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1. 发明公开

EP0591538A1 PROCESS FOR PRODUCING DIMETHYL ETHER 失效
标题翻译： Verfahren zur Herstellung vonDimethyläther。
公开(公告)号：EP0591538A1
公开(公告)日：1994-04-13
申请号：EP92923527.3
申请日：1992-11-11
申请人： FUJIMOTO, Kaoru , NKK CORPORATION
发明人： FUJIMOTO, Kaoru , SHIKADA, Tsutomu , YAMAOKA, Yojiro , SUMIGAMA, Takashi
IPC分类号： C07C43/04 , C07C41/01 , C07C41/09 , B01J23/26 , B01J23/80 , B01J23/86 , B01J29/06
CPC分类号： C07C41/01 , C07C43/043
摘要： A process for producing dimethyl ether from a gaseous mixture comprising carbon monoxide, hydrogen and/or steam, and optionally further carbon dioxide, wherein use is made of either a catalyst prepared by pulverizing a catalytic mixture comprising at least zinc oxide, copper or chromium oxide, and aluminum oxide, compacting the mixture on a high-pressure press, and again pulverizing the compacted mixture, or a catalytic mixture comprising at least zinc oxide, copper oxide and alumina in the form of a slurry suspended in a solvent. This process gives dimethyl ether in a high yield, allows a high conversion of water formed by the reaction into hydrogen, and is free from the problem of clogging caused by the catalyst, and no mechanical strength is required of the catalyst. The process has further advantages such that the carbon monoxide to hydrogen ratio can be widely varied, that the reaction can be conducted even in the presence of carbon dioxide with high concentration, and impurities and catalyst poison little affect the reaction.
摘要翻译：一种从包含一氧化碳，氢气和/或蒸汽的气体混合物和任选的另外的二氧化碳生产二甲醚的方法，其中使用通过粉碎至少包含氧化锌，铜或铬氧化物的催化混合物制备的催化剂和氧化铝，在高压压机上压实混合物，再次粉碎压实的混合物，或至少包含氧化锌，氧化铜和氧化铝的悬浮在溶剂中的浆料形式的催化混合物。该方法以高产率提供二甲醚，允许将通过反应形成的水的高转化率转化为氢气，并且不存在由催化剂引起的堵塞的问题，并且催化剂不需要机械强度。该方法具有能够广泛变化的一氧化碳与氢的比例的优点，即使在高浓度的二氧化碳的存在下也能够进行反应，并且杂质和催化剂毒性对反应几乎没有影响。

2. 发明专利

DE3324570C2 未知
公开(公告)号：DE3324570C2
公开(公告)日：1986-10-16
申请号：DE3324570
申请日：1983-07-07
申请人： ISHIKAWAJIMA-HARIMA JUKOGYO K.K., TOKIO/TOKYO, JP , TOMINAGA, HIROO, MATSUDO, CHIBA, JP , FUJIMOTO, KAORU, TOKYO, JP , SHIKADA, TSUTOMU, TOKIO/TOKYO, JP
发明人： TOMINAGA, HIROO, PROF., MATSUDO, CHIBA, JP , FUJIMOTO, KAORU, PROF. , SHIKADA, TSUTOMU, TOKIO/TOKYO, JP
IPC分类号： B01D53/94 , B01D53/50 , B01D53/60 , B01D53/74 , B01D53/81 , B01D53/86 , B01D53/34
摘要： A process for purifying exhaust gases is disclosed. Exhaust gases discharged when coal or petroleum is burned are forced to pass through reaction media consisting of molten salts whose major component is a hydrogensulfate or hydrogensulfates, whereby desulfurization and denitration can be effected by one step. Harmful compounds such as sulfur oxides, nitrogen oxides and dust particles in the exhaust gases can be efficiently removed and the purified gases can be smoothly diffused.

