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1. 发明申请

WO2011139711A2 ANAEROBIC ORGANISMS IN A PROCESS FOR CONVERTING BIOMASS 审中-公开
标题翻译：生物质转化过程中的厌氧有机体
公开(公告)号：WO2011139711A2
公开(公告)日：2011-11-10
申请号：PCT/US2011/033984
申请日：2011-04-26
申请人： TERRABON, INC. , THE TEXAS A&M UNIVERSITY SYSTEMS , GRANDA, Cesar, B. , HOLTZAPPLE, Mark T. , HOLTZAPPLE, Erik
发明人： GRANDA, Cesar, B. , HOLTZAPPLE, Mark T. , HOLTZAPPLE, Erik
IPC分类号： C12P5/02 , C12P7/64 , C12P7/62 , C12N1/20 , C12N1/14 , C12R1/01 , C12R1/645
CPC分类号： C12P5/00 , C12P7/06 , C12P7/6436 , C12P7/649 , Y02E50/13 , Y02E50/17 , Y02E50/343 , Y02T50/678
摘要： A method for integrating biological conversion of mixed acids to hydrocarbons, hydrocarbon-like molecules, biofuels, and combinations thereof. The method including introducing fermentation products to at least one microorganism chosen from the group consisting of heterotrophic microorganisms, photo-mixotrophic microorganisms, chemo-autotrophic microorganisms, and combinations thereof.
摘要翻译：将混合酸的生物转化与烃类，烃类分子，生物燃料及其组合相结合的方法。所述方法包括将发酵产物引入至少一种选自异养微生物，光混合营养微生物，化学自养微生物及其组合的微生物。

2. 发明申请

WO2009059149A1 SYSTEM AND METHOD FOR PRETREATING BIOMASS 审中-公开
标题翻译：用于预测生物量的系统和方法
公开(公告)号：WO2009059149A1
公开(公告)日：2009-05-07
申请号：PCT/US2008/082011
申请日：2008-10-31
申请人： THE TEXAS A & M UNIVERSITY SYSTEM , HOLTZAPPLE, Mark, T. , GRANDA, Cesar, B.
发明人： HOLTZAPPLE, Mark, T. , GRANDA, Cesar, B.
IPC分类号： B01D11/04 , C02F1/02 , C02F1/16 , C13D1/02 , C13D1/04
CPC分类号： C10L9/08 , B01D11/0219 , B01D11/0284 , C02F11/18 , C10L5/44 , C13B10/02 , C13B10/04 , Y02E50/10 , Y02E50/30
摘要： According to one embodiment, a method for heat treatment of a biomass includes allowing biomass in a pretreatment reactor to undergo a pre-treatment reaction process. The pre-treatment reaction process yields pretreated biomass along with soluble components. A first liquid having a first temperature is transported into the pretreatment reactor and the pretreated biomass elevates the first temperature to a second temperature. At least a port of the soluble components are captured in the first liquid, and the at least a portion of the soluble components in the first liquid and the first liquid are removed from the pretreatment reactor. A second liquid having a third temperature is transported into the pretreatment reactor and the pretreated biomass elevates the third temperature to a fourth temperature, the fourth temperature being less than second temperature.
摘要翻译：根据一个实施方案，用于热处理生物质的方法包括允许预处理反应器中的生物质进行预处理反应过程。预处理反应过程与可溶组分一起产生预处理的生物质。具有第一温度的第一液体被输送到预处理反应器中，并且预处理的生物质将第一温度升高到第二温度。至少一个可溶性组分的端口被捕获在第一液体中，并且第一液体和第一液体中的至少一部分可溶性组分从预处理反应器中除去。具有第三温度的第二液体被输送到预处理反应器中，并且预处理的生物质将第三温度升高到第四温度，第四温度小于第二温度。

