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1. 发明申请

US20030055289A1 Method for preparation of boratabenzene derivatives 失效
公开(公告)号：US20030055289A1
公开(公告)日：2003-03-20
申请号：US09925048
申请日：2001-08-08
申请人： Equistar Chemicals, L.P.
发明人： Vladimir Dragan , Ramesh Krishnamurti
IPC分类号： C07F005/02 , C07F007/22
CPC分类号： C07F5/022 , C07F7/2208
摘要： The present invention provided an improved method for preparing a boratabenzene derivative. The invention includes an improved preparation of 1,4-pentadiyne, 1-haloboracyclohexa-2,5-diene, and 1-methylboracyclohexa-2,5-diene intermediates. These compounds are chemically labile and are not directly isolated from solution. Furthermore, the invention discloses an improved preparation of 1,1-dialkylstannacyclohexa-2,5-diene, another intermediate useful for preparing boratabenzene derivatives.

2. 发明申请

US20010041777A1 Supported olefin polymerization catalysts 失效
公开(公告)号：US20010041777A1
公开(公告)日：2001-11-15
申请号：US09879443
申请日：2001-06-12
申请人： EQUISTAR CHEMICALS, L.P.
发明人： Karen E. Meyer , Mark K. Reinking
IPC分类号： C08F004/44
CPC分类号： B01J31/2295 , B01J31/146 , B01J31/165 , B01J35/023 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F4/65908 , C08F210/08 , C08F2500/12 , C08F2500/24
摘要： Supported heterometallocene catalysts wherein the support is a particulate polymeric material are provided. The catalysts have a transition metal complex containing at least one anionic, polymerization stable heteroatomic ligand associated with the transition metal and a boron activator compound deposited on the support. Polymeric supports used for the heterometallocene catalysts of the invention are homopolymers of ethylene and copolymers of ethylene and C3-8 null-olefins.

3. 发明申请

US20030032744A1 Single-site catalysts containing chelating N-oxide ligands 有权
公开(公告)号：US20030032744A1
公开(公告)日：2003-02-13
申请号：US10272886
申请日：2002-10-17
申请人： EQUISTAR CHEMICALS, L.P.
发明人： Sandor Nagy
IPC分类号： C08F004/44 , B01J031/00
CPC分类号： C08F10/00 , Y10S526/943 , C08F4/64058
摘要： A single-site olefin polymerization catalyst and method of making it are disclosed. The catalyst comprises an activator and an organometallic complex. The complex comprises a Group 3 to 10 transition or lanthanide metal, M, and at least one chelating N-oxide ligand that is bonded to M. Molecular modeling results indicate that single-site catalysts based on certain chelating N-oxide ligands (e.g., 2-hydroxypyridine) will rival the performance of catalysts based on cyclopentadienyl and substituted cyclopentadienyl ligands.

4. 发明申请

US20040077807A1 Supported catalysts which reduce sheeting in olefin polymerization, process for the preparation and the use thereof 失效
标题翻译：减少烯烃聚合反应的载体催化剂，制备方法及其应用
公开(公告)号：US20040077807A1
公开(公告)日：2004-04-22
申请号：US10272789
申请日：2002-10-17
申请人： Equistar Chemicals L.P.
发明人： Karen L. Neal-Hawkins , Sandor M. Nagy , William J. Sartain , Kiran M. Gupte , Kenneth W. Johnson
IPC分类号： C08F004/44 , B01J031/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F210/16 , Y10S526/943 , C08F4/65916 , C08F2/34 , C08F2/002 , C08F210/14 , C08F2500/12 , C08F2500/03 , C08F2500/18 , C08F2500/24
摘要： Olefin polymerization in the presence of heterogeneous supported catalysts is improved by incorporating into the supported catalyst a unifunctional hydrophobic tether comprising a hydrophobic portion containing no basic nitrogen and a univalent reactive group. The unifunctional hydrophobic tether reduces fouling and sheeting in gas phase polymerization processes and improves polymer morphology and bulk density in slurry polymerization processes, while substantially maintaining or enhancing catalyst polymerization activity.
摘要翻译：在非均相负载的催化剂存在下的烯烃聚合通过将含有不含碱性氮和一价反应性基团的疏水部分的单官能疏水系链引入负载型催化剂来改进。单功能疏水系链减少了气相聚合过程中的结垢和铺层，并改善了淤浆聚合过程中的聚合物形态和堆积密度，同时大大维持或增强了催化剂的聚合活性。

