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1. 发明专利

JP2010013465A Method for producing 4-aminodiphenylamine 有权
标题翻译：生产4-氨基二苯胺的方法
公开(公告)号：JP2010013465A
公开(公告)日：2010-01-21
申请号：JP2009203474
申请日：2009-09-03
申请人： Flexsys America Lp , フレクシスアメリカエル. ピー.
发明人： TRIPLETT II RALPH DALE , RAINS ROGER KERANEN
IPC分类号： C07C209/02 , C07C209/32 , C07B61/00 , C07C209/36 , C07C209/38 , C07C209/68 , C07C211/55 , C07C211/56
CPC分类号： C07C209/68 , C07C209/36 , C07C211/56
摘要： PROBLEM TO BE SOLVED: To provide a new method for producing 4-aminodiphenylamine.
SOLUTION: Provided is the method for producing 4-aminodiphenylamine intermediates comprising bringing an aniline or aniline derivative and a nitrobenzene or a nitrobenzene derivative into reactive contact and reacting them in a confined zone at a suitable time and temperature, in the presence of a strong base, a quarternary ammonium salt phase-transfer catalyst and an oxidant. The intermediates produce the 4-aminodiphenylamine or its substituted derivatives by reduction.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种生产4-氨基二苯胺的新方法。解决方案：提供生产4-氨基二苯胺中间体的方法，包括使苯胺或苯胺衍生物和硝基苯或硝基苯衍生物反应接触，并在合适的时间和温度下，在有限区域内，在存在强碱，季铵盐相转移催化剂和氧化剂。中间体通过还原生成4-氨基二苯胺或其取代的衍生物。版权所有（C）2010，JPO＆INPIT

2. 发明专利

JP2010143931A Method for producing 4-aminodiphenylamine 审中-公开
标题翻译：生产4-氨基二苯胺的方法
公开(公告)号：JP2010143931A
公开(公告)日：2010-07-01
申请号：JP2010000730
申请日：2010-01-05
申请人： Flexsys America Lp , フレクシスアメリカエル. ピー.
发明人： TRIPLETT II RALPH DALE , RAINS ROGER KERANEN
IPC分类号： C07C209/02 , C07C209/36 , B01J27/24 , C07B61/00 , C07C209/26 , C07C209/38 , C07C209/68 , C07C211/55 , C07C211/56
CPC分类号： C07C209/68 , C07C209/36 , C07C211/56
摘要： PROBLEM TO BE SOLVED: To provide an excellent method for producing one or more 4-ADPA intermediates by reacting aniline with nitrobenzene in the presence of a strong base and a phase transfer catalyst or in the presence of an organic base and an inorganic salt or a metal-organic salt. SOLUTION: This invention provides a method for producing 4-aminodiphenylamine or a substituted derivative thereof by bringing aniline or an aniline derivative and nitrobenzene or a nitrobenzene derivative into reactive contact and reacting the aniline or the aniline derivative with the nitrobenzene or the nitrobenzene derivative in the presence of a strong base, a suitable phase transfer catalyst, and an oxidizing agent in a confined zone for a suitable time at suitable pressure and a suitable temperature. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：为了提供一种在强碱和相转移催化剂存在下或在有机碱和无机物存在下使苯胺与硝基苯反应制备一种或多种4-ADPA中间体的优异方法盐或金属有机盐。解决方案：本发明提供一种通过将苯胺或苯胺衍生物和硝基苯或硝基苯衍生物反应接触并使苯胺或苯胺衍生物与硝基苯或硝基苯反应而制备4-氨基二苯胺或其取代衍生物的方法衍生物在强碱，合适的相转移催化剂和氧化剂存在下，在合适的压力和合适的温度下在约束区内持续合适的时间。版权所有（C）2010，JPO＆INPIT

