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1. 发明授权

US4462912A Process for removing molybdenum from aqueous manganese salt solutions 失效
标题翻译：从锰盐水溶液中除去钼的方法
公开(公告)号：US4462912A
公开(公告)日：1984-07-31
申请号：US444865
申请日：1982-11-26
申请人： Eberhard Preisler , Bernhard Hofmann , Gerhard Nolte
发明人： Eberhard Preisler , Bernhard Hofmann , Gerhard Nolte
IPC分类号： B01J39/02 , C01G39/00 , C01G45/00 , C22B34/34 , B01D15/00
CPC分类号： C01G39/003 , C01G45/00 , C22B3/24 , C22B34/34 , Y02P10/234 , Y10S210/912
摘要： The disclosure relates to a process for removing molybdenum from aqueous manganese(II)salt solutions by adsorbing the molybdenum on manganese dioxide and separating adsorbend and adsorbate from the purified manganese(II)salt solution. To this end, the disclosure provides for a pH value lower than 5 to be established in the manganese salt solution; for an oxidant capable of oxidizing manganese(II)compounds to manganese(IV)compounds to be added at temperatures between 50.degree. and 80.degree. C., so as to effect oxidation of a small proportion of dissolved manganese(II)salt to manganese dioxide; for resulting precipitate to be allowed to remain in contact over a period of at least 15 minutes with the manganese(II)salt solution, and for the precipitate to be separated from said solution at said temperatures.
摘要翻译：本公开内容涉及通过将钼吸附在二氧化锰上并从分离的吸附剂中并从纯化的锰（II）盐溶液中吸附而从含水（II）盐溶液中除去钼的方法。为此，本公开内容提供了在锰盐溶液中建立的低于5的pH值; 对于能够将锰（II）化合物氧化成在50至80℃温度下加入的锰（IV）化合物的氧化剂，以便将少量溶解的锰（II）盐氧化成二氧化锰 ; 使所得沉淀物与锰（II）盐溶液在至少15分钟的时间内保持接触，并使沉淀物在所述温度下与所述溶液分离。

2. 发明授权

US6043198A High-T.sub.c superconductor or precursor material for the oxide-powder-in-tube method (OPIT) 失效
标题翻译：用于氧化物管内法的高Tc超导体或前体材料（OPIT）
公开(公告)号：US6043198A
公开(公告)日：2000-03-28
申请号：US911699
申请日：1997-08-15
申请人： Marc Neubacher , Joachim Bock , Christoph Lang , Eberhard Preisler , Helga Weis
发明人： Marc Neubacher , Joachim Bock , Christoph Lang , Eberhard Preisler , Helga Weis
IPC分类号： C01G1/00 , C01G29/00 , C04B35/45 , C04B35/626 , C04B35/653 , H01B12/04 , H01B13/00 , H01L39/24 , H01B12/00 , C04B35/50 , H01L39/12
CPC分类号： C04B35/4525 , C04B35/4521 , C04B35/653 , H01L39/2477 , H01L39/248 , Y10S505/733 , Y10S505/739 , Y10S505/782
摘要： The present invention relates to a process for preparing a high-T.sub.c superconductor as a precursor material for the oxide-powder-in-tube method, which involves mixing the oxides of the elements Bi, Sr, Ca and Cu and completely melting them at temperatures of .gtoreq.1000.degree. C., then casting the melt onto a substrate which is kept at room temperature, and disintegrating the cooled melt block and grinding it into a powder.
摘要翻译：本发明涉及一种制备高Tc超导体作为氧化物管内管法的前体材料的方法，其包括将元素Bi，Sr，Ca和Cu的氧化物混合并在温度下完全熔化 > 1000℃，然后将熔体浇铸到保持在室温的基材上，并将冷却的熔体块分解并研磨成粉末。

