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1. 发明授权

US06194125B1 Preparation of photopolymeric letterpress printing plates 有权
标题翻译：光聚合凸版印刷版的制备
公开(公告)号：US06194125B1
公开(公告)日：2001-02-27
申请号：US09334178
申请日：1999-06-16
申请人： Friedrich Goffing , Thomas Loerzer , Hartmut Sandig , Markus Tönnessen
发明人： Friedrich Goffing , Thomas Loerzer , Hartmut Sandig , Markus Tönnessen
IPC分类号： G03F7095
CPC分类号： G03F7/202 , Y10S430/145
摘要： Photopolymeric letterpress printing plates which are to be developed with water or water/alcohol mixtures after imagewise exposure and have, arranged one on top of the other on a dimensionally stable substrate, a layer (A) which may be bonded to the dimensionally stable substrate by an adhesion-promoting layer and is crosslinkable by actinic radiation, a layer (B) which is sensitive to IR radiation and, if required, a parting layer arranged between layer (A) and layer (B), and a peelable protective film applied to the layer (B), are produced by a process in which the layer (A) contains a mixture of at least one polymeric binder which is soluble or dispersible in water or water/alcohol mixtures, copolymerizable ethylenically unsaturated organic compounds which are compatible with the polymeric binder and a photoinitiator, the layer (B) sensitive to IR radiation has an optical density ≧2.5 in the actinic range and contains a film-forming polymeric binder which is soluble or dispersible in water or water/alcohol mixtures and a substance which is finely distributed in this binder and absorbs IR radiation, and the layer (B) sensitive to IR radiation is structured by laser ablation and is then exposed uniformly to actinic radiation, developed and dried in a conventional manner. The novel process is suitable for the production of letterpress printing plates.
摘要翻译：在成像曝光后要用水或水/醇混合物显影的光聚合物凸版印刷版，并且在尺寸稳定的基材上排列成一层，其可以通过以下方式结合到尺寸稳定的基材上：（A）粘合促进层，通过光化辐射可交联，对IR辐射敏感的层（B），如果需要，布置在层（A）和层（B）之间的分离层）和可剥离的保护膜施加到层（B）通过其中层（A）含有可溶于或可分散在水或水/醇混合物中的至少一种聚合物粘合剂的混合物的方法制备，可共聚的烯属不饱和有机化合物与聚合物粘合剂和光引发剂，对IR辐射敏感的层（B）在光化范围内的光密度> = 2.5，并且含有可溶或可分散的成膜聚合物粘合剂在水或水/醇混合物中和精细分布在该粘合剂中并吸收IR辐射的物质，并且对IR辐射敏感的层（B）通过激光烧蚀构成，然后均匀地暴露于光化辐射，显影和干燥常规方法。新工艺适用于生产凸版印刷版。

2. 发明授权

US6037102A Multilayer recording element suitable for the production of flexographic printing plates by digital information transfer 失效
标题翻译：多层记录元件适用于通过数字信息传输生产柔版印刷版
公开(公告)号：US6037102A
公开(公告)日：2000-03-14
申请号：US721545
申请日：1996-09-26
申请人： Thomas Loerzer , Hartmut Sandig , Friedrich Goffing , Alfred Leinenbach , Hans-Jurgen Nisslmuller
发明人： Thomas Loerzer , Hartmut Sandig , Friedrich Goffing , Alfred Leinenbach , Hans-Jurgen Nisslmuller
IPC分类号： G03F7/095 , G03F1/00 , G03F7/00 , G03F7/30 , G03F7/32 , G03F7/34
CPC分类号： G03F7/30 , G03F7/202 , B41C1/05 , Y10S430/145 , Y10S430/146
摘要： A multilayer recording element is suitable for the production of flexographic printing plates by digital information transfer and has, arranged one on top of the other on a dimensionally stable substrate, a layer (A) crosslinkable by actinic radiation, a layer (B) sensitive to IR radiation and, if required, a peelable cover sheet, the layer (A) crosslinkable by actinic radiation being capable of being washed out by means of a developer after imagewise exposure and consisting essentially of a mixture of at least one elastomeric binder, ethylenically unsaturated copolymerizable organic compounds, a photoinitiator and, if required, further assistants, and the layer (B) sensitive to IR radiation being a layer which is soluble or dispersible in the developer and contains, in a film-forming binder having elastomeric character, at least one finely divided substance which has a high absorbance in the wavelength range from 750 to 20,000 nm.
摘要翻译：多层记录元件适用于通过数字信息传输生产柔性版印刷板，并且在尺寸稳定的基板上彼此重叠地布置由光化辐射可交联的层（A），对（B）敏感的层 IR辐射，并且如果需要，可剥离的覆盖片，通过光化辐射可交联的层（A）能够在成像曝光后通过显影剂被洗涤，并且基本上由至少一种弹性体粘合剂，烯属不饱和的可共聚的有机化合物，光引发剂和（如果需要的话）其它助剂，并且对IR辐射敏感的层（B）是可溶或可分散在显影剂中的层，并且至少具有弹性特征的成膜粘合剂一种在750至20,000nm波长范围内具有高吸光度的细碎物质。

