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1. 发明申请

US20110290147A1 COMPOSITION AND METHOD TO PROVIDE STAIN RELEASE AND STAIN REPELLENCY PROPERTIES TO SUBSTRATES 审中-公开
标题翻译：提供不锈钢和不锈钢性能的组合物和方法
公开(公告)号：US20110290147A1
公开(公告)日：2011-12-01
申请号：US13133093
申请日：2009-12-15
申请人： Dirk M. Coppens , Leonardus A. Doelen
发明人： Dirk M. Coppens , Leonardus A. Doelen
IPC分类号： C09D5/00
CPC分类号： C11D3/0036 , B05D5/083 , B05D2203/30 , C04B41/009 , C04B41/4846 , C09D5/1637 , C04B41/4994 , C04B33/00 , C04B14/00 , C04B14/043 , C04B14/048 , C04B14/285 , C04B28/02
摘要： The present invention provides a composition for treatment, the composition comprising a fluorinated compound and a phosphate ester having at least one hydrocarbon residue having at least 6 carbon atoms. There is further provided a method of treatment applying the composition to a substrate.
摘要翻译：本发明提供一种用于处理的组合物，所述组合物包含含氟化合物和具有至少一个具有至少6个碳原子的烃残基的磷酸酯。还提供了一种将组合物施用于基材的方法。

2. 发明授权

US5385999A Polysiloxanes having fluoroaliphatic- and carboxyl-containing terminal groups, their preparation, and their use in treatment of fibrous substrates 失效
标题翻译：具有含氟脂肪族和羧基端基的聚硅氧烷，它们的制备及其在处理纤维基材中的用途
公开(公告)号：US5385999A
公开(公告)日：1995-01-31
申请号：US147338
申请日：1993-11-03
申请人： Claude D'Anvers , Dirk M. Coppens
发明人： Claude D'Anvers , Dirk M. Coppens
IPC分类号： C08G77/385 , C08G77/392 , C14C9/00 , D06M15/643 , D06M15/657 , D06N3/12 , C08G77/06
CPC分类号： C08G77/392 , C08G77/385 , C14C9/00 , D06M15/6433 , D06M15/657 , D06N3/128
摘要： This invention relates to polysiloxanes having fluoroaliphatic- and carboxyl- containing terminal groups, their preparation and their use in imparting water-, oil- and soil-repellency and a soft hand to fibrous substrates such as leather, and to the resulting treated substrate.
摘要翻译：本发明涉及具有氟代脂族和羧基端基的聚硅氧烷，它们的制备及其在赋予水，油和污垢排斥性的柔软手感以及对诸如皮革等纤维底物的柔软手感以及所得处理过的基材。

3. 发明授权

US06171983B2 Fluroaliphatic dimer acid derivatives and use thereof 失效
标题翻译：脂肪族二聚酸衍生物及其用途
公开(公告)号：US06171983B2
公开(公告)日：2001-01-09
申请号：US09391540
申请日：1999-09-08
申请人： Dirk M. Coppens , Richard J. Grant
发明人： Dirk M. Coppens , Richard J. Grant
IPC分类号： C14C900
CPC分类号： C07C311/09 , C04B41/466 , C04B41/4842 , C04B41/4846 , C14C9/00 , D21H21/16 , Y10T428/24438 , Y10T428/31993 , Y10T428/4935 , Y10T442/2164 , Y10T442/2189 , Y10T442/2238 , Y10T442/227
摘要： This invention relates to fluorochemical compositions, their preparation and their use as water- and oil-repellents, and substrates treated therewith. The fluorochemical composition comprises a mixture of fluorochemical compounds and/or polymers, each component having at least two fluoroaliphatic groups and a large hydrocarbon moiety such as derived from dimer acids, and the polymer having at least one fluoroaliphatic group and a plurality of said hydrocarbon moiety.
摘要翻译：本发明涉及含氟化合物组合物，它们的制备及其作为拒水拒油剂的用途以及用其处理的底物。含氟化合物组合物包含含氟化合物和/或聚合物的混合物，每个组分具有至少两个氟脂族基团和大的烃部分，例如衍生自二聚酸，并且具有至少一个氟代脂族基团和多个所述烃部分的聚合物。

