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1. 发明授权

US08871827B2 Hotmelt adhesive comprising radiation-crosslinkable poly(meth)acrylate and oligo(meth)acrylate with nonacrylic C-C double bonds 有权
标题翻译：包含可辐射交联的聚（甲基）丙烯酸酯和具有非丙烯酸C-C双键的低聚（甲基）丙烯酸酯）的热熔粘合剂
公开(公告)号：US08871827B2
公开(公告)日：2014-10-28
申请号：US13487550
申请日：2012-06-04
申请人： Ulrike Licht , Dirk Wulff , Thomas Christ , Ulrich Filges
发明人： Ulrike Licht , Dirk Wulff , Thomas Christ , Ulrich Filges
IPC分类号： C08F20/22 , B29D11/00 , C08F2/46 , C08G61/04 , C09J133/10
CPC分类号： C09J133/10 , C08L2312/06 , Y10T428/2826
摘要： Described is a radiation-crosslinkable hotmelt adhesive comprising at least one radiation-crosslinkable poly(meth)acrylate formed to an extent of at least 60% by weight of C1 to C10 alkyl(meth)acrylates and at least one oligo(meth)acrylate which comprises nonacrylic C C double bonds and has a K value of less than or equal to 20. The hotmelt adhesive comprises a photoinitiator which may be present in the form of an additive not attached to the poly(meth)acrylate and/or not attached to the oligo(meth)acrylate, may be incorporated by copolymerization into the poly(meth)acrylate, and/or may be attached to the oligo(meth)acrylate. The hotmelt adhesive can be used for producing adhesive tapes.
摘要翻译：描述了一种辐射可交联的热熔粘合剂，其包含至少一种以至少60重量％的C 1 -C 10烷基（甲基）丙烯酸酯和至少一种低聚（甲基）丙烯酸酯的至少一种可辐射交联的聚（甲基）丙烯酸酯的程度形成的至少一种低聚（甲基）丙烯酸酯，包括非丙烯酸CC双键，并且具有小于或等于20的K值。热熔粘合剂包括光引发剂，其可以不附着于聚（甲基）丙烯酸酯的添加剂形式存在和/或不附着于聚低级（甲基）丙烯酸酯可以通过共聚合引入聚（甲基）丙烯酸酯中，和/或可以连接到低聚（甲基）丙烯酸酯上。热熔粘合剂可用于生产胶带。

2. 发明申请

US20120315474A1 HOTMELT ADHESIVE COMPRISING RADIATION-CROSSLINKABLE POLY(METH)ACRYLATE AND OLIGO(METH)ACRYLATE WITH NONACRYLIC C-C DOUBLE BONDS 有权
标题翻译：含有非丙烯酸C-C双键的辐射可交联聚（甲基）丙烯酸酯和低聚（甲基）丙烯酸酯的热熔胶
公开(公告)号：US20120315474A1
公开(公告)日：2012-12-13
申请号：US13487550
申请日：2012-06-04
申请人： Ulrike LICHT , Dirk Wulff , Thomas Christ , Ulrich Filges
发明人： Ulrike LICHT , Dirk Wulff , Thomas Christ , Ulrich Filges
IPC分类号： C09J133/10 , C09J7/02
CPC分类号： C09J133/10 , C08L2312/06 , Y10T428/2826
摘要： Described is a radiation-crosslinkable hotmelt adhesive comprising at least one radiation-crosslinkable poly(meth)acrylate formed to an extent of at least 60% by weight of C1 to C10 alkyl (meth)acrylates and at least one oligo(meth)acrylate which comprises nonacrylic C—C double bonds and has a K value of less than or equal to 20.The hotmelt adhesive comprises a photoinitiator which may be present in the form of an additive not attached to the poly(meth)acrylate and/or not attached to the oligo(meth)acrylate, may be incorporated by copolymerization into the poly(meth)acrylate, and/or may be attached to the oligo(meth)acrylate. The hotmelt adhesive can be used for producing adhesive tapes.
摘要翻译：描述了一种辐射可交联的热熔粘合剂，其包含至少一种以至少60重量％的C 1 -C 10烷基（甲基）丙烯酸酯和至少一种低聚（甲基）丙烯酸酯的至少一种可辐射交联的聚（甲基）丙烯酸酯的程度形成的至少一种低聚（甲基）丙烯酸酯，包括非丙烯酸C-C双键，并且具有小于或等于20的K值。热熔粘合剂包括光引发剂，其可以不附着于聚（甲基）丙烯酸酯和/或未附着的添加剂的形式存在（甲基）丙烯酸酯可以通过共聚合引入聚（甲基）丙烯酸酯中，和/或可以连接到低聚（甲基）丙烯酸酯上。热熔粘合剂可用于生产胶带。