3. 发明申请

WO2007009085A2 SYSTEM AND METHOD FOR CONVERTING BIOMASS 审中-公开
标题翻译：用于转化生物量的系统和方法
公开(公告)号：WO2007009085A2
公开(公告)日：2007-01-18
申请号：PCT/US2006/027466
申请日：2006-07-12
申请人： THE TEXAS A & M UNIVERSITY SYSTEM , HOLTZAPPLE, Mark, T. , DAVISON, Richard, R. , GRANDA, Cesar, B. , AGBOGBO, Frank, K. , FU, Zhihong (nmi)
发明人： HOLTZAPPLE, Mark, T. , DAVISON, Richard, R. , GRANDA, Cesar, B. , AGBOGBO, Frank, K. , FU, Zhihong (nmi)
IPC分类号： C12P7/02 , C12P7/40
CPC分类号： C12P7/02 , C12P7/40 , Y02E50/16
摘要： In accordance with the teachings of the present invention, a system and method converting biomass into useful chemicals are provided. In a particular embodiment, the method includes fermenting biomass in one or more fermentors to produce a fermentation broth comprising ammonium carboxylate salts, the fermentors containing an ammonium carbonate or ammonium bicarbonate buffer. The method further includes reacting the ammonium carboxylate salts from the fermentors with a high-molecular-weight amine to produce amine carboxylate salt, and thermally cracking the amine carboxylate salt to produce carboxylic acid. In another embodiment, the ammonium carboxylate salts from the fermentors may be reacted with a low-molecular-weight amine to produce a low- molecular-weight-amine carboxylate salt. The low-molecular-weight amine in the low- molecular-weight-amine carboxylate salt may then be switched with a high-molecular- weight amine to form a high-molecular-weight-amine carboxylate salt, which is then thermally cracked to produce carboxylic acid. In yet another embodiment, the ammonium carboxylate salts from the fermentors may be reacted with a high-molecular-weight alcohol to produce a high-molecular-weight ester, which may be hydrogenated to produce alcohol.
摘要翻译：根据本发明的教导，提供了将生物质转化为有用化学物质的系统和方法。在一个具体实施方案中，该方法包括在一个或多个发酵罐中发酵生物质以产生包含羧酸铵盐的发酵液，所述发酵罐含有碳酸铵或碳酸氢铵缓冲液。该方法还包括使来自发酵罐的羧酸铵盐与高分子量胺反应以产生胺羧酸盐，并热分解胺羧酸盐以产生羧酸。在另一个实施方案中，来自发酵罐的羧酸铵盐可以与低分子量胺反应以产生低分子量胺羧酸盐。然后可以用高分子量胺转化低分子量胺羧酸盐中的低分子量胺以形成高分子量胺羧酸盐，然后将其热裂解产生羧酸。在另一个实施方案中，来自发酵罐的羧酸铵盐可以与高分子量醇反应以产生高分子量酯，其可被氢化以产生醇。

4. 发明申请

WO2008070561A1 A METHOD OF BIOMASS CONVERSION INTO MIXED ALCOHOLS 审中-公开
标题翻译：生物质转化为混合醇的一种方法
公开(公告)号：WO2008070561A1
公开(公告)日：2008-06-12
申请号：PCT/US2007/086106
申请日：2007-11-30
申请人： THE TEXAS A & M UNIVERSITY SYSTEM , GRANDA, Cesar B. , HOLTZAPPLE, Mark T. , DAVISON, Richard R.
发明人： GRANDA, Cesar B. , HOLTZAPPLE, Mark T. , DAVISON, Richard R.
IPC分类号： C12P3/00 , C12P7/02 , C12P7/40 , C12P7/54
CPC分类号： C12P3/00 , C12M21/04 , C12M23/58 , C12M47/06 , C12M47/18 , C12P7/02 , C12P7/40 , C12P7/54
摘要： In one embodiment, the disclosure includes a method of biomass conversion including fermenting biomass to produce a carboxylic acid or carboxylate salt and hydrogen gas, recovering the hydrogen gas, and converting the carboxylic acid or carboxylate salt to an alcohol using the hydrogen gas. In one embodiment, the hydrogen produced by biomass conversion may be converted to an acetate. Another embodiment relates to a biomass conversion system. The system may include: a fermentation unit for fermentation of biomass to a carboxylic acid or carboxylate salt in a fermentation broth and for production of a carbon dioxide and hydrogen gas stream, an extraction unit for extracting the carboxylic acid or carboxylate salt from the fermentation broth, a gas extraction unit for separation of the hydrogen gas and the carbon dioxide, and a production unit for production of an alcohol from the carboxylic acid or carboxylate salt using the hydrogen gas.
摘要翻译：在一个实施方案中，本公开包括生物质转化的方法，包括发酵生物质以产生羧酸或羧酸盐和氢气，回收氢气，并将羧酸或羧酸盐转化为使用氢气的酒精。在一个实施方案中，通过生物质转化产生的氢可以转化成乙酸盐。另一个实施方案涉及生物质转化系统。该系统可以包括：用于将生物质发酵成发酵液中的羧酸或羧酸盐并用于产生二氧化碳和氢气流的发酵单元，用于从发酵液中提取羧酸或羧酸盐的提取单元，用于分离氢气和二氧化碳的气体提取单元以及用于使用氢气从羧酸或羧酸盐产生醇的生产单元。