3. 发明授权

US5409888A Process for producing a high-temperature superconductor and also shaped bodies composed thereof 失效
标题翻译：制造高温超导体的方法以及由其构成的成型体
公开(公告)号：US5409888A
公开(公告)日：1995-04-25
申请号：US179879
申请日：1994-01-11
申请人： Joachim Bock , Eberhard Preisler
发明人： Joachim Bock , Eberhard Preisler
IPC分类号： C04B35/00 , C01G1/00 , C04B35/45 , C04B35/653 , H01B12/00 , H01L39/24 , C01G29/00
CPC分类号： H01L39/2419 , C04B35/4521 , C04B35/653 , Y10S505/739 , Y10S505/782
摘要： To produce a high-temperature superconductor of the composition Bi.sub.2 (Sr,Ca).sub.3 Cu.sub.2 O.sub.8+x having a strontium to calcium ratio of 5:1 to 2:1 and a value of x between 0 and 2, the oxides and/or carbonates of bismuth, strontium, calcium and copper are vigorously mixed in a stoichiometric ratio. The mixture is heated at a temperature of 870.degree. to 1100.degree. C. until a homogeneous melt is obtained. The melt is poured into mold and allowed to solidify in them. The cast bodies removed from the molds are annealed for 6 to 30 hours at 780.degree. to 850.degree. C. Finally, the annealed cast bodies are treated for at least 6 hours at temperatures of 600.degree. to 820.degree. C. in an oxygen atmosphere. The cast bodies can be converted into shaped bodies of the desired sizes by mechanical processes before they are annealed. The shape and size of the shaped bodies may also be determined by the shape and dimensioning of the mold used in producing the cast bodies.
摘要翻译：为了制备锶与钙的比例为5:1-2:1的组成Bi2（Sr，Ca）3Cu2O8 + x的高温超导体，x值在0和2之间，氧化物和/或碳酸盐铋，锶，钙和铜以化学计量比剧烈混合。将混合物在870℃至1100℃的温度下加热直到获得均匀的熔体。将熔体倒入模具中并使其在其中固化。从模具中取出的铸体在780〜850℃退火6〜30小时。最后，将退火后的铸体在氧气氛中600〜820℃的温度下处理6小时以上。在退火之前，铸造体可以通过机械工艺转化成所需尺寸的成型体。成型体的形状和尺寸也可以通过用于制造铸体的模具的形状和尺寸确定。

4. 发明授权

US5362712A Process for removing a copper mold from a molded body 失效
标题翻译：从成形体中除去铜模的工序
公开(公告)号：US5362712A
公开(公告)日：1994-11-08
申请号：US81855
申请日：1993-06-23
申请人： Eberhard Preisler , Joachim Bock
发明人： Eberhard Preisler , Joachim Bock
IPC分类号： C01G1/00 , C01G29/00 , C04B35/45 , C04B35/653 , C04B41/91 , C23F1/18 , H01L39/24 , H01L39/12 , C23F1/00
CPC分类号： C23F1/18 , C04B35/45 , C04B35/653 , H01L39/2419
摘要： In the process for producing molded bodies from precursors of oxidic high-temperature superconductors a copper mold of the desired shape which encloses a solidified bismuth strontium calcium cuprate melt is treated with a solution of a soluble compound containing sulfate anions, an aqueous mineral acid and an oxidizing agent until the copper mold is dissolved. A protective layer of at least one of strontium sulfate or calcium sulfate is formed on the solidified melt.
摘要翻译：在从氧化高温超导体的前体制备成型体的方法中，将含有硫酸铋钙铜酸盐熔体的所需形状的铜模具用含硫酸根阴离子，无机酸水溶液和氧化剂直到铜模溶解。在固化的熔体上形成硫酸锶或硫酸钙中的至少一种的保护层。