4. 发明授权

US5536304A Oil and water repellent compositions 失效
标题翻译：防油和防水组合物
公开(公告)号：US5536304A
公开(公告)日：1996-07-16
申请号：US323381
申请日：1994-10-14
申请人： Dirk M. Coppens , Kathy Allewaert
发明人： Dirk M. Coppens , Kathy Allewaert
IPC分类号： C09K3/18 , C08K5/5435 , C08L83/04 , C08L83/06 , D06M13/02 , D06M13/51 , D06M13/513 , D06M15/263 , D06M15/277 , D06M15/576 , D06M15/643 , D06M15/657 , B32B9/04
CPC分类号： D06M15/657 , C08K5/5435 , C08L83/06 , D06M15/263 , D06M15/277 , D06M15/576 , D06M15/643 , D06M15/6433 , Y10T428/3154 , Y10T428/31663
摘要： The invention relates to a water and oil repellency imparting composition which comprises:(a) a fluoroaliphatic radical-containing agent; and(b) a cyclic carboxylic anhydride-containing polysiloxane. Additionally, the composition may comprise:(c) an extender and/or a plasticizer. The composition provides water and oil repellent properties and a soft hand to fibrous and other substrates treated therewith.
摘要翻译：本发明涉及拒油拒油剂组合物，其包含：（a）含氟脂肪族基团的试剂; 和（b）含环状羧酸酐的聚硅氧烷。另外，组合物可以包含：（c）增量剂和/或增塑剂。该组合物提供斥水斥油性能和柔软的手到纤维和其他处理的底物。

5. 发明申请

US20110294932A1 COMPOSITION AND METHOD FOR PROVIDING STAIN RELEASE OR STAIN REPELLENCY TO SUBSTRATES 审中-公开
标题翻译：用于提供底物释放或不良物质的组合物和方法
公开(公告)号：US20110294932A1
公开(公告)日：2011-12-01
申请号：US13139621
申请日：2009-12-15
申请人： Dirk M. Coppens , Leonardus A. Doelen
发明人： Dirk M. Coppens , Leonardus A. Doelen
IPC分类号： C09D133/08 , C08K5/205 , C08K5/095
CPC分类号： C09D133/08 , C04B41/009 , C04B41/5089 , C09D5/1637 , C09D5/1668 , C09D133/00 , C04B41/483 , C04B41/4846 , C04B41/4876 , C04B33/00 , C04B14/00 , C04B14/048 , C04B14/285 , C04B28/02 , C08L2666/04
摘要： The present invention provides a composition for treatment, the composition comprising dispersed in water (i) a fluorinated compound, (ii) a potassium or lithium silicate and (iii) an acrylic polymer. The invention further provides a method of treating substrates with the composition.
摘要翻译：本发明提供了一种用于处理的组合物，该组合物包括分散在水中（i）氟化化合物，（ii）硅酸钾或硅酸锂和（iii）丙烯酸类聚合物。本发明还提供了一种用该组合物处理底物的方法。

6. 发明授权

US07723417B2 Fluorochemical composition and method for treating a substrate therewith 有权
标题翻译：含氟化合物组合物及其处理方法
公开(公告)号：US07723417B2
公开(公告)日：2010-05-25
申请号：US10808902
申请日：2004-03-25
申请人： Dirk M. Coppens , Dean M. Moren
发明人： Dirk M. Coppens , Dean M. Moren
IPC分类号： C08K5/09
CPC分类号： D06M13/207 , D06M13/224 , D06M15/277 , D06M15/576
摘要： The present invention provides an aqueous composition comprising (i) a fluorochemical compound and (ii) an ester derivative of an alpha-hydroxy acid, the ester derivative having a melting point of not more than 35° C. and a water solubility of not more than 10% by weight at 25° C. The fluorochemical compound is typically dispersed or emulsified in the aqueous composition. The aqueous compositions may provide such advantages as providing good oil- and/or water repellency properties to a substrate upon application at ambient conditions, without the need for a heat treatment. Thus, the aqueous compositions may be used to provide oil- and/or water repellency properties to a substrate such as for example a fibrous substrate, e.g., leather or textile. In particular, repellency properties comparable to those achieved with a heat treatment step may be achieved.
摘要翻译：本发明提供一种水性组合物，其包含（i）含氟化合物和（ii）α-羟基酸的酯衍生物，所述酯衍生物的熔点不超过35℃，水溶性不大于在25℃下为10重量％以下。含氟化合物通常在水性组合物中分散或乳化。含水组合物可以提供这样的优点，例如在环境条件下施用时向基材提供良好的油和/或拒水性质，而不需要热处理。因此，水性组合物可用于向基材例如纤维基材例如皮革或纺织品提供油和/或拒水性能。特别地，可以实现与通过热处理步骤实现的排斥性能相当的排斥性能。