5. 发明申请

US20030191251A1 Process for removal of intermediate hydrogen from cascaded polyolefin slurry reactors 失效
标题翻译：从级联聚烯烃淤浆反应器中除去中间氢的方法
公开(公告)号：US20030191251A1
公开(公告)日：2003-10-09
申请号：US10116404
申请日：2002-04-04
申请人： Equistar Chemicals L.P.
发明人： Patrick J. McGrath
IPC分类号： C08F002/00
CPC分类号： C08F6/003 , B01J2219/00006 , B01J2219/0004 , C08F210/16 , C08L23/02 , C08L23/0815 , C08L2205/02 , C08L2308/00 , Y10S526/905 , C08L23/00 , C08F2/14 , C08F2/00 , C08L2666/06 , C08F210/14 , C08F2500/05 , C08F210/06 , C08F210/08
摘要： Multimodal polyolefin polymers may be prepared in series-connected polymerization reactors where a prior reactor is a slurry reactor employing light solvent as the slurry medium and hydrogen to limit polymer molecular weight, the polymer product from the prior reactor being substantially freed of hydrogen prior to entry into a subsequent polymerization reactor operating at low hydrogen pressure to produce a high molecular weight olefin. The economics and operating performance of such a series slurry reactor polyethylene process can be significantly improved through the use of an intermediate slurry transfer system and hydrogen removal apparatus that employs flash drums in series in conjunction with a warm recycle solvent slurry diluent.
摘要翻译：多峰聚烯烃聚合物可以在串联连接的聚合反应器中制备，其中先前的反应器是使用轻溶剂作为浆料介质的淤浆反应器和氢以限制聚合物分子量，来自先前反应器的聚合物产物在进入之前基本上不含氢气进入在低氢压力下操作以产生高分子量烯烃的随后聚合反应器。通过使用中间浆料转移系统和除氢装置，可以显着改善这种系列淤浆反应器聚乙烯方法的经济性和操作性能，该装置采用与热循环溶剂淤浆稀释剂连用的闪蒸筒。

6. 发明申请

US20030228971A1 Prealkylated olefin polymerization catalysts and olefin polymerization employing such catalysts 失效
标题翻译：使用这种催化剂的预烷基化烯烃聚合催化剂和烯烃聚合
公开(公告)号：US20030228971A1
公开(公告)日：2003-12-11
申请号：US10163703
申请日：2002-06-06
申请人： EQUISTAR CHEMICALS L.P.
发明人： Craig C. Meverden , Michael W. Lynch
IPC分类号： B01J031/00 , B01J037/00 , C08F004/02 , C08F004/60
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65922 , C08F110/02 , C08F4/65916 , C08F2500/03 , C08F2500/18
摘要： Prealkylation of a supported catalyst system comprising a transition metal or inner transition metal complex precatalyst and a bulky, non-coordinating anion on an inorganic support by treatment with a solution of metal alkyl in a ratio of metal of metal alkyl to transition metal or inner transition metal of precatalyst less than 20:1, and in an amount of solution insufficient to form a paste or dispersion provides supported catalysts of high olefin polymerization activity which promote production of polyolefins of low polydispersity and improved morphology.
摘要翻译：通过用金属烷基金属与过渡金属或内部转变的比例的金属烷基溶液处理，在无机载体上包含过渡金属或内过渡金属络合物预催化剂和体积大的非配位阴离子的负载型催化剂体系的预烷基化金属的预催化剂小于20:1，并且在不足以形成糊或分散体的溶液量中，提供了高烯烃聚合活性的负载催化剂，其促进低多分散性和改进形态的聚烯烃的生产。