5. 发明授权

US5250507A Process for producing molded bodies from precursors of oxidic high-temperature superconductors 失效
标题翻译：用于从氧化高温超导体的前体制备成型体的方法
公开(公告)号：US5250507A
公开(公告)日：1993-10-05
申请号：US739871
申请日：1991-08-02
申请人： Eberhard Preisler , Joachim Bock
发明人： Eberhard Preisler , Joachim Bock
IPC分类号： C01G1/00 , C01G29/00 , C04B35/45 , C04B35/653 , C25F3/02 , C25F5/00 , H01B12/00 , H01B13/00 , H01L39/24 , H01B12/02
CPC分类号： C04B35/45 , C04B35/653 , C25F5/00 , H01L39/2419 , Y10S505/728 , Y10S505/739
摘要： In the process for producing molded bodies from precursors of oxidic high-temperature superconductors of the BSCCO type, a copper mold of the desired shape which encloses a solidified bismuth strontium calcium cuprate melt is wired as anode in a direct current circuit composed of anode, cathode and an electrolyte, a dilute sulfuric acid is used as electrolyte and the electrolyte is subjected to a direct current of 1 to 50 mA.cm.sup.-2 until the copper mold wired as anode is dissolved and the BSCCO molded body is laid bare.
摘要翻译：在由BSCCO型氧化物高温超导体的前体生产成型体的方法中，将包含凝固的锶锶钙铜酸盐熔体的期望形状的铜模具作为阳极接线在由阳极，阴极使用电解液，稀硫酸作为电解质，电解液的直流电流为1〜50mA·cm -2，直到铜阳极连接的铜模被溶解，并将BSCCO成型体裸露。

6. 发明授权

US5670434A (Bi,Pb)SrCaCuO precursor material for the oxide powder in tube method (OPIT) 失效
标题翻译：制备高Tc超导体作为氧化物粉末管内法（opit）的前体材料的方法
公开(公告)号：US5670434A
公开(公告)日：1997-09-23
申请号：US594035
申请日：1996-01-30
申请人： Marc Neubacher , Joachim Bock , Christoph Lang , Eberhard Preisler , Helga Weis
发明人： Marc Neubacher , Joachim Bock , Christoph Lang , Eberhard Preisler , Helga Weis
IPC分类号： C01G1/00 , C01G29/00 , C04B35/45 , C04B35/626 , C04B35/653 , H01B12/04 , H01B13/00 , H01L39/24 , C04B35/01 , H01B12/00
CPC分类号： C04B35/4525 , C04B35/4521 , C04B35/653 , H01L39/2477 , H01L39/248 , Y10S505/733 , Y10S505/739 , Y10S505/782
摘要： Process for preparing a high-T.sub.c superconductor as a precursor material for the oxide-powder-in-tube method (OPIT). The present invention relates to a process for preparing a high-T.sub.c superconductor as a precursor material for the oxide-powder-in-tube method, which involves mixing the oxides of the elements Bi, Sr, Ca and Cu and completely melting them at temperatures of >1000.degree. C., then casting the melt onto a substrate which is kept at room temperature, and disintegrating the cooled melt block and grinding it into a powder.
摘要翻译：制备高Tc超导体作为氧化物管内法（OPIT）的前体材料的方法。本发明涉及一种制备高Tc超导体作为氧化物管内管法的前体材料的方法，其包括将元素Bi，Sr，Ca和Cu的氧化物混合并在温度下完全熔化 > 1000℃，然后将熔体浇注到保持在室温的基材上，并将冷却的熔体块分解并粉碎成粉末。

7. 发明授权

US5371068A Process for producing tubular molded parts of high temperature superconductor material 失效
标题翻译：生产高温超导体材料的管状模制件的工艺
公开(公告)号：US5371068A
公开(公告)日：1994-12-06
申请号：US47609
申请日：1993-04-14
申请人： Eberhard Preisler , Joachim Bock , Johannes Holzem , Friedrich-Wilhelm Dorn
发明人： Eberhard Preisler , Joachim Bock , Johannes Holzem , Friedrich-Wilhelm Dorn
IPC分类号： C01G1/00 , B22D13/02 , B28B21/30 , C01G29/00 , C04B35/00 , C04B35/45 , C04B35/653 , C04B41/80 , H01L39/24 , H01L39/12
CPC分类号： C04B35/4521 , B22D13/02 , B28B21/30 , C04B35/653 , H01L39/2419
摘要： To produce tubular molded parts made of high-temperature superconductor oxide material based on bismuth, calcium, strontium and copper, a homogeneous melt of the oxide with a specified stoichiometry is allowed to run at temperatures of 900.degree. to 1100.degree. C. into a casting zone rotating about its horizontal axis. The solidified molded part is removed from the casting zone and it is annealed for 4 to 150 hours at 700.degree. to 900.degree. C. in an oxygen-containing atmosphere. A plant for producing tubular molded parts includes a rotatably arranged mold (4, 9) which is provided at least at one end face with a front plate 6 which reduces its free cross section, a runner 7 extending into the interior of the mold (4, 9) and a crucible 8 arranged above the runner 7 which is capable of feeding the runner 7 with melt (cf. FIG. 2 A).
摘要翻译：为了生产由基于铋，钙，锶和铜的高温超导体氧化物材料制成的管状模制部件，使具有特定化学计量的氧化物的均匀熔体在900至1100℃的温度下进入铸造区域围绕其水平轴线旋转。将凝固的模制件从铸造区域中取出，并在含氧气氛中在700-900℃退火4至150小时。用于生产管状模制件的设备包括可旋转地布置的模具（4,9），其至少在一个端面处设置有前板6，其减小其自由横截面;延伸到模具（4）内部的流道7 ，9）和布置在流道7上方的坩埚8，坩埚8能够将流道7熔化（参见图2A）。

