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    • 7. 发明授权
    • Functionalization of carbon nanotubes
    • 碳纳米管的功能化
    • US07807127B1
    • 2010-10-05
    • US11417294
    • 2006-04-14
    • Farhad ForoharCraig WhitakerWilliam M. Koppes
    • Farhad ForoharCraig WhitakerWilliam M. Koppes
    • D01F9/12
    • B82Y40/00B82Y10/00B82Y30/00C01B32/174C01B2202/02H01L51/0049Y10S977/745Y10S977/748
    • The present invention relates to a carbon nanotube that contains nitrogen based functional groups (such as nitro, nitroso, N-oxide, oxime, hydroxylamine, diazo, azo, and azide) that are covalently attached to lattice carbons of the carbon nanotube, directly or via a chemical linker. The present invention also relates to methods for the preparation of the carbon nanotube from an amino-functionalized carbon nanotube via an amino oxidation reaction. The synthetic methods of the present invention allow the nitrogen based functional groups to be attached selectively to one of two distinct regions of the carbon nanotube, the ends or the sidewall, and thus enable the synthesis of a carbon nanotube having nitrogen based functional groups substantially concentrated on either the ends or the sidewall of the carbon nanotube.
    • 本发明涉及碳纳米管,其直接或间接地共价连接到碳纳米管的格子状碳上的氮基官能团(例如硝基,亚硝基,N-氧化物,肟,羟胺,重氮,偶氮和叠氮化物) 通过化学接头。 本发明还涉及通过氨基氧化反应从氨基官能化的碳纳米管制备碳纳米管的方法。 本发明的合成方法允许氮基官能团选择性地连接到碳纳米管,末端或侧壁的两个不同区域中的一个,从而能够合成具有基本上浓度的基于氮的官能团的碳纳米管 在碳纳米管的两端或侧壁上。
    • 8. 发明授权
    • Spiro(N,N'-dinitroethylenediamino)cyclotriphosphazenes
    • 螺(N,N'-二硝基亚乙基二氨基)环三磷腈
    • US5352829A
    • 1994-10-04
    • US42229
    • 1993-04-02
    • Paritosh R. DaveFarhad ForoharMichael ChaykovskyClifford D. Bedford
    • Paritosh R. DaveFarhad ForoharMichael ChaykovskyClifford D. Bedford
    • C06B25/34C07F9/6593C07F9/547
    • C06B25/34C07F9/65815
    • Energetic nitramine containing cyclotriphosphazene which include 1,1,3,3,-tris-spiro(N,N'-dinitroethylenediamino)cyclotriphosphazene, 1,1-spiro(ethylenediamino)-3,3,5,5-bis-spiro(N,N'-dinitroethylenediamino)cyclotriphosphazene, 1,1,3,3-bis-spiro(N,N'-dinitroethylenediamino)-5,5-dichlorocyclotriphosphazene, 1,1,3,3-bis-spiro(N,N'-dinitroethylenediamino)-5,5-difluorocyclotriphosphazene, 1,1-spiro(N,N'-dinitroethylenediamino)-3,3,5,5-bis-spiro(ethylenediamino)cyclotriphosphazene, 1,1-spiro(ethylenediamino)-3,3-spiro(N,N'-dinitroethylenediamino)-5,5-dichlorocyclotriphosphazene, 1,1-spiro(ethylenediamino)-3,3-spiro(N,N'-dinitroethylenediamino)-5,5-difluorocyclotriphosphazene, 1,1-spiro(N,N'-dinitroethylenediamino)-3,3,5,5-tetrachlorocyclotriphosphazene, and 1,1-spiro(N,N'-dinitroethylenediamino)-3,3,5,5-tetrafluorocyclotriphosphazene, which can be used in explosive compositions.
    • 含有环三磷腈的含能量的硝胺包括1,1,3,3,5,5-三螺(N,N'-二硝基亚乙基二氨基)环三磷腈,1,1-螺(乙二胺基)-3,3,5,5-双 - 螺(N,N'-二硝基亚乙基二氨基)环三磷腈,1,1,3,3-双螺(N,N'-二硝基亚乙基二氨基)-5,5-二氯环三磷腈,1,1,3,3-双螺(N ,N'-二硝基亚乙基二氨基)-5,5-二氟环三磷腈,1,1-螺(N,N'-二硝基亚乙基二氨基)-3,3,5,5-双螺(乙二氨基)环三磷腈,1,1-螺(乙二胺基 )-3,3-螺(N,N'-二硝基亚乙基二氨基)-5,5-二氯环三磷腈,1,1-螺(乙二胺基)-3,3-螺(N,N'-二硝基亚乙基二氨基)-5,5-二氟环三磷腈 ,1,1-螺(N,N'-二硝基亚乙基二氨基)-3,3,5,5-四氯环三磷腈和1,1-螺(N,N'-二硝基亚乙基二氨基)-3,3,5,5-四氟环三磷腈, 可用于爆炸性组合物。