3. 发明授权

US5124073A Continuous preparation of aqueous non-self-emulsifying polymer dispersions 失效
标题翻译：连续制备水性非自发聚合物分散体
公开(公告)号：US5124073A
公开(公告)日：1992-06-23
申请号：US476736
申请日：1990-02-08
申请人： Friedrich Goffing , Joerg Kroker , Rainer Nachtrab , Heino Thiele
发明人： Friedrich Goffing , Joerg Kroker , Rainer Nachtrab , Heino Thiele
IPC分类号： C08J3/02 , C08J3/03
CPC分类号： C08J3/03
摘要： Aqueous non-self-emulsifying polymer dispersions having small particles and a long shelf life and based on highly viscous reaction resins are prepared without the addition of solvents, by means of an intensively dispersing screw apparatus, by a continuous process in which the preparation of the polymer dispersion is carried out in an intensive shear zone of the screw apparatus, the water/reaction resin ratio in this intensive shear zone corresponding to the phase inversion point or being close to it, and the specific energy supply is 0.01-0.15 kWh/kg, the residence time is 0.1-60 sec and the shear gradient is 2,000-20,000 sec.sup.-1.
摘要翻译：通过连续的方法，通过连续方法制备具有小颗粒和长保质期并且基于高粘度反应树脂的水性非自乳化聚合物分散体，而不通过浓缩分散螺杆装置添加溶剂，其中制备聚合物分散体在螺旋装置的强剪切区域中进行，该强化剪切区域中的水/反应树脂比率对应于相转化点或接近相转变点，比能量供应量为0.01-0.15kWh / kg ，停留时间为0.1-60秒，剪切梯度为2,000-20,000秒-1。

4. 发明申请

US20070037934A1 Method for the production of copolymers 审中-公开
标题翻译：制备共聚物的方法
公开(公告)号：US20070037934A1
公开(公告)日：2007-02-15
申请号：US10572093
申请日：2004-09-14
申请人： Matthias Kluglein , Bernhard Lehmann , Stephan Huffer , Friedrich Goffing , Tanja Schneider , Helmut Gumbel
发明人： Matthias Kluglein , Bernhard Lehmann , Stephan Huffer , Friedrich Goffing , Tanja Schneider , Helmut Gumbel
IPC分类号： C08F12/08
CPC分类号： C08G65/329 , C08F8/44 , C08F267/00 , C08F267/04 , C08F283/06 , C08L51/003 , C08L51/08 , C11D3/3757 , C11D3/3769 , C14C3/22 , C08L2666/02 , C08F8/12 , C08F222/08 , C08F212/08 , C08F222/06
摘要： A process for preparing copolymers which comprises copolymerizing (A) at least one ethylenically unsaturated dicarboxylic anhydride derived from at least one dicarboxylic acid having 4 to 8 carbon atoms, (B) at least one vinylaromatic compound, and (C) optionally at least one non-(A) ethylenically unsaturated comonomer containing at least one heteroatom, (D) reacting the copolymer with at least one compound of the formula I a or I b where A1 is C2-C20 alkylene, identical or different, R1 is C1-C30 alkyl, linear or branched, and n is an integer from 1 to 200, hydrolyzing the product with water or an aqueous alkaline solution, and subsequent to hydrolysis adding further free-radical initiator.
摘要翻译：一种制备共聚物的方法，其包括使（A）至少一种衍生自至少一种具有4-8个碳原子的二羧酸的烯键式不饱和二羧酸酐，（B）至少一种乙烯基芳族化合物和（C）任选的至少一种非 - - （A）含有至少一个杂原子的烯属不饱和共聚单体，（D）使共聚物与至少一种式I a或I b的化合物反应，其中A 1是C 2 - 亚烷基，相同或不同，R 1是C 1 -C 30烷基，直链或支链C 1 -C 20烷基，或分支，n为1至200的整数，用水或碱性水溶液水解产物，并在水解后加入另外的自由基引发剂。