7. 发明授权

US07049379B2 Alkylated fluorochemical oligomers and use thereof in the treatment of fibrous substrates 有权
公开(公告)号：US07049379B2
公开(公告)日：2006-05-23
申请号：US10399415
申请日：2001-11-06
申请人： Chetan P. Jariwala , James D. Eggleston , Michael A. Yandrasits , Rudolf Dams , Dirk M. Coppens
发明人： Chetan P. Jariwala , James D. Eggleston , Michael A. Yandrasits , Rudolf Dams , Dirk M. Coppens
IPC分类号： C08F114/18
CPC分类号： C14C9/00 , D06M15/277 , D06M2200/11 , D06M2200/12
摘要： This invention provides a method of treating fibrous substrates, such as leather, by contacting the substrate with a fluorochemical compound comprising: a fluorochemical oligomeric portion comprising an aliphatic backbone with a plurality of pendant fluoroaliphatic groups, each fluoroaliphatic group having a fully fluorinated terminal group and each independently linked to a carbon atom of the aliphatic backbone through an organic linking group; an aliphatic moiety; and a linking group which links the fluorochemical oligomeric portion to the aliphatic moiety. The fluorochemical compounds provide desirable oil, water and stain repellency to fibrous substrates.

8. 发明授权

US06440321B1 Mixed fluorochemical hydrocarbon condensates to impart oil and water repellency to a substrate 失效
标题翻译：混合的含氟烃缩合物以赋予基底油和拒水性
公开(公告)号：US06440321B1
公开(公告)日：2002-08-27
申请号：US09381572
申请日：1999-09-17
申请人： Frans A. Audenaert , Dirk M. Coppens , Rudolf J. Dams
发明人： Frans A. Audenaert , Dirk M. Coppens , Rudolf J. Dams
IPC分类号： C08G1240
CPC分类号： D06M15/437 , C08G12/40 , D06M15/423 , D06M15/429 , D06M2200/11 , D06M2200/12
摘要： A fluorochemical composition to impart water repellency and/or oil repellency to a substrate, the composition comprising one or more condensates of (i) a methylolated amine or a C1-C4 alkoxylated derivative thereof, (ii) a hydrocarbon compound represented by formula (II) and (iii) a fluorinated compound represented by formula (I): Rf—(X1)n—Z1 (I) wherein: Rf is a fluorinated aliphatic group; X1 is an organic divalent linking group; Z1 is selected from the group consisting of hydroxy, thiol, amide or acid groups; and n is 0 or 1; and Rh—Z2 (II) wherein: Rh is a hydrocarbon group having at least 6 carbon atoms and optionally being substituted with 1 to 3 subsituents; Z2 is selected from the group consisting of hydroxy, thiol, amide or acid groups. The invention further provides a method of treatment of a substrate with the fluorochemical composition and a treated substrate.
摘要翻译：一种含氟化合物，其对基质赋予拒水性和/或拒油性，所述组合物包含一种或多种（i）羟甲基化胺或其C1-C4烷氧基化衍生物的缩合物，（ii）由式（II）表示的烃化合物）和（iii）由式（I）表示的氟化化合物：其中：Rf是氟化脂肪族基团; X1是有机二价连接基团; Z1选自羟基，硫醇，酰胺或酸基; 并且n为0或1; 并且其中：Rh是具有至少6个碳原子并且任选地被1至3个取代基取代的烃基; Z2选自羟基，硫醇，酰胺或酸基。本发明还提供了一种用含氟化合物组合物和经处理的底物处理底物的方法。

