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1. 发明申请

WO2008006580A8 PROCESS FOR PREPARING ORGANIC NANOPARTICLES 审中-公开
标题翻译：制备有机纳米颗粒的方法
公开(公告)号：WO2008006580A8
公开(公告)日：2009-01-29
申请号：PCT/EP2007006187
申请日：2007-07-12
申请人： DSM IP ASSETS BV , BROUNS MATTHIAS JOZEF GERTRUDA , FRIEDERICHS JOSEPH PETRONELLA , JANSEN JOHAN FRANZ GRADUS ANTO , DRIESSEN MARCO MARCUS MATHEUS
发明人： BROUNS MATTHIAS JOZEF GERTRUDA , FRIEDERICHS JOSEPH PETRONELLA , JANSEN JOHAN FRANZ GRADUS ANTONIUS , DRIESSEN MARCO MARCUS MATHEUS
IPC分类号： C08F283/01 , C08F263/00 , C08F263/02 , C08G63/676 , C08L51/00 , C08L51/08 , C09D151/00 , C09D151/08 , C09D167/00
CPC分类号： C08F267/06 , C08F263/00 , C08F263/02 , C08F283/01 , C08L51/003 , C08L51/08 , C09D151/003 , C09D151/08 , Y10T428/3179 , Y10T428/31906 , C08L2666/02
摘要： The invention provides a process for preparing organic nanoparticles comprising the steps of: (a) preparing a solution comprising an unsaturated polyester and/or a vinyl ester resin, an initiator and a hydrophobic monomer; (b) emulsifying the solution obtained in step (a) in an aqueous phase; and thereafter (c) curing the emulsified solution. The invention further provides organic nanoparticles obtainable by the process according to the invention; various uses of said nanoparticles; and paper, dye compositions and toner compositions comprising said nanoparticles.
摘要翻译：本发明提供一种制备有机纳米颗粒的方法，包括以下步骤：（a）制备包含不饱和聚酯和/或乙烯基酯树脂，引发剂和疏水性单体的溶液; （b）在水相中乳化步骤（a）中获得的溶液; 然后（c）固化乳化溶液。本发明还提供了可通过本发明的方法获得的有机纳米颗粒; 所述纳米颗粒的各种用途; 以及包含所述纳米颗粒的纸，染料组合物和调色剂组合物。

2. 发明申请

WO2009115588A1 FATTY ACID MODIFIED POLYESTERAMIDE RESIN AND COMPOSITION 审中-公开
标题翻译：脂肪酸改性聚酰胺树脂和组合物
公开(公告)号：WO2009115588A1
公开(公告)日：2009-09-24
申请号：PCT/EP2009/053272
申请日：2009-03-19
申请人： DSM IP Assets B.V. , BENTHEM, VAN, Rudolfus Antonius Theodorus Maria , DERKS, Franciscus Johannes Marie , FRIEDERICHS, Joseph Petronella
发明人： BENTHEM, VAN, Rudolfus Antonius Theodorus Maria , DERKS, Franciscus Johannes Marie , FRIEDERICHS, Joseph Petronella
IPC分类号： C08G63/685 , C08G69/44 , C08L77/12 , C09D177/12 , C09D17/00
CPC分类号： C08G69/44 , C08G63/6858 , C08L77/12 , C09D7/45 , C09D167/08 , C09D177/12
摘要： The invention relates to a fatty acid modified polyesteramide resin obtained from components comprising: i) at least one α, β - unsaturated diacid; ii) optionally at least one other diacid and/or anhydride; iii) at least one alkanol-amine; and iv) at least one fatty acid and/or fatty acid derivative; wherein the molar ratio of component iii) : [component i) + component ii)] is in the range of from 1.2 : 1.0 to 3.0 : 1.0; and wherein component iv) is incorporated in the polyesteramide resin in the range of from 18 to 60 wt% based on the total weight of components i) to iv).
摘要翻译：本发明涉及由以下组分得到的脂肪酸改性聚酯酰胺树脂：包括：i）至少一种α，β-不饱和二酸; ii）任选的至少一种其它二酸和/或酸酐; iii）至少一种烷醇胺; 和iv）至少一种脂肪酸和/或脂肪酸衍生物; 其中组分iii）：[组分i）+组分ii）]的摩尔比在1.2:1.0至3.0:1.0的范围内; 并且其中组分iv）以基于组分i）至iv）的总重量的18至60重量％的范围掺入聚酯酰胺树脂中。