5. 发明申请

WO2007009085A3 PRODUCTION PLANT AND METHOD FOR CONVERTING BIOMASS 审中-公开
标题翻译：生产设备和转化生物质的方法
公开(公告)号：WO2007009085A3
公开(公告)日：2007-04-19
申请号：PCT/US2006027466
申请日：2006-07-12
申请人： TEXAS A & M UNIV SYS , HOLTZAPPLE MARK T , DAVISON RICHARD R , GRANDA CESAR B , AGBOGBO FRANK K , FU ZHIHONG NMI
发明人： HOLTZAPPLE MARK T , DAVISON RICHARD R , GRANDA CESAR B , AGBOGBO FRANK K , FU ZHIHONG NMI
IPC分类号： A23K50/15 , C12P7/02 , C12P7/40
CPC分类号： C12P7/02 , C12P7/40 , Y02E50/16
摘要： In accordance with the teachings of the present invention, a production plant and method for converting biomass into useful chemicals are provided. In a particular embodiment, the method includes fermenting biomass in one or more fermentors to produce a fermentation broth comprising ammonium carboxylate salts, the fermentors containing an ammonium carbonate or ammonium bicarbonate buffer. The method further includes reacting the ammonium carboxylate salts from the fermentors with a high-molecular-weight amine to produce amine carboxylate salt, and thermally cracking the amine carboxylate salt to produce carboxylic acid. In yet another embodiment, the ammonium carboxylate salts from the fermentors may be reacted with a high-molecular-weight alcohol to produce a high-molecular-weight ester, which may be hydrogenated to produce alcohol .
摘要翻译：根据本发明的教导，提供了将生物质转化为有用化学品的生产设备和方法。在一个具体实施方案中，该方法包括在一个或多个发酵罐中发酵生物质以产生包含羧酸铵盐的发酵液，所述发酵罐含有碳酸铵或碳酸氢铵缓冲液。该方法还包括使来自发酵罐的羧酸铵盐与高分子量胺反应以产生胺羧酸盐，并热分解胺羧酸盐以产生羧酸。在另一个实施方案中，来自发酵罐的羧酸铵盐可以与高分子量醇反应以产生高分子量酯，其可被氢化以产生醇。

6. 发明申请

WO2010065643A3 ALTERNATIVE PATHS TO ALCOHOLS AND HYDROCARBONS FROM BIOMASS 审中-公开
标题翻译：来自生物质的酒精和碳氢化合物的替代方案
公开(公告)号：WO2010065643A3
公开(公告)日：2010-09-16
申请号：PCT/US2009066419
申请日：2009-12-02
申请人： TEXAS A & M UNIV SYS , HOLTZAPPLE MARK T , GRANDA CESAR B , TACO SEBASTIAN , ROSS MICHAEL KYLE , LUCE GARY
发明人： HOLTZAPPLE MARK T , GRANDA CESAR B , TACO SEBASTIAN , ROSS MICHAEL KYLE , LUCE GARY
IPC分类号： C07C29/136 , C07C2/12 , C10L1/04 , C12P7/26
CPC分类号： C12P7/40 , C07C1/24 , C07C2/02 , C07C29/149 , C07C67/04 , C10G3/00 , C10G50/00 , C10G2300/1011 , C10G2300/4081 , C10G2300/42 , C10G2400/20 , C10G2400/22 , Y02P30/20 , C07C31/08 , C07C69/14
摘要： A method of producing alcohols, hydrocarbons, or both from biomass by converting biomass into a carboxylic acid, reacting the carboxylic acid with an olefin to produce an ester and hydrogenolyzing the ester to produce alcohol. A method of producing hydrocarbons from biomass by converting at least a portion of the biomass into a carboxylic acid, a ketone, or an ammonium carboxylate salt, reacting at least one of a portion of the carboxylic acid, a portion of the ketone, or a portion of the ammonium carboxylate salt in an oligomerization reactor as at least part of a process that produces an oligomerization product and separating hydrocarbons from the oligomerization product.
摘要翻译：通过将生物质转化为羧酸，从生物质生产醇，烃或二者的方法，使羧酸与烯烃反应生成酯并使该酯氢解，生成醇。通过将至少一部分生物质转化为羧酸，酮或羧酸铵盐，从生物质生产烃的方法，使羧酸的一部分，酮的一部分或部分羧酸铵盐在低聚反应器中作为产生低聚产物并从低聚产物中分离烃的方法的至少一部分。

