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    • 4. 发明授权
    • Process of purifying combustion exhaust gases
    • 净化燃烧废气的过程
    • US5659110A
    • 1997-08-19
    • US375634
    • 1995-01-20
    • Hansjoerg HerdenGernot Mayer-SchwinningGuenter Boening
    • Hansjoerg HerdenGernot Mayer-SchwinningGuenter Boening
    • B01D53/02B01D53/10B01D53/12B01D53/64B01D53/70A63D3/00C01B21/00B01D55/02
    • B01D53/10B01D53/02B01D53/12B01D53/64B01D53/70Y10S95/902
    • The process of purifying oxygen-containing exhaust gases produced by combustion of waste materials including garbage, industrial waste and sewage sludge includes reacting an exhaust gas containing pollutants in a gas-solids suspension at a temperature of 120.degree. to 140.degree. C. and at a gas velocity from 3 to 20 m/s for a reaction time of 0.5 to 10 seconds with a mixture containing naturally occurring zeolites to remove mercury, mercury compounds and polyhalogenated hydrocarbons pollutants from the exhaust gas. The naturally occurring zeolites have a median particle size (d.sub.50) from 5 to 50 micrometers and the gas-solids suspension has a mean suspension density from 0.020 to 10 kg of solids per sm.sup.3 of exhaust gas. The mixture contains from 10 to 20% by weight mordenite, from 60 to 70% by weight clinoptilolite, from 0 to 5% by weight montmorillonite and a remaining balance of SiO.sub.2. The purified gas contains
    • 净化包括垃圾,工业废弃物和污水污泥在内的废弃物燃烧产生的含氧废气的过程包括在120〜140℃的温度和气体 - 固体悬浮液中使含有污染物的废气反应 气体速度为3至20m / s,反应时间为0.5至10秒,含有天然存在的沸石的混合物,以从废气中除去汞,汞化合物和多卤代烃污染物。 天然存在的沸石具有5至50微米的中值粒度(d50),气固体悬浮液的平均悬浮密度为0.020至10kg固体/ sm3废气。 该混合物含有10至20重量%的丝光沸石,60至70重量%的斜发沸石,0至5重量%的蒙脱石和余量的SiO 2。 净化气体每sm3含有<50微克汞,每分子3的多卤代二苯并二恶英和二苯并呋喃<0.1微克TE,PCBs,PCP和PCA / sm3 <1微克。
    • 5. 发明授权
    • Process and apparatus for separating polycyclic and polyhalogenated
hydrocarbons from exhaust gas of a sintering process
    • 用于从烧结过程的废气中分离多环和多卤代烃的方法和设备
    • US5827484A
    • 1998-10-27
    • US761654
    • 1996-12-06
    • Hansjoerg HerdenStefan FederhenGernot Mayer-SchwinningHubert Roth
    • Hansjoerg HerdenStefan FederhenGernot Mayer-SchwinningHubert Roth
    • B01D53/10B01D53/70B01D50/00
    • B01D53/10B01D53/70B01D2257/206
    • The apparatus for separating toxic organic substances from a dust-containing exhaust gas of a sintering plant, includes a clay adsorption agent, advantageously consisting of kaolinite, bentonite, illite and/or mixtures thereof, having a mean particle diameter of from 5 to 100 micrometers; a solids-entraining reactor (4) connected to the sintering plant (1) to receive the exhaust gas containing dust from it and a supply device (5) with feed line (6) for supplying the clay adsorption agent to the solids-entraining reactor (4) to bring the entire exhaust gas containing dust into contact with the clay adsorption agent for a reaction time of from 0.5 to 10 seconds above a dew point of the exhaust gas at a temperature from 90.degree. to 180.degree. C. and at a velocity from 6 to 20 meters per second to thus form a gas-solids suspension having a mean suspension density of from 5 to 500 g solids per sm.sup.3 of the exhaust gas; a cyclone (R) for separating and recycling recovered solids from the gas-solids suspension to form a partially purified gas; and a multifield electrostatic precipitator (7) connected to the cyclone(R) to form separated solids and a purified gas from the partially purified gas; and a recycling device (9) for recycling the separated solids formed in the electrostatic precipitator (7) to the solids-entraining reactor (4).
    • 用于从烧结设备的含尘废气中分离有毒有机物质的装置包括粘土吸附剂,其有利地由平均粒径为5至100微米的高岭石,膨润土,伊利石和/或其混合物组成 ; 连接到烧结设备(1)以接收来自其的灰尘的废气的固体携带反应器(4)和具有用于将粘土吸附剂供应到固体进料反应器的进料管线(6)的供应装置(5) (4)使得含有灰尘的整个废气与粘土吸附剂接触,反应时间在废气的露点以上的温度为90℃至180℃的反应时间为0.5至10秒,并且在 速度为6至20米/秒,从而形成气体 - 固体悬浮液,其平均悬浮密度为每sm3废气5至500克固体; 用于从气固体悬浮液中分离和再循环回收的固体以形成部分纯化的气体的旋风分离器(R) 和与旋风分离器(R)连接以形成分离的固体的多叶静电除尘器(7)和来自部分纯化气体的净化气体; 以及用于将形成在静电除尘器(7)中的分离的固体再循环到固体携带反应器(4)的回收装置(9)。