5. 发明授权

US6020108A Preparation of photopolymeric letterpress printing plates 失效
标题翻译：光聚合凸版印刷版的制备
公开(公告)号：US6020108A
公开(公告)日：2000-02-01
申请号：US721534
申请日：1996-09-26
申请人： Friedrich Goffing , Thomas Loerzer , Hartmut Sandig , Markus Tonnessen
发明人： Friedrich Goffing , Thomas Loerzer , Hartmut Sandig , Markus Tonnessen
IPC分类号： G03F7/004 , B41C1/055 , B41N1/12 , G03F1/00 , G03F7/00 , G03F7/027 , G03F7/028 , G03F7/033 , G03F7/11 , G03F7/095
CPC分类号： G03F7/202 , Y10S430/145
摘要： Photopolymeric letterpress printing plates which are to be developed with water or water/alcohol mixtures after imagewise exposure and have, arranged one on top of the other on a dimensionally stable substrate, a layer (A) which may be bonded to the dimensionally stable substrate by an adhesion-promoting layer and is crosslinkable by actinic radiation, a layer (B) which is sensitive to IR radiation and, if required, a parting layer arranged between layer (A) and layer (B), and a peelable protective film applied to the layer (B), are produced by a process in which the layer (A) contains a mixture of at least one polymeric binder which is soluble or dispersible in water or water/alcohol mixtures, copolymerizable ethylenically unsaturated organic compounds which are compatible with the polymeric binder and a photoinitiator, the layer (B) sensitive to IR radiation has an optical density.gtoreq.2.5 in the actinic range and contains a film-forming polymeric binder which is soluble or dispersible in water or water/alcohol mixtures and a substance which is finely distributed in this binder and absorbs IR radiation, and the layer (B) sensitive to IR radiation is structured by laser ablation and is then exposed uniformly to actinic radiation, developed and dried in a conventional manner. The novel process is suitable for the production of letterpress printing plates.
摘要翻译：在成像曝光后要用水或水/醇混合物显影的光聚合物凸版印刷版，并且在尺寸稳定的基材上排列成一层，其可以通过以下方式结合到尺寸稳定的基材上：（A）粘合促进层，通过光化辐射可交联，对IR辐射敏感的层（B），如果需要，布置在层（A）和层（B）之间的分离层）和可剥离的保护膜施加到层（B）通过其中层（A）含有可溶于或可分散在水或水/醇混合物中的至少一种聚合物粘合剂的混合物的方法制备，可共聚的烯属不饱和有机化合物与聚合物粘合剂和光引发剂，对IR辐射敏感的层（B）在光化范围内具有≥2.5的光密度，并且包含可溶或可分散的成膜聚合物粘合剂在水或水/醇混合物中和精细分布在该粘合剂中并吸收IR辐射的物质，并且对IR辐射敏感的层（B）通过激光烧蚀构成，然后均匀地暴露于光化辐射，显影和干燥常规方式。该新型工艺适用于生产凸版印刷版。

6. 发明授权

US5593811A Multilayer, sheet-like, photosensitive recording material for the production of printing plates 失效
标题翻译：用于生产印版的多层，片状，感光记录材料
公开(公告)号：US5593811A
公开(公告)日：1997-01-14
申请号：US576770
申请日：1995-12-21
申请人： Thomas Loerzer , Stefan Wegener , Friedrich Goffing
发明人： Thomas Loerzer , Stefan Wegener , Friedrich Goffing
IPC分类号： B32B27/00 , G03F7/00 , G03F7/11 , G03C11/12 , G03C1/805 , G03C1/85 , G03F7/30
CPC分类号： G03F7/11
摘要： (A) being a photosensitive relief-forming layer in which imagewise exposure to actinic light results in different solubilities of the exposed and unexposed parts, and this layer consists of a mixture of:(a1)one or more polymeric binders,(a2)one or more photopolymerization initiators,(a3)one or more organic compounds which are compatible with the binder (a1) and contain photopolymerizable olefinically unsaturated groups and, if required,(a4)one or more assistants,(B) being a smooth or dull, nontacky release layer (B) which is transparent to light, soluble or swellable in the relevant liquid media and formed by a polymer forming strong films and additives contained therein, and(C) being a cover sheet which can be detached from the release layer (B), the release layer (B) containing a metal salt as an additive,is suitable for the production of printing plates.
摘要翻译：（A）是光敏浮雕形成层，其中成像曝光于光化光导致暴露和未曝光部分的不同溶解度，并且该层由以下混合物组成：（a1）一种或多种聚合物粘合剂，（a2）一种或更多的光聚合引发剂，（a3）一种或多种与粘合剂（a1）相容并含有可光聚合的烯属不饱和基团的有机化合物，如果需要，（a4）一种或多种助剂，（B）光滑或无光泽，非粘性释放层（B），其在相关液体介质中对于光可溶或可膨胀是透明的，并且由形成其中所含的强膜和添加剂的聚合物形成，和（C）可以从剥离层分离的覆盖片（ B），含有金属盐作为添加剂的剥离层（B）适用于制造印刷版。

