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1. 发明申请

WO2008023170A1 TAILORED CONTROL OF SURFACE PROPERTIES BY CHEMICAL MODIFICATION 审中-公开
标题翻译：化学修饰对表面特性的定制控制
公开(公告)号：WO2008023170A1
公开(公告)日：2008-02-28
申请号：PCT/GB2007/003194
申请日：2007-08-22
申请人： ISIS INNOVATION LIMITED , MOLONEY, Mark , GRIFFITHS, Jon-Paul
发明人： MOLONEY, Mark , GRIFFITHS, Jon-Paul
IPC分类号： C08J7/12 , B05D5/10 , C03C17/28 , C09C1/00 , D06M13/00 , D06M13/03 , D06M13/11 , D06M13/288 , D06M13/338 , D06M13/322 , D21H25/02 , C07C241/02 , C07C245/14 , C07C243/18 , C07C249/16
CPC分类号： C08J7/12 , C01P2004/61 , C01P2004/64 , C03C17/28 , C07C245/12 , C07C245/20 , C07F9/3882 , C09C3/08 , C09C3/10 , D06M13/03 , D06M13/11 , D06M13/288 , D06M13/338
摘要： A process for producing a substrate having an adhesive surface, which process comprises: (a) contacting the substrate with a carbene precursor, which carbene precursor is a compound of the following formula (I): whose substituent groups are defined herein, provided that when R is aryl or heteroaryl, said aryl or heteroaryl may be substituted by one, two, three, four or five groups, which groups are independently selected from various groups including -L B -W B ; and (b) either: (i) when W A or W B comprises an adhesive functional group, generating a carbene reactive intermediate from the carbene precursor so that it reacts with the substrate to functionalise the surface, thereby yielding said substrate having an adhesive surface; or (ii) when W A or W B comprises a group which is a precursor of an adhesive functional group, generating a carbene reactive intermediate from the carbene precursor so that it reacts with the substrate to functionalise the surface, and (c) converting said group which is a precursor into an adhesive functional group thereby yielding said substrate having an adhesive surface. The invention further relates to carbene precursor compounds for use in the process, substrates produced by the process and to processes for preparing certain precursor compounds.
摘要翻译：一种制备具有粘合剂表面的基材的方法，该方法包括：（a）使基材与卡宾前体接触，所述卡宾前体是下式（I）的化合物：其取代基在本文中定义，条件是当 R是芳基或杂芳基，所述芳基或杂芳基可以被一个，两个，三个，四个或五个基团取代，这些基团独立地选自各种基团，包括-L B-B B ; 和（b）：（i）当W A A或W B B包含粘合官能团时，从卡宾前体产生卡宾反应性中间体，使其与衬底以使表面功能化，由此产生具有粘合剂表面的所述衬底; 或（ii）当W A A或W B B包含作为粘合官能团的前体的基团时，从卡宾前体产生卡宾反应性中间体，使其反应其中所述基底使表面功能化，和（c）将作为前体的基团转化为粘合官能团，从而产生具有粘合剂表面的所述基材。本发明还涉及用于该方法的卡宾前体化合物，通过该方法制备的底物和用于制备某些前体化合物的方法。

2. 发明申请

WO2006075183A3 SURFACE FUNCTIONALISATION USING ARYLCARBENE REACTIVE INTERMEDIATES 审中-公开
标题翻译：使用ARYLCARBENE反应中间体的表面功能
公开(公告)号：WO2006075183A3
公开(公告)日：2006-09-14
申请号：PCT/GB2006000139
申请日：2006-01-17
申请人： ISIS INNOVATION , MOLONEY MARK GERARD , GRIFFITHS JON-PAUL
发明人： MOLONEY MARK GERARD , GRIFFITHS JON-PAUL
IPC分类号： C08J7/12
CPC分类号： C08J7/12
摘要： A process for producing a substrate having a functionalised surface, which process comprises: (a) contacting the substrate with a carbene precursor, which carbene precursor is a compound of formula (III) or (IV) whose substituent groups are defined herein: (b) generating a carbene reactive intermediate from the carbene precursor so that it reacts with the substrate to functionalise the surface, thereby yielding an activated substrate; and (c) further functionalising the activated substrate obtained in (b). In (c), the activated substrate may be further functionalised by treating the activated substrate with a diazonium salt for the introduction of colour and/or another desired activity, and/or by treatment with hydrogen peroxide to produce a biocidal substrate. The invention further relates to carbene precursor compounds for use in the surface functionalisation process, and to processes for preparing certain precursor compounds.
摘要翻译：一种制备具有官能化表面的基材的方法，该方法包括：（a）使底物与卡宾前体接触，该卡宾前体是其取代基在本文中定义的式（III）或（IV）化合物：（b ）从卡宾前体产生卡宾反应中间体，使其与基材反应以使表面功能化，从而产生活化的底物; 和（c）进一步功能化（b）中获得的活化底物。在（c）中，通过用重氮盐处理活化的底物以引入颜色和/或其它所需活性，和/或通过用过氧化氢处理以产生杀生物底物，活化的底物可以进一步官能化。本发明还涉及用于表面官能化方法的卡宾前体化合物，以及制备某些前体化合物的方法。