3. 发明申请

WO2003016361A1 AQUEOUS SOLUTION, DISPERSION OR SUSPENSION OF AN IMIDE POLYMER HAVING LOW GLASS TRANSITION TEMPERATURE 审中-公开
标题翻译：水溶液，具有低玻璃化转变温度的聚酰亚胺的分散或悬浮液
公开(公告)号：WO2003016361A1
公开(公告)日：2003-02-27
申请号：PCT/NL2002/000544
申请日：2002-08-13
申请人： DSM N.V. , FRIEDERICHS, Joseph, Petronella
发明人： FRIEDERICHS, Joseph, Petronella
IPC分类号： C08F8/30
CPC分类号： C08F8/30
摘要： The invention relates to an aqueous solution, dispersion or suspension of a second polymer that is obtained by converting in a first polymer that is prepared from a) 15-50 mol% unsaturated anhydride monomer units, b) 0-85 mol% vinyl aromatic monomer units, c) 0-85 mol% aliphatic vinyl monomer units, and where the total of moles of a), b) and c) is 100%, at least a part of the anhydride monomer units with a compound that contains a terminal amine group into imide monomer units in such a way that the second polymer has a glass transition temperature of 10 °C or lower. The invention also relates to use of the solution, dispersion or suspension in a glue.
摘要翻译：本发明涉及第二聚合物的水溶液，分散体或悬浮液，其通过在由a）15-50mol％不饱和酸酐单体单元制备的第一聚合物中转化而获得，b）0-85mol％乙烯基芳族单体单元，c）0-85摩尔％脂族乙烯基单体单元，并且其中a），b）和c）的摩尔数合计为100％，至少一部分酸酐单体单元与含有末端胺的化合物以第二聚合物的玻璃化转变温度为10℃以下的方式组合成酰亚胺单体单元。本发明还涉及溶液，分散体或悬浮液在胶中的用途。

4. 发明申请

WO2012175622A1 POLYMER, PROCESS AND USE 审中-公开
标题翻译：聚合物，工艺和用途
公开(公告)号：WO2012175622A1
公开(公告)日：2012-12-27
申请号：PCT/EP2012/061991
申请日：2012-06-21
申请人： DSM IP ASSETS B.V. , FRIEDERICHS, Joseph, Petronella , VERMEULEN, Jacobus, Adriaan, Antonius , DRIESSEN, Marco, Marcus, Matheus , JANSEN, Johan, Franz, Gradus, Antonius , UDDING, Jan, Henderikus
发明人： FRIEDERICHS, Joseph, Petronella , VERMEULEN, Jacobus, Adriaan, Antonius , DRIESSEN, Marco, Marcus, Matheus , JANSEN, Johan, Franz, Gradus, Antonius , UDDING, Jan, Henderikus
IPC分类号： C08G69/00 , C08G69/42 , C08G83/00
CPC分类号： C08G69/26 , C04B24/287 , C08G69/00 , C08G69/42 , C08G83/005 , C09D175/04 , C09D177/06
摘要： There is described a process for producing a gel free hyperbranched polyamide polymer P having a polydispersity of at least 1.1 and a weight average molecular weight of at least 300 daltons, having primary amino groups (useful as a crosslinker). The process comprises the step of reacting Reagent A, a compound comprising at least one amino group (-NH 2 ) and one functional group selected from the group consisting of a further amino group (-NH 2 ), thiol (-SH) and a secondary amine radical (-NHR); (where R denotes a hydrocarbo group) (=functional amine) and Reagent B, an alpha -beta unsaturated Michael-reactive ester comprising a plurality of ester groups (=diester);in a molar ratio of amine A to diester B greater than 1 but less than 3 (preferably 2.1 to 2.9);to form the polyamide in a two stage reaction Michael addition and then amidation. The amine in kept in excess with at least 5% of water by total weight of the amine and diester, a reaction temperature less than the boiling point of the amine; and is held under reduced pressure (30 mbar to 1 atms). Gelation does not occur even after substantially all ethylenic (-C=C- ) double bonds; and >95% ester [ -C(O)=O ] groups have reacted. This violates the Flory rules which predict a gel would form based on the number of functional groups present and their degree of conversion. These polymers may be used as a replacement for polyethylene imine (PEI) for example on plastics; in coatings, colours and/or adhesives; with metals; on textiles and fibres; in water treatment, paper, mineral processing and/or chemically modified Various chemical modifications and further reactions of these polymers are also described. A diverse range of other uses are also described including as additives for composite compositions, such as specialty additives for superplasticizers in concrete admixtures.
摘要翻译：描述了具有至少1.1的多分散性和至少300道尔顿的具有伯氨基（可用作交联剂）的无凝胶超支化聚酰胺聚合物P的方法。该方法包括使试剂A，包含至少一个氨基（-NH 2）和一个选自另外的氨基（-NH 2），硫醇（-SH）和仲胺（-NH 2）的官能团的化合物自由基（-NHR）; （其中R表示烃基）（=官能胺）和试剂B，包含多个酯基（=二酯）的α-不饱和Michael反应性酯;胺A与二酯B的摩尔比大于1 但小于3（优选2.1至2.9）;在两步反应中形成聚酰胺迈克尔加成然后酰胺化。胺与胺和二酯的总重量与至少5％的水保持过量，反应温度小于胺的沸点; 并保持在减压（30mbar至1atms）下。即使在基本上所有的乙烯基（-C = C-）双键之后，凝胶也不会发生; 和> 95％酯[-C（O）= O]基团已经反应。这违反了Flory规则，根据存在的功能组的数量及其转化程度，预测凝胶将形成。这些聚合物可用作例如聚乙烯亚胺（PEI）在塑料上的替代物; 在涂料，颜色和/或粘合剂中; 与金属; 纺织和纤维; 在水处理，纸，矿物加工和/或化学改性中也描述了这些聚合物的各种化学修饰和进一步的反应。还描述了多种其他用途，包括作为复合组合物的添加剂，例如混凝土外加剂中的超增塑剂的专用添加剂。