7. 发明授权

US5094797A Preparation of pigmented curable polyester molding compounds 失效
标题翻译：可固化聚酯模塑料的制备
公开(公告)号：US5094797A
公开(公告)日：1992-03-10
申请号：US588536
申请日：1990-09-26
申请人： Helmut Heel , Jan Holoch , Gerd Esswein , Friedrich Goffing
发明人： Helmut Heel , Jan Holoch , Gerd Esswein , Friedrich Goffing
IPC分类号： C08F283/01 , C08F299/04 , C08J3/22 , C08K3/04 , C08L67/06
CPC分类号： C08J3/226 , C08K3/04 , C08L67/06 , C08J2367/06 , Y10S525/935
摘要： Pigmented curable polyester molding compounds which cure to give homogeneously colored moldings contain an unsaturated polyester, copolymerizable monomers, a thermoplastic polymer and a color pigment and are prepared by dispersing the pigment in the molten thermoplastic in an extruder.
摘要翻译：固化得到均匀着色的模制品的着色固化性聚酯模塑料包含不饱和聚酯，可共聚单体，热塑性聚合物和着色颜料，并通过将颜料分散在熔融热塑性塑料中而制备。

8. 发明授权

US06190832B1 Preparation of photopolymeric gravure printing plates 失效
标题翻译：光聚合凹版印刷板的制备
公开(公告)号：US06190832B1
公开(公告)日：2001-02-20
申请号：US09181458
申请日：1998-10-28
申请人： Friedrich Goffing , Thomas Loerzer , Hartmut Sandig , Markus Tönnessen
发明人： Friedrich Goffing , Thomas Loerzer , Hartmut Sandig , Markus Tönnessen
IPC分类号： G03F100
CPC分类号： G03F7/202 , Y10S430/145
摘要： Photopolymeric gravure printing plates which are to be developed with water or water/alcohol mixtures after imagewise exposure and have, arranged one on top of the other on a dimensionally stable substrate, a layer (A) which may be bonded to the dimensionally stable substrate by an adhesion-promoting layer and is crosslinkable by actinic radiation, a layer (B) which is sensitive to IR radiation and, if required, a parting layer arranged between layer (A) and layer (B), and a peelable protective film applied to the layer (B), are produced by a process in which the layer (A) consists of a mixture of at least one polymeric binder which is soluble or dispersible in water or water/alcohol mixtures, copolymerizable ethylenically unsaturated organic compounds which are compatible with this polymeric binder, a photoinitiator or photoinitiator system and, if required, further assistants, the parting layer which may be arranged between layer (A) and layer (B) is oxygen-permeable and the layer (B) sensitive to IR radiation has an optical density ≧2.5 in the actinic range and contains a film-forming polymeric binder which is soluble or dispersible in water or water/alcohol mixtures and at least one substance which is finely distributed in this binder, absorbs IR radiation and has a high absorbence in the wavelength range from 750 to 20,000 nm, the layer (B) sensitive to IR radiation is structured by laser ablation after the protective film has been peeled off and is then exposed uniformly to actinic radiation, developed with water or water/alcohol mixtures and dried in a conventional manner. The novel process is suitable for the production of gravure printing plates.
摘要翻译：在成像曝光后要用水或水/醇混合物显影的光聚合凹版印刷版，并且在尺寸稳定的基材上排列成彼此的尺寸稳定的基底上的层（A），其可以通过粘合促进层，通过光化辐射可交联，对IR辐射敏感的层（B），如果需要，布置在层（A）和层（B）之间的分离层）和可剥离的保护膜施加到层（B）通过其中层（A）由至少一种可溶于或可分散在水或水/醇混合物中的聚合物粘合剂的混合物组成的方法制备，可共聚的烯键式不饱和有机化合物与该聚合物粘合剂，光引发剂或光引发剂体系，并且如果需要，还可以使用其它助剂，可以布置在层（A）和层（B）之间的分离层是透氧的，并且层（B 对于IR辐射敏感的光学密度在光化范围内具有≥2.5的光密度，并且包含可溶于或分散于水或水/醇混合物中的成膜聚合物粘合剂，以及精细分布在该粘合剂中的至少一种物质，红外辐射，并且在750〜20000nm的波长范围内具有高吸收度，在保护膜被剥离后，对激光烧蚀构成对红外线辐射敏感的层（B），然后均匀地暴露于光化辐射下，与水或水/醇混合物，并以常规方式干燥。该新方法适用于生产凹版印刷版。