7. 发明申请

US20030212175A1 Oriented high density polyethylene film, compositions and process suitable for preparation thereof 失效
标题翻译：定向高密度聚乙烯薄膜，适用于其制备的组合物和方法
公开(公告)号：US20030212175A1
公开(公告)日：2003-11-13
申请号：US10464276
申请日：2003-06-18
申请人： Equistar Chemicals, L.P.
发明人： Richard F. Tate , James V. Krohn
IPC分类号： C08K005/09 , C08F008/00
CPC分类号： C08J5/18 , C08J2323/06 , C08K5/09 , C08L23/06
摘要： The draw ratio and/or rate of stretch of HDPE in film orientation can be increased, or the breakage frequency at a given draw ratio and draw rate decreased by the addition of an orientation improving amount of a normally solid fatty carboxylic acid having a melting point lower than the orientation temperature of the film.
摘要翻译：可以提高膜取向中HDPE的拉伸比和/或拉伸速度，或者通过添加取向改善量的具有熔点的常规固体脂肪羧酸，给定拉伸比和拉伸速率下的断裂频率低于膜的取向温度。

8. 发明申请

US20030166805A1 Diimine complexes for olefin polymerization 失效
标题翻译：用于烯烃聚合的二亚胺络合物
公开(公告)号：US20030166805A1
公开(公告)日：2003-09-04
申请号：US10087028
申请日：2002-03-01
申请人： Equistar Chemicals L.P.
发明人： Linda N. Winslow
IPC分类号： C08F004/44 , B01J031/00 , C07F015/00 , C07C002/02
CPC分类号： C07F15/065 , C07C2/32 , C07C2531/22 , C07F15/0066 , C07F15/025 , C07F15/045 , C08F10/00 , C08F110/02 , C08F4/7006
摘要： The present invention provides a catalyst comprising a diimine complex coordinated a transition metal. The complex includes a Group 3 to 10 transition or lanthanide metal and one or more anionic or neutral ligands in an amount that satisfies the valency of the metal such that the complex has a net zero charge. The present invention also discloses a method for coupling olefins utilizing the catalyst of the present invention.
摘要翻译：本发明提供了一种催化剂，其包含配位过渡金属的二亚胺络合物。络合物包括第3至10族过渡金属或镧系元素金属和一种或多种以满足金属化合价的量的阴离子或中性配体，使得络合物具有净零电荷。本发明还公开了一种利用本发明的催化剂偶联烯烃的方法。