5. 发明申请

WO2008006580A3 PROCESS FOR PREPARING ORGANIC NANOPARTICLES 审中-公开
公开(公告)号：WO2008006580A3
公开(公告)日：2008-01-17
申请号：PCT/EP2007/006187
申请日：2007-07-12
申请人： DSM IP ASSETS B.V. , BROUNS, Matthias Jozef Gertruda , FRIEDERICHS, Joseph Petronella , JANSEN, Johan Franz Gradus Antonius , DRIESSEN, Marco Marcus Matheus
发明人： BROUNS, Matthias Jozef Gertruda , FRIEDERICHS, Joseph Petronella , JANSEN, Johan Franz Gradus Antonius , DRIESSEN, Marco Marcus Matheus
IPC分类号： C08F283/01 , C08G63/676 , C09D151/00 , C09D151/08 , C08L51/00 , C08L51/08 , C09D167/00 , C08F263/02 , C08F263/00
摘要： The invention provides a process for preparing organic nanoparticles comprising the steps of: (a) preparing a solution comprising an unsaturated polyester and/or a vinyl ester resin, an initiator and a hydrophobic monomer; (b) emulsifying the solution obtained in step (a) in an aqueous phase; and thereafter (c) curing the emulsified solution. The invention further provides organic nanoparticles obtainable by the process according to the invention; various uses of said nanoparticles; and paper, dye compositions and toner compositions comprising said nanoparticles.