3. 发明申请

WO0192423A3 SURFACE TREATED CARBON BLACK HAVING IMPROVED DISPERSABILITY IN RUBBER 审中-公开
标题翻译：表面处理碳黑在橡胶中具有改进的分散性
公开(公告)号：WO0192423A3
公开(公告)日：2002-05-10
申请号：PCT/US0116455
申请日：2001-05-22
申请人： FLEXSYS AMERICA LP , COLUMBIAN CHEM , LAMBA RAKSHIT , IGNATZ HOOVER FREDERICK
发明人： LAMBA RAKSHIT , IGNATZ-HOOVER FREDERICK
IPC分类号： C08K9/04 , C08L21/00 , C09C1/56 , C09D17/00
CPC分类号： C09C1/56 , C01P2004/62 , C01P2004/64 , C01P2006/22 , C08K9/04
摘要： The invention comprises a composition comprising a combination of carbon black and at least one surface treating agent selected from the group consisting of quinone compounds, quinoneimine compounds and quinonediimine compounds, as well as methods of obtaining the composition and the use of the composition in dispersing carbon black in a natural or synthetic polymer. The composition achieves increased dispersibility and improved mixing characteristics of the carbon black and improved processability of the carbon black containing polymer.
摘要翻译：本发明包括一种组合物，其包含炭黑和选自醌化合物，醌亚胺化合物和醌二亚胺化合物的至少一种表面处理剂的组合，以及获得该组合物的方法和该组合物在分散碳中的用途黑色为天然或合成聚合物。该组合物实现了增加的分散性和改善的炭黑混合特性，并提高了含炭黑聚合物的加工性能。

4. 发明申请

WO0170870A3 PYRIMIDINE DERIVATIVES AS HARDNESS STABILIZERS 审中-公开
标题翻译：哌嗪衍生物作为硬度稳定剂
公开(公告)号：WO0170870A3
公开(公告)日：2002-01-03
申请号：PCT/US0109156
申请日：2001-03-21
申请人： FLEXSYS AMERICA LP , LIN HORNG JAU , DATTA RABINDRA NATH , MAENDER OTTO WILLIAM
发明人： LIN HORNG-JAU , DATTA RABINDRA NATH , MAENDER OTTO WILLIAM
IPC分类号： B60C1/00 , C07D417/12 , C08K5/36 , C08K5/37 , C08K5/378 , C08K5/42 , C08K5/43 , C08K5/44 , C08K5/47 , C08L7/00 , C08L9/06 , C08L21/00
CPC分类号： C08K5/44 , C08K5/37 , C08K5/378 , C08K5/42 , C08K5/47 , C08L21/00
摘要： The invention comprises a vulcanizable composition comprising a sulfur vulcanizable rubber, a sulfur vulcanizing agent, an accelerating agent selected from the group consisting of non-thiazole sulfenamide accelerators and a hardness stabilization agent comprising a pyrimidine derivative of formula (I), where X=H, R1 through R4, NR3R4, OR5, SR5, SO2R6, M, (SO3)zM (M=metal ion), and n and z can be the same or different and 1, 2 or 3, depending on whether the respective valence of X and M is 1, 2 or 3, R1 through R4 are the same or different and selected from the group consisting of the substituents H, halogen, OH, NH2, alkyl, cycloalkyl, aryl, alkylaryl, aralkyl, with each of such substituents optionally having additional functional groups selected form the group consisting of NH2, OH, substituted amino, substituted hydroxyl, halogen, and carbonyl containing group, R3 and R4 may be in the same constituent together with N to form a heterocyclic group, R5 is the same as any of R1 through R4, or a radical derived from a carbon based heterocyclic group containing at least one of S or N, or both S and N, R6 is selected from the same as any of R1 through R4, OH, OM, O R5, NH2 NR3R4 the respective amount of accelerating agent and hardness stabilization agent being effective to not substantially inhibit vulcanization and to stabilize the hardness properties of said rubber upon vulcanization, the amount of accelerating agent in said composition being greater than about 0.6 phr when said rubber is SBR and at least about 0.5 phr when said rubber is natural rubber, and the amount of hardness stabilization agent being at least about 0.5 phr. The invention also comprises a method of improving the hardness stabilization of a composition comprising a sulfur vulcanizable rubber by adding the above accelerators and pyrimidine derivative to the composition.
摘要翻译：本发明包括可硫化组合物，其包含硫可硫化橡胶，硫硫化剂，选自非噻唑次磺酰胺促进剂的促进剂和包含式（I）的嘧啶衍生物的硬化稳定剂，其中X = H ，R 1至R 4，NR 3 R 4，OR 5，SR 5，SO 2 R 6，M，（SO 3）z M（M =金属离子），并且n和z可以相同或不同且为1,2或3，这取决于 X和M是1,2或3，R 1至R 4相同或不同，并且选自取代基H，卤素，OH，NH 2，烷基，环烷基，芳基，烷基芳基，芳烷基，各取代基任选地具有选自由NH 2，OH，取代的氨基，取代的羟基，卤素和含羰基的基团组成的组的另外的官能团，R 3和R 4可以与N一起形成相同的组分以形成杂环基，R5是相同的作为R1到R中的任一个 4或衍生自含有S或N中的至少一种或S和N两者的碳基杂环基的基团，R 6选自与R 1至R 4，OH，OM，O R 5，NH 2 NR 3 R 4中的任一个相同的基团相应量的促进剂和硬度稳定剂有效地基本不抑制硫化并稳定硫化时所述橡胶的硬度性质，当所述橡胶为SBR时，所述组合物中的促进剂的量大于约0.6phr，并且至少当所述橡胶是天然橡胶时，约0.5phr，并且硬度稳定剂的量为至少约0.5phr。本发明还包括通过将上述加速剂和嘧啶衍生物加入到组合物中来改善包含硫可硫化橡胶的组合物的硬度稳定性的方法。