3. 发明申请

WO2010100413A3 CROSS-LINKABLE POLYMERS 审中-公开
标题翻译：交联聚合物
公开(公告)号：WO2010100413A3
公开(公告)日：2010-11-18
申请号：PCT/GB2010000373
申请日：2010-03-02
申请人： OXFORD ADVANCED SURFACES LTD , GRIFFITHS JON PAUL , EASON MICHAEL DOUGLAS , WINCEWICZ RICHARD CHARLES , HUNTER STUART JAMES
发明人： GRIFFITHS JON PAUL , EASON MICHAEL DOUGLAS , WINCEWICZ RICHARD CHARLES , HUNTER STUART JAMES
IPC分类号： C07C311/49 , C08J3/24 , C08K5/435 , C09J125/08
CPC分类号： C07C311/49 , C08J7/04 , Y10T428/2998 , Y10T428/31536
摘要： The invention provides a functionalised compound which is a sulfonylhydrazone compound of formula (XXXa) wherein n is an integer equal to or greater than 3; L is a single bond or a linker group of formula (XII) as defined herein, R and R2 are as defined herein, and Q is a polymer or a dendrimer. Further provided are the uses of the functionalised compound as a cross linking agent or as an adhesive. The invention further provides a process for cross linking or adhering a first substrate to a second substrate, which process comprises contacting the first and second substrates with a functionalised compound of the invention, and generating carbene reactive intermediate groups from the reactive intermediate precursor groups, so that carbene reactive intermediate groups react with the first and second substrates, thereby cross linking or adhering the first and second substrates. The resulting cross-linked products are also provided. The invention also provides an adhesive composition comprising the functionalised compound of the invention, a process for producing the functionalised compounds of the invention, and precursor compounds which are used in that process.
摘要翻译：本发明提供了官能化的化合物，其是式（XXXa）的磺酰腙化合物，其中n是等于或大于3的整数; L是如本文所定义的式（XII）的单键或连接基团，R和R 2如本文所定义，并且Q是聚合物或树枝状聚合物。还提供了官能化的化合物作为交联剂或作为粘合剂的用途。本发明进一步提供了用于将第一基材交联或粘合至第二基材的方法，该方法包括使第一和第二基材与本发明的官能化的化合物接触并由反应性中间体前体基团产生卡宾反应性中间体基团，如此卡宾反应性中间体基团与第一和第二基底反应，从而交联或粘附第一和第二基底。还提供了所得到的交联产物。本发明还提供了包含本发明的官能化的化合物的粘合剂组合物，用于制备本发明的官能化的化合物的方法以及在该方法中使用的前体化合物。