6. 发明申请

WO2008006580A2 PROCESS FOR PREPARING ORGANIC NANOPARTICLES 审中-公开
标题翻译：制备有机纳米粒子的方法
公开(公告)号：WO2008006580A2
公开(公告)日：2008-01-17
申请号：PCT/EP2007006187
申请日：2007-07-12
申请人： DSM IP ASSETS BV , BROUNS MATTHIAS JOZEF GERTRUDA , FRIEDERICHS JOSEPH PETRONELLA , JANSEN JOHAN FRANZ GRADUS ANTO , DRIESSEN MARCO MARCUS MATHEUS
发明人： BROUNS MATTHIAS JOZEF GERTRUDA , FRIEDERICHS JOSEPH PETRONELLA , JANSEN JOHAN FRANZ GRADUS ANTO , DRIESSEN MARCO MARCUS MATHEUS
IPC分类号： C08F283/01 , C08G63/676 , C08L51/00 , C09D151/00 , C09D151/08
CPC分类号： C08F267/06 , C08F263/00 , C08F263/02 , C08F283/01 , C08L51/003 , C08L51/08 , C09D151/003 , C09D151/08 , Y10T428/3179 , Y10T428/31906 , C08L2666/02
摘要： The invention provides a process for preparing organic nanoparticles comprising the steps of: (a) preparing a solution comprising an unsaturated polyester and/or a vinyl ester resin, an initiator and a hydrophobic monomer; (b) emulsifying the solution obtained in step (a) in an aqueous phase; and thereafter (c) curing the emulsified solution. The invention further provides organic nanoparticles obtainable by the process according to the invention; various uses of said nanoparticles; and paper, dye compositions and toner compositions comprising said nanoparticles.
摘要翻译：本发明提供了一种制备有机纳米粒子的方法，其包括以下步骤：（a）制备包含不饱和聚酯和/或乙烯基酯树脂，引发剂和疏水单体的溶液; （b）将步骤（a）中获得的溶液在水相中乳化; 之后（c）固化乳化溶液。本发明还提供可通过本发明方法获得的有机纳米粒子; 所述纳米颗粒的各种用途; 和包含所述纳米颗粒的纸张，染料组合物和调色剂组合物。

7. 发明申请

WO2004031249A1 AQUEOUS POLYMER DISPERSION, PREPARATION AND USE THEREOF 审中-公开
标题翻译：水性聚合物分散体，其制备和使用
公开(公告)号：WO2004031249A1
公开(公告)日：2004-04-15
申请号：PCT/FI2003/000731
申请日：2003-10-06
申请人： RAISIO CHEMICALS LTD , ABBEELE VAN DEN, Henk, Jan, Frans , FRIEDERICHS, Joseph, Petronella , LUTTIKHEDDE, Hendrik, Jan, Gerrit
发明人： ABBEELE VAN DEN, Henk, Jan, Frans , FRIEDERICHS, Joseph, Petronella , LUTTIKHEDDE, Hendrik, Jan, Gerrit
IPC分类号： C08F8/32
CPC分类号： C09D135/06 , C08F8/32 , C08F222/08
摘要： The present invention relates to an aqueous polymer dispersion comprising a copolymer of anhydride monomer units and vinyl monomer units, which copolymer has been subjected to an imidization reaction. The present invention further relates to a method for the production and use of such a dispersion.
摘要翻译：本发明涉及包含酸酐单体单元和乙烯基单体单元的共聚物的聚合物水分散体，该共聚物已经进行了酰亚胺化反应。本发明还涉及一种生产和使用这种分散体的方法。

8. 发明申请

WO2003064482A3 PROCESS FOR THE PREPARATION OF A COPOLYMER OF MALEIC ANHYDRIDE AND AN ALKYL VINYL ETHER, COPOLYMERS OF MALEIC ANHYDRIDE AND AN ALKYL VINYL ETHER AND AN APPARATUS 审中-公开
公开(公告)号：WO2003064482A3
公开(公告)日：2003-08-07
申请号：PCT/NL2003/000044
申请日：2003-01-22
申请人： DSM IP ASSETS B.V. , VAN BENTHEM, Rudolfus, Antonius, Theodorus, Maria , FRIEDERICHS, Joseph, Petronella , MOREAU, Dominique, Jean, Joseph, Sophie
发明人： VAN BENTHEM, Rudolfus, Antonius, Theodorus, Maria , FRIEDERICHS, Joseph, Petronella , MOREAU, Dominique, Jean, Joseph, Sophie
IPC分类号： C08F222/06
摘要： Process for the preparation of a copolymer of maleic anhydride and an alkyl vinyl ether, comprising the steps of supplying maleic anhydride and the alkyl vinyl ether and an initiator, together forming a feed flow, through an inlet to a reactor wherein maleic anhydride and the alkyl vinyl ether react to a copolymer of maleic anhydride an alkyl vinyl ether thereby forming a reaction mixture with the maleic anhydride, the alkyl vinyl ether and the initiator characterized in that the process is a continuous process and the reactor is a loop reactor wherein the reaction mixture is internally circulated, whereby this reaction mixture arrives at the inlet before the maleic anhydride and alkyl vinyl ether have completely reacted while a remainder of initiator is still present. The invention further relates to copolymer of maleic anhydride and alkyl vinyl ether, including hydrolyzed or alcoholized copolymers, characterized in that a molecular weight distribution, expressed as Mw/Mn, is less than 2. The invention also relates to an apparatus for conducting the process of the invention.