3. 发明申请

US20120263950A1 PRESSURE-SENSITIVE ADHESIVE DISPERSION COMPRISING POLYMERS WITH UREIDO GROUPS OR UREIDO-ANALOGOUS GROUPS AND WITH GLYCIDYL GROUPS 有权
标题翻译：包含尿素组或尿嘧啶类和聚糖类聚合物的压敏胶粘剂分散体
公开(公告)号：US20120263950A1
公开(公告)日：2012-10-18
申请号：US13443284
申请日：2012-04-10
申请人： Matthias GERST , Dirk Wulff , Heinrich Harrer
发明人： Matthias GERST , Dirk Wulff , Heinrich Harrer
IPC分类号： C09J163/00 , B32B27/38
CPC分类号： C09J4/00 , C08F2/22 , C09J7/385 , C09J109/06 , C09J133/02 , C09J133/066 , C09J133/068 , C09J133/08 , C09J133/12 , C09J133/14 , C09J139/04 , C09J2201/606 , C09J2433/00 , Y10T428/287 , C08F2220/185 , C08F220/14 , C08F2220/387 , C08F220/20 , C08F220/06 , C08F212/08 , C08F2220/325
摘要： A description is given of a pressure-sensitive adhesive dispersion comprising a water-dispersed polymer P1 formed by emulsion polymerization. The polymer P1 is formed from a monomer mixture comprising (a) at least 40% by weight of C4 to C20 alkyl (meth)acrylates which when polymerized as homopolymers have a glass transition temperature of −30° C. or less, (b) at least 0.05% by weight of (meth)acrylate monomers having a substituent of the formula where X is CH2, O, NH or NR and R is a C1 to C4 alkyl group, (c) at least 0.1% by weight of acid monomers. The monomer mixture comprises alternatively at least 0.05% by weight of glycidyl (meth)acrylate and/or the pressure-sensitive adhesive dispersion comprises at least one further polymer P2 which contains glycidyl groups.
摘要翻译：给出了包含通过乳液聚合形成的水分散聚合物P1的压敏粘合剂分散体的描述。聚合物P1由包含（a）至少40重量％的（甲基）丙烯酸C 4至C 20烷基酯的单体混合物形成，当聚均为均聚物的玻璃化转变温度为-30℃或更低时，（b）至少0.05重量％的具有下式的取代基的（甲基）丙烯酸酯单体，其中X是CH 2，O，NH或NR，R是C 1至C 4烷基，（c）至少0.1重量％的酸单体。单体混合物可选地包含至少0.05重量％的（甲基）丙烯酸缩水甘油酯和/或压敏粘合剂分散体包含至少一种含有缩水甘油基的另外的聚合物P2。