9. 发明申请

US20030162295A1 Injection pump assembly for a combinatorial reactor and related method 失效
标题翻译：用于组合反应器的注射泵组件及相关方法
公开(公告)号：US20030162295A1
公开(公告)日：2003-08-28
申请号：US10085912
申请日：2002-02-28
申请人： Equistar Chemicals L.P.
发明人： Ronnie E Wilson
IPC分类号： G01N035/10
CPC分类号： B01J19/0046 , B01J2219/00353 , B01J2219/00364 , B01J2219/00394 , B01L3/021 , C40B60/14 , Y10T137/0318 , Y10T137/0486 , Y10T137/0502 , Y10T436/11 , Y10T436/117497 , Y10T436/118339 , Y10T436/119163 , Y10T436/25 , Y10T436/2575
摘要： An injection pump assembly 10 in a chemical delivery system for simultaneously delivering reagents into a combinatorial reactor system having multiple injectors. The assembly 10 has a plurality of injectors 12, each injector 12 being in fluid communication with one of the multiple reactors. Each injector 12 has (1) a pump 14 in which a plunger 18 sealingly moves to ingest, store and discharge a flushing solvent 20; (2) a pipette assembly 22 for loading, storing, and discharging one or more reagents into one of the reactors in the combinatorial reactor system, first and second reservoirs for retaining some of the reagents; (3) one or more hollow needles 32, each for selectively delivering a reagent 24 to the first 28 or the second 24 reservoir; (4) a first valve 34 positioned downstream of the first 28 reservoir; and (5) a second valve 36 positioned downstream of the second 30 reservoir. When each valve 34, 36 is in a closed position, the reagents 24, 48 can be stored in isolation from each other. When each valve 34, 36 is in an open position, the reagents 24, 48 may flow through the pipette assembly 22. A 3-way valve 38 is positioned between the pump 14 and the pipette assembly 22. An actuator assembly 46 is in operable communication with each of the plurality of injectors so that the 3-way valves 38 of each injector may be repositioned in unison, thereby delivering precise amounts of the flushing solvent 20 and the reagents 24, 48 in varied or consistent amounts to each reactor in the combinatorial reactor system. The inventive method involves operation of the disclosed injection pump assembly.
摘要翻译：用于同时将试剂输送到具有多个注射器的组合反应器系统中的化学递送系统中的注射泵组件10。组件10具有多个喷射器12，每个喷射器12与多个反应器中的一个流体连通。每个喷射器12具有（1）泵14，其中柱塞18密封地移动以摄取，储存和排出冲洗溶剂20; （2）用于将一种或多种试剂装载，储存和排出到组合反应器系统中的一个反应器中的移液管组件22，用于保留一些试剂的第一和第二储存器; （3）一个或多个中空针32，每个用于选择性地将试剂24输送到第一28或第二24储存器; （4）位于第一28储存器下游的第一阀34; 和（5）位于第二30储存器下游的第二阀36。当每个阀34,36处于关闭位置时，试剂24,48可以彼此隔离存储。当每个阀34,36处于打开位置时，试剂24,48可以流过移液管组件22.三通阀38定位在泵14和移液管组件22之间。致动器组件46处于可操作的状态与多个喷射器中的每一个连通，使得每个喷射器的三通阀38可以一致地重新定位，从而以不同或一致的量将精确量的冲洗溶剂20和试剂24,48以一定的量递送到组合反应器系统。本发明的方法涉及所公开的注射泵组件的操作。

10. 发明申请

US20020115561A1 Single-site catalysts based on caged diimide ligands 失效
标题翻译：基于笼式二酰亚胺配体的单位点催化剂
公开(公告)号：US20020115561A1
公开(公告)日：2002-08-22
申请号：US10118107
申请日：2002-04-08
申请人： EQUISTAR CHEMICALS, L.P.
发明人： Gregory G. Hlatky , Jonathan L. Schuchardt
IPC分类号： B01J031/00 , C07F005/00
CPC分类号： C07F15/065 , C07C251/20 , C07C2603/90 , C07F15/045 , C08F10/00 , C08F4/7006
摘要： Single-site catalysts useful for polymerizing olefins are disclosed. The organometallic catalysts incorporate a Group 3 to 10 transition, lanthanide or actinide metal and a caged diimide ligand. The diimide ligands are made by a tandem Diels-Alder and photochemical null2null2null cycloaddition sequence to give a multicyclic dione, followed by condensation with a primary amine. Because a wide variety of caged diimide ligands are easy to prepare from commercially available dienes and dienophiles, the invention enables the preparation of a new family of single-site catalysts. Based on their unique structure and geometry, the catalysts offer polyolefin producers new ways to improve activity, control comonomer incorporation, or regulate polyolefin tacticity.
摘要翻译：公开了可用于聚合烯烃的单中心催化剂。有机金属催化剂包含第3至10族过渡态，镧系元素或锕系金属和笼状二酰亚胺配体。二酰亚胺配体由串联狄尔斯 - 阿尔德和光化学[2 + 2]环加成顺序制备，得到多环二酮，然后与伯胺缩合。由于各种笼形二酰亚胺配体易于由市售二烯和亲双烯体制备，本发明使得能够制备新的单中心催化剂系列。基于其独特的结构和几何结构，催化剂为聚烯烃生产商提供了改善活性，控制共聚单体掺入或调节聚烯烃立体规整度的新途径。

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