8. 发明授权

US5294601A High-temperature superconductor comprising barium sulfate, strontium sulfate or mixtures thereof and a process for its preparation 失效
标题翻译：包含硫酸钡，硫酸锶或其混合物的高温超导体及其制备方法
公开(公告)号：US5294601A
公开(公告)日：1994-03-15
申请号：US911466
申请日：1992-07-10
申请人： Joachim Bock , Eberhard Preisler
发明人： Joachim Bock , Eberhard Preisler
IPC分类号： C01G1/00 , C01G29/00 , C04B35/00 , C04B35/45 , C04B35/653 , H01B12/00 , H01B13/00 , H01L39/24 , C01F11/02 , C01G3/02 , H01L39/12
CPC分类号： H01L39/2419 , C04B35/4521 , C04B35/4525 , Y10S505/739 , Y10S505/782 , Y10S505/785
摘要： The invention relates to a high-temperature superconductor composed of the oxides of bismuth, strontium, calcium and copper and, optionally, of lead, and having the composition Bi.sub.2-a+b+c Pb.sub.a (Sr, Ca).sub.3-b-c Cu.sub.2+d O.sub.x, where a=0 to 0.7; b+c=0 to 0.5; d=-0.1 to 0.1 and x=7 to 10 and a Sr:Ca ratio of 2.8:1 to 1:2.8 as well as of strontium and/or barium sulfates. Said superconductor can be prepared by intimately mixing the oxides of bismuth, strontium, calcium and copper and optionally of lead with strontium and/or barium sulfates, melting the mixture by heating to temperatures of 870 to 1300.degree. C., higher temperatures being required for higher strontium and/or barium sulfate contents, pouring the melt into molds and allowing it to solidify slowly therein and subjecting the moldings removed from the molds to a heat treatment at temperatures of 700 to 900.degree. C. in an oxygen-containing atmosphere.
摘要翻译：本发明涉及由铋，锶，钙和铜的氧化物和任选的铅组成的具有Bi 2-a + b + c Pba（Sr，Ca）3-bc Cu 2+的组成的高温超导体， d Ox，其中a = 0至0.7; b + c = 0〜0.5; d = -0.1至0.1和x = 7至10，Sr：Ca比为2.8:1至1:2.8，以及锶和/或硫酸钡。所述超导体可以通过将铋，锶，钙和铜的氧化物和任选的铅与锶和/或硫酸钡紧密混合来制备，通过加热至870至1300℃的温度将该混合物熔化，需要较高的温度较高的锶和/或硫酸钡含量，将熔体注入模具中并使其在其中缓慢固化，并使在模具中除去的模制品在含氧气氛中在700-900℃的温度下进行热处理。