9. 发明授权

US5994032A Preparation of photopolymeric gravure printing plates 失效
标题翻译：光聚合凹版印刷板的制备
公开(公告)号：US5994032A
公开(公告)日：1999-11-30
申请号：US721536
申请日：1996-09-26
申请人： Friedrich Goffing , Thomas Loerzer , Hartmut Sandig , Markus Tonnessen
发明人： Friedrich Goffing , Thomas Loerzer , Hartmut Sandig , Markus Tonnessen
IPC分类号： G03F7/004 , B41C1/10 , B41N1/12 , G03F1/00 , G03F7/027 , G03F7/028 , G03F7/033 , G03F7/11 , G03F7/095 , G03F7/36
CPC分类号： G03F7/202 , Y10S430/145
摘要： Photopolymeric gravure printing plates which are to be developed with water or water/alcohol mixtures after imagewise exposure and have, arranged one on top of the other on a dimensionally stable substrate, a layer (A) which may be bonded to the dimensionally stable substrate by an adhesion-promoting layer and is crosslinkable by actinic radiation, a layer (B) which is sensitive to IR radiation and, if required, a parting layer arranged between layer (A) and layer (B), and a peelable protective film applied to the layer (B), are produced by a process in which the layer (A) consists of a mixture of at least one polymeric binder which is soluble or dispersible in water or water/alcohol mixtures, copolymerizable ethylenically unsaturated organic compounds which are compatible with this polymeric binder, a photoinitiator or photoinitiator system and, if required, further assistants, the parting layer which may be arranged between layer (A) and layer (B) is oxygen-permeable and the layer (B) sensitive to IR radiation has an optical density .gtoreq.2.5 in the actinic range and contains a film-forming polymeric binder which is soluble or dispersible in water or water/alcohol mixtures and at least one substance which is finely distributed in this binder, absorbs IR radiation and has a high absorbence in the wavelength range from 750 to 20,000 nm, the layer (B) sensitive to IR radiation is structured by laser ablation after the protective film has been peeled off and is then exposed uniformly to actinic radiation, developed with water or water/alcohol mixtures and dried in a conventional manner. The novel process is suitable for the production of gravure printing plates.
摘要翻译：在成像曝光后要用水或水/醇混合物显影的光聚合凹版印刷版，并且在尺寸稳定的基材上排列成彼此的尺寸稳定的基底上的层（A），其可以通过粘合促进层，通过光化辐射可交联，对IR辐射敏感的层（B），如果需要，布置在层（A）和层（B）之间的分离层）和可剥离的保护膜施加到层（B）通过其中层（A）由至少一种可溶于或可分散在水或水/醇混合物中的聚合物粘合剂的混合物组成的方法制备，可共聚的烯键式不饱和有机化合物与该聚合物粘合剂，光引发剂或光引发剂体系，并且如果需要，还可以使用其它助剂，可以布置在层（A）和层（B）之间的分离层是透氧的，并且层（B 对于IR辐射敏感的光学密度在光化范围内具有> / = 2.5的光密度，并且包含可溶于或分散于水或水/醇混合物中的成膜聚合物粘合剂和精细分布在该粘合剂中的至少一种物质，吸收红外辐射，并且在750至20,000nm的波长范围内具有高吸收度，在保护膜已经被剥离并然后均匀地暴露于光化辐射之后，对IR辐射敏感的层（B）由激光烧蚀构成，然后均匀地暴露于光化辐射用水或水/醇混合物，并以常规方式干燥。该新型工艺适用于生产凹版印刷版。

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