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    • 1. 发明申请
    • METHOD FOR ELECTROLYTIC PRODUCTION AND REFINING OF METALS
    • 电解生产和金属精炼方法
    • WO2007106709A9
    • 2008-01-03
    • PCT/US2007063555
    • 2007-03-08
    • ELKEM ASDONALD SADOWAYJOHANSEN KAIMYHRE BJORNENGVOLL MARIANNEENGVOLL KRISTER
    • DONALD SADOWAYJOHANSEN KAIMYHRE BJORNENGVOLL MARIANNEENGVOLL KRISTER
    • C22B15/00
    • C25C3/28C25B1/006C25C3/34C25C7/005
    • The present invention relates to a method for electrolytic production and refining of metals having a melting point above about 1000 0C, particularly silicon, where there is provided a first electrolytic cell having an upper molten electrolyte layer of a first electrolyte, a lower molten alloy layer of an alloy of the metal to be refined and at least one metal more noble than the metal to be refined. The lower alloy layer is the cathode in the first cell and an anode is positioned in the upper molten electrolyte layer. A second electrolytic cell is also provided with an upper molten metal layer of the same metal as the metal to be refined, said layer constituting a cathode, a lower molten alloy layer, said lower layer constituting an anode, said alloy having a higher density than the metal to be refined, and an intermediate molten electrolyte layer having a density between the density of the upper and lower molten layers. Both electrolytes are oxide based electrolytes containing oxide of the metal to be refined, and the electrolyte is in molten state and has a melting point below the operating temperature of the process. Raw material comprising an oxide of the metal to be refined is added to the first cell and direct electric current is passed through the anode to the cathode such that the metal to be refined is moved from the anode and deposited in molten state at the cathode. The two cells can be operated in two separate steps. One to produce an alloy and the other to refine metal from the alloy.
    • 本发明涉及熔点高于约1000℃,特别是硅的金属的电解生产和精炼方法,其中提供了具有第一电解质的上部熔融电解质层的第一电解槽,下部熔融合金层 要被精炼的金属的合金和至少一种比待精炼的金属更贵的金属。 下合金层是第一电池中的阴极,阳极位于上部熔融电解质层中。 第二电解槽还设置有与待精炼的金属相同的金属的上部熔融金属层,所述层构成阴极,下部熔融合金层,所述下层构成阳极,所述合金的密度高于 待精炼的金属,以及具有上下熔融层的密度之间的密度的中间熔融电解质层。 两种电解质都是含有待精炼金属的氧化物的基于氧化物的电解质,电解质处于熔融状态,熔点低于工艺的工作温度。 将包含待精炼金属的氧化物的原料加入到第一电池中,直接电流通过阳极进入阴极,使得待精炼的金属从阳极移动并在阴极处以熔融状态沉积。 两个电池可以在两个单独的步骤中操作。 一种是生产合金,另一种是从合金中精炼金属。
    • 2. 发明申请
    • METHOD FOR ELECTROLYTIC PRODUCTION AND REFINING OF METALS
    • 金属电解生产和精炼的方法
    • WO2007106709A2
    • 2007-09-20
    • PCT/US2007/063555
    • 2007-03-08
    • ELKEM ASDONALD, SadowayJOHANSEN, KaiMYHRE, BjornENGVOLL, MarianneENGVOLL, Krister
    • DONALD, SadowayJOHANSEN, KaiMYHRE, BjornENGVOLL, MarianneENGVOLL, Krister
    • C25B1/00C25C3/36
    • C25C3/28C25B1/006C25C3/34C25C7/005
    • The present invention relates to a method for electrolytic production and refining of metals having a melting point above about 1000 0C, particularly silicon, where there is provided a first electrolytic cell having an upper molten electrolyte layer of a first electrolyte, a lower molten alloy layer of an alloy of the metal to be refined and at least one metal more noble than the metal to be refined. The lower alloy layer is the cathode in the first cell and an anode is positioned in the upper molten electrolyte layer. A second electrolytic cell is also provided with an upper molten metal layer of the same metal as the metal to be refined, said layer constituting a cathode, a lower molten alloy layer, said lower layer constituting an anode, said alloy having a higher density than the metal to be refined, and an intermediate molten electrolyte layer having a density between the density of the upper and lower molten layers. Both electrolytes are oxide based electrolytes containing oxide of the metal to be refined, and the electrolyte is in molten state and has a melting point below the operating temperature of the process. Raw material comprising an oxide of the metal to be refined is added to the first cell and direct electric current is passed through the anode to the cathode such that the metal to be refined is moved from the anode and deposited in molten state at the cathode. The two cells can be operated in two separate steps. One to produce an alloy and the other to refine metal from the alloy.