3. 发明专利

GB2124606A PURIFYING EXHAUST GASES 未知
公开(公告)号：GB2124606A
公开(公告)日：1984-02-22
申请号：GB8318538
申请日：1983-07-08
申请人： ISHIKAWAJIMA HARIMA HEAVY IND , TOMINAGA HIROO , FUJIMOTO KAORU , SHIKADA TSUTOMU
发明人： TOMINAGA HIROO , FUJIMOTO KAORU , SHIKADA TSUTOMU
IPC分类号： B01D53/94 , B01D53/50 , B01D53/60 , B01D53/74 , B01D53/81 , B01D53/86
摘要： A process for purifying exhaust gases is disclosed. Exhaust gases discharged when coal or petroleum is burned are forced to pass through reaction media consisting of molten salts whose major component is a hydrogensulfate or hydrogensulfates, whereby desulfurization and denitration can be effected by one step. Harmful compounds such as sulfur oxides, nitrogen oxides and dust particles in the exhaust gases can be efficiently removed and the purified gases can be smoothly diffused.

4. 发明专利

GB2124606B PURIFYING EXHAUST GASES 未知
公开(公告)号：GB2124606B
公开(公告)日：1985-11-20
申请号：GB8318538
申请日：1983-07-08
申请人： ISHIKAWAJIMA HARIMA HEAVY IND , TOMINAGA HIROO , FUJIMOTO KAORU , SHIKADA TSUTOMU
发明人： TOMINAGA HIROO , FUJIMOTO KAORU , SHIKADA TSUTOMU
IPC分类号： B01D53/94 , B01D53/50 , B01D53/60 , B01D53/74 , B01D53/81 , B01D53/86
摘要： A process for purifying exhaust gases is disclosed. Exhaust gases discharged when coal or petroleum is burned are forced to pass through reaction media consisting of molten salts whose major component is a hydrogensulfate or hydrogensulfates, whereby desulfurization and denitration can be effected by one step. Harmful compounds such as sulfur oxides, nitrogen oxides and dust particles in the exhaust gases can be efficiently removed and the purified gases can be smoothly diffused.

5. 发明专利

DE3324570A1 未知
公开(公告)号：DE3324570A1
公开(公告)日：1984-01-12
申请号：DE3324570
申请日：1983-07-07
申请人： ISHIKAWAJIMA HARIMA HEAVY IND , TOMINAGA HIROO , FUJIMOTO KAORU , SHIKADA TSUTOMU
发明人： TOMINAGA HIROO PROF , FUJIMOTO KAORU PROF , SHIKADA TSUTOMU
IPC分类号： B01D53/94 , B01D53/50 , B01D53/60 , B01D53/74 , B01D53/81 , B01D53/86 , B01D53/34
摘要： A process for purifying exhaust gases is disclosed. Exhaust gases discharged when coal or petroleum is burned are forced to pass through reaction media consisting of molten salts whose major component is a hydrogensulfate or hydrogensulfates, whereby desulfurization and denitration can be effected by one step. Harmful compounds such as sulfur oxides, nitrogen oxides and dust particles in the exhaust gases can be efficiently removed and the purified gases can be smoothly diffused.

6. 发明公开

EP0591538A4 PROCESS FOR PRODUCING DIMETHYL ETHER. 失效
标题翻译：一种用于制备二甲醚的过程。
公开(公告)号：EP0591538A4
公开(公告)日：1995-01-04
申请号：EP92923527
申请日：1992-11-11
申请人： FUJIMOTO KAORU , NIPPON KOKAN KK
发明人： FUJIMOTO KAORU , SHIKADA TSUTOMU , YAMAOKA YOJIRO , SUMIGAMA TAKASHI
IPC分类号： C07C41/01 , C07C43/04 , B01J23/26 , B01J23/80 , B01J23/86 , B01J29/06 , C07C41/09
CPC分类号： C07C41/01 , C07C43/043
摘要： A process for producing dimethyl ether from a gaseous mixture comprising carbon monoxide, hydrogen and/or steam, and optionally further carbon dioxide, wherein use is made of either a catalyst prepared by pulverizing a catalytic mixture comprising at least zinc oxide, copper or chromium oxide, and aluminum oxide, compacting the mixture on a high-pressure press, and again pulverizing the compacted mixture, or a catalytic mixture comprising at least zinc oxide, copper oxide and alumina in the form of a slurry suspended in a solvent. This process gives dimethyl ether in a high yield, allows a high conversion of water formed by the reaction into hydrogen, and is free from the problem of clogging caused by the catalyst, and no mechanical strength is required of the catalyst. The process has further advantages such that the carbon monoxide to hydrogen ratio can be widely varied, that the reaction can be conducted even in the presence of carbon dioxide with high concentration, and impurities and catalyst poison little affect the reaction.