4. 发明申请

US20120261070A1 PRESSURE-SENSITIVE ADHESIVE DISPERSION COMPRISING POLYMERS WITH UREIDO GROUPS OR WITH UREIDO-ANALOGOUS GROUPS AND PREPARED BY STAGE POLYMERIZATION 有权
标题翻译：包含尿素组合或尿素类聚合物的聚合物的压敏粘合剂分散体，并通过阶段聚合制备
公开(公告)号：US20120261070A1
公开(公告)日：2012-10-18
申请号：US13443044
申请日：2012-04-10
申请人： Matthias GERST , Dirk Wulff , Thomas Christ
发明人： Matthias GERST , Dirk Wulff , Thomas Christ
IPC分类号： B32B7/12 , C09J4/02
CPC分类号： C09J4/00 , C09J133/00 , C09J133/14 , Y10T428/2848 , Y10T428/2887
摘要： A description is given of a pressure-sensitive adhesive dispersion comprising a water-dispersed polymer P1 formed by emulsion polymerization. The polymer P1 is formed from a monomer mixture comprising (a) at least 40% by weight of C4 to C20 alkyl (meth)acrylates which when polymerized as homopolymers have a glass transition temperature of −30° C. or less, (b) at least 0.05% by weight of (meth)acrylate monomers having a substituent of the formula where X is CH2, O, NH or NR and R is a C1 to C4 alkyl group, (c) at least 0.1% by weight of acid monomers. The polymer P1 is prepared by polymerization in at least 2 stages, the glass transition temperature of a polymer from monomers of the first stage being lower by at least 20° C. than the glass transition temperature of a polymer from monomers of a later, second stage.
摘要翻译：给出了包含通过乳液聚合形成的水分散聚合物P1的压敏粘合剂分散体的描述。聚合物P1由包含（a）至少40重量％的（甲基）丙烯酸C 4至C 20烷基酯的单体混合物形成，当聚均为均聚物的玻璃化转变温度为-30℃或更低时，（b）至少0.05重量％的具有下式的取代基的（甲基）丙烯酸酯单体，其中X是CH 2，O，NH或NR，R是C 1至C 4烷基，（c）至少0.1重量％的酸单体。聚合物P1通过至少两个阶段的聚合制备，聚合物的玻璃化转变温度从第一阶段的单体的玻璃化转变温度比聚合物的玻璃化转变温度低至少20℃，后者的第二阶段的单体阶段。

5. 发明申请

US20120043493A1 SOUND DEADENER COMPOSITION WITH EMULSION POLYMER AND FLUORINATED COMPOUND 审中-公开
标题翻译：具有乳液聚合物和氟化合物的声衰减剂组合物
公开(公告)号：US20120043493A1
公开(公告)日：2012-02-23
申请号：US13211856
申请日：2011-08-17
申请人： Gledison FONSECA , Dirk Wulff , Axel Weiss
发明人： Gledison FONSECA , Dirk Wulff , Axel Weiss
IPC分类号： E04B1/74 , B05D3/02
CPC分类号： C08K13/02 , C09D5/024 , G10K11/165
摘要： A description is given of a sound deadener composition comprising a polymer dispersion comprising (a) at least one water-dispersed polymer obtainable by emulsion polymerization of free-radically polymerizable monomers and having a glass transition temperature in the range from −60 to +60° C.; (b) inorganic fillers; and (c) at least one fluorinated compound selected from perfluoroalkyl-substituted carboxylic acids and their salts, fluorocarbon resins, surface-active, fluoroaliphatic polymeric esters, and fluorine-containing, acrylate-based copolymers. A description is also given of a method for damping oscillations or vibrations of components of vehicles and machines, using the sound deadener composition of the invention.
摘要翻译：描述了包含聚合物分散体的声音减弱剂组合物，其包含（a）至少一种水分散聚合物，其可通过可自由基聚合的单体的乳液聚合获得并且玻璃化转变温度在-60至+60° C。; （b）无机填料; 和（c）至少一种选自全氟烷基取代的羧酸及其盐的氟化化合物，氟碳树脂，表面活性，氟代脂族聚合酯和含氟丙烯酸酯基共聚物。还给出了使用本发明的消音组合物来抑制车辆和机器的部件的振动或振动的方法的描述。