    • 本发明涉及一种用于电解生产和精炼熔点高于约1000℃的金属,特别是硅的方法,其中提供了第一电解槽,其具有上部熔融电解质层 第一电解质,待精炼金属与至少一种比待精炼金属更贵重的金属的合金的下熔融合金层。 下部合金层是第一电池中的阴极,并且阳极位于上部熔融电解质层中。 第二电解槽还具有与待精炼的金属相同金属的上部熔融金属层,所述层构成阴极,下部熔融合金层,所述下部层构成阳极,所述合金的密度高于 待精炼的金属以及中间熔融电解质层,所述中间熔融电解质层的密度介于上部和下部熔融层的密度之间。 这两种电解质都是含有待精制金属的氧化物的氧化物基电解质,并且电解质处于熔融状态并具有低于该工艺操作温度的熔点。 将包含待精制的金属的氧化物的原材料添加到第一电池中,并将直流电流通过阳极到达阴极,使得待精制的金属从阳极移动并在阴极处以熔融状态沉积。 这两个电池可以分两个步骤操作。 一个生产合金,另一个精炼合金中的金属。
    • 3. 发明申请
    • METHOD FOR ELECTROLYTIC PRODUCTION AND REFINING OF METALS
    • 电解生产和金属精炼方法
    • WO2007106709A3
    • 2007-11-29
    • PCT/US2007063555
    • 2007-03-08
    • ELKEM ASDONALD SADOWAYJOHANSEN KAIMYHRE BJORNENGVOLL MARIANNEENGVOLL KRISTER
    • DONALD SADOWAYJOHANSEN KAIMYHRE BJORNENGVOLL MARIANNEENGVOLL KRISTER
    • C22B15/00
    • C25C3/28C25B1/006C25C3/34C25C7/005
    • The present invention relates to a method for electrolytic production and refining of metals having a melting point above about 1000 0C, particularly silicon, where there is provided a first electrolytic cell having an upper molten electrolyte layer of a first electrolyte, a lower molten alloy layer of an alloy of the metal to be refined and at least one metal more noble than the metal to be refined. The lower alloy layer is the cathode in the first cell and an anode is positioned in the upper molten electrolyte layer. A second electrolytic cell is also provided with an upper molten metal layer of the same metal as the metal to be refined, said layer constituting a cathode, a lower molten alloy layer, said lower layer constituting an anode, said alloy having a higher density than the metal to be refined, and an intermediate molten electrolyte layer having a density between the density of the upper and lower molten layers. Both electrolytes are oxide based electrolytes containing oxide of the metal to be refined, and the electrolyte is in molten state and has a melting point below the operating temperature of the process. Raw material comprising an oxide of the metal to be refined is added to the first cell and direct electric current is passed through the anode to the cathode such that the metal to be refined is moved from the anode and deposited in molten state at the cathode. The two cells can be operated in two separate steps. One to produce an alloy and the other to refine metal from the alloy.
    • 本发明涉及熔点高于约1000℃,特别是硅的金属的电解生产和精炼方法,其中提供了具有第一电解质的上部熔融电解质层的第一电解槽,下部熔融合金层 要被精炼的金属的合金和至少一种比待精炼的金属更贵的金属。 下合金层是第一电池中的阴极,阳极位于上部熔融电解质层中。 第二电解槽还设置有与待精炼的金属相同的金属的上部熔融金属层,所述层构成阴极,下部熔融合金层,所述下层构成阳极,所述合金的密度高于 待精炼的金属,以及具有上下熔融层的密度之间的密度的中间熔融电解质层。 两种电解质都是含有待精炼金属的氧化物的基于氧化物的电解质,电解质处于熔融状态,熔点低于工艺的工作温度。 将包含待精炼金属的氧化物的原料加入到第一电池中,直接电流通过阳极进入阴极,使得待精炼的金属从阳极移动并在阴极处以熔融状态沉积。 两个电池可以在两个单独的步骤中操作。 一种是生产合金,另一种是从合金中精炼金属。