7. 发明申请

WO1993010069A1 PROCESS FOR PRODUCING DIMETHYL ETHER 审中-公开
标题翻译：生产二甲醚的方法
公开(公告)号：WO1993010069A1
公开(公告)日：1993-05-27
申请号：PCT/JP1992001467
申请日：1992-11-11
申请人： NKK CORPORATION , FUJIMOTO, Kaoru , SHIKADA, Tsutomu , YAMAOKA, Yojiro , SUMIGAMA, Takashi
发明人： NKK CORPORATION
IPC分类号： C07C43/04
CPC分类号： C07C41/01 , C07C43/043
摘要： A process for producing dimethyl ether from a gaseous mixture comprising carbon monoxide, hydrogen and/or steam, and optionally further carbon dioxide, wherein use is made of either a catalyst prepared by pulverizing a catalytic mixture comprising at least zinc oxide, copper or chromium oxide, and aluminum oxide, compacting the mixture on a high-pressure press, and again pulverizing the compacted mixture, or a catalytic mixture comprising at least zinc oxide, copper oxide and alumina in the form of a slurry suspended in a solvent. This process gives dimethyl ether in a high yield, allows a high conversion of water formed by the reaction into hydrogen, and is free from the problem of clogging caused by the catalyst, and no mechanical strength is required of the catalyst. The process has further advantages such that the carbon monoxide to hydrogen ratio can be widely varied, that the reaction can be conducted even in the presence of carbon dioxide with high concentration, and impurities and catalyst poison little affect the reaction.
摘要翻译：一种从包含一氧化碳，氢气和/或蒸汽以及任选的另外的二氧化碳的气体混合物生产二甲醚的方法，其中使用通过粉碎至少包含氧化锌，铜或铬氧化物的催化混合物制备的催化剂和氧化铝，在高压压机上压实混合物，再次粉碎压实的混合物，或至少包含氧化锌，氧化铜和氧化铝的悬浮在溶剂中的浆料的催化混合物。该方法以高产率提供二甲醚，允许将通过反应形成的水的高转化率转化为氢气，并且不存在由催化剂引起的堵塞的问题，并且催化剂不需要机械强度。该方法具有能够大幅度变化的一氧化碳与氢的比例，即使在高浓度的二氧化碳的存在下也能够进行反应，并且杂质和催化剂的毒性对反应几乎没有影响。

