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1. 发明授权

US07453013B2 Catalytic method for the production of carbonyl compounds 失效
公开(公告)号：US07453013B2
公开(公告)日：2008-11-18
申请号：US11898339
申请日：2007-09-11
申请人： Franco Antognoli , Paul Rys
发明人： Franco Antognoli , Paul Rys
IPC分类号： C07C45/28
CPC分类号： B01J31/0218 , B01J31/0215 , B01J31/28 , B01J2231/70 , C07C45/28
摘要： The invention relates to a catalytic method for the production of aliphatic and aromatic carbonyl compounds with at least one aldehyde or ketone function, whereby said compounds can also comprise at least one aldehyde and ketone function. A starting material comprising at least one aliphatic- and/or aromatic-bonded functional group of formula (I), where R1═H, alkyl or aryl, X═H, or a group which may be substituted by the sulphinyl group of a sulphoxide during the catalytic reaction, n=a whole number from 1 to 8, is oxidised in the presence of a sulphoxide and/or a sulphide and the presence of iron salts or redox pairs of iron/copper or silver/copper salts, by means of an oxidising agent with a redox potential of E0>+2 V vs. NHE, whereby the sulphoxide or sulphide has a catalytic function. The method permits the production of carbonyl compounds, in particular, (poly)aldehydes and (poly)ketones with high selectivity, whereby the formation of alcohols and carboxylic acids, dimerisation products and other by-products is reduced to a minimum or essentially prevented. The final products obtained find application as important intermediates and final products.

2. 发明授权

US07273954B2 Catalytic method for the production of carbonyl compounds 有权
标题翻译：用于生产羰基化合物的催化方法
公开(公告)号：US07273954B2
公开(公告)日：2007-09-25
申请号：US10534878
申请日：2003-11-14
申请人： Franco Antognoli , Paul Rys
发明人： Franco Antognoli , Paul Rys
IPC分类号： C07C45/28
CPC分类号： B01J31/0218 , B01J31/0215 , B01J31/28 , B01J2231/70 , C07C45/28
摘要： The invention relates to a catalytic method for the production of aliphatic and aromatic carbonyl compounds with at least one aldehyde or ketone function, whereby said compounds can also comprise at least one aldehyde and ketone function. A starting material comprising at least one aliphatic- and/or aromatic-bonded functional group of formula (I), where R1=H, alkyl or aryl, X=H, or a group which may be substituted by the sulphinyl group of a sulphoxide during the catalytic reaction, n=a whole number from 1 to 8, is oxidised in the presence of a sulphoxide and/or a sulphide and the presence of iron salts or redox pairs of iron/copper or silver/copper salts, by means of an oxidising agent with a redox potential of Eo>+2 V vs. NHE, whereby the sulphoxide or sulphide has a catalytic function. The method permits the production of carbonyl compounds, in particular, (poly)aldehydes and (poly)ketones with high selectivity, whereby the formation of alcohols and carboxylic acids, dimerisation products and other by-products is reduced to a minimum or essentially prevented. The final products obtained find application as important intermediates and final products.
摘要翻译：本发明涉及一种生产具有至少一种醛或酮官能团的脂族和芳族羰基化合物的催化方法，其中所述化合物还可以包含至少一种醛和酮官能团。包含至少一种式（I）的脂族 - 和/或芳基键合官能团的起始材料，其中R 1 = H，烷基或芳基，X = H或可以是在催化反应期间由亚砜的亚磺酰基取代，n = 1至8的整数，在亚砜和/或硫化物的存在下被氧化，并且铁/铜的铁盐或氧化还原对的存在或银/铜盐，通过氧化还原电位与NHE的氧化还原电位相反，由此亚砜或硫化物具有催化功能。该方法允许以高选择性生产羰基化合物，特别是（多）醛和（聚）酮，由此将醇和羧酸，二聚产物和其它副产物的形成降低到最小或基本上被预防。获得的最终产品可用作重要的中间体和最终产品。