9. 发明申请

WO1997033685A1 METHOD FOR PREPARING A MORTAR 审中-公开
标题翻译：制备麦芽糖的方法
公开(公告)号：WO1997033685A1
公开(公告)日：1997-09-18
申请号：PCT/NL1997000059
申请日：1997-02-13
申请人： DSM N.V. , COURAGE, Antonius, Johannes, Franciscus, Maria , FRIEDERICHS, Joseph, Petronella
发明人： DSM N.V.
IPC分类号： B01J02/28
CPC分类号： C04B20/1029 , B01J2/28 , C04B18/02 , C04B40/0028 , C04B2103/0053 , Y10S106/07 , C04B14/06 , C04B20/008 , C04B14/28 , C04B28/02 , C04B40/0633 , C04B18/021
摘要： Method for preparing a concrete mortar which contains a fraction of inorganic grains having a diameter
摘要翻译：制备含有一部分直径小于500μm的无机颗粒的混凝土砂浆的方法，其中含有无机颗粒的部分以颗粒状的形式加入，所述颗粒材料含有无机颗粒，所述无机颗粒借助于水结合以形成颗粒状材料。结果，得到均质的砂浆。

10. 发明申请

WO2009007446A1 ORGANIC NANO-PARTICLES AND PROCESS FOR THEIR PREPARATION 审中-公开
标题翻译：有机纳米颗粒及其制备方法
公开(公告)号：WO2009007446A1
公开(公告)日：2009-01-15
申请号：PCT/EP2008/059071
申请日：2008-07-11
申请人： DSM IP Assets B.V. , BROUNS, Matthias Jozef Gertruda , FRIEDERICHS, Joseph Petronella , JANSEN, Johan Franz Gradus Antonius , DRIESSEN, Marco Marcus Matheus
发明人： BROUNS, Matthias Jozef Gertruda , FRIEDERICHS, Joseph Petronella , JANSEN, Johan Franz Gradus Antonius , DRIESSEN, Marco Marcus Matheus
IPC分类号： C08F283/01 , C08G63/676 , C09D151/00 , C09D151/08 , C08L51/00 , C08L51/08 , C09D167/00 , C08F263/00
CPC分类号： C08F283/01 , A61K8/91 , A61K2800/413 , A61Q5/02 , C08F263/00 , C08L51/003 , C08L51/08 , C09D151/003 , C09D151/08 , Y10T428/31902 , C08L2666/02
摘要： There is disclosed a process for preparing organic nano-particles comprising the steps of: (a) preparing a solution comprising an unsaturated polyester and/or a vinyl ester resin and a hydrophobic monomer; (b) dispersing the solution obtained in step (a) in an aqueous phase to form a stable emulsion where the aqueous phase is the continuous phase; and (c) using an initiator to cure the emulsion obtained in step (b) in the presence of a water soluble inhibitor to form a dispersion of nano-particles. The invention further provides organic nano-particles obtainable by the process according to the invention; various uses of said nano-particles; such as in paper, dye, toner and personal care compositions and topical medicaments comprising said nano-particles.
摘要翻译：公开了一种制备有机纳米颗粒的方法，包括以下步骤：（a）制备包含不饱和聚酯和/或乙烯基酯树脂和疏水单体的溶液; （b）将步骤（a）中获得的溶液分散在水相中以形成稳定的乳液，其中水相是连续相; 和（c）使用引发剂在水溶性抑制剂的存在下固化步骤（b）中获得的乳液以形成纳米颗粒的分散体。本发明还提供可通过本发明方法获得的有机纳米颗粒; 所述纳米颗粒的各种用途; 例如纸，染料，调色剂和个人护理组合物以及包含所述纳米颗粒的局部药物。

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