6. 发明申请

US20120016079A1 PROCESS FOR PREPARING SOLUTIONS OF RADIATION-SENSITIVE, FREE-RADICALLY POLYMERIZABLE ORGANIC COMPOUNDS 有权
标题翻译：制备辐射敏感性，无机可聚合有机化合物溶液的方法
公开(公告)号：US20120016079A1
公开(公告)日：2012-01-19
申请号：US13258899
申请日：2010-03-30
申请人： Verena Weiskopf , Franz Niklaus Windlin , Harald Winsel , Markus Ruckpaul , Dirk Wulff , Uwe Duesterwald , Ulrike Licht
发明人： Verena Weiskopf , Franz Niklaus Windlin , Harald Winsel , Markus Ruckpaul , Dirk Wulff , Uwe Duesterwald , Ulrike Licht
IPC分类号： C08F220/10 , C08K5/07 , C08F2/06
CPC分类号： C08F220/06 , C07C68/02 , C08F212/08 , C08F212/12 , C08F2220/1825 , C09D133/08 , C09J133/08 , C09J2201/606 , C09J2201/61 , C07C69/96 , C08F2220/301
摘要： A description is given of a process for preparing solutions of radiation-sensitive, free-radically polymerizable organic compounds, where a first starting compound, which has an acid halide group, and a second starting compound, which has an alcoholic hydroxyl group, are esterified with one another in a solvent or in a solvent mixture. The solvent comprises one or more ketones having a boiling point of below 150° C. under atmospheric pressure (1 bar), or the solvent mixture is composed to an extent of at least 50% by weight of said ketones. One of the two starting compounds has at least one radiation-sensitive group and the other of the two starting compounds has at least one ethylenically unsaturated, free-radically polymerizable group. A description is also given of corresponding solutions of radiation-sensitive, free-radically polymerizable organic compounds and of their use for preparing radiation-crosslinkable, free-radically copolymerized copolymers, more particularly for hotmelt pressure-sensitive adhesives or aqueous polymer dispersions.
摘要翻译：描述了制备具有卤化物基团的第一起始化合物和具有醇羟基的第二起始化合物的辐射敏感的可自由基聚合的有机化合物的溶液的方法，所述方法被酯化彼此在溶剂或溶剂混合物中。溶剂包含一种或多种在大气压（1巴）下沸点低于150℃的酮，或溶剂混合物的组成为所述酮的至少50重量％。两种起始化合物中的一种具有至少一个辐射敏感性基团，并且两种起始化合物中的另一种具有至少一个烯键式不饱和的可自由基聚合的基团。还给出了对辐射敏感的可自由基聚合的有机化合物的相应解决方案的描述，以及它们用于制备辐射可交联的自由基共聚共聚物的用途，更特别地用于热熔粘合剂或水性聚合物分散体。

7. 发明授权

US09587144B2 Pressure-sensitive adhesive dispersion comprising polymers with ureido groups or ureido-analogous groups and with glycidyl groups 有权
标题翻译：包含具有脲基或脲基 - 类似基团和缩水甘油基的聚合物的压敏粘合剂分散体
公开(公告)号：US09587144B2
公开(公告)日：2017-03-07
申请号：US13443284
申请日：2012-04-10
申请人： Matthias Gerst , Dirk Wulff , Heinrich Harrer
发明人： Matthias Gerst , Dirk Wulff , Heinrich Harrer
IPC分类号： C09J4/00 , C09J133/14 , C09J7/02 , C09J133/08 , C09J133/12 , C09J109/06 , C09J139/04 , C09J133/02 , C08F2/22 , C09J133/06
CPC分类号： C09J4/00 , C08F2/22 , C09J7/385 , C09J109/06 , C09J133/02 , C09J133/066 , C09J133/068 , C09J133/08 , C09J133/12 , C09J133/14 , C09J139/04 , C09J2201/606 , C09J2433/00 , Y10T428/287 , C08F2220/185 , C08F220/14 , C08F2220/387 , C08F220/20 , C08F220/06 , C08F212/08 , C08F2220/325
摘要： A description is given of a pressure-sensitive adhesive dispersion comprising a water-dispersed polymer P1 formed by emulsion polymerization. The polymer P1 is formed from a monomer mixture comprising (a) at least 40% by weight of C4 to C20 alkyl (meth)acrylates which when polymerized as homopolymers have a glass transition temperature of −30° C. or less, (b) at least 0.05% by weight of (meth)acrylate monomers having a substituent of the formula where X is CH2, O, NH or NR and R is a C1 to C4 alkyl group, (c) at least 0.1% by weight of acid monomers. The monomer mixture comprises alternatively at least 0.05% by weight of glycidyl (meth)acrylate and/or the pressure-sensitive adhesive dispersion comprises at least one further polymer P2 which contains glycidyl groups.
摘要翻译：给出了包含通过乳液聚合形成的水分散聚合物P1的压敏粘合剂分散体的描述。聚合物P1由包含（a）至少40重量％的（甲基）丙烯酸C 4至C 20烷基酯的单体混合物形成，当聚均为均聚物的玻璃化转变温度为-30℃或更低时，（b）至少0.05重量％的具有下式的取代基的（甲基）丙烯酸酯单体，其中X是CH 2，O，NH或NR，R是C 1至C 4烷基，（c）至少0.1重量％的酸单体。单体混合物可选地包含至少0.05重量％的（甲基）丙烯酸缩水甘油酯和/或压敏粘合剂分散体包含至少一种含有缩水甘油基的另外的聚合物P2。