5. 发明申请

WO9936395A9 PREPARATION OF N-PHENYL-BENZOQUINONEIMINE FROM HYDROXYDIPHENYLAMINES 审中-公开
标题翻译：从羟基二苯胺制备N-苯基 - 苯并喹啉酮亚胺
公开(公告)号：WO9936395A9
公开(公告)日：1999-11-11
申请号：PCT/IB9900424
申请日：1999-01-14
申请人： FLEXSYS AMERICA LP
发明人： FIELDS DONALD L JR , STERN MICHAEL K , LODAYA JAYANT S
IPC分类号： B01J27/20 , C07B61/00 , C07C249/02 , C07C251/22
CPC分类号： C07C249/02 , C07C251/22
摘要： A hydroxydiphenylamine compound can be converted to an N-phenylquinoneimine by reacting the hydroxydiphenylamine with oxygen or an oxygen containing gas in the presence of a modified activated carbon catalyst, the catalyst having had surface oxides removed therefrom.
摘要翻译：通过使羟基二苯胺与氧或含氧气体在改性活性炭催化剂存在下反应，可以将羟基二苯胺化合物转化为N-苯基醌亚胺，所述催化剂具有从中除去表面氧化物。

6. 发明申请

WO2011053781A3 PROCESS OF FORMING VULCANIZABLE ELASTOMERIC COMPOSITIONS USING ULTRA ACCELERATORS AND PRODUCTS FORMED THEREFROM 审中-公开
标题翻译：使用超级加速器和形成的产品形成可组合的弹性体组合物的方法
公开(公告)号：WO2011053781A3
公开(公告)日：2011-09-29
申请号：PCT/US2010054711
申请日：2010-10-29
申请人： FLEXSYS AMERICA LP , IGNATZ-HOOVER FREDERICK , FRANCIS ROBERT ARTHUR , HARING ROBERT
发明人： IGNATZ-HOOVER FREDERICK , FRANCIS ROBERT ARTHUR , HARING ROBERT
IPC分类号： C08K5/39 , B29D30/00 , C08K3/36 , C08K5/40 , C08K5/54 , C08K13/02
CPC分类号： C08K5/40 , B60C1/00 , C08K5/39 , C08K5/54 , C08L21/00
摘要： A vulcanizable elastomeric composition and a method of forming said composition is presented. The method generally comprises the mixing of sulfur and an ultra- accelerator into a mixture of an elastomeric polymer matrix, fillers, and silane coupling agent during the silanization reaction step, prior to the occurrence of vulcanization. The addition of the ultra-accelerator, such as TBzTD, enhances the efficiency of the silanization reaction and forms at least one bond with the elastomeric polymer matrix. The silanization reaction step may comprise multiple mixing substeps in which the ultra- accelerator may be incorporated into the elastomeric composition.
摘要翻译：提出了可硫化的弹性体组合物和形成所述组合物的方法。该方法通常包括在硅烷化反应步骤之前，在发生硫化之前将硫和超促进剂混合到弹性体聚合物基质，填料和硅烷偶联剂的混合物中。加入超促进剂如TBzTD可提高硅烷化反应的效率，并与弹性聚合物基体形成至少一个键。硅烷化反应步骤可以包括多个混合子步骤，其中超促进剂可以结合到弹性体组合物中。