9. 发明授权

US06294103B1 Use of amphiphilic copolymers containing a fluorinated monomer to impart waterproofness to leather 有权
标题翻译：使用含有氟化单体的两亲共聚物可赋予皮革防水性
公开(公告)号：US06294103B1
公开(公告)日：2001-09-25
申请号：US09297814
申请日：1999-05-04
申请人： Dirk M. Coppens
发明人： Dirk M. Coppens
IPC分类号： C14C900
CPC分类号： C14C9/00
摘要： The present invention provides an amphiphilic copolymer comprising recurring units (I) and (II), wherein: Rf represents a fluorinated alkyl group having at least 3 carbon atoms; Q and Q′ each independently represents an organic liking group or a chemical linkage; R1 and R2 each independently represents hydrogen or a C1 to C4 alkyl group; and Rh represents a hydrocarbon group having at least 8 carbon atoms and optionally containing 1 to 3 substituents; and a recurring unit comprising at least one carboxylic acid group or salt thereof. The present invention also provides a method for making the above amphiphilic copolymer. The amphiphilic copolymer can be used in a leather treatment to provide waterproofness to the leather.
摘要翻译：本发明提供了包含重复单元（I）和（II）的两亲共聚物，其中：Rf表示具有至少3个碳原子的氟化烷基; Q和Q'各自独立地表示有机喜好基团或化学键; R 1和R 2各自独立地表示氢或C 1至C 4烷基; 并且Rh表示具有至少8个碳原子并且任选地含有1至3个取代基的烃基; 和包含至少一个羧酸基团或其盐的重复单元。本发明还提供了制备上述两亲性共聚物的方法。两亲性共聚物可以用于皮革处理以为皮革提供防水性。

10. 发明授权

US06197426B1 Fluorochemical copolymer and fluorochemical copolymer compositions useful for imparting repellency properties to a substrate 失效
标题翻译：含氟化合物共聚物和含氟化合物共聚物组合物可用于赋予基材排斥性能
公开(公告)号：US06197426B1
公开(公告)日：2001-03-06
申请号：US09005465
申请日：1998-01-12
申请人： Dirk M. Coppens
发明人： Dirk M. Coppens
IPC分类号： B32B2728
CPC分类号： D06M15/263 , C08F220/22 , D06M15/277 , D06M2200/11 , D06M2200/12 , Y10T428/3154
摘要： A method is disclosed of treating a substrate, comprising applying to the substrate a fluorochemical composition comprising fluorochemical copolymer derived from at least one fluorochemical monomer A, at least one monomer B, at least one monomer C and at least one monomer D, wherein the fluorochemical monomer A contains a fluoroaliphatic group and is an ester of an &agr;,&bgr;-ethylenically unsaturated carboxylic acid, the monomer B is an ester of an &agr;,&bgr;-ethylenically unsaturated carboxylic acid, the monomer C is an ethylenically unsaturated dicarboxylic acid anhydride, the monomer D is an ester of an &agr;,&bgr;-ethylenically unsaturated carboxylic acid, the fluorochemical monomer A and the monomers B and C contain only one polymerizable group and monomer D contains, as a second polymerizable group, an ethylenically unsaturated group that has a higher affinity to copolymerize with the monomer C than fluorochemical monomer A or monomers B or D.
摘要翻译：公开了一种处理基材的方法，其包括将含有至少一种含氟化合物单体A，至少一种单体B，至少一种单体C和至少一种单体D的含氟共聚物的含氟化合物应用于该基材，其中含氟化合物单体A包含氟脂族基团，并且是α，β-烯属不饱和羧酸的酯，单体B是α，β-烯键式不饱和羧酸的酯，单体C是烯键式不饱和二羧酸酐，单体D是α，β-烯键式不饱和羧酸的酯，含氟单体A和单体B和C仅含有一个可聚合基团，单体D含有作为第二可聚合基团的烯键式不饱和基团与含氟单体A或单体B或D的亲油性与单体C共聚。

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