4. 发明申请

WO2010106326A1 OPTICAL COATING 审中-公开
标题翻译：光学涂料
公开(公告)号：WO2010106326A1
公开(公告)日：2010-09-23
申请号：PCT/GB2010/000490
申请日：2010-03-18
申请人： OXFORD ENERGY TECHNOLOGIES LTD. , WAKEFIELD, Gareth , GARDENER, Martin, Ryan , GRIFFITHS, Jon-Paul , WINCEWICZ, Richard, Charles , PODGORSKI, Tadeusz, Antoni
发明人： WAKEFIELD, Gareth , GARDENER, Martin, Ryan , GRIFFITHS, Jon-Paul , WINCEWICZ, Richard, Charles , PODGORSKI, Tadeusz, Antoni
IPC分类号： G02B1/11 , H01L31/0216
CPC分类号： G02B1/113 , H01L31/02161 , H01L31/02168 , H01L31/055 , Y02E10/52 , Y10T428/24421
摘要： An optical coating, comprising porous particles, or formed from porous precursor particles. The average thickness of the coating is in the range of from 75 to 400 nm, and the surface roughness of the coating is in the range of from 2 to 300 nm. This coating provides broadband antireflective properties across the visible and near infrared part of the electromagnetic spectrum.
摘要翻译：包括多孔颗粒或由多孔前体颗粒形成的光学涂层。涂层的平均厚度在75〜400nm的范围内，涂层的表面粗糙度在2〜300nm的范围内。该涂层在电磁光谱的可见光和近红外部分提供宽带抗反射性能。

5. 发明申请

WO2010100413A2 CROSS-LINKABLE POLYMERS 审中-公开
标题翻译：交联聚合物
公开(公告)号：WO2010100413A2
公开(公告)日：2010-09-10
申请号：PCT/GB2010/000373
申请日：2010-03-02
申请人： OXFORD ADVANCED SURFACES LTD , GRIFFITHS, Jon, Paul , EASON, Michael, Douglas , WINCEWICZ, Richard, Charles , HUNTER, Stuart, James
发明人： GRIFFITHS, Jon, Paul , EASON, Michael, Douglas , WINCEWICZ, Richard, Charles , HUNTER, Stuart, James
CPC分类号： C07C311/49 , C08J7/04 , Y10T428/2998 , Y10T428/31536
摘要： The invention provides a functionalised compound which is a sulfonylhydrazone compound of formula (XXXa) wherein n is an integer equal to or greater than 3; L is a single bond or a linker group of formula (XII) as defined herein, R and R2 are as defined herein, and Q is a polymer or a dendrimer. Further provided are the uses of the functionalised compound as a cross linking agent or as an adhesive. The invention further provides a process for cross linking or adhering a first substrate to a second substrate, which process comprises contacting the first and second substrates with a functionalised compound of the invention, and generating carbene reactive intermediate groups from the reactive intermediate precursor groups, so that carbene reactive intermediate groups react with the first and second substrates, thereby cross linking or adhering the first and second substrates. The resulting cross-linked products are also provided. The invention also provides an adhesive composition comprising the functionalised compound of the invention, a process for producing the functionalised compounds of the invention, and precursor compounds which are used in that process.
摘要翻译：本发明提供官能化化合物，其为式（ⅩⅩaa）的磺酰腙化合物，其中n为等于或大于3的整数; L是如本文所定义的单键或式（XII）的连接基团，R和R 2如本文所定义，Q是聚合物或树枝状聚合物。还提供了官能化化合物作为交联剂或粘合剂的用途。本发明还提供了将第一基底交联或粘合到第二基底的方法，该方法包括使第一和第二底物与本发明的官能化化合物接触，并从反应性中间体前体基团产生卡宾反应性中间体，因此该卡宾反应性中间体与第一和第二基材反应，从而交联或粘合第一和第二基材。还提供了所得的交联产物。本发明还提供了包含本发明的官能化化合物，本发明的官能化化合物的制备方法和在该方法中使用的前体化合物的粘合剂组合物。