7. 发明申请

WO0192423A8 SURFACE TREATED CARBON BLACK HAVING IMPROVED DISPERSABILITY IN RUBBER 审中-公开
标题翻译：表面处理碳黑在橡胶中具有改进的分散性
公开(公告)号：WO0192423A8
公开(公告)日：2003-03-06
申请号：PCT/US0116455
申请日：2001-05-22
申请人： FLEXSYS AMERICA LP , COLUMBIAN CHEM , LAMBA RAKSHIT , IGNATZ-HOOVER FREDERICK
发明人： LAMBA RAKSHIT , IGNATZ-HOOVER FREDERICK
IPC分类号： C08K9/04 , C08L21/00 , C09C1/56 , C09D17/00
CPC分类号： C09C1/56 , C01P2004/62 , C01P2004/64 , C01P2006/22 , C08K9/04
摘要： The invention comprises a composition comprising a combination of carbon black and at least one surface treating agent selected from the group consisting of quinone compounds, quinoneimine compounds and quinonediimine compounds, as well as methods of obtaining the composition and the use of the composition in dispersing carbon black in a natural or synthetic polymer. The composition achieves increased dispersibility and improved mixing characteristics of the carbon black and improved processability of the carbon black containing polymer.
摘要翻译：本发明包括一种组合物，其包含炭黑和选自醌化合物，醌亚胺化合物和醌二亚胺化合物的至少一种表面处理剂的组合，以及获得该组合物的方法和该组合物在分散碳中的用途黑色为天然或合成聚合物。该组合物实现了增加的分散性和改善的炭黑混合特性，并提高了含炭黑聚合物的加工性能。

8. 发明申请

WO0198252A3 ZEOLITE SUPPORT LOADED WITH A BASE MATERIAL FOR USE IN THE COUPLING OF ANILINE AND NITROBENZENE 审中-公开
标题翻译：用于在尼龙和硝基苯偶联中使用的碱性材料的ZEOLITE支持
公开(公告)号：WO0198252A3
公开(公告)日：2002-03-14
申请号：PCT/US0119666
申请日：2001-06-20
申请人： FLEXSYS AMERICA LP , VERA ANTONIO L DE , RAINS ROGER KERANAN
发明人： DE VERA ANTONIO L , RAINS ROGER KERANAN
IPC分类号： B01J31/26 , B01J29/00 , B01J29/40 , B01J29/44 , B01J31/02 , C07B61/00 , C07C209/00 , C07C209/36 , C07C209/38 , C07C209/48 , C07C211/51 , C07C211/54 , C07C211/55 , B01J29/04 , B01J29/85 , C07C209/02
CPC分类号： C07C209/36 , B01J29/40 , B01J29/44 , B01J31/0239 , B01J31/0254 , B01J2229/26 , B01J2229/42 , B01J2531/985 , C07C211/51 , C07C211/55
摘要： This invention provides a composition suitable for use in a reaction zone where aniline is reacted with nitrobenzene to obtain intermediates of 4-amino-diphenylamine comprising a solide support having interior channels with base material employed in the reaction loaded into the channels. The cross-sectional dimensions of the channels are such as to provide a restricted transition state with regard to the reaction and to improve the selectivity of the reaction in favor of the intermediates The invention also provides a method for loading the base material in the solid support. The invention further provides a process for carrying out the above reaction using the above composition.
摘要翻译：本发明提供一种适用于反应区的组合物，其中苯胺与硝基苯反应以获得4-氨基 - 二苯胺的中间体，其包含具有内部通道的固体支持体，所述中间体具有加载到通道中的反应中使用的基础材料。通道的横截面尺寸是为了提供关于反应的限制性过渡态，并提高反应有利于中间体的选择性本发明还提供了一种将固体载体中的基材装载的方法。本发明还提供了使用上述组合物进行上述反应的方法。