8. 发明授权

US09365745B2 Pressure-sensitive adhesive dispersion comprising polymers with ureido groups or with ureido-analogous groups and prepared by stage polymerization 有权
标题翻译：压敏粘合剂分散体包含具有脲基或脲基 - 类似基团并通过阶段聚合制备的聚合物
公开(公告)号：US09365745B2
公开(公告)日：2016-06-14
申请号：US13443044
申请日：2012-04-10
申请人： Matthias Gerst , Dirk Wulff , Thomas Christ
发明人： Matthias Gerst , Dirk Wulff , Thomas Christ
IPC分类号： C09J4/02 , C09J133/04 , C09J133/14 , C09J4/00 , C09J133/00
CPC分类号： C09J4/00 , C09J133/00 , C09J133/14 , Y10T428/2848 , Y10T428/2887
摘要： A description is given of a pressure-sensitive adhesive dispersion comprising a water-dispersed polymer P1 formed by emulsion polymerization. The polymer P1 is formed from a monomer mixture comprising (a) at least 40% by weight of C4 to C20 alkyl (meth)acrylates which when polymerized as homopolymers have a glass transition temperature of −30° C. or less, (b) at least 0.05% by weight of (meth)acrylate monomers having a substituent of the formula where X is CH2, O, NH or NR and R is a C1 to C4 alkyl group, (c) at least 0.1% by weight of acid monomers. The polymer P1 is prepared by polymerization in at least 2 stages, the glass transition temperature of a polymer from monomers of the first stage being lower by at least 20° C. than the glass transition temperature of a polymer from monomers of a later, second stage.
摘要翻译：给出了包含通过乳液聚合形成的水分散聚合物P1的压敏粘合剂分散体的描述。聚合物P1由包含（a）至少40重量％的（甲基）丙烯酸C 4至C 20烷基酯的单体混合物形成，当聚均为均聚物的玻璃化转变温度为-30℃或更低时，（b）至少0.05重量％的具有下式的取代基的（甲基）丙烯酸酯单体，其中X是CH 2，O，NH或NR，R是C 1至C 4烷基，（c）至少0.1重量％的酸单体。聚合物P1通过至少两个阶段的聚合制备，聚合物的玻璃化转变温度从第一阶段的单体的玻璃化转变温度比聚合物的玻璃化转变温度低至少20℃，后者的第二阶段的单体阶段。