7. 发明申请

WO2010065643A2 ALTERNATIVE PATHS TO ALCOHOLS AND HYDROCARBONS FROM BIOMASS 审中-公开
标题翻译：用生物质替代醇和碳氢化合物的途径
公开(公告)号：WO2010065643A2
公开(公告)日：2010-06-10
申请号：PCT/US2009/066419
申请日：2009-12-02
申请人： THE TEXAS A&M UNIVERSITY SYSTEM , HOLTZAPPLE, Mark, T. , GRANDA, Cesar, B. , TACO, Sebastian , ROSS, Michael, Kyle , LUCE, Gary
发明人： HOLTZAPPLE, Mark, T. , GRANDA, Cesar, B. , TACO, Sebastian , ROSS, Michael, Kyle , LUCE, Gary
IPC分类号： C07C29/136 , C07C2/12 , C12P7/26 , C10L1/04
CPC分类号： C12P7/40 , C07C1/24 , C07C2/02 , C07C29/149 , C07C67/04 , C10G3/00 , C10G50/00 , C10G2300/1011 , C10G2300/4081 , C10G2300/42 , C10G2400/20 , C10G2400/22 , Y02P30/20 , C07C31/08 , C07C69/14
摘要： A method of producing alcohols, hydrocarbons, or both from biomass by converting biomass into a carboxylic acid, reacting the carboxylic acid with an olefin to produce an ester and hydrogenolyzing the ester to produce alcohol. A method of producing hydrocarbons from biomass by converting at least a portion of the biomass into a carboxylic acid, a ketone, or an ammonium carboxylate salt, reacting at least one of a portion of the carboxylic acid, a portion of the ketone, or a portion of the ammonium carboxylate salt in an oligomerization reactor as at least part of a process that produces an oligomerization product and separating hydrocarbons from the oligomerization product.
摘要翻译：通过将生物质转化成羧酸来生产醇，烃或两者的方法，使羧酸与烯烃反应以产生酯并且将所述酯氢解以产生醇。通过将生物质的至少一部分转化为羧酸，酮或羧酸铵盐，由生物质生产烃的方法，使至少一部分羧酸，部分酮或部分羧酸铵盐在低聚反应器中作为生产低聚产物和从低聚产物分离烃的方法的至少一部分。

8. 发明申请

WO2012078651A2 INTEGRATION OF FERMENTATION WITH MEMBRANE 审中-公开
标题翻译：发酵与膜的整合
公开(公告)号：WO2012078651A2
公开(公告)日：2012-06-14
申请号：PCT/US2011/063560
申请日：2011-12-06
申请人： TERRABON MIX-ALCO INC. , GRANDA, Cesar B.
发明人： GRANDA, Cesar B.
IPC分类号： C12P7/06 , C12P7/26 , C12P7/40 , C12P7/62 , C12P5/02 , C12M1/12
CPC分类号： B01D61/025 , B01D61/022 , B01D61/14 , B01D61/58 , B01D65/08 , B01D2311/04 , B01D2311/06 , B01D2311/08 , B01D2311/2673 , B01D2321/22 , C02F1/004 , C02F1/048 , C02F1/06 , C02F1/441 , C02F1/442 , C02F1/444 , C02F1/52 , C02F9/00 , C02F11/02 , C02F11/122 , C02F11/127 , C02F2301/046 , C02F2303/02 , C02F2303/24 , Y02E50/17 , B01D2311/2642 , B01D2311/2649 , B01D2311/25
摘要： Herein disclosed is a method comprising a) fermenting biomass to produce a fermentation broth; b) separating the fermentation broth into a liquid stream and a solid or slurry stream; c) passing the liquid stream through a reverse osmosis membrane to obtain a permeate and a retentate; and d) concentrating the retentate. Herein disclosed is a method comprising a) fermenting biomass in a first fermentor to produce a first fermentation broth; b) separating the first fermentation broth into a fist liquid stream and a first solid or slurry stream; c) introducing the first solid or slurry stream into a second fermentor to produce a second fermentation broth, wherein the second fermentor comprises a lower fermentation products concentration than the first fermentor; d) separating the second fermentation broth into a second liquid stream and a second solid or slurry stream; and e) passing the second liquid stream through a reverse osmosis membrane.
摘要翻译：本文公开的方法包括：a）发酵生物质以产生发酵液; b）将发酵液分离成液体流和固体或浆料流; c）使液体流通过反渗透膜以获得渗透物和渗余物; 和d）集中滞留物。本文公开的方法包括：a）在第一发酵罐中发酵生物质以产生第一发酵液; b）将第一发酵液分离成第一液体流和第一固体或浆料流; c）将第一固体或浆料流引入第二发酵罐以产生第二发酵液，其中第二发酵罐包含比第一发酵罐低的发酵产物浓度; d）将第二发酵液分离成第二液体流和第二固体或浆料流; 和e）使第二液体流通过反渗透膜。