9. 发明授权

US5244876A Method for joining parts of ceramic high-temperature superconductor material 失效
标题翻译：陶瓷高温超导体材料接合方法
公开(公告)号：US5244876A
公开(公告)日：1993-09-14
申请号：US966589
申请日：1992-10-26
申请人： Eberhard Preisler , Joachim Bock , Johannes Holzem , Werner Horst
发明人： Eberhard Preisler , Joachim Bock , Johannes Holzem , Werner Horst
IPC分类号： C04B35/45 , C04B37/00 , H01L39/02
CPC分类号： C04B35/4525 , C04B37/005 , H01L39/02 , C04B2237/06 , C04B2237/34 , C04B2237/78 , C04B2237/80 , Y10S505/739 , Y10S505/782
摘要： Method for joining parts of ceramic high-temperature superconductor material of the composition Bi.sub.(2+a-b) (Sr.sub.1-c) Ca.sub.c) .sub.(3-a) Pb.sub.b Cu.sub.(2+d) O.sub.x, where a is 0 to 0.3, b is 0 to 0.5, c is 0.1 to 0.9 and d is 0 to 2 and x has a value depending on the state of oxidation of the metals present, the end faces of the parts located at a gap spacing apart from one another are heated by means of a fuel gas/oxygen flame to temperatures from 750.degree. to 875.degree. C. Simultaneously, a rod of the same material above the spacing gap is heated until the melt thereof drips off into the gap between the end faces of the two parts, completely filling the gap. At least the joint region between the two parts is then heat-treated for 7 to 100 hours at temperatures between 780.degree. and 850.degree. C.
摘要翻译：组合物Bi（2 + ab）（Sr1-c）Cac）（3-a）PbbCu（2 + d）Ox的陶瓷高温超导体材料部分的方法，其中a为0至0.3，b为0 至0.5，c为0.1至0.9，d为0至2，x具有取决于存在的金属的氧化状态的值，位于间隔间隔的部分的端面通过燃料气体/氧气火焰至750℃至875℃的温度。同时，将间隔间隔上方的相同材料的棒加热直到其熔体滴落到两部分的端面之间的间隙中，完全填充差距。至少两部分之间的接合区域在780〜850℃的温度下进行7〜100小时的热处理。

10. 发明授权

US5162300A Process for producing a high-temperature superconductor 失效
标题翻译：生产高温超导体的工艺
公开(公告)号：US5162300A
公开(公告)日：1992-11-10
申请号：US676784
申请日：1991-03-28
申请人： Joachim Bock , Eberhard Preisler
发明人： Joachim Bock , Eberhard Preisler
IPC分类号： C01G1/00 , C01G29/00 , C04B35/00 , C04B35/45 , H01B12/00 , H01B13/00 , H01L39/24
CPC分类号： H01L39/2419 , C01G29/006 , C04B35/4521 , C01P2002/50 , C01P2002/72 , C01P2004/84 , Y10S505/782
摘要： To produce a high-temperature superconductor of the composition Bi.sub.(2+a) (Sr.sub.(1-b) Ca.sub.b).sub.(3-a) Cu.sub.(2+c) O.sub.(8+x), where a is from 0 to 0.3, b is from 0.1 to 0.9 and c is from 0 to 2, and x has a value which depends on the oxidation state of the metals contained, oxides and/or carbonates of bismuth, strontium, calcium and copper are thoroughly mixed. In this process, the copper compound is used as a mixture of copper(I) oxide and copper(II) oxide. Then the mixture of oxides and/or carbonates is first allowed to react mutually in an inert gas atmosphere at temperatures from 700.degree. to 800.degree. C. for 0.5 to 36 hours before subsequently treating the mixture in an oxygen-containing atmosphere at temperatures from 700.degree. to 875.degree. C. for 3 to 60 hours.
摘要翻译：为了制备组成为Bi（2 + a）（Sr（1-b）Cab）（3-a）Cu（2 + c）O（8 + x）的高温超导体，其中a为0至0.3 ，b为0.1〜0.9，c为0〜2，x的值取决于所含金属的氧化态，铋，锶，钙，铜的氧化物和/或碳酸盐充分混合。在该方法中，铜化合物用作氧化铜（I）和氧化铜（II）的混合物。然后首先使氧化物和/或碳酸盐的混合物在惰性气体气氛中在700至800℃的温度下相互反应0.5至36小时，随后在含氧气氛中在700℃的温度下处理混合物 DEG至875℃3至60小时。

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