6. 发明申请

WO2010100410A1 CHEMICAL AGENTS CAPABLE OF FORMING COVALENT 3-D NETWORKS 审中-公开
标题翻译：形成合并三维网络的化学试剂
公开(公告)号：WO2010100410A1
公开(公告)日：2010-09-10
申请号：PCT/GB2010/000368
申请日：2010-03-02
申请人： OXFORD ADVANCED SURFACES LTD , GRIFFITHS, Jon-Paul , EASON, Michael, Douglas , BEAL, Sarah, Louise , VICKERS, Sarah , WINCEWICZ, Richard, Charles , KING, David, Simon
发明人： GRIFFITHS, Jon-Paul , EASON, Michael, Douglas , BEAL, Sarah, Louise , VICKERS, Sarah , WINCEWICZ, Richard, Charles , KING, David, Simon
IPC分类号： C07C245/14 , C07C251/80
CPC分类号： C07C311/49 , C08J7/04 , Y10T428/2998 , Y10T428/31536
摘要： The invention provides a functionalised compound of formula (II), which functionalised compound comprises n carbene precursor groups which are the same or different, wherein n is an integer equal to or greater than 3: wherein x is 1, E is a group which is capable of being converted into a carbene reactive intermediate group, Q is a core moiety, a polymer or a dendrimer, and each of the [R] x -E-L- groups, which are the same or different, is independently selected from a group of formula (Ie) and a group of formula (Ia): wherein L is a single bond or a linker group as defined herein, R is a terminal group as defined herein, and R 1 is as defined herein. Further provided is the use of the functionalised compound as an agent for producing a chemically-bound three-dimensional network on or within a substrate. Processes for producing the following products using the functionalised compounds of the invention are also provided, as are the resulting products: a chemically- bound three-dimensional network on or within a substrate; a chemically-bound three- dimensional network between a first substrate and a second substrate; a film or a coating; a coated substrate; a product which comprises a first substrate, a second substrate and a composition at an interface of the first and second substrates; a treated particle. The invention further provides a process for cross linking a first substrate to a second substrate, using a functionalised compound of the invention, and the resulting cross-linked product. The invention also provides a process for producing the functionalised compounds of the invention.
摘要翻译：本发明提供了官能化的式（II）化合物，该官能化化合物包含相同或不同的n个卡宾前体基团，其中n为等于或大于3的整数，其中x为1，E为能够转化为卡宾反应性中间体，Q是核心部分，聚合物或树枝状大分子，并且相同或不同的[R] xEL-基团中的每一个独立地选自式（ Ie）和式（Ia）的基团：其中L是单键或如本文所定义的连接基团，R是如本文所定义的端基，并且R 1如本文所定义。还提供了使用官能化化合物作为在基底上或内部产生化学结合的三维网络的试剂。还提供了使用本发明的官能化化合物生产以下产物的方法，以及所得产物：底物上或内部的化学结合的三维网络; 在第一衬底和第二衬底之间的化学结合的三维网络; 薄膜或涂层; 涂布基材; 产品，其包括第一基板，第二基板和在第一和第二基板的界面处的组合物; 经处理的颗粒。本发明还提供了使用本发明的官能化化合物和所得交联产物将第一底物交联到第二底物的方法。本发明还提供了制备本发明的官能化化合物的方法。

7. 发明申请

WO2006075183A2 SURFACE FUNCTIONALISATION USING ARYLCARBENE REACTIVE INTERMEDIATES 审中-公开
标题翻译：芳香烃反应中间体的表面官能团化
公开(公告)号：WO2006075183A2
公开(公告)日：2006-07-20
申请号：PCT/GB2006/000139
申请日：2006-01-17
申请人： ISIS INNOVATION LIMITED , MOLONEY, Mark, Gerard , GRIFFITHS, Jon-Paul
发明人： MOLONEY, Mark, Gerard , GRIFFITHS, Jon-Paul
IPC分类号： C08J7/12
CPC分类号： C08J7/12
摘要： A process for producing a substrate having a functionalised surface, which process comprises: (a) contacting the substrate with a carbene precursor, which carbene precursor is a compound of formula (III) or (IV) whose substituent groups are defined herein: (b) generating a carbene reactive intermediate from the carbene precursor so that it reacts with the substrate to functionalise the surface, thereby yielding an activated substrate; and (c) further functionalising the activated substrate obtained in (b). In (c), the activated substrate may be further functionalised by treating the activated substrate with a diazonium salt for the introduction of colour and/or another desired activity, and/or by treatment with hydrogen peroxide to produce a biocidal substrate. The invention further relates to carbene precursor compounds for use in the surface functionalisation process, and to processes for preparing certain precursor compounds.
摘要翻译：一种制备具有官能化表面的基材的方法，该方法包括：（a）使基材与碳烯前体接触，该碳烯前体是式（III）或（IV）的化合物，其（b）由卡宾前体生成卡宾反应性中间体，使其与底物反应以使表面官能化，从而产生活化的底物; 和（c）使（b）中获得的活化基材进一步官能化。在（c）中，可以通过用重氮盐处理活化的底物以引入颜色和/或另一期望的活性，和/或通过用过氧化氢处理以产生杀生物底物来进一步官能化活化的底物。本发明进一步涉及用于表面官能化方法的卡宾前体化合物，以及制备某些前体化合物的方法。

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