9. 发明申请

WO2012078651A3 INTEGRATION OF FERMENTATION WITH MEMBRANE 审中-公开
标题翻译：发酵与膜的整合
公开(公告)号：WO2012078651A3
公开(公告)日：2012-12-27
申请号：PCT/US2011063560
申请日：2011-12-06
申请人： TERRABON MIX ALCO INC , GRANDA CESAR B
发明人： GRANDA CESAR B
IPC分类号： C12P7/06 , C12M1/12 , C12P5/02 , C12P7/26 , C12P7/40 , C12P7/62
CPC分类号： B01D61/025 , B01D61/022 , B01D61/14 , B01D61/58 , B01D65/08 , B01D2311/04 , B01D2311/06 , B01D2311/08 , B01D2311/2673 , B01D2321/22 , C02F1/004 , C02F1/048 , C02F1/06 , C02F1/441 , C02F1/442 , C02F1/444 , C02F1/52 , C02F9/00 , C02F11/02 , C02F11/122 , C02F11/127 , C02F2301/046 , C02F2303/02 , C02F2303/24 , Y02E50/17 , B01D2311/2642 , B01D2311/2649 , B01D2311/25
摘要： Herein disclosed is a method comprising a) fermenting biomass to produce a fermentation broth; b) separating the fermentation broth into a liquid stream and a solid or slurry stream; c) passing the liquid stream through a reverse osmosis membrane to obtain a permeate and a retentate; and d) concentrating the retentate. Herein disclosed is a method comprising a) fermenting biomass in a first fermentor to produce a first fermentation broth; b) separating the first fermentation broth into a fist liquid stream and a first solid or slurry stream; c) introducing the first solid or slurry stream into a second fermentor to produce a second fermentation broth, wherein the second fermentor comprises a lower fermentation products concentration than the first fermentor; d) separating the second fermentation broth into a second liquid stream and a second solid or slurry stream; and e) passing the second liquid stream through a reverse osmosis membrane.
摘要翻译：本文公开了一种方法，其包括a）发酵生物质以产生发酵液; b）将发酵液分离成液体流和固体或浆液流; c）使液体流通过反渗透膜以获得渗透物和渗余物; 和d）浓缩滞留物。本文公开了一种方法，其包括a）在第一发酵罐中发酵生物质以产生第一发酵液; b）将第一发酵液分离成第一液体流和第一固体或浆液流; c）将第一固体或淤浆物流引入第二发酵罐以产生第二发酵液，其中第二发酵罐包含比第一发酵罐更低的发酵产物浓度; d）将第二发酵液分离成第二液体流和第二固体或浆液流; 和e）使第二液体流通过反渗透膜。

10. 发明申请

WO2011139711A3 ANAEROBIC ORGANISMS IN A PROCESS FOR CONVERTING BIOMASS 审中-公开
标题翻译：生物质转化过程中的厌氧有机体
公开(公告)号：WO2011139711A3
公开(公告)日：2012-01-12
申请号：PCT/US2011033984
申请日：2011-04-26
申请人： TERRABON INC , TEXAS A & M UNIV SYS , GRANDA CESAR B , HOLTZAPPLE MARK T , HOLTZAPPLE ERIK
发明人： GRANDA CESAR B , HOLTZAPPLE MARK T , HOLTZAPPLE ERIK
IPC分类号： C12P5/02 , C12N1/14 , C12N1/20 , C12P7/62 , C12P7/64 , C12R1/01 , C12R1/645
CPC分类号： C12P5/00 , C12P7/06 , C12P7/6436 , C12P7/649 , Y02E50/13 , Y02E50/17 , Y02E50/343 , Y02T50/678
摘要： A method for integrating biological conversion of mixed acids to hydrocarbons, hydrocarbon-like molecules, biofuels, and combinations thereof. The method including introducing fermentation products to at least one microorganism chosen from the group consisting of heterotrophic microorganisms, photo-mixotrophic microorganisms, chemo-autotrophic microorganisms, and combinations thereof.
摘要翻译：将混合酸的生物转化与烃类，烃类分子，生物燃料及其组合相结合的方法。所述方法包括将发酵产物引入至少一种选自异养微生物，光混合营养微生物，化学自养微生物及其组合的微生物。

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