3. 发明申请

US20080004474A1 Catalytic method for the production of carbonyl compounds 失效
标题翻译：用于生产羰基化合物的催化方法
公开(公告)号：US20080004474A1
公开(公告)日：2008-01-03
申请号：US11898339
申请日：2007-09-11
申请人： Franco Antognoli , Paul Rys
发明人： Franco Antognoli , Paul Rys
IPC分类号： C07C45/28
CPC分类号： B01J31/0218 , B01J31/0215 , B01J31/28 , B01J2231/70 , C07C45/28
摘要： The invention relates to a catalytic method for the production of aliphatic and aromatic carbonyl compounds with at least one aldehyde or ketone function, whereby said compounds can also comprise at least one aldehyde and ketone function. A starting material comprising at least one aliphatic- and/or aromatic-bonded functional group of formula (I), where R1═H, alkyl or aryl, X═H, or a group which may be substituted by the sulphinyl group of a sulphoxide during the catalytic reaction, n=a whole number from 1 to 8, is oxidised in the presence of a sulphoxide and/or a sulphide and the presence of iron salts or redox pairs of iron/copper or silver/copper salts, by means of an oxidising agent with a redox potential of E0>+2 V vs. NHE, whereby the sulphoxide or sulphide has a catalytic function. The method permits the production of carbonyl compounds, in particular, (poly)aldehydes and (poly)ketones with high selectivity, whereby the formation of alcohols and carboxylic acids, dimerisation products and other by-products is reduced to a minimum or essentially prevented. The final products obtained find application as important intermediates and final products.
摘要翻译：本发明涉及一种生产具有至少一种醛或酮官能团的脂族和芳族羰基化合物的催化方法，其中所述化合物还可以包含至少一种醛和酮官能团。包含至少一种式（I）的脂族 - 和/或芳族键合的官能团的原料，其中R 1 -H，烷基或芳基，XH或可以被在亚锡和/或硫化物的存在下，在催化反应期间n = 1至8的整数的亚砜的亚硫酰基被氧化，并且铁/铜或银/铜的铁盐或氧化还原对的存在，铜盐，通过氧化还原电位为E 0 O 2 + + 2V对NHE的氧化剂，由此亚砜或硫化物具有催化功能。该方法允许以高选择性生产羰基化合物，特别是（多）醛和（聚）酮，由此将醇和羧酸，二聚产物和其它副产物的形成降低到最小或基本上被预防。获得的最终产品可用作重要的中间体和最终产品。

4. 发明申请

US20060135817A1 Catalytic method for the production of carbonyl compounds 有权
标题翻译：用于生产羰基化合物的催化方法
公开(公告)号：US20060135817A1
公开(公告)日：2006-06-22
申请号：US10534878
申请日：2003-11-14
申请人： Franco Antognoli , Paul Rys
发明人： Franco Antognoli , Paul Rys
IPC分类号： C07C45/28
CPC分类号： B01J31/0218 , B01J31/0215 , B01J31/28 , B01J2231/70 , C07C45/28
摘要： The invention relates to a catalytic method for the production of aliphatic and aromatic carbonyl compounds with at least one aldehyde or ketone function, whereby said compounds can also comprise at least one aldehyde and ketone function. A starting material comprising at least one aliphatic- and/or aromatic-bonded functional group of formula (I), where R1=H, alkyl or aryl, X=H, or a group which may be substituted by the sulphinyl group of a sulphoxide during the catalytic reaction, n=a whole number from 1 to 8, is oxidised in the presence of a sulphoxide and/or a sulphide and the presence of iron salts or redox pairs of iron/copper or silver/copper salts, by means of an oxidising agent with a redox potential of Eo>+2 V vs. NHE, whereby the sulphoxide or sulphide has a catalytic function. The method permits the production of carbonyl compounds, in particular, (poly)aldehydes and (poly)ketones with high selectivity, whereby the formation of alcohols and carboxylic acids, dimerisation products and other by-products is reduced to a minimum or essentially prevented. The final products obtained find application as important intermediates and final products.
摘要翻译：本发明涉及一种生产具有至少一种醛或酮官能团的脂族和芳族羰基化合物的催化方法，其中所述化合物还可以包含至少一种醛和酮官能团。包含至少一种式（I）的脂族 - 和/或芳基键合官能团的起始材料，其中R 1 = H，烷基或芳基，X = H或可以是在催化反应期间由亚砜的亚磺酰基取代，n = 1至8的整数，在亚砜和/或硫化物的存在下被氧化，并且铁/铜的铁盐或氧化还原对的存在或银/铜盐，通过氧化还原电位与NHE的氧化还原电位相反，由此亚砜或硫化物具有催化功能。该方法允许以高选择性生产羰基化合物，特别是（多）醛和（聚）酮，由此将醇和羧酸，二聚产物和其它副产物的形成降低到最小或基本上被预防。获得的最终产品可用作重要的中间体和最终产品。

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