 and A2 together are a single bond; R1, R2 and R3 are, for example, each independently of the others C1-C18alkyl, phenyl or C5-C8cycloalkyl; R4 is, for example, unsubstituted or substituted C1-C18alkyl, unsubstituted or substituted phenyl or C5-C8cycloalkyl; IN, when x is 1, is a radical of formula when x is 2, is a radical of formula R13 and R14 are, for example, each independently of the other C1-C12alkyl; Y is, for example, —(CH2)a—O—; X is OR15 or N(R16)(R17); R15 is, for example, hydrogen or C1-C4alkyl; R16 and R17 are, for example, hydrogen or C1-C12alkyl; X1 has, for example, one of the meanings of X; and R18 is, for example, —(CH2)a—; in photochemically and combined photochemically and thermally crosslinkable formulations.
摘要翻译：本发明涉及式（I）的表面活性光引发剂的使用，其单位是随机或嵌段排列，其中n为1至1000的数; m是从0到100的数字; p是从0到10,000的数字; x是数字1，或者当n是1时，x也可以是数字2; A1和A2是例如C1-C18烷基; 或A1和A2一起是单键; R 1，R 2和R 3例如各自独立地为C 1 -C 18烷基，苯基或C 5 -C 8环烷基; R4是例如未取代或取代的C1-C18烷基，未取代或取代的苯基或C5-C8环烷基; IN，当x为1时，是式的基团x为2，式R 13和R 14的基团例如各自独立地为C 1 -C 12烷基; Y为例如 - （CH 2）a -O-; X是OR 15或N（R 16）（R 17）; R 15是例如氢或C 1 -C 4烷基; R 16和R 17是例如氢或C 1 -C 12烷基; X1具有例如X的含义之一; 并且R 18是例如 - （CH 2）a - ;在光化学和组合的光化学和热交联的制剂中。

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