9. 发明授权

US08648212B2 Process for preparing solutions of radiation-sensitive, free-radically polymerizable organic compounds 有权
标题翻译：制备辐射敏感的可自由基聚合的有机化合物的方法
公开(公告)号：US08648212B2
公开(公告)日：2014-02-11
申请号：US13258899
申请日：2010-03-30
申请人： Verena Weiskopf , Franz Niklaus Windlin , Harald Winsel , Markus Ruckpaul , Dirk Wulff , Uwe Duesterwald , Ulrike Licht
发明人： Verena Weiskopf , Franz Niklaus Windlin , Harald Winsel , Markus Ruckpaul , Dirk Wulff , Uwe Duesterwald , Ulrike Licht
IPC分类号： C08F220/10 , C08K5/07 , C08F2/06
CPC分类号： C08F220/06 , C07C68/02 , C08F212/08 , C08F212/12 , C08F2220/1825 , C09D133/08 , C09J133/08 , C09J2201/606 , C09J2201/61 , C07C69/96 , C08F2220/301
摘要： A description is given of a process for preparing solutions of radiation-sensitive, free-radically polymerizable organic compounds, where a first starting compound, which has an acid halide group, and a second starting compound, which has an alcoholic hydroxyl group, are esterified with one another in a solvent or in a solvent mixture. The solvent comprises one or more ketones having a boiling point of below 150° C. under atmospheric pressure (1 bar), or the solvent mixture is composed to an extent of at least 50% by weight of said ketones. One of the two starting compounds has at least one radiation-sensitive group and the other of the two starting compounds has at least one ethylenically unsaturated, free-radically polymerizable group. A description is also given of corresponding solutions of radiation-sensitive, free-radically polymerizable organic compounds and of their use for preparing radiation-crosslinkable, free-radically copolymerized copolymers, more particularly for hotmelt pressure-sensitive adhesives or aqueous polymer dispersions.
摘要翻译：描述了制备具有卤化物基团的第一起始化合物和具有醇羟基的第二起始化合物的辐射敏感的可自由基聚合的有机化合物的溶液的方法，所述方法被酯化彼此在溶剂或溶剂混合物中。溶剂包含一种或多种在大气压（1巴）下沸点低于150℃的酮，或溶剂混合物的组成为所述酮的至少50重量％。两种起始化合物中的一种具有至少一个辐射敏感性基团，并且两种起始化合物中的另一种具有至少一个烯键式不饱和的可自由基聚合的基团。还给出了对辐射敏感的可自由基聚合的有机化合物的相应解决方案的描述，以及它们用于制备辐射可交联的自由基共聚共聚物的用途，更特别地用于热熔粘合剂或水性聚合物分散体。

10. 发明授权

US08461235B2 Use of polymer powder containing UV absorber for the stabilisation of polymers against the effects of UV radiation 失效
标题翻译：使用含有紫外线吸收剂的聚合物粉末来稳定聚合物以抵抗紫外线辐射的影响
公开(公告)号：US08461235B2
公开(公告)日：2013-06-11
申请号：US12756061
申请日：2010-04-07
申请人： Rainer Dyllick-Brenzinger , Oliver Koch , Dirk Wulff , Alban Glaser
发明人： Rainer Dyllick-Brenzinger , Oliver Koch , Dirk Wulff , Alban Glaser
IPC分类号： C08K5/53
CPC分类号： C08K5/005
摘要： The present invention relates to the use, for stabilizing polymers, in particular polyolefins, with respect to exposure to UV radiation, of fine-particle polymer powders comprising at least one UV absorber. The present invention further relates to stabilizer mixtures for stabilizing polymers with respect to exposure to UV radiation, oxygen and heat, which, inter alia, comprise these polymer powders, and to a process for stabilizing polymers, in particular polyolefins, with respect to exposure to UV radiation, oxygen and heat, which comprises adding, to the polymers, in particular to the polyolefins, an effective amount of these stabilizers. The present invention further relates to polymers, in particular polyolefins, which have been stabilized with respect to exposure to UV radiation or with respect to exposure to UV radiation, oxygen and heat, which comprise an effective amount of these polymer powders or, respectively, stabilizer mixtures, and to articles produced from these stabilized polymers, in particular polyolefins.
摘要翻译：本发明涉及用于稳定聚合物，特别是关于暴露于UV辐射的聚烯烃，包含至少一种UV吸收剂的细颗粒聚合物粉末的用途。本发明还涉及用于稳定聚合物相对于暴露于UV辐射，氧和热的稳定剂混合物，其特别包括这些聚合物粉末，以及用于稳定聚合物，特别是聚烯烃的方法，涉及暴露于 UV辐射，氧气和热量，其包括向聚合物，特别是聚烯烃中加入有效量的这些稳定剂。本发明还涉及聚合物，特别是聚烯烃，其已经相对于暴露于UV辐射或相对于暴露于UV辐射，氧和热而被稳定，其包含有效量的这些聚合物粉末或分别为稳定剂混合物，以及由这些稳定的聚合物，特别是聚烯烃生产的制品。

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