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1. 发明授权

US06686501B2 Processes for preparing 3.3-dimethylbutyric acid 有权
标题翻译：制备3.3-二甲基丁酸的方法
公开(公告)号：US06686501B2
公开(公告)日：2004-02-03
申请号：US10068631
申请日：2002-02-05
申请人： Dennis E. Jackman
发明人： Dennis E. Jackman
IPC分类号： C07C5300
CPC分类号： C07C51/353 , C07C53/126
摘要： A process for preparing 3,3-dimethylbutyric acid includes the steps of reacting trimethylpyruvic acid with a first portion of hydrazine to obtain a ketazine, and treating the ketazine with base and a second portion of hydrazine.
摘要翻译：制备3,3-二甲基丁酸的方法包括使三甲基丙酮酸与肼的第一部分反应以获得酮连氮，并用肼和第二部分肼处理酮连氮的步骤。

2. 发明授权

US6025514A Process for preparing methyl dithiocarbazinate by reacting methyl bromide with the reaction product of carbon disulfide, hydrazine and an adjunct base 有权
标题翻译：甲基溴与二硫化碳，肼和辅助基质反应生成甲基二硫代肼基甲酸甲酯的方法
公开(公告)号：US6025514A
公开(公告)日：2000-02-15
申请号：US157483
申请日：1998-09-21
申请人： Dennis E. Jackman , David T. Erdman , Peter E. Newallis , Daniel M. Wasleski , Vijay C. Desai , Jeffrey D. Macke , Vidyanatha A. Prasad
发明人： Dennis E. Jackman , David T. Erdman , Peter E. Newallis , Daniel M. Wasleski , Vijay C. Desai , Jeffrey D. Macke , Vidyanatha A. Prasad
IPC分类号： C07C337/02 , C07C333/28
CPC分类号： C07C337/02
摘要： Disclosed herein is a process for preparing high yields of methyl dithiocarbazinate by reacting carbon disulfide, hydrazine and a base in an aqueous medium, in an effective ratio to form a dithiocarbazinate salt followed by methylating the dithiocarbazinate salt with methyl bromide.
摘要翻译：本文公开了通过使二硫代肼，肼和碱在水性介质中以有效的比例以有效的比例反应制备高产率的二硫代肼基甲酸甲酯的方法，以形成二硫代肼基甲酸盐，然后用甲基溴甲基化二硫代肼基甲酸盐。

3. 发明授权

US5408033A Process for the preparation of an epoxide from ketones using an alcohol or ether catalyst 失效
标题翻译：使用醇或醚催化剂从酮制备环氧化物的方法
公开(公告)号：US5408033A
公开(公告)日：1995-04-18
申请号：US41117
申请日：1993-04-01
申请人： Dennis E. Jackman
发明人： Dennis E. Jackman
IPC分类号： C07D301/02 , C07D303/08
CPC分类号： C07D303/08 , C07D301/02
摘要： An epoxide is produced by reacting a sulfonium salt with a ketone in the presence of a low molecular weight alcohol or ether and an alkali metal hydroxide at a temperature of from about 60.degree. to about 90.degree. C. The alkali metal hydroxide is in the solid form. The reaction is generally carried out in the presence of an organic solvent such as toluene. The preferred low molecular weight ether is diethylene glycol. Water is not added to the reaction mixture.
摘要翻译：在低分子量醇或醚和碱金属氢氧化物的存在下，在大约60℃至大约90℃的温度下，使锍盐与酮反应生成环氧化物。碱金属氢氧化物是固体形成。反应通常在有机溶剂如甲苯的存在下进行。优选的低分子量醚是二甘醇。不向反应混合物中加入水。

4. 发明授权

US4659819A Production of S-substituted isothioureas 失效
标题翻译： S-取代的异硫脲的生产
公开(公告)号：US4659819A
公开(公告)日：1987-04-21
申请号：US632132
申请日：1984-07-18
申请人： Dennis E. Jackman , Dietmar B. Westphal , Thomas Schmidt
发明人： Dennis E. Jackman , Dietmar B. Westphal , Thomas Schmidt
IPC分类号： C07B61/00 , C07C67/00 , C07C325/00 , C07C335/30 , C07D239/56 , C07D251/38 , C07D253/06 , C07D253/07 , C07D239/38
CPC分类号： C07D239/56 , C07D251/38 , C07D253/07
摘要： In the production of an S-substituted isothiourea including the function group ##STR1## in which R.sup.1 is an alkyl, alkenyl, aryl or aralkyl radical, wherein a thiourea including the functional group ##STR2## is reacted with an etherifying agent to replace H by R.sup.1, the improvement which comprises effecting the reaction in two steps, in the first step reacting the thiourea material with an etherifying agent including the radical Rin whichR is an alkyl, alkenyl aryl or aralkyl radical different from R.sup.1 thereby to produce the ether ##STR3## and in the second step reacting the ether with a compound of the formula R.sup.1 SH. The process is particularly applicable to the production of the known herbicide ##STR4## from the corresponding thiourea where in the first step methyl bromide or methyl iodide is used to form the S-methyl isothiourea which is then interchanged with ethyl mercaptan. Higher overall yields and/or economies are thereby achieved.
摘要翻译：在制备包含其中R 1为烷基，烯基，芳基或芳烷基的官能团的S-取代的异硫脲，其中将包含官能团的硫脲与醚化剂反应以用H代替H R1的改进包括在两个步骤中进行反应，在使硫脲材料与包含其中R是不同于R 1的烷基，烯基芳基或芳烷基的基团R的醚化剂反应的第一步中，并且在第二步中使醚与式R1SH的化合物反应。该方法特别适用于从相应的硫脲生产已知的除草剂，其中在第一步中使用甲基溴或甲基碘形成S-甲基异硫脲，然后与乙硫醇交换。从而实现更高的整体产量和/或经济。