9. 发明申请

WO2004052834A8 PROCESS FOR PREPARING 4-AMINODIPHENYLAMINE INTERMEDIATES 审中-公开
标题翻译：制备4-氨基二苯胺中间体的方法
公开(公告)号：WO2004052834A8
公开(公告)日：2005-03-31
申请号：PCT/IB0306492
申请日：2003-12-04
申请人： FLEXSYS AMERICA LP , TRIPLETT II RALPH DALE , RAINS ROGER KERANEN
发明人： TRIPLETT II RALPH DALE , RAINS ROGER KERANEN
IPC分类号： C07C209/36 , C07C209/68 , C07C211/55 , C07C211/56
CPC分类号： C07C209/68 , C07C209/36 , C07C211/55 , C07C211/56
摘要： The invention is directed to a method of producing 4-aminodiphenylamine comprising the steps of: (a)reacting an aniline or derivative thereof and nitrobenzene in a confined zone in the presence of a mixture comprising a base and an oxidant comprising hydrogen peroxide in an amount of from about 0.01 to about 0.60 moles of hydrogen peroxide to moles of nitrobenzene to obtain at least one 4-aminodiphenylamine intermediate; and (b) reducing the intermediate to 4-aminodiphenylamine, and (c) optionally, reductively alkylating 4-aminodiphenylamine to an alkylated derivative of the 4-aminodiphenylamine. The invention further pertains to a method of producing a 4-aminodiphenylamine intermediate as obtained in the above reaction.
摘要翻译：本发明涉及一种生产4-氨基二苯胺的方法，包括以下步骤：（a）在限制区内使苯胺或其衍生物与硝基苯在含有碱和氧化剂存在下反应，所述混合物包含一定量的过氧化氢约0.01至约0.60摩尔过氧化氢至硝基苯的摩尔数，以获得至少一种4-氨基二苯胺中间体; 和（b）将中间体还原成4-氨基二苯胺，和（c）任选地将4-氨基二苯胺还原烷基化为4-氨基二苯胺的烷基化衍生物。本发明还涉及上述反应得到的4-氨基二苯胺中间体的制造方法。

10. 发明申请

WO0242262A3 ALKYLTHIO- AND ARYL(HETEROYL)THIO-SUBSTITUTED P-PHENYLENEDIAMINES, THEIR MANUFACTURE AND THEIR USE IN RUBBER 审中-公开
标题翻译：烷基和芳基（芳基）取代的对苯二甲酸乙二醇酯，它们的制造及其在橡胶中的用途
公开(公告)号：WO0242262A3
公开(公告)日：2003-03-27
申请号：PCT/US0145213
申请日：2001-11-20
申请人： FLEXSYS AMERICA LP , MAENDER OTTO WILLIAM , ROSTEK CHARLES J , KATRITZKY ALAN R , ODENS HERMAN H , VORONKOV MICHAEL V
发明人： MAENDER OTTO WILLIAM , ROSTEK CHARLES J , KATRITZKY ALAN R , ODENS HERMAN H , VORONKOV MICHAEL V
IPC分类号： C07D239/40 , C07C319/14 , C07C321/28 , C07C321/30 , C07C323/35 , C07C323/36 , C07C323/37 , C07C323/52 , C07C323/62 , C07D213/70 , C07D235/28 , C07D239/56 , C08K5/00 , C08K5/372 , C08K5/375 , C08K5/378 , C08L21/00
CPC分类号： C07D213/70 , C07C323/35 , C07C323/36 , C07C323/37 , C07C323/52 , C07C323/62 , C07D235/28 , C07D239/56 , C08K5/3725 , C08K5/378 , C08L21/00
摘要： A composition comprising 2-alkylthio- or 2-aryl(heteroyl)thio-substituted p-phenylenediamine of formula (I), where X and Y are the same or different and selected from the group NH2 or NHR (whwere R is alkyl, cycloakyl or aryl); and R' is alkyl, cycloalkyl, alkylene aryl, arylene, alkyle3-propionate,bridging groups or carbon based heteroclic group containing at least one of S or N, or both S and N; its method of preparation, and its use as an antidegradant in natural or synthetic rubber.
摘要翻译：包含式（I）的2-烷硫基 - 或2-芳基（杂芳基）硫代取代的对苯二胺的组合物，其中X和Y相同或不同并选自NH 2或NHR（R为烷基，环烷基或芳基）; 并且R'是烷基，环烷基，亚烷基芳基，亚芳基，3-烷基丙酸酯，含有S或N中的至少一个或S和N两者的桥基或碳基杂环基团; 其制备方法及其在天然或合成橡胶中作为抗降解剂的用途。

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