8. 发明专利

JP2000313604A PRODUCTION OF SYNTHESIS GAS 失效
公开(公告)号：JP2000313604A
公开(公告)日：2000-11-14
申请号：JP12258299
申请日：1999-04-28
申请人： NIPPON KOKAN KK , FUJIMOTO KAORU
发明人： SHIKADA TSUTOMU , ONO YOTARO , FUJIMOTO KAORU
IPC分类号： C01B3/38 , B01J23/755
摘要： PROBLEM TO BE SOLVED: To prevent the deactivation of catalyst and stably produce synthesis gas over a long period by separately introducing oxygen and a hydrocarbon to the inlet side of a fluidized bed of a catalyst for the production of synthesis gas from a gas containing a hydrocarbon, carbon dioxide gas and oxygen. SOLUTION: The catalyst is preferably a solid solution composed of nickel oxide and magnesium oxide. Silica, etc., can be used as a carrier for the catalyst. The particle diameter of the catalyst is preferably about 0.1-500 μm. The hydrocarbon to be used as a raw material is methane, 2-5C hydrocarbons, their mixture, natural gas, LPG, etc. Air can be used as the oxygen in addition to pure oxygen. The hydrocarbon, carbon dioxide gas and oxygen gas are blown into a reactor from a part below the fluidized bed and, in the present process, oxygen of an amount necessary for keeping the reaction temperature is introduced separately from hydrocarbon into the reactor from a part below the fluidized bed. The reaction temperature is 600-1000 deg.C, the reaction pressure is 1-100 atm and the contacting time is 0.1-10 g-cat.h/mol. The yield of synthesis gas is >=50%.

9. 发明专利

JPH09173845A CATALYST FOR MANUFACTURING DIMETHYL ETHER, MANUFACTURE THEREOF AND MANUFACTURE OF DIMETHYL ETHER 失效
公开(公告)号：JPH09173845A
公开(公告)日：1997-07-08
申请号：JP34333695
申请日：1995-12-28
申请人： NIPPON KOKAN KK , FUJIMOTO KAORU
发明人： SHIKADA TSUTOMU , ONO YOTARO , FUJIMOTO KAORU
IPC分类号： B01J23/80 , C07C41/01 , C07C43/04
摘要： PROBLEM TO BE SOLVED: To manufacture dimethyl ether with high yield by manufacturing a catalyst, which is used for producing dimethyl ether by passing mixed gas through slurry, in such a manner that oxide of copper, oxide of zinc, and alumina are prepicitated in a pore of alumina. SOLUTION: The catalyst for producing dimethyl ether is prepared by precipitating oxide of copper, oxide of zinc, and alumina in the pores of alumina. And dimetnyl ether is produced by passing mixed gas of carbon monoxide and hydrogen through slurry in which the catalyst is suspended, and at that moment, gas or mixed gas containing carbon dioxide and/or water vapor is led into pores of alumina to produce dimethyl ether with a high yield. The ratio between copper oxide, zinc oxide, and alumina to be precipitated in the pores of alumina is such that the ratio of copper oxide to zinc oxide is 1:(0.1-5) and alumina is (0-0.5).

10. 发明专利

JPH07304693A CATALYTIC DEHYDROGENATIVE CONDENSATION PROCESS FOR LOWER ALKANE 失效
公开(公告)号：JPH07304693A
公开(公告)日：1995-11-21
申请号：JP12441794
申请日：1994-05-13
申请人： AGENCY IND SCIENCE TECHN , FUJIMOTO KAORU
发明人： YAKIDA HIROSHI , OGATA ATSUSHI , KOBUCHI TAMOTSU , MIZUNO KOICHI , TAMORI YUKIO , FUJIMOTO KAORU
IPC分类号： B01J21/18 , C07B61/00 , C07C2/76 , C07C2/84 , C07C9/06 , C07C11/04 , C07C11/24
摘要： PURPOSE:To obtain an unsaturated compound such as an olefinic compound which is useful as a starting substance for chemistry and hydrogen by the direct dehydrogenative condensation reaction of a lower alkane in the presence of activated carbon with no generation of carbon dioxide. CONSTITUTION:A lower alkane (suitably natural gas containing methane) is subjected to the dehydrogenative condensation reaction in the presence of activated carbon such as coconut shell activated carbon at elevated temperature, usually 1300 deg.C. In this reaction, the lower alkane is preferably used in the form of a mixture thereof with hydrogen to be brought into contact with the activated carbon. The molar ratio of the lower alkane and hydrogen is 1/3-3/1. The contact time of the lower alkane is preferably 4-8, when it is expressed with the weight of the activated carbon/the feed rate of the lower alkane in mole/hour.

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