5. 发明授权

US06545172B1 Processes for the production of methyl dithiocarbazinate 有权
标题翻译：生产二硫代肼基甲酸甲酯的方法
公开(公告)号：US06545172B1
公开(公告)日：2003-04-08
申请号：US10124850
申请日：2002-04-18
申请人： Vidyanatha A. Prasad , Klaus Jelich , Dennis E. Jackman
发明人： Vidyanatha A. Prasad , Klaus Jelich , Dennis E. Jackman
IPC分类号： C07C33300
CPC分类号： C07C337/02
摘要： A process for the production of methyl dithiocarbazinate includes the steps of providing a mixture comprising hydrazine, solvent, carbon disulfide and base; adding methyl bromide to the mixture; cooling the reaction mixture; and recovering methyl dithiocarbazinate. The methyl dithiocarbazinate may be recovered by filtering the reaction mixture to yield a solid methyl dithiocarbazinate retentate and a liquid filtrate; acidifying the filterate with a mineral acid; and adding methyl isobutylketone to the acidified filterate.
摘要翻译：制备二硫代肼基甲酸甲酯的方法包括提供包含肼，溶剂，二硫化碳和碱的混合物的步骤; 向混合物中加入甲基溴; 冷却反应混合物; 并回收二硫代肼基甲酸甲酯。可以通过过滤反应混合物回收二硫代肼基甲酸甲酯，得到二硫代肼基甲酸固体甲基季戊四醇酯和液体滤液; 用无机酸酸化过滤物; 并向酸化的过滤器中加入甲基异丁基酮。

6. 发明授权

US06222045B1 Process for manufacturing substituted triazolinones 有权
标题翻译：制备取代的三唑啉酮的方法
公开(公告)号：US06222045B1
公开(公告)日：2001-04-24
申请号：US09665092
申请日：2000-09-20
申请人： Dennis E. Jackman
发明人： Dennis E. Jackman
IPC分类号： C07D24912
CPC分类号： C07D249/12
摘要： The present invention relates to a process for manufacturing substituted triazolinones, which are intermediates in the preparation of herbicidally active compounds. In particular, this invention relates to the reaction of an isothiocyanate with an alkanol to produce a thionocarbamate intermediate product; alkylation of the intermediate product, reaction of the alkylated intermediate with and alkoxycarbobyl or aryloxycarbonyl hydrazine and reaction of the resultant compound with a base to produce a substituted triazolinone. In this context the terms “alkanol” and “alkylation” represent generic terms and thus, include the use of alkanols and alkylating agents having an alkyl group, an alkenyl group, an alkynyl group, a cycloalkyl group, a cycloalkylalkyl group, an aryl group or an arylalkyl group.
摘要翻译：本发明涉及制备取代三唑啉酮的方法，它是制备除草活性化合物的中间体。特别地，本发明涉及异硫氰酸酯与链烷醇反应产生硫代氨基甲酸酯中间产物; 中间产物的烷基化，烷基化中间体与烷氧基羰基或芳氧基羰基肼的反应，并将所得化合物与碱反应，生成取代的三唑啉酮。在本文中，术语“烷醇”和“烷基化”表示通用术语，因此包括使用具有烷基，链烯基，炔基，环烷基，环烷基烷基，芳基的烷醇和烷基化剂或芳基烷基。

7. 发明授权

US6071858A Stable, dry compositions for use as herbicides 有权
标题翻译：用作除草剂的稳定的干燥组合物
公开(公告)号：US6071858A
公开(公告)日：2000-06-06
申请号：US165139
申请日：1998-10-01
申请人： Thomas F. Modrcin , Vijay C. Desai , Peter E. Newallis , Klaus Jelich , John W. Brandriff , Dennis E. Jackman
发明人： Thomas F. Modrcin , Vijay C. Desai , Peter E. Newallis , Klaus Jelich , John W. Brandriff , Dennis E. Jackman
IPC分类号： A01N43/82 , A01N43/64
CPC分类号： A01N43/82
摘要： The present invention relates to a dry composition that can be used as a herbicide. The composition contains N-(4-fluorophenyl)-N-(1-methylethyl)-2-[[5-(trifluoromethyl)-1,3,4-thiadiazol-2-yl]oxy]acetamide, 4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5-(4H)-one, and a pH adjusting agent. The pH adjusting agent is present in an amount such that it constitutes from about 0.1% to about 10% of the composition, and the resulting pH is from about 2.8 to about 5.4. The molar ratio of 4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5-(4H)-one to N-(4-fluorophenyl)-N-(1-methylethyl)-2-[[5-(trifluoromethyl)-1,3,4-thiadiazol-2-yl]oxy]acetamide in the composition is from about 1:1 to about 1:6.
摘要翻译：本发明涉及可用作除草剂的干组合物。该组合物含有N-（4-氟苯基）-N-（1-甲基乙基）-2 - [[5-（三氟甲基）-1,3,4-噻二唑-2-基]氧基]乙酰胺，4-氨基-6- - （1,1-二甲基乙基）-3-（甲硫基）-1,2,4-三嗪-5-（4H） - 酮和pH调节剂。 pH调节剂的存在量使其占组合物的约0.1％至约10％，所得pH为约2.8至约5.4。 4-氨基-6-（1,1-二甲基乙基）-3-（甲硫基）-1,2,4-三嗪-5-（4H） - 酮与N-（4-氟苯基）-N- （1-甲基乙基）-2 - [[5-（三氟甲基）-1,3,4-噻二唑-2-基]氧基]乙酰胺为约1:1至约1:6。

8. 发明授权

US4954627A Process for desulfurization of isothioureas and isothioamides 失效
标题翻译：异硫脲和异硫脲的脱硫方法
公开(公告)号：US4954627A
公开(公告)日：1990-09-04
申请号：US277739
申请日：1988-11-30
申请人： Dennis E. Jackman , John G. Morgan
发明人： Dennis E. Jackman , John G. Morgan
IPC分类号： C07D253/075 , C07D277/68 , C07D277/74
CPC分类号： C07D253/075 , C07D277/68 , C07D277/74
摘要： The present invention is directed to a process for desulfurizing a compound selected from isothioureas and isothioamides comprising heating the compound to be desulfurized in the presence of a mercaptanol to produce the corresponding desulfurized keto compound.
摘要翻译：本发明涉及一种用于脱硫选自异硫脲和异硫代酰胺的化合物的方法，包括在硫醇存在下加热待脱硫化合物以产生相应的脱硫酮基化合物。

9. 发明授权

US4946995A Process for the production of thiocarbohydrazide 失效
标题翻译：硫代碳酰肼的生产工艺
公开(公告)号：US4946995A
公开(公告)日：1990-08-07
申请号：US325403
申请日：1989-03-17
申请人： Dennis E. Jackman , Gary W. Combs , Westphal Dietmar B.
发明人： Dennis E. Jackman , Gary W. Combs , Westphal Dietmar B.
IPC分类号： C07C337/06
CPC分类号： C07C337/06
摘要： TCH is produced by a process which does not require expensive measures to remove hydrazine. In this process, hydrazinium dithiocarbazinate is reacted with an amine other than hydrazine or a strong base, optionally in the presence of water. It is preferred that a sulfur suppressing compound also be included in the reaction mixture. The precipitated TCH is removed from the reaction mixture to leave a mother liquor. Hydrazinium-dithiocarbazinate may then be added to the mother liquor. TCH precipitates and may be readily recovered.
摘要翻译： TCH通过不需要昂贵措施去除肼的方法生产。在该方法中，二肼基肼基肼与肼或强碱（任选在水存在下）反应。反应混合物中也优选含硫抑制化合物。将沉淀的TCH从反应混合物中除去以留下母液。然后可将肼 - 二硫代肼基肼肼加入到母液中。 TCH沉淀并可容易地回收。

10. 发明授权

US4614822A Catalytic oxidation of 3,3-dimethyl-2-hydroxybutyric acid to 2-oxo acid and preparation of 4-amino-6-tert.-butyl-3-thio-1,2,4-triazine-5(4-H)-one 失效
标题翻译： 3,3-二甲基-2-羟基丁酸催化氧化成2-氧代酸，制备4-氨基-6-叔丁基-3-硫代-1,2,4-三嗪-5（4-H） -一
公开(公告)号：US4614822A
公开(公告)日：1986-09-30
申请号：US181542
申请日：1980-08-26
申请人： Dennis E. Jackman
发明人： Dennis E. Jackman
IPC分类号： C07C51/373 , C07C59/185 , C07D253/06
CPC分类号： C07C51/373
摘要： Sodium 3,3-dimethyl-2-hydroxybutyrate and ruthenium dioxide hydrate are added to water, the pH rendered alkaline, and sodium hypochlorite is slowly added to produce sodium 3,3-dimethyl-2-oxobutyrate in high yield and purity. The solid catalyst is filtered off and may be re-used while the filtrate can be directly used in further synthesis.
摘要翻译：将3,3-二甲基-2-羟基丁酸钠和二氧化钌水合物加入到水中，pH变为碱性，缓慢加入次氯酸钠，以高产率和纯度生产3,3-二甲基-2-氧代丁酸钠。滤出固体催化剂，可以重新使用，同时可以将滤液直接用于进一步合成。

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